Date Printed: 4/23/2015
Safety Data Sheet
1. Identification
Page 1 / 6
* Trusted Quality Since 1921 *
www.rustoleum.com
Product Name:
Product Identifier: 108402 Supercedes Date: 9/15/2014
Product Use/Class: Cleaner
Supplier:
Preparer: Regulatory Department
Emergency Telephone:
FLOOR 1-GL 2PK ANTSLP CLEAN & ETCH
SOLN
Rust-Oleum Corporation
11 Hawthorn Parkway
Vernon Hills, IL 60061
USA
24 Hour Hotline: 847-367-7700
Revision Date: 4/23/2015
Manufacturer:
Rust-Oleum Corporation
11 Hawthorn Parkway
Vernon Hills, IL 60061
USA
2. Hazard Identification
EMERGENCY OVERVIEW: Causes severe skin and eye burns. Do not taste or swallow. Harmful if swallowed. Causes Serious
Eye Irritation. Causes skin irritation. May cause eye, skin, or respiratory tract irritation. KEEP OUT OF REACH OF CHILDREN.
Harmful if inhaled. Causes eye irritation. Use ventilation necessary to keep exposures below recommended exposure limits, if any.
Classification
Symbol(s) of Product
Signal Word
Danger
GHS HAZARD STATEMENTS
Acute Toxicity, Dermal, category 5 H313 May be harmful in contact with skin.
Skin Irritation, category 2 H315 Causes skin irritation.
Aspiration Hazard, category 2 H305 May be harmful if swallowed and enters airways.
Skin Irritation, category 3 H316 Causes mild skin irritation.
Eye Irritation, category 2B H320 Causes eye irritation.
Acute Toxicity, Inhalation, category 4 H332 Harmful if inhaled.
Skin Corrosion, category 1 H314 Causes severe skin burns and eye damage.
GHS PRECAUTIONARY STATEMENTS
P102 Keep out of reach of children.
P103 Read label before use.
P202 Do not handle until all safety precautions have been read and understood.
P234 Keep only in original container.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P262 Do not get in eyes, on skin, or on clothing.
P264 Wash … thoroughly after handling.
Date Printed: 4/23/2015
7664-38-2
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P281 Use personal protective equipment as required.
P285 In case of inadequate ventilation wear respiratory protection.
P312 Call a POISON CENTER or doctor/physician if you feel unwell.
P335 Brush off loose particles from skin.
P351 Rinse cautiously with water for several minutes.
P374 Fight fire with normal precautions from a reasonable distance.
P402 Store in a dry place.
P321 Specific treatment (see … on this label).
P352 Wash with plenty of soap and water.
P362 Take off contaminated clothing and wash before reuse.
P332+P313 If skin irritation occurs: Get medical advice/attention.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for
breathing.
P310 Immediately call a POISON CENTER or doctor/physician.
P363 Wash contaminated clothing before reuse.
P301+P330+P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin
with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
P405 Store locked up.
P501 Dispose of contents/container to …
P302+P350 IF ON SKIN: Gently wash with plenty of soap and water.
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3. Composition/Information On Ingredients
HAZARDOUS SUBSTANCES
Chemical Name CAS-No. Wt.%
Range
Phosphoric Acid
The text for GHS Hazard Statements shown above (if any) is given in the "16. Other Information" section.
25-50
GHS Symbols
GHS05-GHS07
GHS Statements
H290-302-314-332
4. First-aid Measures
FIRST AID - EYE CONTACT: Immediately flush eyes with plenty of water for at least 15 minutes holding eyelids open. Get medical
attention. Do NOT allow rubbing of eyes or keeping eyes closed.
FIRST AID - SKIN CONTACT: Remove contaminated clothing. Wash skin with soap and water. Get medical attention. Wash skin
with soap and water. Remove contaminated clothing. Get medical attention if irritation develops or persists.
FIRST AID - INHALATION: If affected by inhalation of dust, vapor or spray mist, remove to fresh air. If breathing difficulty persists,
get medical attention immediately. If you experience difficulty in breathing, leave the area to obtain fresh air. If continued difficulty is
experienced, get medical assistance immediately. Remove to fresh air. If not breathing, give artificial respiration. If breathing is
difficult, give oxygen. Get immediate medical attention. Do NOT use mouth-to-mouth resuscitation.
FIRST AID - INGESTION: Swallowing less than an ounce will not cause significant harm. For larger amounts, do not induce
vomiting, but give one or two glasses of water to drink and get medical attention. If swallowed, rinse mouth with water. If feeling
unwell, get medical attention.
5. Fire-fighting Measures
EXTINGUISHING MEDIA:
UNUSUAL FIRE AND EXPLOSION HAZARDS: No unusual fire or explosion hazards noted. FLASH POINT IS TESTED TO BE
GREATER THAN 200 DEGREES F. Keep containers tightly closed.
Alcohol Film Forming Foam, Carbon Dioxide, Dry Chemical, Dry Sand, Water Fog
Date Printed: 4/23/2015
SPECIAL FIREFIGHTING PROCEDURES: Use water spray to keep fire-exposed containers cool. Containers may explode when
heated. Water may be used to cool closed containers to prevent buildup of steam. If water is used, fog nozzles are preferred.
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6. Accidental Release Measures
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Neutralize liquid acid spills with sodium bicarbonate (NaHCO3).
If spilled, contain spilled material and remove with inert absorbent. Dispose of contaminated absorbent, container, and unused
contents in accordance with local, state, and federal regulations. Do not incinerate closed containers
7. Handling and Storage
HANDLING: Wash thoroughly after handling. Follow all MSDS/label precautions even after container is emptied because it may
retain product residues. Wash hands before eating. Remove contaminated clothing and launder before reuse. Use only with
adequate ventilation. Avoid breathing fumes, vapors, or mist. Avoid contact with eyes, skin and clothing.
STORAGE: Keep away from heat, sparks, flame and sources of ignition. Keep from freezing. Store in a dry, well ventilated place.
Keep container tightly closed when not in use.
8. Exposure Controls/Personal Protection
Chemical Name CAS-No.
Phosphoric Acid 7664-38-2 30.0 1 mg/m3 3 mg/m3 1 mg/m3 N.E.
PERSONAL PROTECTION
ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne
levels below recommended exposure limits. Prevent build-up of vapors by opening all doors and windows to achieve crossventilation.
RESPIRATORY PROTECTION: A respiratory protection program that meets OSHA 1910.134 and ANSI Z88.2 requirements must be
followed whenever workplace conditions warrant a respirator's use.
SKIN PROTECTION: Where contact is likely, wear chemical resistant gloves, a chemical suit, rubber boots and chemical safety
goggles plus a face shield. Use gloves to prevent prolonged skin contact. Nitrile or Neoprene gloves may afford adequate skin
protection.
EYE PROTECTION: Use safety eyewear designed to protect against splash of liquids.
OTHER PROTECTIVE EQUIPMENT: Refer to safety supervisor or industrial hygienist for further information regarding personal
protective equipment and its application. Refer to safety supervisor or industrial hygienist for further guidance regarding types of
personal protective equipment and their applications.
HYGIENIC PRACTICES: Wash thoroughly with soap and water before eating, drinking or smoking. Remove contaminated clothing
immediately and launder before reuse.
Weight %
Less Than
ACGIH TLV-
TWA
ACGIH TLV-
STEL
OSHA PEL-TWA
OSHA PEL-
CEILING
9. Physical and Chemical Properties
Appearance:
Odor:
Relative Density:
Freeze Point, °C:
Solubility in Water:
Decompostion Temp., °C:
Boiling Range, °C:
Flammability:
Evaporation Rate:
Vapor Density:
Liquid
Solvent Like
1.139
N.D.
Miscible
No Information
212 - 392
Supports Combustion
Slower than Ether
Heavier than Air
Physical State:
Odor Threshold:
pH:
Viscosity:
Partition Coefficient, n-octanol/
water:
Explosive Limits, vol%:
Flash Point, °C:
Auto-ignition Temp., °C:
Vapor Pressure:
Liquid
N.E.
N.A.
No Information
No Information
N.A. - N.A.
>93
No Information
No Information
(See "Other information" Section for abbreviation legend)
10. Stability and Reactivity
CONDITIONS TO AVOID: Avoid contact with strong reducing or oxidizing agents. Avoid contact with strong acid and strong bases.
INCOMPATIBILITY: Incompatible with strong oxidizing agents, strong acids and strong alkalies. Avoid contact with strong oxidizing
and reducing agents.
Date Printed: 4/23/2015
HAZARDOUS DECOMPOSITION: By open flame, carbon monoxide and carbon dioxide. When heated to decomposition, it emits
acrid smoke and irritating fumes.
HAZARDOUS POLYMERIZATION: Will not occur under normal conditions.
STABILITY: This product is stable under normal storage conditions.
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11. Toxicological information
EFFECTS OF OVEREXPOSURE - EYE CONTACT: Irritating, and may injure eye tissue if not removed promptly. Causes Serious
Eye Irritation
EFFECTS OF OVEREXPOSURE - SKIN CONTACT: Substance is corrosive. Causes severe skin burns. Corrosive; causes skin
burning. Low hazard for usual industrial handling or commercial handling by trained personnel.
EFFECTS OF OVEREXPOSURE - INHALATION: Avoid breathing fumes, spray, vapors, or mist. High gas, vapor, mist or dust
concentrations may be harmful if inhaled.
EFFECTS OF OVEREXPOSURE - INGESTION: Substance may be harmful if swallowed.
EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS: Effects of overexposure may include irritation of the nose and throat,
irritation of the digestive tract and signs of nervous system depression (e.g., headache, drowsiness, loss of coordination and fatigue).
PRIMARY ROUTE(S) OF ENTRY: Eye Contact, Ingestion, Inhalation, Skin Absorption, Skin Contact
ACUTE TOXICITY VALUES
The acute effects of this product have not been tested. Data on individual components are tabulated below:
CAS-No. Chemical Name Oral LD50 Dermal LD50 Vapor LC50
7664-38-2 Phosphoric Acid 1530 mg/kg Rat 2730 mg/kg Rabbit N.I.
N.I. - No Information
12. Ecological Information
ECOLOGICAL INFORMATION: Product is a mixture of listed components. Product is a mixture of listed components.
13. Disposal Information
DISPOSAL INFORMATION: Dispose of material in accordance to local, state, and federal regulations and ordinances. Do not allow
to enter waterways, wastewater, soil, storm drains or sewer systems.
14. Transport Information
Domestic (USDOT) International (IMDG) Air (IATA) TDG (Canada)
UN Number: N.A. 3066 3066 N.A.
Proper Shipping Name:
Hazard Class: N.A. 8 8 N.A.
Packing Group: N.A. III III N.A.
Limited Quantity: No Yes No No
Paint Products in
Limited Quantities
Paint and Paint Related
Products
Paint and Paint
Related Products
Paint Products in
Limited Quantities
15. Regulatory Information
Date Printed: 4/23/2015
U.S. Federal Regulations:
CERCLA - SARA Hazard Category
This product has been reviewed according to the EPA ‘Hazard Categories’ promulgated under Sections 311 and 312 of the
Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to
meet the following categories:
Acute Health Hazard, Chronic Health Hazard
Sara Section 313:
This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the
Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:
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Chemical Name
Phosphoric Acid 7664-38-2
CAS-No.
Toxic Substances Control Act:
This product contains the following chemical substances subject to the reporting requirements of TSCA 12(b) if exported from
the United States:
No TSCA 12(b) components exist in this product.
CALIFORNIA PROPOSITION 65:
No Proposition 65 Carcinogens exist in this product.
CALIFORNIA PROPOSITION 65 REPRODUCTIVE TOXINS
No Proposition 65 Reproductive Toxins exist in this product.
International Regulations:
CANADIAN WHMIS:
This SDS has been prepared in compliance with Controlled Product Regulations except for the use of the 16 headings.
16. Other Information
HMIS RATINGS
Health: 2* Flammability: 1 Physical Hazard: 0 Personal Protection: X
CANADIAN WHMIS CLASS: D2A
NFPA RATINGS
Health: 2 Flammability: 1 Instability 0
VOLATILE ORGANIC COMPOUNDS, g/L:
MSDS REVISION DATE:
REASON FOR REVISION:
Legend: N.A. - Not Applicable, N.E. - Not Established, N.D. - Not Determined
4/23/2015
No Information
0
Date Printed: 4/23/2015
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Text for GHS Hazard Statements shown in Section 3 describing each ingredient:
H290 May be corrosive to metals.
H302 Harmful if swallowed.
H314 Causes severe skin burns and eye damage.
H332 Harmful if inhaled.
Icons for GHS Pictograms shown in Section 3 describing each ingredient:
GHS05
GHS07
Rust-Oleum Corporation believes, to the best of its knowledge, information and belief, the information contained herein to be
accurate and reliable as of the date of this safety data sheet. However, because the conditions of handling, use, and storage of
these materials are beyond our control, we assume no responsibility or liability for personal injury or property damage incurred by
the use of these materials. Rust-Oleum Corporation makes no warranty, expressed or implied, regarding the accuracy or
reliability of the data or results obtained from their use. All materials may present unknown hazards and should be used with
caution. The information and recommendations in this material safety data sheet are offered for the users’ consideration and
examination. It is the responsibility of the user to determine the final suitability of this information and to comply with all applicable
international, federal, state, and local laws and regulations.
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