Rubbermaid Commercial FG401692 User Manual

CINNAMON SPICE MB9000

Safety Data Sheet

according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Date of issue: 03/11/2015 Version: 1.0

05/20/2015

EN (English)

Page 1

Product name

CINNAMON SPICE MB9000

Product code

1830284

SKU #

FG401692

Use of the substance/mixture

Aerosol For professional use only Air care products Odour agents

Emergency number

24-Hour Emergency: INFOTRAC: 1-800535-5063

Flam. Aerosol 1

H222

Skin Irrit. 2

H315

Eye Irrit. 2A

H319

Skin Sens. 1

H317

STOT SE 3

H335

Hazard pictograms (GHS-US)

GHS02

GHS07

Signal word (GHS-US)

Danger

Hazard statements (GHS-US)

H222 - Extremely flammable aerosol H315 - Causes skin irritation H317 - May cause an allergic skin reaction H319 - Causes serious eye irritation H335 - May cause respiratory irritation

Precautionary statements (GHS-US)

P211 - Do not spray on an open flame or other ignition source P251 - Pressurized container: Do not pierce or burn, even after use P280 - Wear protective gloves P302+P352 - If on skin: Wash with plenty of water P304+P340 - If inhaled: Remove person to fresh air and keep comfortable for breathing P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P312 - Call a doctor if you feel unwell P333+P313 - If skin irritation or rash occurs: Get medical advice/attention P337+P313 - If eye irritation persists: Get medical advice/attention P410+P412 - Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

1.2. Relevant identified uses of the substance or mixture and uses advised against

1.3. Details of the supplier of the safety data sheet

Rubbermaid Commercial Products LLC 3124 Valley Avenue Winchester, VA 22601-2694 - USA T (540) 6678700

www.rubbermaidcommercial.com

1.4. Emergency telephone number

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture GHS-US classification

Full text of H-phrases: see section 16

2.2. Label elements GHS-US labelling

2.3. Other hazards

No additional information available

CINNAMON SPICE MB9000

Safety Data Sheet

according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

05/20/2015

EN (English)

2/9

Name

Product identifier

GHS-US classification

Alcohol

(CAS No) 64-17-5

20 - 50

Flam. Liq. 2, H225 Skin Irrit. 2, H315 Eye Irrit. 2A, H319 STOT SE 3, H335

HEXYLENE GLYCOL

(CAS No) 107-41-5

10 - 20

Skin Irrit. 2, H315 Eye Irrit. 2A, H319

EUGENOL

(CAS No) 97-53-0

0,1 - 1

Eye Irrit. 2A, H319 Skin Sens. 1, H317

a-METHYLCINNAMALDEHYDE

(CAS No) 101-39-3

0,1 - 1

Skin Sens. 1, H317

CINNAMYL ALCOHOL

(CAS No) 104-54-1

0,1 - 1

Acute Tox. 4 (Oral), H302 Skin Sens. 1, H317

PHELANDRENE

(CAS No) 1329-99-3

0,1 - 1

Flam. Liq. 3, H226 Acute Tox. 4 (Oral), H302 Asp. Tox. 1, H304

DIHYDROEUGENOL

(CAS No) 2785-87-7

0,1 - 1

Eye Irrit. 2A, H319 Skin Sens. 1, H317

LIMONENE

(CAS No) 5989-27-5

< 0,1

Flam. Liq. 3, H226 Skin Irrit. 2, H315 Skin Sens. 1, H317 Asp. Tox. 1, H304 Aquatic Acute 1, H400 Aquatic Chronic 1, H410

First-aid measures general

Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible).

First-aid measures after inhalation

Cough. Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell.

First-aid measures after skin contact

Remove/Take off immediately all contaminated clothing. If skin irritation persists, take medical advice. Wash with plenty of soap and water. Wash contaminated clothing before reuse.

First-aid measures after eye contact

Rinse cautiously with water for several minutes. Direct contact with the eyes is likely to be irritating. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.

First-aid measures after ingestion

Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention.

Symptoms/injuries after inhalation

Shortness of breath. May cause an allergic skin reaction. May cause respiratory irritation.

Symptoms/injuries after skin contact

Causes skin irritation.

Symptoms/injuries after eye contact

Causes serious eye irritation.

Suitable extinguishing media

Foam. Dry powder. Carbon dioxide. Water spray. Sand.

Unsuitable extinguishing media

Do not use a heavy water stream.

Fire hazard

Extremely flammable aerosol.

Explosion hazard

May form flammable/explosive vapour-air mixture. Heat may build pressure, rupturing closed containers, spreading fire and increasing risk of burns and injuries.

Reactivity

Stable under normal conditions of use.

2.4. Unknown acute toxicity (GHS US)

Not applicable

SECTION 3: Composition/information on ingredients

3.1. Substance

Not applicable

3.2. Mixture

Full text of H-phrases: see section 16

SECTION 4: First aid measures

4.1. Description of first aid measures

4.2. Most important symptoms and effects, both acute and delayed

4.3. Indication of any immediate medical attention and special treatment needed

No additional information available

SECTION 5: Firefighting measures

5.1. Extinguishing media

5.2. Special hazards arising from the substance or mixture

CINNAMON SPICE MB9000

Safety Data Sheet

according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

05/20/2015

EN (English)

3/9

Firefighting instructions

Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment. DO NOT fight fire when fire reaches explosives. Evacuate area.

Protection during firefighting

Do not enter fire area without proper protective equipment, including respiratory protection.

General measures

No open flames. No smoking. Isolate from fire, if possible, without unnecessary risk. Remove ignition sources. Use special care to avoid static electric charges.

Emergency procedures

Evacuate unnecessary personnel.

Protective equipment

Equip cleanup crew with proper protection.

Emergency procedures

Ventilate area.

Methods for cleaning up

Ventilate spillage area. Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials.

Additional hazards when processed

Handle empty containers with care because residual vapours are flammable. Hazardous waste due to potential risk of explosion. Pressurized container: Do not pierce or burn, even after use.

Precautions for safe handling

No open flames. No smoking. Use only non-sparking tools. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapour. Do not spray on an open flame or other ignition source.

Hygiene measures

Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reuse.

Technical measures

Comply with applicable regulations. Proper grounding procedures to avoid static electricity should be followed.

Storage conditions

Keep only in the original container in a cool, well ventilated place away from : Direct sunlight, Heat sources, Ignition sources. Do not expose to temperatures exceeding 50 °C/ 122 °F.

Incompatible products

Strong bases. Strong acids.

Incompatible materials

Sources of ignition. Direct sunlight. Heat sources.

CINNAMON SPICE MB9000

ACGIH

Not applicable

OSHA

Not applicable

EUGENOL (97-53-0)

ACGIH

Not applicable

OSHA

Not applicable

LIMONENE (5989-27-5)

ACGIH

Not applicable

5.3. Advice for firefighters

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

6.1.1. For non-emergency personnel

6.1.2. For emergency responders

6.2. Environmental precautions

Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters.

6.3. Methods and material for containment and cleaning up

6.4. Reference to other sections

See Heading 8. Exposure controls and personal protection.

SECTION 7: Handling and storage

7.1. Precautions for safe handling

7.2. Conditions for safe storage, including any incompatibilities

7.3. Specific end use(s)

No additional information available

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

CINNAMON SPICE MB9000

Safety Data Sheet

according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

05/20/2015

EN (English)

4/9

LIMONENE (5989-27-5)

OSHA

Not applicable

Alcohol (64-17-5)

ACGIH

ACGIH STEL (ppm)

1000 ppm

ACGIH

Remark (ACGIH)

URT irr

OSHA

OSHA PEL (TWA) (mg/m³)

1900 mg/m³

OSHA

OSHA PEL (TWA) (ppm)

1000 ppm

HEXYLENE GLYCOL (107-41-5)

ACGIH

ACGIH Ceiling (ppm)

25 ppm

ACGIH

Remark (ACGIH)

Eye & URT irr

OSHA

Not applicable

a-METHYLCINNAMALDEHYDE (101-39-3)

ACGIH

Not applicable

OSHA

Not applicable

CINNAMYL ALCOHOL (104-54-1)

ACGIH

Not applicable

OSHA

Not applicable

PHELANDRENE (1329-99-3)

ACGIH

Not applicable

OSHA

Not applicable

DIHYDROEUGENOL (2785-87-7)

ACGIH

Not applicable

OSHA

Not applicable

Appropriate engineering controls

Provide local exhaust or general room ventilation to minimize mist and/or vapour concentrations.

Personal protective equipment

Avoid all unnecessary exposure.

Hand protection

Wear protective gloves.

Eye protection

None under normal use.

Respiratory protection

None under normal use.

Other information

Do not eat, drink or smoke during use.

Physical state

Liquid

Appearance

Clear Transparent Liquid.

Colour

colourless to slightly yellow

Odour

characteristic

Odour threshold

No data available

pH : No data available

Relative evaporation rate (butylacetate=1)

No data available

Melting point

No data available

Freezing point

No data available

Boiling point

No data available

Flash point

No data available

Auto-ignition temperature

No data available

8.2. Exposure controls

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

CINNAMON SPICE MB9000

Safety Data Sheet

according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

05/20/2015

EN (English)

5/9

Decomposition temperature

No data available

Flammability (solid, gas)

Extremely flammable aerosol

Vapour pressure

4,5 - 5,5 bar

Relative vapour density at 20 °C

No data available

Relative density

0,7

Solubility

No data available

Log Pow

No data available

Log Kow

No data available

Viscosity, kinematic

No data available

Viscosity, dynamic

No data available

Explosive properties

No data available

Oxidising properties

No data available

Explosive limits

1,8 - 19 vol %

Acute toxicity

Not classified

Alcohol (64-17-5)

LD50 oral rat

7060 mg/kg

LD50 dermal rabbit

> 16000 mg/kg

LC50 inhalation rat (mg/l)

> 20 mg/l/4h

ATE US (oral)

7060,000 mg/kg bodyweight

CINNAMYL ALCOHOL (104-54-1)

ATE US (oral)

500,000 mg/kg bodyweight

PHELANDRENE (1329-99-3)

ATE US (oral)

500,000 mg/kg bodyweight

Skin corrosion/irritation

Causes skin irritation.

Serious eye damage/irritation

Causes serious eye irritation.

Respiratory or skin sensitisation

May cause an allergic skin reaction.

Germ cell mutagenicity

Not classified Based on available data, the classification criteria are not met

Carcinogenicity

Not classified

9.2. Other information

No additional information available

SECTION 10: Stability and reactivity

10.1. Reactivity

Stable under normal conditions of use.

10.2. Chemical stability

Extremely flammable aerosol. Contains gas under pressure; may explode if heated. Extreme risk of explosion by shock, friction, fire or other sources of ignition.

10.3. Possibility of hazardous reactions

Not established.

10.4. Conditions to avoid

Direct sunlight. Extremely high or low temperatures. Heat. Sparks. Open flame. Overheating.

10.5. Incompatible materials

Oxidizing agent. Strong acids. Strong bases.

10.6. Hazardous decomposition products

May release flammable gases. fume. Carbon monoxide. Carbon dioxide.

SECTION 11: Toxicological information

11.1. Information on toxicological effects

CINNAMON SPICE MB9000

Safety Data Sheet

according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

05/20/2015

EN (English)

6/9

Reproductive toxicity

Not classified Based on available data, the classification criteria are not met

Specific target organ toxicity (single exposure)

May cause respiratory irritation.

Specific target organ toxicity (repeated exposure)

Not classified

Aspiration hazard

Not classified

Potential adverse human health effects and symptoms

Based on available data, the classification criteria are not met.

Symptoms/injuries after inhalation

Shortness of breath. May cause an allergic skin reaction. May cause respiratory irritation.

Symptoms/injuries after skin contact

Causes skin irritation.

Symptoms/injuries after eye contact

Causes serious eye irritation.

EUGENOL (97-53-0)

LC50 fish 1

5,6 mg/l

EC50 other aquatic organisms 1

15,4 mg/l EC50 waterflea (48 h)

EC50 other aquatic organisms 2

1,9 mg/l IC50 algea (72 h) mg/l

Alcohol (64-17-5)

LC50 fish 1

13000 mg/l

EC50 Daphnia 1

9300 mg/l

EC50 other aquatic organisms 1

275 mg/l EC50 waterflea (48 h)

EC50 other aquatic organisms 2

5012 mg/l IC50 algea (72 h) mg/l

HEXYLENE GLYCOL (107-41-5)

LC50 fish 1

> 1000 mg/l

EC50 other aquatic organisms 2

> 1000 mg/l IC50 algea (72 h) mg/l

CINNAMYL ALCOHOL (104-54-1)

EC50 other aquatic organisms 2

> 10 mg/l IC50 algea (72 h) mg/l

CINNAMON SPICE MB9000

Persistence and degradability

Not established.

Alcohol (64-17-5)

Persistence and degradability

Not established.

CINNAMON SPICE MB9000

Bioaccumulative potential

Not established.

Alcohol (64-17-5)

Bioaccumulative potential

Not established.

Effect on ozone layer

None to our knowledge

Effect on the global warming

No known ecological damage caused by this product.

SECTION 12: Ecological information

12.1. Toxicity

12.2. Persistence and degradability

12.3. Bioaccumulative potential

12.4. Mobility in soil

No additional information available

12.5. Other adverse effects

CINNAMON SPICE MB9000

Safety Data Sheet

according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

05/20/2015

EN (English)

7/9

Other information

Avoid release to the environment.

Waste disposal recommendations

Dispose in a safe manner in accordance with local/national regulations. Container under pressure. Do not drill or burn even after use.

Additional information

Handle empty containers with care because residual vapours are flammable. Flammable vapours may accumulate in the container.

Ecology - waste materials

Avoid release to the environment.

Transport document description

UN1950 Aerosols, 2.1

UN-No.(DOT)

UN1950

Proper Shipping Name (DOT)

Aerosols

Transport hazard class(es) (DOT)

2.1 - Class 2.1 - Flammable gas 49 CFR 173.115

Hazard labels (DOT)

2.1 - Flammable gas

DOT Special Provisions (49 CFR 172.102)

N82 - See 173.306 of this subchapter for classification criteria for flammable aerosols.

DOT Packaging Exceptions (49 CFR 173.xxx)

306

DOT Packaging Non Bulk (49 CFR 173.xxx)

None

DOT Packaging Bulk (49 CFR 173.xxx)

None

DOT Quantity Limitations Passenger aircraft/rail (49 CFR 173.27)

75 kg

DOT Quantity Limitations Cargo aircraft only (49 CFR 175.75)

150 kg

DOT Vessel Stowage Location

A - The material may be stowed ‘‘on deck’’ or ‘‘under deck’’ on a cargo vessel and on a passenger vessel.

DOT Vessel Stowage Other

48 - Stow ‘‘away from’’ sources of heat,87 - Stow ‘‘separated from’’ Class 1 (explosives) except Division 14,126 - Segregation same as for Class 9, miscellaneous hazardous materials

Other information

No supplementary information available.

Transport document description

UN 1950 AEROSOLS, 2.1, (D)

Class (ADR)

2 - Gases

Classification code (ADR)

Danger labels (ADR)

2.1 - Flammable gases

Tunnel restriction code (ADR)

: D LQ : 1l

Excepted quantities (ADR)

UN-No. (IMDG)

1950

Proper Shipping Name (IMDG)

AEROSOLS

Class (IMDG)

2 - Gases

SECTION 13: Disposal considerations

13.1. Waste treatment methods

SECTION 14: Transport information

In accordance with DOT

Additional information

ADR

Transport by sea

CINNAMON SPICE MB9000

Safety Data Sheet

according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

05/20/2015

EN (English)

8/9

UN-No. (IATA)

1950

Proper Shipping Name (IATA)

Aerosols, flammable

Class (IATA)

EUGENOL (97-53-0)