Date Printed: 9/11/2014
Safety Data Sheet
* Trusted Quality Since 1921 *
www.rustoleum.com
1. Identification
Product Name: SIE S40 1-GL EPOXY GLOSS CLEAR Revision Date: 9/11/2014
Product Identifier: 208066 Supercedes Date: New SDS
Product Use/Class: Topcoat/Epoxy Part B
Page 1 / 6
Supplier:
Preparer: Regulatory Department
Emergency Telephone:
Rust-Oleum Corporation
11 Hawthorn Parkway
Vernon Hills, IL 60061
USA
24 Hour Hotline: 847-367-7700
Manufacturer:
Rust-Oleum Corporation
11 Hawthorn Parkway
Vernon Hills, IL 60061
USA
2. Hazard Identification
EMERGENCY OVERVIEW: Causes eye irritation. Causes skin irritation. May cause allergic skin reaction. May cause eye, skin, or
respiratory tract irritation. KEEP OUT OF REACH OF CHILDREN. Harmful if inhaled. Use ventilation necessary to keep exposures
below recommended exposure limits, if any.
Classification
Symbol(s) of Product
Signal Word
Danger
Possible Hazards
2% of the mixture consists of ingredient(s) of unknown acute toxicity
GHS HAZARD STATEMENTS
Acute Toxicity, Dermal, category 5 H313 May be harmful in contact with skin.
Skin Irritation, category 2 H315 Causes skin irritation.
Aspiration Hazard, category 2 H305 May be harmful if swallowed and enters airways.
Skin Irritation, category 3 H316 Causes mild skin irritation.
Eye Irritation, category 2B H320 Causes eye irritation.
Acute Toxicity, Oral, category 4 H302 Harmful if swallowed.
Skin Corrosion, category 1 H314 Causes severe skin burns and eye damage.
Skin Sensitizer, category 1 H317 May cause an allergic skin reaction.
GHS PRECAUTIONARY STATEMENTS
P102 Keep out of reach of children.
P103 Read label before use.
P202 Do not handle until all safety precautions have been read and understood.
P234 Keep only in original container.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
Date Printed: 9/11/2014
PROPRIET
ARY
9046-10-0
112-57-2
P262 Do not get in eyes, on skin, or on clothing.
P264 Wash … thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P281 Use personal protective equipment as required.
P285 In case of inadequate ventilation wear respiratory protection.
P312 Call a POISON CENTER or doctor/physician if you feel unwell.
P335 Brush off loose particles from skin.
P351 Rinse cautiously with water for several minutes.
P374 Fight fire with normal precautions from a reasonable distance.
P402 Store in a dry place.
P321 Specific treatment (see … on this label).
P352 Wash with plenty of soap and water.
P362 Take off contaminated clothing and wash before reuse.
P332+P313 If skin irritation occurs: Get medical advice/attention.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P330 Rinse mouth.
P501 Dispose of contents/container to …
P302+P350 IF ON SKIN: Gently wash with plenty of soap and water.
P363 Wash contaminated clothing before reuse.
P301+P330+P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin
with water/shower.
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for
breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
P405 Store locked up.
P272 Contaminated work clothing should not be allowed out of the workplace.
P333+P313 If skin irritation or rash occurs: Get medical advice/attention.
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
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3. Composition/Information On Ingredients
HAZARDOUS SUBSTANCES
Chemical Name CAS-No. Wt.%
Range
Polyamine Polymer
Polyoxyalkyleneamine
Tetraethylenepentamine
The text for GHS Hazard Statements shown above (if any) is given in the "16. Other Information" section.
10-25
1.0-2.5
1.0-2.5
GHS Symbols
GHS05-GHS07
GHS05-GHS06
GHS Statements
H302-314-317
H311-314
4. First-aid Measures
FIRST AID - EYE CONTACT: Immediately flush eyes with plenty of water for at least 15 minutes holding eyelids open. Get medical
attention. Do NOT allow rubbing of eyes or keeping eyes closed.
FIRST AID - SKIN CONTACT: Wash skin with soap and water. Remove contaminated clothing. Get medical attention if irritation
develops or persists.
FIRST AID - INHALATION: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get
immediate medical attention. Do NOT use mouth-to-mouth resuscitation. If you experience difficulty in breathing, leave the area to
obtain fresh air. If continued difficulty is experienced, get medical assistance immediately.
Date Printed: 9/11/2014
FIRST AID - INGESTION: If swallowed, do not induce vomiting. If victim is conscious and alert, give 2 to 4 cupfuls of water or milk.
Call a physician or poison control center immediately. Never give anything by mouth to an unconscious person. Treat
symptomatically and supportively. Swallowing less than an ounce will not cause significant harm. For larger amounts, do not induce
vomiting, but give one or two glasses of water to drink and get medical attention. If swallowed, rinse mouth with water. If feeling
unwell, get medical attention.
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5. Fire-fighting Measures
EXTINGUISHING MEDIA:
UNUSUAL FIRE AND EXPLOSION HAZARDS: FLASH POINT IS TESTED TO BE GREATER THAN 200 DEGREES F. No unusual
fire or explosion hazards noted. Keep containers tightly closed.
SPECIAL FIREFIGHTING PROCEDURES: Water may be used to cool closed containers to prevent buildup of steam. Full protective
equipment including self-contained breathing apparatus should be used. Evacuate area and fight fire from a safe distance. If water is
used, fog nozzles are preferred.
Alcohol Film Forming Foam, Carbon Dioxide, Dry Chemical, Dry Sand, Water Fog
6. Accidental Release Measures
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Contain spilled liquid with sand or earth. DO NOT use
combustible materials such as sawdust. Dispose of according to local, state (provincial) and federal regulations. Do not incinerate
closed containers. If spilled, contain spilled material and remove with inert absorbent. Dispose of contaminated absorbent, container,
and unused contents in accordance with local, state, and federal regulations. Do not incinerate closed containers
7. Handling and Storage
HANDLING: Wash thoroughly after handling. Use only in a well-ventilated area. Follow all MSDS/label precautions even after
container is emptied because it may retain product residues. Avoid contact with eyes, skin and clothing. Wash hands before eating.
Remove contaminated clothing and launder before reuse. Use only with adequate ventilation. Avoid breathing fumes, vapors, or
mist.
STORAGE: Keep containers tightly closed. Isolate from heat, electrical equipment, sparks and open flame. Store in a dry, well
ventilated place. Keep container tightly closed when not in use.
8. Exposure Controls/Personal Protection
Chemical Name CAS-No.
Polyamine Polymer PROPRIETARY 25.0 N.E. N.E. N.E. N.E.
Polyoxyalkyleneamine 9046-10-0 5.0 N.E. N.E. N.E. N.E.
Tetraethylenepentamine 112-57-2 5.0
Weight %
Less Than
ACGIH TLV-
TWA
1.0 ppm (AIHA
WEEL, skin)
ACGIH TLV-
STEL
N.E. N.E. N.E.
OSHA PEL-TWA
OSHA PEL-
CEILING
PERSONAL PROTECTION
ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne
levels below recommended exposure limits. Prevent build-up of vapors by opening all doors and windows to achieve crossventilation.
RESPIRATORY PROTECTION: A respiratory protection program that meets OSHA 1910.134 and ANSI Z88.2 requirements must be
followed whenever workplace conditions warrant a respirator's use. A NIOSH/MSHA approved air purifying respirator with an organic
vapor cartridge or canister may be permissible under certain circumstances where airborne concentrations are expected to exceed
exposure limits.
Protection provided by air purifying respirators is limited. Use a positive pressure air supplied respirator if there is any potential for an
uncontrolled release, exposure levels are not known, or in any other circumstances where air purifying respirators may not provide
adequate protection.
SKIN PROTECTION: Use gloves to prevent prolonged skin contact. Nitrile or Neoprene gloves may afford adequate skin protection.
EYE PROTECTION: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European Standard EN166. Use safety eyewear designed to protect against splash of
liquids.
OTHER PROTECTIVE EQUIPMENT: Refer to safety supervisor or industrial hygienist for further information regarding personal
protective equipment and its application. Refer to safety supervisor or industrial hygienist for further guidance regarding types of
personal protective equipment and their applications.
HYGIENIC PRACTICES: Wash thoroughly with soap and water before eating, drinking or smoking. Remove contaminated clothing
immediately and launder before reuse.
Date Printed: 9/11/2014
9. Physical and Chemical Properties
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Appearance:
Odor:
Relative Density:
Freeze Point, °C:
Solubility in Water:
Decompostion Temp., °C:
Boiling Range, °C:
Flammability:
Evaporation Rate:
Vapor Density:
(See "Other information" Section for abbreviation legend)
Liquid
Solvent Like
1.033
N.D.
Miscible
No Information
212 - 552
Does not Support Combustion
Slower than Ether
Heavier than Air
Physical State:
Odor Threshold:
pH:
Viscosity:
Partition Coefficient, n-octanol/
water:
Explosive Limits, vol%:
Flash Point, °C:
Auto-ignition Temp., °C:
Vapor Pressure:
Liquid
N.E.
N.D.
N.D.
No Information
4.0 - 19.9
>93
No Information
N.D.
10. Stability and Reactivity
CONDITIONS TO AVOID: Avoid contact with strong acid and strong bases. Avoid temperatures above 120 ° F.
INCOMPATIBILITY: Incompatible with strong oxidizing agents, strong acids and strong alkalies.
HAZARDOUS DECOMPOSITION: When heated to decomposition, it emits acrid smoke and irritating fumes.
HAZARDOUS POLYMERIZATION: Will not occur under normal conditions.
STABILITY: This product is stable under normal storage conditions.
11. Toxicological information
EFFECTS OF OVEREXPOSURE - EYE CONTACT: Causes eye burns. Extremely irritating to the eyes and may cause severe
damage, including blindness. Substance causes severe eye irritation. Injury may be permanent. Irritating, and may injure eye tissue
if not removed promptly.
EFFECTS OF OVEREXPOSURE - SKIN CONTACT: Contact causes severe skin irritation and possible burns. May cause skin
sensitization, an allergic reaction, which becomes evident upon re-exposure to this material. Low hazard for usual industrial handling
or commercial handling by trained personnel.
EFFECTS OF OVEREXPOSURE - INHALATION: High vapor concentrations are irritating to the eyes, nose, throat and lungs. High
gas, vapor, mist or dust concentrations may be harmful if inhaled. Avoid breathing fumes, spray, vapors, or mist.
EFFECTS OF OVEREXPOSURE - INGESTION: Substance may be harmful if swallowed.
EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS: Reports have associated repeated and prolonged occupational
overexposure to solvents with permanent brain and nervous system damage.
PRIMARY ROUTE(S) OF ENTRY: Eye Contact, Ingestion, Inhalation, Skin Absorption, Skin Contact
ACUTE TOXICITY VALUES
The acute effects of this product have not been tested. Data on individual components are tabulated below:
CAS-No. Chemical Name Oral LD50 Dermal LD50 Vapor LC50
112-57-2 Tetraethylenepentamine 2100 mg/kg Rat 660 µL/kg Rabbit N.I.
N.I. - No Information
12. Ecological Information
ECOLOGICAL INFORMATION: Product is a mixture of listed components. Product is a mixture of listed components.
13. Disposal Information
DISPOSAL INFORMATION: Dispose of material in accordance to local, state, and federal regulations and ordinances. Do not allow
to enter waterways, wastewater, soil, storm drains or sewer systems.
Date Printed: 9/11/2014
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14. Transport Information
Domestic (USDOT) International (IMDG) Air (IATA) TDG (Canada)
UN Number: N.A. N.A. N.A. N.A.
Proper Shipping Name: Not Regulated Not Regulated Not Regulated Not Regulated
Hazard Class: N.A. N.A. N.A. N.A.
Packing Group: N.A. N.A. N.A. N.A.
Limited Quantity: No No No No
15. Regulatory Information
U.S. Federal Regulations:
CERCLA - SARA Hazard Category
This product has been reviewed according to the EPA ‘Hazard Categories’ promulgated under Sections 311 and 312 of the
Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to
meet the following categories:
Acute Health Hazard, Chronic Health Hazard
Sara Section 313:
This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the
Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:
No Sara 313 components exist in this product.
Toxic Substances Control Act:
This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported from
the United States:
No TSCA components exist in this product.
Inventory Information
Country Value
USA (TSCA) No Information
Canada (DSL) No Information
Mexico(INSQ) No Information
Europe (EINECS) No Information
Japan (ENCS) No Information
Philippines (PICCS) No Information
China (IECSC) No Information
Australia (AICS) No Information
Korea (KECI) No Information
New Zealand (NZIOC) No Information
No Information
CALIFORNIA PROPOSITION 65:
Warning: This products contains a substance known to the State of California to cause cancer.
No Proposition 65 Carcinogens exist in this product.
CALIFORNIA PROPOSITION 65 REPRODUCTIVE TOXINS
Warning: This product contains a substance known to the State of California to cause birth defects or other reproductive
harm.
No Proposition 65 Reproductive Toxins exist in this product.
Date Printed: 9/11/2014
International Regulations:
CANADIAN WHMIS:
This SDS has been prepared in compliance with Controlled Product Regulations except for the use of the 16 headings.
16. Other Information
HMIS RATINGS
Health: 2* Flammability: 1 Physical Hazard: 0 Personal Protection: X
CANADIAN WHMIS CLASS: D2A
NFPA RATINGS
Health: 2 Flammability: 1 Instability 0
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VOLATILE ORGANIC COMPOUNDS, g/L:
MSDS REVISION DATE:
REASON FOR REVISION:
Legend: N.A. - Not Applicable, N.E. - Not Established, N.D. - Not Determined
9/11/2014
No Information
13
Text for GHS Hazard Statements shown in Section 3 describing each ingredient:
H302 Harmful if swallowed.
H311 Toxic in contact with skin.
H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
Icons for GHS Pictograms shown in Section 3 describing each ingredient:
GHS05
GHS06
GHS07
Rust-Oleum Corporation believes, to the best of its knowledge, information and belief, the information contained herein to be
accurate and reliable as of the date of this safety data sheet. However, because the conditions of handling, use, and storage of
these materials are beyond our control, we assume no responsibility or liability for personal injury or property damage incurred by
the use of these materials. Rust-Oleum Corporation makes no warranty, expressed or implied, regarding the accuracy or
reliability of the data or results obtained from their use. All materials may present unknown hazards and should be used with
caution. The information and recommendations in this material safety data sheet are offered for the users’ consideration and
examination. It is the responsibility of the user to determine the final suitability of this information and to comply with all applicable
international, federal, state, and local laws and regulations.
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