Date Printed: 8/26/2014
Safety Data Sheet
* Trusted Quality Since 1921 *
www.rustoleum.com
1. Identification
Product Name: ICWB LSPR 12PK SAFETY RED MARKING Revision Date: 8/26/2014
Product Identifier: 203038 Supercedes Date: New SDS
Product Use/Class:
Supplier:
Preparer: Regulatory Department
Marking Paint/Industrial Choice Water
Based Aerosols
Rust-Oleum Corporation
11 Hawthorn Parkway
Vernon Hills, IL 60061
USA
Manufacturer:
Rust-Oleum Corporation
11 Hawthorn Parkway
Vernon Hills, IL 60061
USA
Page 1 / 7
Emergency Telephone:
24 Hour Hotline: 847-367-7700
2. Hazard Identification
EMERGENCY OVERVIEW: Harmful if swallowed. Extremely flammable liquid and vapor. Vapors may cause flash fire or explosion.
Contents Under Pressure. Harmful if inhaled. May affect the brain or nervous system causing dizziness, headache or nausea. May
cause eye, skin, or respiratory tract irritation. KEEP OUT OF REACH OF CHILDREN. Harmful if inhaled. Causes eye irritation.
Use ventilation necessary to keep exposures below recommended exposure limits, if any. Vapor Harmful. Causes Eye, Skin, Nose,
and Throat Irritation.
Classification
Symbol(s) of Product
Signal Word
Danger
GHS HAZARD STATEMENTS
Flammable Aerosol, category 1 H222 Extremely flammable aerosol.
Flammable Liquid, category 1 H224 Extremely flammable liquid and vapour.
Acute Toxicity, Oral, category 5 H303 May be harmful if swallowed.
Acute Toxicity, Dermal, category 5 H313 May be harmful in contact with skin.
Skin Irritation, category 2 H315 Causes skin irritation.
Eye Irritation, category 2 H319 Causes serious eye irritation.
Acute Toxicity, Inhalation, category 4 H332 Harmful if inhaled.
STOT, single exposure, category 3, RTI H335 May cause respiratory irritation.
STOT, single exposure, category 3, NE H336 May cause drowsiness or dizziness.
Aspiration Hazard, category 2 H305 May be harmful if swallowed and enters airways.
Eye Irritation, category 2B H320 Causes eye irritation.
Flammable Aerosol, category 1 H280 Contains gas under pressure; may explode if heated
GHS PRECAUTIONARY STATEMENTS
P211 Do not spray on an open flame or other ignition source.
P220 Keep/Store away from clothing/…/combustible materials.
Date Printed: 8/26/2014
68476-86-8
64742-89-8
1330-20-7
1317-65-3
14807-96-6
100-41-4
13463-67-7
P235 Keep cool.
P251 Pressurized container: Do not pierce or burn, even after use.
P375 Fight fire remotely due to the risk of explosion.
P102 Keep out of reach of children.
P103 Read label before use.
P202 Do not handle until all safety precautions have been read and understood.
P234 Keep only in original container.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P262 Do not get in eyes, on skin, or on clothing.
P264 Wash … thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P281 Use personal protective equipment as required.
P285 In case of inadequate ventilation wear respiratory protection.
P312 Call a POISON CENTER or doctor/physician if you feel unwell.
P351 Rinse cautiously with water for several minutes.
P374 Fight fire with normal precautions from a reasonable distance.
P402 Store in a dry place.
P210 Keep away from heat/sparks/open flames/hot surfaces. – No smoking.
P410+P412 Protect from sunlight. Do no expose to temperatures exceeding 50°C/ 122°F.
P240 Ground/bond container and receiving equipment.
P241 Use explosion-proof electrical/ventilating/lighting/…/ equipment.
P242 Use only non-sparking tools.
P243 Take precautionary measures against static discharge.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin
with water/shower.
P370+P378 In case of fire: Use … for extinction.
P403+P235 Store in a well-ventilated place. Keep cool.
P501 Dispose of contents/container to …
P321 Specific treatment (see … on this label).
P352 Wash with plenty of soap and water.
P362 Take off contaminated clothing and wash before reuse.
P332+P313 If skin irritation occurs: Get medical advice/attention.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
P337+P313 If eye irritation persists: Get medical advice/attention.
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for
breathing.
P405 Store locked up.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P302+P350 IF ON SKIN: Gently wash with plenty of soap and water.
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3. Composition/Information On Ingredients
HAZARDOUS SUBSTANCES
Chemical Name CAS-No. Wt.%
Range
Liquefied Petroleum Gas
Aliphatic Hydrocarbon
Xylene
Limestone
Talc
Ethylbenzene
Titanium Dioxide
10-25
10-25
2.5-10
2.5-10
2.5-10
1.0-2.5
1.0-2.5
GHS Symbols
GHS02
GHS02-GHS07
GHS Statements
H226
H225-332
Date Printed: 8/26/2014
Page 3 / 7
The text for GHS Hazard Statements shown above (if any) is given in the "16. Other Information" section.
4. First-aid Measures
FIRST AID - EYE CONTACT: Immediately flush eyes with plenty of water for at least 15 minutes holding eyelids open. Get medical
attention. Do NOT allow rubbing of eyes or keeping eyes closed.
FIRST AID - SKIN CONTACT: Wash skin with soap and water. Remove contaminated clothing. Get medical attention if irritation
develops or persists.
FIRST AID - INHALATION: If you experience difficulty in breathing, leave the area to obtain fresh air. If continued difficulty is
experienced, get medical assistance immediately. Remove to fresh air. If not breathing, give artificial respiration. If breathing is
difficult, give oxygen. Get immediate medical attention. Do NOT use mouth-to-mouth resuscitation.
FIRST AID - INGESTION: Aspiration hazard: Do not induce vomiting or give anything by mouth because this material can enter the
lungs and cause severe lung damage. Get immediate medical attention. If swallowed, get medical attention.
5. Fire-fighting Measures
EXTINGUISHING MEDIA:
Alcohol Film Forming Foam, Carbon Dioxide, Dry Chemical, Dry Sand, Water Fog
UNUSUAL FIRE AND EXPLOSION HAZARDS: FLASH POINT IS LESS THAN 20 °. F. - EXTREMELY FLAMMABLE LIQUID AND
VAPOR!Water spray may be ineffective. Closed containers may explode when exposed to extreme heat. Vapors may form explosive
mixtures with air. Vapors can travel to a source of ignition and flash back. Keep containers tightly closed. Isolate from heat,
electrical equipment, sparks and open flame. Perforation of the pressurized container may cause bursting of the can. Closed
containers may explode when exposed to extreme heat due to buildup of steam. No unusual fire or explosion hazards noted.
SPECIAL FIREFIGHTING PROCEDURES: Evacuate area and fight fire from a safe distance. Full protective equipment including
self-contained breathing apparatus should be used. Water may be used to cool closed containers to prevent pressure buildup and
possible autoignition or explosion. Use water spray to keep fire-exposed containers cool. Containers may explode when heated.
6. Accidental Release Measures
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Contain spilled liquid with sand or earth. DO NOT use
combustible materials such as sawdust. Remove all sources of ignition, ventilate area and remove with inert absorbent and nonsparking tools. Dispose of according to local, state (provincial) and federal regulations. Do not incinerate closed containers. Isolate
the hazard area and deny entry to unnecessary and unprotected personnel. Ventilate area, isolate spilled material, and remove with
inert absorbent. Dispose of contaminated absorbent, container, and unused contents in accordance with local, state, and federal
regulations.
7. Handling and Storage
HANDLING: Wash thoroughly after handling. Wash hands before eating. Use only in a well-ventilated area. Follow all MSDS/label
precautions even after container is emptied because it may retain product residues. Avoid breathing fumes, vapors, or mist. Remove
contaminated clothing and launder before reuse. Use only with adequate ventilation. Avoid contact with eyes, skin and clothing.
STORAGE: Keep containers tightly closed. Isolate from heat, electrical equipment, sparks and open flame. Contents under
pressure. Do not store above 120 ° F. Store large quantities in buildings designed and protected for storage of NFPA Class I
flammable liquids. Contents under pressure. Do not expose to heat or store above 120 ° F. Product should be stored in tightly
sealed containers and protected from heat, moisture, and foreign materials. Store in a dry, well ventilated place. Keep container
tightly closed when not in use. Keep away from heat, sparks, flame and sources of ignition. Avoid excess heat.
8. Exposure Controls/Personal Protection
Chemical Name CAS-No.
Liquefied Petroleum Gas 68476-86-8 25.0 N.E. N.E. N.E. N.E.
Aliphatic Hydrocarbon 64742-89-8 15.0 100 ppm N.E. 100 ppm N.E.
Xylene 1330-20-7 10.0 100 ppm 150 ppm 100 ppm N.E.
Limestone 1317-65-3 10.0 N.E. N.E.
Talc 14807-96-6 5.0 2 mg/m3 N.E.
Ethylbenzene 100-41-4 5.0 20 ppm 125 ppm 100 ppm N.E.
Titanium Dioxide 13463-67-7 5.0 10 mg/m3 N.E.
Weight %
Less Than
PERSONAL PROTECTION
ACGIH TLV-
TWA
ACGIH TLV-
STEL
OSHA PEL-TWA
15 mg/m3 [Total
Dust]
0.1 mg/m3
[Respirable]
15 mg/m3 [Total
Dust]
OSHA PEL-
CEILING
N.E.
N.E.
N.E.
Date Printed: 8/26/2014
ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne
levels below recommended exposure limits. Use explosion-proof ventilation equipment. Prevent build-up of vapors by opening all
doors and windows to achieve cross-ventilation. Provide general dilution of local exhaust ventilation in volume and pattern to keep
TLV of hazardous ingredients below acceptable limits.
RESPIRATORY PROTECTION: A respiratory protection program that meets OSHA 1910.134 and ANSI Z88.2 requirements must be
followed whenever workplace conditions warrant a respirator's use. A NIOSH/MSHA approved air purifying respirator with organic
vapor cartridge or canister may be permissible under certain circumstances where airborne concentrations are expected to exceed
exposure limits.
SKIN PROTECTION: Use impervious gloves to prevent skin contact and absorption of this material through the skin. Nitrile or
Neoprene gloves may afford adequate skin protection. Use gloves to prevent prolonged skin contact.
EYE PROTECTION: Use safety eyewear designed to protect against splash of liquids.
OTHER PROTECTIVE EQUIPMENT: Refer to safety supervisor or industrial hygienist for further information regarding personal
protective equipment and its application. Refer to safety supervisor or industrial hygienist for further guidance regarding types of
personal protective equipment and their applications.
HYGIENIC PRACTICES: Wash thoroughly with soap and water before eating, drinking or smoking. Remove contaminated clothing
immediately and launder before reuse.
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9. Physical and Chemical Properties
Appearance:
Odor:
Relative Density:
Freeze Point, °C:
Solubility in Water:
Decompostion Temp., °C:
Boiling Range, °C:
Flammability:
Evaporation Rate:
Vapor Density:
(See "Other information" Section for abbreviation legend)
Aerosolized Mist
Mild
0.850
ND
Miscible
No Information
-34 - 415
Supports Combustion
Faster than Ether
Heavier than Air
Physical State:
Odor Threshold:
pH:
Viscosity:
Partition Coefficient, n-octanol/
water:
Explosive Limits, vol%:
Flash Point, °C:
Auto-ignition Temp., °C:
Vapor Pressure:
Liquid
N.E.
N.D.
N.D.
No Information
0.9 - 12.6
-105
No Information
N.D.
10. Stability and Reactivity
CONDITIONS TO AVOID: Avoid temperatures above 120 ° F. Avoid all possible sources of ignition. Avoid contact with strong acid
and strong bases.
INCOMPATIBILITY: Incompatible with strong oxidizing agents, strong acids and strong alkalies.
HAZARDOUS DECOMPOSITION: By open flame, carbon monoxide and carbon dioxide. When heated to decomposition, it emits
acrid smoke and irritating fumes. Contains solvents which may form carbon monoxide, carbon dioxide, and formaldehyde.
HAZARDOUS POLYMERIZATION: Will not occur under normal conditions.
STABILITY: This product is stable under normal storage conditions.
11. Toxicological information
EFFECTS OF OVEREXPOSURE - EYE CONTACT: Causes Serious Eye Irritation
EFFECTS OF OVEREXPOSURE - SKIN CONTACT: Substance may cause slight skin irritation. Prolonged or repeated contact may
cause skin irritation. May cause skin irritation. Allergic reactions are possible.
EFFECTS OF OVEREXPOSURE - INHALATION: Harmful if inhaled. High gas, vapor, mist or dust concentrations may be harmful if
inhaled. Avoid breathing fumes, spray, vapors, or mist. High vapor concentrations are irritating to the eyes, nose, throat and lungs.
Prolonged or excessive inhalation may cause respiratory tract irritation.
EFFECTS OF OVEREXPOSURE - INGESTION: Aspiration hazard if swallowed; can enter lungs and cause damage. Harmful if
swallowed.
EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS: IARC lists Ethylbenzene as a possible human carcinogen (group 2B).
Overexposure to xylene in laboratory animals has been associated with liver abnormalities, kidney, lung, spleen, eye and blood
damage as well as reproductive disorders. Effects in humans, due to chronic overexposure, have included liver, cardiac
abnormalities and nervous system damage. Contains Titanium Dioxide. Titanium Dioxide is listed as a Group 2B-"Possibly
carcinogenic to humans" by IARC. No significant exposure to Titanium Dioxide is thought to occur during the use of products in which
Titanium Dioxide is bound to other materials, such as in paints during brush application or drying. Risk of overexposure depends on
duration and level of exposure to dust from repeated sanding of surfaces or spray mist and the actual concentration of Titanium
Dioxide in the formula. (Ref: IARC Monograph, Vol. 93, 2010)May cause central nervous system disorder (e.g., narcosis involving a
Date Printed: 8/26/2014
loss of coordination, weakness, fatigue, mental confusion, and blurred vision) and/or damage. Reports have associated repeated and
prolonged occupational overexposure to solvents with permanent brain and nervous system damage. High concentrations may lead
to central nervous system effects (drowsiness, dizziness, nausea, headaches, paralysis, and blurred vision) and/or damage.
PRIMARY ROUTE(S) OF ENTRY: Eye Contact, Ingestion, Inhalation, Skin Absorption, Skin Contact
ACUTE TOXICITY VALUES
The acute effects of this product have not been tested. Data on individual components are tabulated below:
CAS-No.
64742-89-8 Aliphatic Hydrocarbon N.I. 3000 mg/kg Rabbit N.I.
1330-20-7 Xylene 4300 mg/kg Rat N.I. 47635 mg/L Rat
100-41-4 Ethylbenzene 3500 mg/kg Rat 15354 mg/kg Rabbit 17.2 mg/L Rat
13463-67-7 Titanium Dioxide >10000 mg/kg Rat N.I. N.I.
N.I. - No Information
Chemical Name Oral LD50 Dermal LD50 Vapor LC50
Page 5 / 7
12. Ecological Information
ECOLOGICAL INFORMATION: Product is a mixture of listed components. Product is a mixture of listed components.
13. Disposal Information
DISPOSAL INFORMATION: Dispose of material in accordance to local, state, and federal regulations and ordinances. Do not allow
to enter waterways, wastewater, soil, storm drains or sewer systems.
14. Transport Information
Domestic (USDOT) International (IMDG) Air (IATA) TDG (Canada)
UN Number: N.A. 1950 1950 N.A.
Proper Shipping Name:
Hazard Class: N.A. 2.1 2.1 N.A.
Packing Group: N.A. N.A. N.A. N.A.
Limited Quantity: Yes Yes Yes Yes
Paint Products in
Limited Quantities
Aerosols Aerosols
Paint Products in
Limited Quantities
15. Regulatory Information
U.S. Federal Regulations:
CERCLA - SARA Hazard Category
This product has been reviewed according to the EPA ‘Hazard Categories’ promulgated under Sections 311 and 312 of the
Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to
meet the following categories:
Fire Hazard, Pressure Hazard, Acute Health Hazard, Chronic Health Hazard
Sara Section 313:
This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the
Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:
Chemical Name
Xylene 1330-20-7
Ethylbenzene 100-41-4
CAS-No.
Toxic Substances Control Act:
This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported from
the United States:
Chemical Name
Acetaldehyde 75-07-0
CAS-No.
Date Printed: 8/26/2014
Inventory Information
Country Value
USA (TSCA) No Information
Canada (DSL) No Information
Mexico(INSQ) No Information
Europe (EINECS) No Information
Japan (ENCS) No Information
Philippines (PICCS) No Information
China (IECSC) No Information
Australia (AICS) No Information
Korea (KECI) No Information
New Zealand (NZIOC) No Information
No Information
CALIFORNIA PROPOSITION 65:
Warning: This products contains a substance known to the State of California to cause cancer.
Chemical Name
Ethylbenzene
Titanium Dioxide
CAS-No.
100-41-4
13463-67-7
Page 6 / 7
CALIFORNIA PROPOSITION 65 REPRODUCTIVE TOXINS
Warning: This product contains a substance known to the State of California to cause birth defects or other reproductive
harm.
Chemical Name
Toluene
CAS-No.
108-88-3
International Regulations:
CANADIAN WHMIS:
This SDS has been prepared in compliance with Controlled Product Regulations except for the use of the 16 headings.
16. Other Information
HMIS RATINGS
Health: 2* Flammability: 4 Physical Hazard: 0 Personal Protection: X
CANADIAN WHMIS CLASS: B2 D2A
NFPA RATINGS
Health: 2 Flammability: 4 Instability 0
VOLATILE ORGANIC COMPOUNDS, g/L:
565
MSDS REVISION DATE:
REASON FOR REVISION:
Legend: N.A. - Not Applicable, N.E. - Not Established, N.D. - Not Determined
8/26/2014
No Information
Date Printed: 8/26/2014
Page 7 / 7
Text for GHS Hazard Statements shown in Section 3 describing each ingredient:
H225 Highly flammable liquid and vapour.
H226 Flammable liquid and vapour.
H332 Harmful if inhaled.
Icons for GHS Pictograms shown in Section 3 describing each ingredient:
GHS02
GHS07
Rust-Oleum Corporation believes, to the best of its knowledge, information and belief, the information contained herein to be
accurate and reliable as of the date of this safety data sheet. However, because the conditions of handling, use, and storage of
these materials are beyond our control, we assume no responsibility or liability for personal injury or property damage incurred by
the use of these materials. Rust-Oleum Corporation makes no warranty, expressed or implied, regarding the accuracy or
reliability of the data or results obtained from their use. All materials may present unknown hazards and should be used with
caution. The information and recommendations in this material safety data sheet are offered for the users’ consideration and
examination. It is the responsibility of the user to determine the final suitability of this information and to comply with all applicable
international, federal, state, and local laws and regulations.
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