Rust-Oleum 1686830 User Manual

Date Printed: 8/25/2014
Safety Data Sheet
* Trusted Quality Since 1921 *
www.rustoleum.com
1. Identification
Product Name: IC +SSPR 6PK GLOSS UNIVERSAL GRAY Revision Date: 8/25/2014
Product Identifier: 1686830 Supercedes Date: New SDS
Product Use/Class: Topcoat/Aerosol
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Preparer: Regulatory Department
Emergency Telephone:
Rust-Oleum Corporation 11 Hawthorn Parkway Vernon Hills, IL 60061 USA
24 Hour Hotline: 847-367-7700
Manufacturer:
Rust-Oleum Corporation 11 Hawthorn Parkway Vernon Hills, IL 60061 USA
2. Hazard Identification
EMERGENCY OVERVIEW: May cause eye, skin, or respiratory tract irritation. KEEP OUT OF REACH OF CHILDREN. Harmful if
inhaled. Harmful if swallowed. Causes eye irritation. Use ventilation necessary to keep exposures below recommended exposure limits, if any. Harmful if inhaled. May affect the brain or nervous system causing dizziness, headache or nausea. Vapor Harmful. Causes Eye, Skin, Nose, and Throat Irritation. Extremely flammable liquid and vapor. Vapors may cause flash fire or explosion.
Classification
Symbol(s) of Product
Signal Word
Danger

GHS HAZARD STATEMENTS

Flammable Liquid, category 3 H226 Flammable liquid and vapour. Acute Toxicity, Oral, category 5 H303 May be harmful if swallowed. Acute Toxicity, Dermal, category 5 H313 May be harmful in contact with skin. Skin Irritation, category 2 H315 Causes skin irritation. Eye Irritation, category 2 H319 Causes serious eye irritation. Acute Toxicity, Inhalation, category 4 H332 Harmful if inhaled. STOT, single exposure, category 3, RTI H335 May cause respiratory irritation. STOT, single exposure, category 3, NE H336 May cause drowsiness or dizziness. Organic Peroxide, categories C, D H242 Heating may cause a fire. Aspiration Hazard, category 2 H305 May be harmful if swallowed and enters airways. Eye Irritation, category 2B H320 Causes eye irritation. Flammable Liquid, category 1 H224 Extremely flammable liquid and vapour.

GHS PRECAUTIONARY STATEMENTS

P102 Keep out of reach of children. P103 Read label before use. P202 Do not handle until all safety precautions have been read and understood.
Date Printed: 8/25/2014
67-64-1
68476-86-8
64742-49-0
1330-20-7
1317-80-2
64742-88-7
100-41-4
5131-66-8
P234 Keep only in original container. P260 Do not breathe dust/fume/gas/mist/vapours/spray. P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P262 Do not get in eyes, on skin, or on clothing. P264 Wash … thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P271 Use only outdoors or in a well-ventilated area. P273 Avoid release to the environment. P280 Wear protective gloves/protective clothing/eye protection/face protection. P281 Use personal protective equipment as required. P285 In case of inadequate ventilation wear respiratory protection. P312 Call a POISON CENTER or doctor/physician if you feel unwell. P351 Rinse cautiously with water for several minutes. P374 Fight fire with normal precautions from a reasonable distance. P402 Store in a dry place. P211 Do not spray on an open flame or other ignition source. P220 Keep/Store away from clothing/…/combustible materials. P375 Fight fire remotely due to the risk of explosion. P210 Keep away from heat/sparks/open flames/hot surfaces. – No smoking. P240 Ground/bond container and receiving equipment. P241 Use explosion-proof electrical/ventilating/lighting/…/ equipment. P242 Use only non-sparking tools. P243 Take precautionary measures against static discharge. P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin
with water/shower. P370+P378 In case of fire: Use … for extinction. P403+P235 Store in a well-ventilated place. Keep cool. P501 Dispose of contents/container to … P321 Specific treatment (see … on this label). P352 Wash with plenty of soap and water. P362 Take off contaminated clothing and wash before reuse. P332+P313 If skin irritation occurs: Get medical advice/attention. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. P337+P313 If eye irritation persists: Get medical advice/attention. P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for
breathing. P405 Store locked up. P403+P233 Store in a well-ventilated place. Keep container tightly closed. P302+P350 IF ON SKIN: Gently wash with plenty of soap and water. P420 Store away from other materials. P411+P235 Store at temperatures not exceeding …°C/…°F. Keep cool. P235+P410 Keep cool. Protect from sunlight.
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3. Composition/Information On Ingredients
HAZARDOUS SUBSTANCES
Chemical Name CAS-No. Wt.%
Range
Acetone Liquefied Petroleum Gas Naphtha, Petroleum, Hydrotreated Light Xylene Titanium Dioxide Mineral Spirits Ethylbenzene Propylene Glycol Monobutyl Ether
25-50 25-50
2.5-10
2.5-10
2.5-10
1.0-2.5
1.0-2.5
1.0-2.5
GHS Symbols
GHS02
GHS02
GHS06 GHS02-GHS07 GHS02-GHS07
GHS Statements
H225
H226
H331 H225-332 H226-302
Date Printed: 8/25/2014
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The text for GHS Hazard Statements shown above (if any) is given in the "16. Other Information" section.
4. First-aid Measures
FIRST AID - EYE CONTACT: Immediately flush eyes with plenty of water for at least 15 minutes holding eyelids open. Get medical
attention. Do NOT allow rubbing of eyes or keeping eyes closed.
FIRST AID - SKIN CONTACT: Wash skin with soap and water. Remove contaminated clothing. Get medical attention if irritation develops or persists.
FIRST AID - INHALATION: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get immediate medical attention. Do NOT use mouth-to-mouth resuscitation. If you experience difficulty in breathing, leave the area to obtain fresh air. If continued difficulty is experienced, get medical assistance immediately.
FIRST AID - INGESTION: If swallowed, get medical attention.
5. Fire-fighting Measures
EXTINGUISHING MEDIA:
Alcohol Film Forming Foam, Carbon Dioxide, Dry Chemical, Water Fog
UNUSUAL FIRE AND EXPLOSION HAZARDS: No unusual fire or explosion hazards noted. Closed containers may explode when exposed to extreme heat due to buildup of steam. Keep containers tightly closed. Isolate from heat, electrical equipment, sparks and open flame. FLASH POINT IS LESS THAN 20 °. F. - EXTREMELY FLAMMABLE LIQUID AND VAPOR!Water spray may be ineffective. Closed containers may explode when exposed to extreme heat. Vapors may form explosive mixtures with air. Vapors can travel to a source of ignition and flash back. Perforation of the pressurized container may cause bursting of the can.
SPECIAL FIREFIGHTING PROCEDURES: Water may be used to cool closed containers to prevent pressure buildup and possible autoignition or explosion. Evacuate area and fight fire from a safe distance. Use water spray to keep fire-exposed containers cool. Containers may explode when heated. Full protective equipment including self-contained breathing apparatus should be used.
6. Accidental Release Measures
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Remove all sources of ignition, ventilate area and remove with
inert absorbent and non-sparking tools. Dispose of according to local, state (provincial) and federal regulations. Do not incinerate closed containers. Ventilate area, isolate spilled material, and remove with inert absorbent. Dispose of contaminated absorbent, container, and unused contents in accordance with local, state, and federal regulations. Contain spilled liquid with sand or earth. DO NOT use combustible materials such as sawdust. Isolate the hazard area and deny entry to unnecessary and unprotected personnel.
7. Handling and Storage
HANDLING: Wash thoroughly after handling. Wash hands before eating. Remove contaminated clothing and launder before reuse.
Use only with adequate ventilation. Follow all MSDS/label precautions even after container is emptied because it may retain product residues. Avoid breathing fumes, vapors, or mist. Avoid contact with eyes, skin and clothing.
STORAGE: Product should be stored in tightly sealed containers and protected from heat, moisture, and foreign materials. Store in a dry, well ventilated place. Keep container tightly closed when not in use. Keep containers tightly closed. Isolate from heat, electrical equipment, sparks and open flame. Keep away from heat, sparks, flame and sources of ignition. Avoid excess heat. Do not store above 120 ° F. Store large quantities in buildings designed and protected for storage of NFPA Class II combustible liquids.
8. Exposure Controls/Personal Protection
Chemical Name CAS-No.
Acetone 67-64-1 35.0 500 ppm 750 ppm 1000 ppm N.E. Liquefied Petroleum Gas 68476-86-8 30.0 N.E. N.E. N.E. N.E. Naphtha, Petroleum, Hydrotreated Light Xylene 1330-20-7 10.0 100 ppm 150 ppm 100 ppm N.E.
Titanium Dioxide 1317-80-2 10.0 10 mg/m3 N.E.
Mineral Spirits 64742-88-7 5.0 100 ppm N.E. 100 ppm N.E. Ethylbenzene 100-41-4 5.0 20 ppm 125 ppm 100 ppm N.E. Propylene Glycol Monobutyl Ether
64742-49-0 10.0 200 mg/m3 N.E. N.E. N.E.
5131-66-8 5.0 N.E. N.E. N.E. N.E.
Weight %
Less Than
PERSONAL PROTECTION
ACGIH TLV-
TWA
ACGIH TLV-
STEL
OSHA PEL-TWA
15 mg/m3 (Total
Dust)
OSHA PEL-
CEILING
N.E.
Date Printed: 8/25/2014
ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below recommended exposure limits. Prevent build-up of vapors by opening all doors and windows to achieve cross­ventilation. Use explosion-proof ventilation equipment. Provide general dilution of local exhaust ventilation in volume and pattern to keep TLV of hazardous ingredients below acceptable limits.
RESPIRATORY PROTECTION: A respiratory protection program that meets OSHA 1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirator's use. A NIOSH/MSHA approved air purifying respirator with organic vapor cartridge or canister may be permissible under certain circumstances where airborne concentrations are expected to exceed exposure limits.
SKIN PROTECTION: Use gloves to prevent prolonged skin contact. Nitrile or Neoprene gloves may afford adequate skin protection.
EYE PROTECTION: Use safety eyewear designed to protect against splash of liquids.
OTHER PROTECTIVE EQUIPMENT: Refer to safety supervisor or industrial hygienist for further guidance regarding types of
personal protective equipment and their applications.
HYGIENIC PRACTICES: Wash thoroughly with soap and water before eating, drinking or smoking. Remove contaminated clothing immediately and launder before reuse.
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9. Physical and Chemical Properties
Appearance: Odor: Relative Density: Freeze Point, °C: Solubility in Water: Decompostion Temp., °C: Boiling Range, °C: Flammability: Evaporation Rate: Vapor Density:
(See "Other information" Section for abbreviation legend)
Aerosolized Mist Solvent Like
0.761 ND Slight No Information
-34 - 662 Supports Combustion Faster than Ether Heavier than Air
Physical State: Odor Threshold: pH: Viscosity: Partition Coefficient, n-octanol/
water:
Explosive Limits, vol%: Flash Point, °C: Auto-ignition Temp., °C: Vapor Pressure:
Liquid N.E. N.A. N.D.
No Information
0.7 - 13.0
-105 No Information ND
10. Stability and Reactivity
CONDITIONS TO AVOID: Avoid temperatures above 120 ° F. Avoid contact with strong acid and strong bases. Avoid all possible
sources of ignition.
INCOMPATIBILITY: Incompatible with strong oxidizing agents, strong acids and strong alkalies.
HAZARDOUS DECOMPOSITION: By open flame, carbon monoxide and carbon dioxide. When heated to decomposition, it emits
acrid smoke and irritating fumes. Contains solvents which may form carbon monoxide, carbon dioxide, and formaldehyde.
HAZARDOUS POLYMERIZATION: Will not occur under normal conditions.
STABILITY: This product is stable under normal storage conditions.
11. Toxicological information
EFFECTS OF OVEREXPOSURE - EYE CONTACT: Causes Serious Eye Irritation
EFFECTS OF OVEREXPOSURE - SKIN CONTACT: Causes skin irritation. Allergic reactions are possible. May cause skin
irritation. Allergic reactions are possible.
EFFECTS OF OVEREXPOSURE - INHALATION: Harmful if inhaled. High gas, vapor, mist or dust concentrations may be harmful if inhaled. Avoid breathing fumes, spray, vapors, or mist. High vapor concentrations are irritating to the eyes, nose, throat and lungs. Prolonged or excessive inhalation may cause respiratory tract irritation.
EFFECTS OF OVEREXPOSURE - INGESTION: Harmful if swallowed.
EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS: IARC lists Ethylbenzene as a possible human carcinogen (group 2B).
Overexposure to xylene in laboratory animals has been associated with liver abnormalities, kidney, lung, spleen, eye and blood damage as well as reproductive disorders. Effects in humans, due to chronic overexposure, have included liver, cardiac abnormalities and nervous system damage. Contains Titanium Dioxide. Titanium Dioxide is listed as a Group 2B-"Possibly carcinogenic to humans" by IARC. No significant exposure to Titanium Dioxide is thought to occur during the use of products in which Titanium Dioxide is bound to other materials, such as in paints during brush application or drying. Risk of overexposure depends on duration and level of exposure to dust from repeated sanding of surfaces or spray mist and the actual concentration of Titanium Dioxide in the formula. (Ref: IARC Monograph, Vol. 93, 2010)High concentrations may lead to central nervous system effects (drowsiness, dizziness, nausea, headaches, paralysis, and blurred vision) and/or damage. Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. May cause central nervous system disorder (e.g., narcosis involving a loss of coordination, weakness, fatigue, mental confusion, and blurred vision) and/or
Date Printed: 8/25/2014
damage.
PRIMARY ROUTE(S) OF ENTRY: Eye Contact, Ingestion, Inhalation, Skin Absorption, Skin Contact
ACUTE TOXICITY VALUES The acute effects of this product have not been tested. Data on individual components are tabulated below:
CAS-No.
64742-49-0 Naphtha, Petroleum, Hydrotreated Light >5000 mg/kg Rat >3160 mg/kg Rabbit N.I. 1330-20-7 Xylene 4300 mg/kg Rat N.I. 47635 mg/L Rat 64742-88-7 Mineral Spirits >5000 mg/kg Rat 3000 mg/kg Rabbit >5.28 mg/L Rat 100-41-4 Ethylbenzene 3500 mg/kg Rat 15354 mg/kg Rabbit 17.2 mg/L Rat 5131-66-8 Propylene Glycol Monobutyl Ether 1900 mg/kg Rat N.I. N.I.
N.I. - No Information
Chemical Name Oral LD50 Dermal LD50 Vapor LC50
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12. Ecological Information
ECOLOGICAL INFORMATION: Product is a mixture of listed components.
13. Disposal Information
DISPOSAL INFORMATION: Dispose of material in accordance to local, state, and federal regulations and ordinances. Do not allow
to enter waterways, wastewater, soil, storm drains or sewer systems.
14. Transport Information
Domestic (USDOT) International (IMDG) Air (IATA) TDG (Canada)
UN Number: N.A. 1950 1950 N.A.
Proper Shipping Name:
Hazard Class: N.A. 2.1 2.1 N.A.
Packing Group: N.A. N.A. N.A. N.A.
Limited Quantity: Yes Yes Yes Yes
Paint Products in
Limited Quantities
Aerosols Aerosols
Paint Products in
Limited Quantities
15. Regulatory Information
U.S. Federal Regulations:
CERCLA - SARA Hazard Category
This product has been reviewed according to the EPA ‘Hazard Categories’ promulgated under Sections 311 and 312 of the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to meet the following categories:
Fire Hazard, Pressure Hazard, Acute Health Hazard, Chronic Health Hazard
Sara Section 313:
This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:
Chemical Name
Xylene 1330-20-7 Ethylbenzene 100-41-4
CAS-No.
Toxic Substances Control Act:
This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported from the United States:
No TSCA components exist in this product.
Date Printed: 8/25/2014
Inventory Information
Country Value
USA (TSCA) No Information Canada (DSL) No Information Mexico(INSQ) No Information Europe (EINECS) No Information Japan (ENCS) No Information Philippines (PICCS) No Information China (IECSC) No Information Australia (AICS) No Information Korea (KECI) No Information New Zealand (NZIOC) No Information
No Information
CALIFORNIA PROPOSITION 65:
Warning: This products contains a substance known to the State of California to cause cancer.
Chemical Name
Titanium Dioxide Ethylbenzene
CAS-No.
1317-80-2 100-41-4
CALIFORNIA PROPOSITION 65 REPRODUCTIVE TOXINS
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Warning: This product contains a substance known to the State of California to cause birth defects or other reproductive harm.
No Proposition 65 Reproductive Toxins exist in this product.
International Regulations:
CANADIAN WHMIS:
This SDS has been prepared in compliance with Controlled Product Regulations except for the use of the 16 headings.
16. Other Information
HMIS RATINGS
Health: 2* Flammability: 4 Physical Hazard: 0 Personal Protection: X
CANADIAN WHMIS CLASS: B2 D2A
NFPA RATINGS
Health: 2 Flammability: 4 Instability 0
VOLATILE ORGANIC COMPOUNDS, g/L:
MSDS REVISION DATE:
REASON FOR REVISION:
8/25/2014
No Information
515
Legend: N.A. - Not Applicable, N.E. - Not Established, N.D. - Not Determined
Date Printed: 8/25/2014
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Text for GHS Hazard Statements shown in Section 3 describing each ingredient:
H225 Highly flammable liquid and vapour. H226 Flammable liquid and vapour. H302 Harmful if swallowed. H331 Toxic if inhaled. H332 Harmful if inhaled.
Icons for GHS Pictograms shown in Section 3 describing each ingredient:
GHS02
GHS06
GHS07
Rust-Oleum Corporation believes, to the best of its knowledge, information and belief, the information contained herein to be accurate and reliable as of the date of this safety data sheet. However, because the conditions of handling, use, and storage of these materials are beyond our control, we assume no responsibility or liability for personal injury or property damage incurred by the use of these materials. Rust-Oleum Corporation makes no warranty, expressed or implied, regarding the accuracy or reliability of the data or results obtained from their use. All materials may present unknown hazards and should be used with caution. The information and recommendations in this material safety data sheet are offered for the users’ consideration and examination. It is the responsibility of the user to determine the final suitability of this information and to comply with all applicable international, federal, state, and local laws and regulations.
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