Date Printed: 8/13/2014
Safety Data Sheet
1. Identification
Page 1 / 7
* Trusted Quality Since 1921 *
www.rustoleum.com
Product Name:
Product Identifier: 209563 Supercedes Date: 8/12/2014
Product Use/Class: Topcoat/Aerosols
Supplier:
Preparer: Regulatory Department
Emergency Telephone:
ROHPER LSPR 6PK HAMMER METAL
GOLD 15OZ
Rust-Oleum Corporation
11 Hawthorn Parkway
Vernon Hills, IL 60061
USA
24 Hour Hotline: 847-367-7700
Revision Date: 8/13/2014
Manufacturer:
Rust-Oleum Corporation
11 Hawthorn Parkway
Vernon Hills, IL 60061
USA
2. Hazard Identification
EMERGENCY OVERVIEW: Harmful if inhaled. Harmful if swallowed. Causes eye irritation. Extremely flammable liquid and vapor.
Vapors may cause flash fire or explosion. Use ventilation necessary to keep exposures below recommended exposure limits, if any.
Harmful if inhaled. May affect the brain or nervous system causing dizziness, headache or nausea. Vapor Harmful. Causes Eye,
Skin, Nose, and Throat Irritation. Contents Under Pressure. May cause eye, skin, or respiratory tract irritation. KEEP OUT OF
REACH OF CHILDREN.
Classification
Symbol(s) of Product
Signal Word
Danger
GHS HAZARD STATEMENTS
Flammable Aerosol, category 1 H222 Extremely flammable aerosol.
Flammable Liquid, category 1 H224 Extremely flammable liquid and vapour.
Flammable Aerosol, category 1 H280 Contains gas under pressure; may explode if heated
Acute Toxicity, Oral, category 5 H303 May be harmful if swallowed.
Aspiration Hazard, category 2 H305 May be harmful if swallowed and enters airways.
Acute Toxicity, Dermal, category 5 H313 May be harmful in contact with skin.
Skin Irritation, category 2 H315 Causes skin irritation.
Eye Irritation, category 2 H319 Causes serious eye irritation.
Eye Irritation, category 2B H320 Causes eye irritation.
Acute Toxicity, Inhalation, category 4 H332 Harmful if inhaled.
STOT, single exposure, category 3, RTI H335 May cause respiratory irritation.
STOT, single exposure, category 3, NE H336 May cause drowsiness or dizziness.
GHS PRECAUTIONARY STATEMENTS
P102 Keep out of reach of children.
P103 Read label before use.
Date Printed: 8/13/2014
67-64-1
68476-86-8
64742-49-0
1330-20-7
5131-66-8
100-41-4
108-65-6
P202 Do not handle until all safety precautions have been read and understood.
P210 Keep away from heat/sparks/open flames/hot surfaces. – No smoking.
P211 Do not spray on an open flame or other ignition source.
P220 Keep/Store away from clothing/…/combustible materials.
P234 Keep only in original container.
P235 Keep cool.
P240 Ground/bond container and receiving equipment.
P241 Use explosion-proof electrical/ventilating/lighting/…/ equipment.
P242 Use only non-sparking tools.
P243 Take precautionary measures against static discharge.
P251 Pressurized container: Do not pierce or burn, even after use.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P262 Do not get in eyes, on skin, or on clothing.
P264 Wash … thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P281 Use personal protective equipment as required.
P285 In case of inadequate ventilation wear respiratory protection.
P302+P350 IF ON SKIN: Gently wash with plenty of soap and water.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin
with water/shower.
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for
breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
P312 Call a POISON CENTER or doctor/physician if you feel unwell.
P321 Specific treatment (see … on this label).
P332+P313 If skin irritation occurs: Get medical advice/attention.
P337+P313 If eye irritation persists: Get medical advice/attention.
P351 Rinse cautiously with water for several minutes.
P352 Wash with plenty of soap and water.
P362 Take off contaminated clothing and wash before reuse.
P370+P378 In case of fire: Use … for extinction.
P374 Fight fire with normal precautions from a reasonable distance.
P375 Fight fire remotely due to the risk of explosion.
P402 Store in a dry place.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P403+P235 Store in a well-ventilated place. Keep cool.
P405 Store locked up.
P410+P412 Protect from sunlight. Do no expose to temperatures exceeding 50°C/ 122°F.
P501 Dispose of contents/container to …
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3. Composition/Information On Ingredients
HAZARDOUS SUBSTANCES
Chemical Name CAS-No. Wt.%
Range
Acetone
Liquefied Petroleum Gas
Naphtha, Petroleum, Hydrotreated Light
Xylene
Propylene Glycol Monobutyl Ether
Ethylbenzene
2-Propanol, 1-Methoxy-, Acetate
25-50
10-25
2.5-10
2.5-10
1.0-2.5
1.0-2.5
1.0-2.5
GHS Symbols
GHS02
GHS02
GHS02-GHS07
GHS02-GHS07
GHS02-GHS06
GHS Statements
H225
H226
H226-302
H225-332
H226-310
Date Printed: 8/13/2014
The text for GHS Hazard Statements shown above (if any) is given in the "16. Other Information" section.
Page 3 / 7
4. First-aid Measures
FIRST AID - EYE CONTACT: Immediately flush eyes with plenty of water for at least 15 minutes holding eyelids open. Get medical
attention. Do NOT allow rubbing of eyes or keeping eyes closed.
FIRST AID - SKIN CONTACT: Wash skin with soap and water. Remove contaminated clothing. Get medical attention if irritation
develops or persists.
FIRST AID - INHALATION: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get
immediate medical attention. Do NOT use mouth-to-mouth resuscitation. If you experience difficulty in breathing, leave the area to
obtain fresh air. If continued difficulty is experienced, get medical assistance immediately.
FIRST AID - INGESTION: Aspiration hazard: Do not induce vomiting or give anything by mouth because this material can enter the
lungs and cause severe lung damage. Get immediate medical attention. If swallowed, get medical attention.
5. Fire-fighting Measures
EXTINGUISHING MEDIA:
UNUSUAL FIRE AND EXPLOSION HAZARDS: FLASH POINT IS LESS THAN 20 °. F. - EXTREMELY FLAMMABLE LIQUID AND
VAPOR!Water spray may be ineffective. Closed containers may explode when exposed to extreme heat due to buildup of steam.
Closed containers may explode when exposed to extreme heat. Vapors may form explosive mixtures with air. Vapors can travel to a
source of ignition and flash back. Keep containers tightly closed. Isolate from heat, electrical equipment, sparks and open flame.
Perforation of the pressurized container may cause bursting of the can. No unusual fire or explosion hazards noted.
SPECIAL FIREFIGHTING PROCEDURES: Water may be used to cool closed containers to prevent pressure buildup and possible
autoignition or explosion. Full protective equipment including self-contained breathing apparatus should be used. Evacuate area and
fight fire from a safe distance. Use water spray to keep fire-exposed containers cool. Containers may explode when heated.
Alcohol Film Forming Foam, Carbon Dioxide, Dry Chemical, Dry Sand, Water Fog
6. Accidental Release Measures
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Contain spilled liquid with sand or earth. DO NOT use
combustible materials such as sawdust. Isolate the hazard area and deny entry to unnecessary and unprotected personnel. Remove
all sources of ignition, ventilate area and remove with inert absorbent and non-sparking tools. Dispose of according to local, state
(provincial) and federal regulations. Do not incinerate closed containers. Ventilate area, isolate spilled material, and remove with
inert absorbent. Dispose of contaminated absorbent, container, and unused contents in accordance with local, state, and federal
regulations.
7. Handling and Storage
HANDLING: Wash thoroughly after handling. Wash hands before eating. Remove contaminated clothing and launder before reuse.
Use only with adequate ventilation. Follow all MSDS/label precautions even after container is emptied because it may retain product
residues. Avoid breathing fumes, vapors, or mist. Avoid contact with eyes, skin and clothing.
STORAGE: Store in a dry, well ventilated place. Keep container tightly closed when not in use. Keep containers tightly closed.
Isolate from heat, electrical equipment, sparks and open flame. Contents under pressure. Do not store above 120 ° F. Store large
quantities in buildings designed and protected for storage of NFPA Class I flammable liquids. Keep away from heat, sparks, flame
and sources of ignition. Avoid excess heat. Product should be stored in tightly sealed containers and protected from heat, moisture,
and foreign materials.
8. Exposure Controls/Personal Protection
Chemical Name CAS-No.
Acetone 67-64-1 45.0 500 ppm 750 ppm 1000 ppm N.E.
Liquefied Petroleum Gas 68476-86-8 25.0 N.E. N.E. N.E. N.E.
Naphtha, Petroleum,
Hydrotreated Light
Xylene 1330-20-7 5.0 100 ppm 150 ppm 100 ppm N.E.
Propylene Glycol Monobutyl
Ether
Ethylbenzene 100-41-4 5.0 20 ppm 125 ppm 100 ppm N.E.
2-Propanol, 1-Methoxy-, Acetate 108-65-6 5.0 N.E. N.E. N.E. N.E.
PERSONAL PROTECTION
64742-49-0 10.0 200 mg/m3 N.E. N.E. N.E.
5131-66-8 5.0 N.E. N.E. N.E. N.E.
Weight %
Less Than
ACGIH TLV-
TWA
ACGIH TLV-
STEL
OSHA PEL-TWA
OSHA PEL-
CEILING
Date Printed: 8/13/2014
ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne
levels below recommended exposure limits. Use explosion-proof ventilation equipment. Provide general dilution of local exhaust
ventilation in volume and pattern to keep TLV of hazardous ingredients below acceptable limits. Prevent build-up of vapors by
opening all doors and windows to achieve cross-ventilation.
RESPIRATORY PROTECTION: A respiratory protection program that meets OSHA 1910.134 and ANSI Z88.2 requirements must be
followed whenever workplace conditions warrant a respirator's use. A NIOSH/MSHA approved air purifying respirator with organic
vapor cartridge or canister may be permissible under certain circumstances where airborne concentrations are expected to exceed
exposure limits.
SKIN PROTECTION: Use gloves to prevent prolonged skin contact. Nitrile or Neoprene gloves may afford adequate skin protection.
EYE PROTECTION: Use safety eyewear designed to protect against splash of liquids.
OTHER PROTECTIVE EQUIPMENT: Refer to safety supervisor or industrial hygienist for further guidance regarding types of
personal protective equipment and their applications.
HYGIENIC PRACTICES: Wash thoroughly with soap and water before eating, drinking or smoking. Remove contaminated clothing
immediately and launder before reuse.
Page 4 / 7
9. Physical and Chemical Properties
Appearance:
Odor:
Relative Density:
Freeze Point, °C:
Solubility in Water:
Decompostion Temp., °C:
Boiling Range, °C:
Flammability:
Evaporation Rate:
Vapor Density:
(See "Other information" Section for abbreviation legend)
Aerosolized Mist
Solvent Like
0.752
N.D.
Slight
No Information
-34 - 399
Supports Combustion
Faster than Ether
Heavier than Air
Physical State:
Odor Threshold:
pH:
Viscosity:
Partition Coefficient, n-octanol/
water:
Explosive Limits, vol%:
Flash Point, °C:
Auto-ignition Temp., °C:
Vapor Pressure:
Liquid
N.E.
N.A.
N.D.
No Information
0.7 - 13.0
-105
No Information
N.D.
10. Stability and Reactivity
CONDITIONS TO AVOID: Avoid temperatures above 120 ° F. Avoid contact with strong acid and strong bases. Avoid all possible
sources of ignition.
INCOMPATIBILITY: Incompatible with strong oxidizing agents, strong acids and strong alkalies.
HAZARDOUS DECOMPOSITION: By open flame, carbon monoxide and carbon dioxide. When heated to decomposition, it emits
acrid smoke and irritating fumes. Contains solvents which may form carbon monoxide, carbon dioxide, and formaldehyde.
HAZARDOUS POLYMERIZATION: Will not occur under normal conditions.
STABILITY: This product is stable under normal storage conditions.
11. Toxicological information
EFFECTS OF OVEREXPOSURE - EYE CONTACT: Causes Serious Eye Irritation
EFFECTS OF OVEREXPOSURE - SKIN CONTACT: May cause skin irritation. Allergic reactions are possible.
EFFECTS OF OVEREXPOSURE - INHALATION: Harmful if inhaled. High gas, vapor, mist or dust concentrations may be harmful if
inhaled. Avoid breathing fumes, spray, vapors, or mist. High vapor concentrations are irritating to the eyes, nose, throat and lungs.
Prolonged or excessive inhalation may cause respiratory tract irritation.
EFFECTS OF OVEREXPOSURE - INGESTION: Harmful if swallowed.
EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS: May cause central nervous system disorder (e.g., narcosis involving a
loss of coordination, weakness, fatigue, mental confusion, and blurred vision) and/or damage. High concentrations may lead to
central nervous system effects (drowsiness, dizziness, nausea, headaches, paralysis, and blurred vision) and/or damage. Reports
have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage.
Overexposure to xylene in laboratory animals has been associated with liver abnormalities, kidney, lung, spleen, eye and blood
damage as well as reproductive disorders. Effects in humans, due to chronic overexposure, have included liver, cardiac
abnormalities and nervous system damage. IARC lists Ethylbenzene as a possible human carcinogen (group 2B).
PRIMARY ROUTE(S) OF ENTRY: Eye Contact, Ingestion, Inhalation, Skin Absorption, Skin Contact
Date Printed: 8/13/2014
ACUTE TOXICITY VALUES
The acute effects of this product have not been tested. Data on individual components are tabulated below:
CAS-No. Chemical Name Oral LD50 Dermal LD50 Vapor LC50
64742-49-0 Naphtha, Petroleum, Hydrotreated Light >5000 mg/kg Rat >3160 mg/kg Rabbit N.I.
1330-20-7 Xylene 4300 mg/kg Rat N.I. 47635 mg/L Rat
5131-66-8 Propylene Glycol Monobutyl Ether 1900 mg/kg Rat N.I. N.I.
100-41-4 Ethylbenzene 3500 mg/kg Rat 15354 mg/kg Rabbit 17.2 mg/L Rat
108-65-6 2-Propanol, 1-Methoxy-, Acetate 8532 mg/kg Rat >5 g/kg Rabbit N.I.
N.I. - No Information
Page 5 / 7
12. Ecological Information
ECOLOGICAL INFORMATION: Product is a mixture of listed components.
13. Disposal Information
DISPOSAL INFORMATION: Dispose of material in accordance to local, state, and federal regulations and ordinances. Do not allow
to enter waterways, wastewater, soil, storm drains or sewer systems.
14. Transport Information
Domestic (USDOT) International (IMDG) Air (IATA) TDG (Canada)
UN Number: N.A. 1950 1950 N.A.
Proper Shipping Name:
Hazard Class: N.A. 2.1 2.1 N.A.
Packing Group: N.A. N.A. N.A. N.A.
Limited Quantity: Yes Yes Yes Yes
Paint Products in
Limited Quantities
Aerosols Aerosols
Paint Products in
Limited Quantities
15. Regulatory Information
U.S. Federal Regulations:
CERCLA - SARA Hazard Category
This product has been reviewed according to the EPA ‘Hazard Categories’ promulgated under Sections 311 and 312 of the
Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to
meet the following categories:
Fire Hazard, Pressure Hazard, Acute Health Hazard, Chronic Health Hazard
Sara Section 313:
This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the
Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:
Chemical Name
Xylene 1330-20-7
Ethylbenzene 100-41-4
CAS-No.
Toxic Substances Control Act:
This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported from
the United States:
No TSCA components exist in this product.
Date Printed: 8/13/2014
Inventory Information
Country Value
USA (TSCA) No Information
Canada (DSL) No Information
Mexico(INSQ) No Information
Europe (EINECS) No Information
Japan (ENCS) No Information
Philippines (PICCS) No Information
China (IECSC) No Information
Australia (AICS) No Information
Korea (KECI) No Information
New Zealand (NZIOC) No Information
No Information
CALIFORNIA PROPOSITION 65:
Warning: This products contains a substance known to the State of California to cause cancer.
Chemical Name
Ethylbenzene
CAS-No.
100-41-4
CALIFORNIA PROPOSITION 65 REPRODUCTIVE TOXINS
Page 6 / 7
Warning: This product contains a substance known to the State of California to cause birth defects or other reproductive
harm.
No Proposition 65 Reproductive Toxins exist in this product.
International Regulations:
CANADIAN WHMIS:
This SDS has been prepared in compliance with Controlled Product Regulations except for the use of the 16 headings.
16. Other Information
HMIS RATINGS
Health: 2* Flammability: 4 Physical Hazard: 0 Personal Protection: X
CANADIAN WHMIS CLASS: B2 D2A
NFPA RATINGS
Health: 2 Flammability: 4 Instability 0
VOLATILE ORGANIC COMPOUNDS, g/L:
MSDS REVISION DATE:
REASON FOR REVISION:
8/13/2014
No Information
497
Legend: N.A. - Not Applicable, N.E. - Not Established, N.D. - Not Determined
Date Printed: 8/13/2014
Page 7 / 7
Text for GHS Hazard Statements shown in Section 3 describing each ingredient:
H225 Highly flammable liquid and vapour.
H226 Flammable liquid and vapour.
H302 Harmful if swallowed.
H310 Fatal in contact with skin.
H332 Harmful if inhaled.
Icons for GHS Pictograms shown in Section 3 describing each ingredient:
GHS02
GHS06
GHS07
Rust-Oleum Corporation believes, to the best of its knowledge, information and belief, the information contained herein to be
accurate and reliable as of the date of this safety data sheet. However, because the conditions of handling, use, and storage of
these materials are beyond our control, we assume no responsibility or liability for personal injury or property damage incurred by
the use of these materials. Rust-Oleum Corporation makes no warranty, expressed or implied, regarding the accuracy or
reliability of the data or results obtained from their use. All materials may present unknown hazards and should be used with
caution. The information and recommendations in this material safety data sheet are offered for the users’ consideration and
examination. It is the responsibility of the user to determine the final suitability of this information and to comply with all applicable
international, federal, state, and local laws and regulations.
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