Rust-Oleum 208060 User Manual

Date Printed: 9/11/2014

Safety Data Sheet

1. Identification

Page 1 / 7

* Trusted Quality Since 1921 *

www.rustoleum.com

Product Name:

Product Identifier: 208060 Supercedes Date: New SDS

Product Use/Class: White Pastel Base/Sierra S-40

Supplier:

Preparer: Regulatory Department

Emergency Telephone:

SIE S40 1-GL EPOXY GLOSS WHIT PASTEL
BAS

Rust-Oleum Corporation
11 Hawthorn Parkway
Vernon Hills, IL 60061
USA

24 Hour Hotline: [phone]

Revision Date: 9/11/2014

Manufacturer:

Rust-Oleum Corporation
11 Hawthorn Parkway
Vernon Hills, IL 60061
USA

2. Hazard Identification

EMERGENCY OVERVIEW: May cause eye, skin, or respiratory tract irritation. KEEP OUT OF REACH OF CHILDREN. Harmful if

inhaled. Harmful if swallowed. Causes severe skin and eye burns. Causes eye irritation. Vapors extremely irritating to eyes and
respiratory tract. Use ventilation necessary to keep exposures below recommended exposure limits, if any. Avoid contact with eyes,
skin and clothing.

Classification

Symbol(s) of Product

Signal Word

Danger

GHS HAZARD STATEMENTS

Acute Toxicity, Oral, category 4 H302 Harmful if swallowed.
Acute Toxicity, Dermal, category 4 H312 Harmful in contact with skin.
Acute Toxicity, Dermal, category 5 H313 May be harmful in contact with skin.
Skin Irritation, category 2 H315 Causes skin irritation.
Eye Irritation, category 2 H319 Causes serious eye irritation.
Acute Toxicity, Inhalation, category 3 H331 Toxic if inhaled.
Corrosive to Metals, category 1 H290 May be corrosive to metals.
Aspiration Hazard, category 2 H305 May be harmful if swallowed and enters airways.
Skin Corrosion, category 1 H314 Causes severe skin burns and eye damage.
Eye Irritation, category 2B H320 Causes eye irritation.
Skin Corrosion, category 1 H314 Causes severe skin burns and eye damage.
Skin Sensitizer, category 1 H317 May cause an allergic skin reaction.

GHS PRECAUTIONARY STATEMENTS

P102 Keep out of reach of children.
P103 Read label before use.
P202 Do not handle until all safety precautions have been read and understood.

Date Printed: 9/11/2014

13463-67-7

PROPRIET

ARY

1344-28-1

9046-10-0

112-57-2

P234 Keep only in original container.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P262 Do not get in eyes, on skin, or on clothing.
P264 Wash … thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P281 Use personal protective equipment as required.
P285 In case of inadequate ventilation wear respiratory protection.
P312 Call a POISON CENTER or doctor/physician if you feel unwell.
P351 Rinse cautiously with water for several minutes.
P360 Rinse immediately contaminated clothing and skin with plenty of water before removing

clothes.
P361 Remove/Take off immediately all contaminated clothing.
P374 Fight fire with normal precautions from a reasonable distance.
P402 Store in a dry place.
P406 Store in corrosive resistant/… container with a resistant inner liner.
P302+P350 IF ON SKIN: Gently wash with plenty of soap and water.
P501 Dispose of contents/container to …
P322 Specific measures (see … on this label).
P363 Wash contaminated clothing before reuse.
P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302+P352 IF ON SKIN: Wash with plenty of soap and water.
P321 Specific treatment (see … on this label).
P352 Wash with plenty of soap and water.
P362 Take off contaminated clothing and wash before reuse.
P332+P313 If skin irritation occurs: Get medical advice/attention.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if

present and easy to do. Continue rinsing.
P337+P313 If eye irritation persists: Get medical advice/attention.
P311 Call a POISON CENTER or doctor/physician.
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for

breathing.
P405 Store locked up.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P390 Absorb spillage to prevent material damage.
P310 Immediately call a POISON CENTER or doctor/physician.
P301+P330+P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin

with water/shower.
P272 Contaminated work clothing should not be allowed out of the workplace.
P333+P313 If skin irritation or rash occurs: Get medical advice/attention.

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3. Composition/Information On Ingredients

HAZARDOUS SUBSTANCES

Chemical Name CAS-No. Wt.%

Range

Titanium Dioxide
Polyamine Polymer

Aluminum Oxide
Polyoxyalkyleneamine
Glacial Acetic Acid

Tetraethylenepentamine

64-19-7

25-50

10-25

2.5-10

1.0-2.5

1.0-2.5

1.0-2.5

GHS Symbols

GHS05-GHS07

GHS02-GHS05­GHS07

GHS05-GHS06

GHS Statements

H302-314-317

H226-290-312-332

H311-314

Date Printed: 9/11/2014

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The text for GHS Hazard Statements shown above (if any) is given in the "16. Other Information" section.

4. First-aid Measures

FIRST AID - EYE CONTACT: Immediately flush eyes with plenty of water for at least 15 minutes holding eyelids open. Get medical

attention. Do NOT allow rubbing of eyes or keeping eyes closed.

FIRST AID - SKIN CONTACT: Wash skin with soap and water. Remove contaminated clothing. Get medical attention if irritation
develops or persists. Immediately flush skin with plenty of water for at least 15 minutes while removing clothing. Get medical
attention immediately. Wash clothing separately before reuse. Destroy contaminated shoes.

FIRST AID - INHALATION: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get
immediate medical attention. Do NOT use mouth-to-mouth resuscitation. If you experience difficulty in breathing, leave the area to
obtain fresh air. If continued difficulty is experienced, get medical assistance immediately.

FIRST AID - INGESTION: Swallowing less than an ounce will not cause significant harm. For larger amounts, do not induce
vomiting, but give one or two glasses of water to drink and get medical attention. If swallowed, do not induce vomiting. If victim is
conscious and alert, give 2 to 4 cupfuls of water or milk. Call a physician or poison control center immediately. Never give anything
by mouth to an unconscious person. Treat symptomatically and supportively. Do not induce vomiting unless advised by a physician.
Call nearest Poison Control Center or Physician immediately.

5. Fire-fighting Measures

EXTINGUISHING MEDIA:

Alcohol Film Forming Foam, Carbon Dioxide, Dry Chemical, Water Fog

UNUSUAL FIRE AND EXPLOSION HAZARDS: FLASH POINT IS TESTED TO BE GREATER THAN 200 DEGREES F. No unusual
fire or explosion hazards noted. Keep containers tightly closed.

SPECIAL FIREFIGHTING PROCEDURES: Water may be used to cool closed containers to prevent buildup of steam. Containers
can rupture and release highly toxic material if exposed to heat. Substance is non-combustible but reacts with many metals to form
explosive hydrogen gas. Use water spray to keep fire-exposed containers cool. Containers may explode when heated.

6. Accidental Release Measures

STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Dispose of according to local, state (provincial) and federal

regulations. Do not incinerate closed containers. Avoid runoff into sewers and waterways. Provide ventilation and approach spill
from upwind using proper personal protective equipment as indicated in Section 8. Carefully neutralize spill with sodium bicarbonate
(NaHCO3). Contain spilled liquid with sand or earth. DO NOT use combustible materials such as sawdust.

7. Handling and Storage

HANDLING: Avoid contact with eyes. Wash hands before eating. Wash thoroughly after handling. Remove contaminated clothing

and launder before reuse. Use only with adequate ventilation. Follow all MSDS/label precautions even after container is emptied
because it may retain product residues. Avoid breathing fumes, vapors, or mist. Avoid contact with eyes, skin and clothing.

STORAGE: Keep from freezing. Keep container closed when not in use. Store in a dry, well ventilated place. Keep container tightly
closed when not in use.

8. Exposure Controls/Personal Protection

Chemical Name CAS-No.

Titanium Dioxide 13463-67-7 45.0 10 mg/m3 N.E.

Polyamine Polymer PROPRIETARY 15.0 N.E. N.E. N.E. N.E.

Aluminum Oxide 1344-28-1 5.0

Polyoxyalkyleneamine 9046-10-0 5.0 N.E. N.E. N.E. N.E.
Glacial Acetic Acid 64-19-7 5.0 10 ppm 15 ppm 10 ppm N.E.

Tetraethylenepentamine 112-57-2 5.0

Weight %

Less Than

ACGIH TLV-

TWA

1 mg/m3

[Respirable]

1.0 ppm (AIHA
WEEL, skin)

ACGIH TLV-

STEL

N.E.

N.E. N.E. N.E.

OSHA PEL-TWA

15 mg/m3 [Total

Dust]

5 mg/m3

[Respirable]

OSHA PEL-

CEILING

N.E.

N.E.

PERSONAL PROTECTION

ENGINEERING CONTROLS: Prevent build-up of vapors by opening all doors and windows to achieve cross-ventilation. Use

process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below recommended exposure
limits. Provide general dilution of local exhaust ventilation in volume and pattern to keep TLV of hazardous ingredients below
acceptable limits.

Date Printed: 9/11/2014

RESPIRATORY PROTECTION: A NIOSH/MSHA approved air purifying respirator with organic vapor cartridge or canister may be
permissible under certain circumstances where airborne concentrations are expected to exceed exposure limits. A respiratory
protection program that meets OSHA 1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions
warrant a respirator's use.

SKIN PROTECTION: Nitrile or Neoprene gloves may afford adequate skin protection. Use gloves to prevent prolonged skin contact.
Use impervious gloves to prevent skin contact and absorption of this material through the skin.

EYE PROTECTION: Use safety eyewear designed to protect against splash of liquids. Use ANSI Z87.1 approved safety eyewear.

OTHER PROTECTIVE EQUIPMENT: Refer to safety supervisor or industrial hygienist for further information regarding personal

protective equipment and its application. Refer to safety supervisor or industrial hygienist for further guidance regarding types of
personal protective equipment and their applications.

HYGIENIC PRACTICES: Wash thoroughly with soap and water before eating, drinking or smoking. Remove contaminated clothing
immediately and launder before reuse.

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9. Physical and Chemical Properties

Appearance:
Odor:
Relative Density:
Freeze Point, °C:
Solubility in Water:
Decompostion Temp., °C:
Boiling Range, °C:
Flammability:
Evaporation Rate:
Vapor Density:

(See "Other information" Section for abbreviation legend)

Liquid
Solvent Like

1.759
N.D.
Miscible
No Information
212 - 392
Does not Support Combustion
Slower than Ether
Heavier than Air

Physical State:
Odor Threshold:
pH:
Viscosity:
Partition Coefficient, n-octanol/

water:

Explosive Limits, vol%:
Flash Point, °C:
Auto-ignition Temp., °C:
Vapor Pressure:

Liquid
N.E.
N.D.
N.D.

No Information

4.0 - 19.9
>93
No Information
N.D.

10. Stability and Reactivity

CONDITIONS TO AVOID: Avoid contact with strong acid and strong bases. Avoid contact with metals.

INCOMPATIBILITY: Incompatible with strong oxidizing agents, strong acids and strong alkalies. Product slowly corrodes copper,

aluminum,zinc, and galvanized surfaces

HAZARDOUS DECOMPOSITION: When heated to decomposition, it emits acrid smoke and irritating fumes. By open flame, carbon
monoxide and carbon dioxide. Decomposition produces hydrogen chloride, chlorine and hydrogen gases.

HAZARDOUS POLYMERIZATION: Will not occur under normal conditions.

STABILITY: This product is stable under normal storage conditions.

11. Toxicological information

EFFECTS OF OVEREXPOSURE - EYE CONTACT: Causes eye burns. Causes eye irritation. Substance causes severe eye

irritation. Injury may be permanent.

EFFECTS OF OVEREXPOSURE - SKIN CONTACT: Contact causes severe skin irritation and possible burns. Substance may
cause slight skin irritation. Severely irritating; may cause permanent skin damage.

EFFECTS OF OVEREXPOSURE - INHALATION: Low hazard for usual industrial handling or commercial handling by trained
personnel. Routine handling and application does not require use of respiratory protection; however, if air monitoring demonstrates
vapor, mist, or dust levels above applicable limits, wear an appropriate, properly fitted respirator (NIOSH/MSHA approved) during
handling and application. Follow respirator manufacturer's directions for respirator use. Harmful if inhaled. High gas, vapor, mist or
dust concentrations may be harmful if inhaled. Avoid breathing fumes, spray, vapors, or mist. High vapor concentrations are irritating
to the eyes, nose, throat and lungs.

EFFECTS OF OVEREXPOSURE - INGESTION: Substance may be harmful if swallowed. Corrosive and may cause severe and
permanent damage to mouth, throat and stomach.

EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS: Contains Titanium Dioxide. Titanium Dioxide is listed as a Group
2B-"Possibly carcinogenic to humans" by IARC. No significant exposure to Titanium Dioxide is thought to occur during the use of
products in which Titanium Dioxide is bound to other materials, such as in paints during brush application or drying. Risk of
overexposure depends on duration and level of exposure to dust from repeated sanding of surfaces or spray mist and the actual
concentration of Titanium Dioxide in the formula. (Ref: IARC Monograph, Vol. 93, 2010)Repeated exposure to low concentrations of
HCl vapor or mist may cause bleeding of nose and gums.

PRIMARY ROUTE(S) OF ENTRY: Eye Contact, Ingestion, Inhalation, Skin Absorption, Skin Contact

Date Printed: 9/11/2014

ACUTE TOXICITY VALUES
The acute effects of this product have not been tested. Data on individual components are tabulated below:

CAS-No.

13463-67-7 Titanium Dioxide >10000 mg/kg Rat N.I. N.I.
1344-28-1 Aluminum Oxide >5000 mg/kg Rat N.I. N.I.
64-19-7 Glacial Acetic Acid 3310 mg/kg Rat 1060 µL/kg Rabbit 11.4 mg/L Rat
112-57-2 Tetraethylenepentamine 2100 mg/kg Rat 660 µL/kg Rabbit N.I.

N.I. - No Information

Chemical Name Oral LD50 Dermal LD50 Vapor LC50

Page 5 / 7

12. Ecological Information

ECOLOGICAL INFORMATION: Product is a mixture of listed components.

13. Disposal Information

DISPOSAL INFORMATION: Dispose of material in accordance to local, state, and federal regulations and ordinances. Do not allow

to enter waterways, wastewater, soil, storm drains or sewer systems.

14. Transport Information

Domestic (USDOT) International (IMDG) Air (IATA) TDG (Canada)

UN Number: N.A. 3066 3066 N.A.

Proper Shipping Name:

Hazard Class: N.A. 8 8 N.A.

Packing Group: N.A. III III N.A.

Limited Quantity: No Yes No No

Paint Products in

Limited Quantities

Paint and Paint Related

Products

Paint and Paint

Related Products

Paint Products in

Limited Quantities

15. Regulatory Information

U.S. Federal Regulations:

CERCLA - SARA Hazard Category

This product has been reviewed according to the EPA ‘Hazard Categories’ promulgated under Sections 311 and 312 of the
Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to
meet the following categories:

Acute Health Hazard

Sara Section 313:

This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the
Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:

Chemical Name

Aluminum Oxide 1344-28-1

CAS-No.

Toxic Substances Control Act:

This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported from
the United States:

No TSCA components exist in this product.

Date Printed: 9/11/2014

Inventory Information

Country Value

USA (TSCA) No Information
Canada (DSL) No Information
Mexico(INSQ) No Information
Europe (EINECS) No Information
Japan (ENCS) No Information
Philippines (PICCS) No Information
China (IECSC) No Information
Australia (AICS) No Information
Korea (KECI) No Information
New Zealand (NZIOC) No Information

No Information

CALIFORNIA PROPOSITION 65:

Warning: This products contains a substance known to the State of California to cause cancer.

Chemical Name

Titanium Dioxide

CAS-No.

13463-67-7

CALIFORNIA PROPOSITION 65 REPRODUCTIVE TOXINS

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Warning: This product contains a substance known to the State of California to cause birth defects or other reproductive
harm.

No Proposition 65 Reproductive Toxins exist in this product.

International Regulations:

CANADIAN WHMIS:

This SDS has been prepared in compliance with Controlled Product Regulations except for the use of the 16 headings.

16. Other Information

HMIS RATINGS

Health: 2* Flammability: 0 Physical Hazard: 1 Personal Protection: X

CANADIAN WHMIS CLASS: D2A

NFPA RATINGS

Health: 2 Flammability: 1 Instability 0

VOLATILE ORGANIC COMPOUNDS, g/L:

MSDS REVISION DATE:

REASON FOR REVISION:

9/11/2014

No Information

0

Legend: N.A. - Not Applicable, N.E. - Not Established, N.D. - Not Determined

Date Printed: 9/11/2014

Text for GHS Hazard Statements shown in Section 3 describing each ingredient:

H226 Flammable liquid and vapour.
H290 May be corrosive to metals.
H302 Harmful if swallowed.
H311 Toxic in contact with skin.
H312 Harmful in contact with skin.
H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
H332 Harmful if inhaled.

Icons for GHS Pictograms shown in Section 3 describing each ingredient:

GHS02

GHS05

GHS06

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GHS07

Rust-Oleum Corporation believes, to the best of its knowledge, information and belief, the information contained herein to be
accurate and reliable as of the date of this safety data sheet. However, because the conditions of handling, use, and storage of
these materials are beyond our control, we assume no responsibility or liability for personal injury or property damage incurred by
the use of these materials. Rust-Oleum Corporation makes no warranty, expressed or implied, regarding the accuracy or
reliability of the data or results obtained from their use. All materials may present unknown hazards and should be used with
caution. The information and recommendations in this material safety data sheet are offered for the users’ consideration and
examination. It is the responsibility of the user to determine the final suitability of this information and to comply with all applicable
international, federal, state, and local laws and regulations.