Date Printed: 9/22/2014
Safety Data Sheet
1. Identification
Page 1 / 6
* Trusted Quality Since 1921 *
www.rustoleum.com
Product Name:
Product Identifier: 213898 Supercedes Date: 9/12/2014
Product Use/Class: Paint Supplement/Aggregate
Supplier:
Preparer: Regulatory Department
Emergency Telephone:
CPS 1-LB ALUMINUM OXIDE FOR
ULTRAWEAR
Rust-Oleum Corporation
11 Hawthorn Parkway
Vernon Hills, IL 60061
USA
24 Hour Hotline: 847-367-7700
Revision Date: 9/22/2014
Manufacturer:
Rust-Oleum Corporation
11 Hawthorn Parkway
Vernon Hills, IL 60061
USA
2. Hazard Identification
EMERGENCY OVERVIEW: Harmful if inhaled. May cause delayed lung damage. May cause eye, skin, or respiratory tract
irritation. KEEP OUT OF REACH OF CHILDREN. Causes eye irritation. Use ventilation necessary to keep exposures below
recommended exposure limits, if any.
Classification
Symbol(s) of Product
Signal Word
Warning
GHS HAZARD STATEMENTS
Acute Toxicity, Dermal, category 5 H313 May be harmful in contact with skin.
Skin Irritation, category 2 H315 Causes skin irritation.
Aspiration Hazard, category 2 H305 May be harmful if swallowed and enters airways.
Eye Irritation, category 2B H320 Causes eye irritation.
Skin Irritation, category 3 H316 Causes mild skin irritation.
GHS PRECAUTIONARY STATEMENTS
P102 Keep out of reach of children.
P103 Read label before use.
P202 Do not handle until all safety precautions have been read and understood.
P234 Keep only in original container.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P262 Do not get in eyes, on skin, or on clothing.
P264 Wash … thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
Date Printed: 9/22/2014
1344-28-1
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P281 Use personal protective equipment as required.
P285 In case of inadequate ventilation wear respiratory protection.
P312 Call a POISON CENTER or doctor/physician if you feel unwell.
P351 Rinse cautiously with water for several minutes.
P374 Fight fire with normal precautions from a reasonable distance.
P402 Store in a dry place.
P335 Brush off loose particles from skin.
P321 Specific treatment (see … on this label).
P352 Wash with plenty of soap and water.
P362 Take off contaminated clothing and wash before reuse.
P332+P313 If skin irritation occurs: Get medical advice/attention.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P302+P350 IF ON SKIN: Gently wash with plenty of soap and water.
3. Composition/Information On Ingredients
HAZARDOUS SUBSTANCES
Chemical Name CAS-No. Wt.%
Range
GHS Symbols
GHS Statements
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Aluminum Oxide
The text for GHS Hazard Statements shown above (if any) is given in the "16. Other Information" section.
75-100
4. First-aid Measures
FIRST AID - EYE CONTACT: Immediately flush eyes with plenty of water for at least 15 minutes holding eyelids open. Get medical
attention. Do NOT allow rubbing of eyes or keeping eyes closed.
FIRST AID - SKIN CONTACT: Wash skin with soap and water. Remove contaminated clothing. Get medical attention if irritation
develops or persists.
FIRST AID - INHALATION: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get
immediate medical attention. Do NOT use mouth-to-mouth resuscitation. If you experience difficulty in breathing, leave the area to
obtain fresh air. If continued difficulty is experienced, get medical assistance immediately.
FIRST AID - INGESTION: Swallowing less than an ounce will not cause significant harm. For larger amounts, do not induce
vomiting, but give one or two glasses of water to drink and get medical attention. If swallowed, rinse mouth with water. If feeling
unwell, get medical attention.
5. Fire-fighting Measures
EXTINGUISHING MEDIA:
UNUSUAL FIRE AND EXPLOSION HAZARDS: No unusual fire or explosion hazards noted. Keep containers tightly closed. FLASH
POINT IS TESTED TO BE GREATER THAN 200 DEGREES F.
SPECIAL FIREFIGHTING PROCEDURES: If water is used, fog nozzles are preferred. Water may be used to cool closed containers
to prevent buildup of steam.
Alcohol Film Forming Foam, Carbon Dioxide, Dry Chemical, Dry Sand, Water Fog
6. Accidental Release Measures
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Dispose of according to local, state (provincial) and federal
regulations. Do not incinerate closed containers. Sweep up gently to avoid dust cloud formation.
7. Handling and Storage
HANDLING: Use only with adequate ventilation. Wash thoroughly after handling. Wash hands before eating. Remove contaminated
clothing and launder before reuse. Follow all MSDS/label precautions even after container is emptied because it may retain product
residues. Avoid breathing fumes, vapors, or mist. Avoid contact with eyes, skin and clothing.
STORAGE: Keep container closed when not in use. Store in a dry, well ventilated place. Keep container tightly closed when not in
use.
Date Printed: 9/22/2014
8. Exposure Controls/Personal Protection
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Chemical Name CAS-No.
Aluminum Oxide 1344-28-1 100.0
PERSONAL PROTECTION
ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne
levels below recommended exposure limits. Provide general dilution of local exhaust ventilation in volume and pattern to keep TLV of
hazardous ingredients below acceptable limits. Prevent build-up of vapors by opening all doors and windows to achieve crossventilation.
RESPIRATORY PROTECTION: A respiratory protection program that meets OSHA 1910.134 and ANSI Z88.2 requirements must be
followed whenever workplace conditions warrant a respirator's use.
SKIN PROTECTION: Use gloves to prevent prolonged skin contact. Nitrile or Neoprene gloves may afford adequate skin protection.
EYE PROTECTION: Wear safety glasses with side shields (or goggles) and a face shield. Use safety eyewear designed to protect
against splash of liquids.
OTHER PROTECTIVE EQUIPMENT: Refer to safety supervisor or industrial hygienist for further information regarding personal
protective equipment and its application. Refer to safety supervisor or industrial hygienist for further guidance regarding types of
personal protective equipment and their applications.
HYGIENIC PRACTICES: Wash thoroughly with soap and water before eating, drinking or smoking. Remove contaminated clothing
immediately and launder before reuse.
Weight %
Less Than
ACGIH TLV-
TWA
1 mg/m3
[Respirable]
ACGIH TLV-
STEL
N.E.
OSHA PEL-TWA
5 mg/m3
[Respirable]
OSHA PEL-
CEILING
N.E.
9. Physical and Chemical Properties
Appearance:
Odor:
Relative Density:
Freeze Point, °C:
Solubility in Water:
Decompostion Temp., °C:
Boiling Range, °C:
Flammability:
Evaporation Rate:
Vapor Density:
Particulate Solid
Mild
3.973
N.D.
None
No Information
999 - N.D.
Does not Support Combustion
Slower than Ether
Heavier than Air
Physical State:
Odor Threshold:
pH:
Viscosity:
Partition Coefficient, n-octanol/
water:
Explosive Limits, vol%:
Flash Point, °C:
Auto-ignition Temp., °C:
Vapor Pressure:
Solid
N.E.
N.A.
N.D.
No Information
N.A. - N.A.
>93
No Information
N.D.
(See "Other information" Section for abbreviation legend)
10. Stability and Reactivity
CONDITIONS TO AVOID: Avoid contact with strong acid and strong bases.
INCOMPATIBILITY: Not applicable for this product. Incompatible with strong oxidizing agents, strong acids and strong alkalies.
HAZARDOUS DECOMPOSITION: May produce hazardous fumes when heated to decomposition as in welding. Fumes may
contain: carbon monoxide, carbon dioxide, chlorine, hydrogen chloride, cyanide, and methylene diphenyl diisocyanate. When heated
to decomposition, it emits acrid smoke and irritating fumes.
HAZARDOUS POLYMERIZATION: Will not occur under normal conditions.
STABILITY: This product is stable under normal storage conditions.
11. Toxicological information
EFFECTS OF OVEREXPOSURE - EYE CONTACT: Irritating, and may injure eye tissue if not removed promptly.
EFFECTS OF OVEREXPOSURE - SKIN CONTACT: Low hazard for usual industrial handling or commercial handling by trained
personnel.
EFFECTS OF OVEREXPOSURE - INHALATION: Harmful if inhaled. Avoid breathing fumes, spray, vapors, or mist. High gas,
vapor, mist or dust concentrations may be harmful if inhaled.
EFFECTS OF OVEREXPOSURE - INGESTION: Expected to be a low ingestion hazard.
EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS: No Information
PRIMARY ROUTE(S) OF ENTRY: Eye Contact, Ingestion, Inhalation, Skin Absorption, Skin Contact
Date Printed: 9/22/2014
ACUTE TOXICITY VALUES
The acute effects of this product have not been tested. Data on individual components are tabulated below:
CAS-No. Chemical Name Oral LD50 Dermal LD50 Vapor LC50
1344-28-1 Aluminum Oxide >5000 mg/kg Rat N.I. N.I.
N.I. - No Information
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12. Ecological Information
ECOLOGICAL INFORMATION: Product is a mixture of listed components.
13. Disposal Information
DISPOSAL INFORMATION: Dispose of material in accordance to local, state, and federal regulations and ordinances. Do not allow
to enter waterways, wastewater, soil, storm drains or sewer systems.
14. Transport Information
Domestic (USDOT) International (IMDG) Air (IATA) TDG (Canada)
UN Number: N.A. N.A. N.A. N.A.
Proper Shipping Name: Not Regulated Not Regulated Not Regulated Not Regulated
Hazard Class: N.A. N.A. N.A. N.A.
Packing Group: N.A. N.A. N.A. N.A.
Limited Quantity: No No No No
15. Regulatory Information
U.S. Federal Regulations:
CERCLA - SARA Hazard Category
This product has been reviewed according to the EPA ‘Hazard Categories’ promulgated under Sections 311 and 312 of the
Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to
meet the following categories:
Acute Health Hazard, Chronic Health Hazard
Sara Section 313:
This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the
Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:
Chemical Name
Aluminum Oxide 1344-28-1
Toxic Substances Control Act:
This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported from
the United States:
CAS-No.
No TSCA components exist in this product.
Date Printed: 9/22/2014
Inventory Information
Country Value
USA (TSCA) No Information
Canada (DSL) No Information
Mexico(INSQ) No Information
Europe (EINECS) No Information
Japan (ENCS) No Information
Philippines (PICCS) No Information
China (IECSC) No Information
Australia (AICS) No Information
Korea (KECI) No Information
New Zealand (NZIOC) No Information
No Information
CALIFORNIA PROPOSITION 65:
Warning: This products contains a substance known to the State of California to cause cancer.
No Proposition 65 Carcinogens exist in this product.
CALIFORNIA PROPOSITION 65 REPRODUCTIVE TOXINS
Warning: This product contains a substance known to the State of California to cause birth defects or other reproductive
harm.
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No Proposition 65 Reproductive Toxins exist in this product.
International Regulations:
CANADIAN WHMIS:
This SDS has been prepared in compliance with Controlled Product Regulations except for the use of the 16 headings.
16. Other Information
HMIS RATINGS
Health: 1* Flammability: 1 Physical Hazard: 0 Personal Protection: X
CANADIAN WHMIS CLASS: D2A
NFPA RATINGS
Health: 1 Flammability: 1 Instability 0
VOLATILE ORGANIC COMPOUNDS, g/L:
MSDS REVISION DATE:
REASON FOR REVISION:
Legend: N.A. - Not Applicable, N.E. - Not Established, N.D. - Not Determined
9/22/2014
No Information
0
Icons for GHS Pictograms shown in Section 3 describing each ingredient:
No GHS Pictograms exist for Section 3
Date Printed: 9/22/2014
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Rust-Oleum Corporation believes, to the best of its knowledge, information and belief, the information contained herein to be
accurate and reliable as of the date of this safety data sheet. However, because the conditions of handling, use, and storage of
these materials are beyond our control, we assume no responsibility or liability for personal injury or property damage incurred by
the use of these materials. Rust-Oleum Corporation makes no warranty, expressed or implied, regarding the accuracy or
reliability of the data or results obtained from their use. All materials may present unknown hazards and should be used with
caution. The information and recommendations in this material safety data sheet are offered for the users’ consideration and
examination. It is the responsibility of the user to determine the final suitability of this information and to comply with all applicable
international, federal, state, and local laws and regulations.
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