Page 1
Reference Cell Recharge, AgCl/KCl Gel
Safety Data Sheet
According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations And According To The Hazardous
Products Regulation (February 11, 2015).
Revision Date: 06/21/2016
Date of Issue: 06/21/2016
Version: 1.0
06/21/2016
EN (English US) 1/6
Product Form: Mixture
Product Name: Reference Cell Recharge, AgCl/KCl Gel
Part Number: 9210102, 9210220
Synonyms: Gelled Reference Solution
Rosemount TUpH Series Sensor Maintenance
Name, Address, and Telephone of the Responsible Party
Company
Emerson Automation Solutions | Rosemount
6021 Innovation Blvd.
Shakopee, MN 55379
Emergency Number
:
Within USA and Canada: 1-800-424-9300 CCN725412
Outside USA and Canada: +1 703-741-5970 (collect calls accepted)
Aquatic Acute 2
H401
Aquatic Chronic 3
H412
Hazard Statements (GHS-US/CA)
:
H401 - Toxic to aquatic life.
H412 - Harmful to aquatic life with long lasting effects.
Precautionary Statements (GHSUS/CA)
:
P273 - Avoid release to the environment.
P501 - Dispose of contents/container in accordance with local, regional, national, and
international regulations.
Name
Product Identifier
% *
GHS Ingredient Classification
Water
(CAS No) 7732-18-5
73.98
Not classified
Potassium chloride
(CAS No) 7447-40-7
23
Not classified
Xanthan gum
(CAS No) 11138-66-2
2
Comb. Dust
Sodium benzoate
(CAS No) 532-32-1
1
Comb. Dust
Eye Irrit. 2A, H319
Silver chloride
(CAS No) 7783-90-6
0.02
Met. Corr. 1, H290
Aquatic Acute 1, H400
Aquatic Chronic 1, H410
1501085 REV 1
SECTION 1: IDENTIFICATION
Product Identifier
Intended Use of the Product
Emergency Telephone Number
SECTION 2: HAZARDS IDENTIFICATION
Classification of the Substance or Mixture
GHS-US/CA Classification
Full text of hazard classes and H-statements : see section 16
Label Elements
GHS-US/CA Labeling
Other Hazards
Exposure may aggravate pre-existing eye, skin, or respiratory conditions.
Unknown Acute Toxicity Not available
SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS
Mixture
Full text of H-phrases: see section 16
*Percentages are listed in weight by weight percentage (w/w%) for liquid and solid ingredients. Gas ingredients are listed in volume
by volume percentage (v/v%).
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Reference Cell Recharge, AgCl/KCl Gel
Safety Data Sheet
According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations And According To The Hazardous Products Regulation (February 11, 2015).
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General: Not expected to present a significant hazard under anticipated conditions of normal use.
Inhalation: Prolonged exposure may cause irritation.
Skin Contact: Prolonged exposure may cause skin irritation.
Eye Contact: May cause slight irritation to eyes.
Ingestion: Ingestion may cause adverse effects.
Chronic Symptoms: None expected under normal conditions of use.
If exposed or concerned, get medical advice and attention. If medical advice is needed, have product container or label at hand.
Precautionary Measures Fire: Exercise caution when fighting any chemical fire.
Firefighting Instructions: Use water spray or fog for cooling exposed containers.
Protection During Firefighting: Do not enter fire area without proper protective equipment, including respiratory protection.
Hazardous Combustion Products: Carbon oxides (CO, CO2). Halogenated compounds. Metal oxides.
Other Information: Do not allow run-off from fire fighting to enter drains or water courses.
Reference to Other Sections
Refer to section 9 for flammability properties.
General Measures: Avoid prolonged contact with eyes, skin and clothing. Avoid breathing (vapor, mist, spray).
Protective Equipment: Use appropriate personal protection equipment (PPE).
Emergency Procedures: Evacuate unnecessary personnel.
Protective Equipment: Equip cleanup crew with proper protection.
Emergency Procedures: Upon arrival at the scene, a first responder is expected to recognize the presence of dangerous goods,
protect oneself and the public, secure the area, and call for the assistance of trained personnel as soon as conditions permit.
For Containment: Contain any spills with dikes or absorbents to prevent migration and entry into sewers or streams.
Suitable Extinguishing Media: Use extinguishing media appropriate for surrounding fire.
Unsuitable Extinguishing Media: Do not use a heavy water stream. Use of heavy stream of water may spread fire.
Fire Hazard: Not considered flammable but may burn at high temperatures.
Explosion Hazard: Product is not explosive.
Reactivity: Hazardous reactions will not occur under normal conditions.
1501085 REV 1
SECTION 4: FIRST AID MEASURES
Description of First-aid Measures
General: Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where
possible).
Inhalation: When symptoms occur: go into open air and ventilate suspected area. Obtain medical attention if breathing difficulty
persists.
Skin Contact: Remove contaminated clothing. Gently wash with plenty of soap and water. Obtain medical attention if irritation
develops or persists.
Eye Contact: Rinse cautiously with water for at least 5 minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Obtain medical attention if redness, pain, or irritation occurs.
Ingestion: Rinse mouth. Do NOT induce vomiting. Obtain medical attention.
Most Important Symptoms and Effects Both Acute and Delayed
Indication of Any Immediate Medical Attention and Special Treatment Needed
SECTION 5: FIRE-FIGHTING MEASURES
Extinguishing Media
Special Hazards Arising From the Substance or Mixture
Advice for Firefighters
SECTION 6: ACCIDENTAL RELEASE MEASURES
Personal Precautions, Protective Equipment and Emergency Procedures
For Non-Emergency Personnel
For Emergency Personnel
Environmental Precautions
Prevent entry to sewers and public waters. Avoid release to the environment.
Methods and Materials for Containment and Cleaning Up
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Reference Cell Recharge, AgCl/KCl Gel
Safety Data Sheet
According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations And According To The Hazardous Products Regulation (February 11, 2015).
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Methods for Cleaning Up: Clean up spills immediately and dispose of waste safely. Transfer spilled material to a suitable container
for disposal. Contact competent authorities after a spill.
See Section 8 for exposure controls and personal protection and Section 13 for disposal considerations.
Precautions for Safe Handling: Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking
and when leaving work. Avoid prolonged contact with eyes, skin and clothing. Avoid breathing vapors, mist, spray.
Hygiene Measures: Handle in accordance with good industrial hygiene and safety procedures.
Technical Measures: Comply with applicable regulations.
Storage Conditions: Keep container closed when not in use. Store in a dry, cool place. Keep/Store away from direct sunlight,
extremely high or low temperatures and incompatible materials.
Incompatible Materials: Strong acids, strong bases, strong oxidizers.
Appropriate Engineering Controls: Emergency eye wash fountains and safety showers should be available in the immediate vicinity
of any potential exposure. Ensure adequate ventilation, especially in confined areas. Ensure all national/local regulations are
observed.
Personal Protective Equipment: Gloves. Protective clothing. In case of splash hazard: safety glasses.
Materials for Protective Clothing: Chemically resistant materials and fabrics.
Hand Protection: Wear protective gloves.
Eye Protection: Chemical goggles or safety glasses.
Skin and Body Protection: Wear suitable protective clothing.
Respiratory Protection: If exposure limits are exceeded or irritation is experienced, approved respiratory protection should be worn.
In case of inadequate ventilation, oxygen deficient atmosphere, or where exposure levels are not known wear approved respiratory
protection.
Other Information: When using, do not eat, drink or smoke
Physical State
:
Liquid
Appearance
:
Not available
Odor
:
Not available
Odor Threshold
:
Not available
pH : Not available
Evaporation Rate
:
Not available
Melting Point
:
Not available
Freezing Point
:
Not available
Boiling Point
:
Not available
Flash Point
:
Not available
1501085 REV 1
Reference to Other Sections
SECTION 7: HANDLING AND STORAGE
Precautions for Safe Handling
Conditions for Safe Storage, Including Any Incompatibilities
Specific End Use(s)
Rosemount TUpH Series Sensor Maintenance
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
Control Parameters
For substances listed in section 3 that are not listed here, there are no established Exposure limits from the manufacturer, supplier,
importer, or the appropriate advisory agency including: ACGIH (TLV), AIHA (WEEL), NIOSH (REL), OSHA (PEL), Canadian provincial
governments, or the Mexican government.
Exposure Controls
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
Information on Basic Physical and Chemical Properties
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Reference Cell Recharge, AgCl/KCl Gel
Safety Data Sheet
According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations And According To The Hazardous Products Regulation (February 11, 2015).
06/21/2016
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Auto-ignition Temperature
:
Not available
Decomposition Temperature
:
Not available
Flammability (solid, gas)
:
Not available
Lower Flammable Limit
:
Not available
Upper Flammable Limit
:
Not available
Vapor Pressure
:
Not available
Relative Vapor Density at 20°C
:
Not available
Relative Density
:
Not available
Specific Gravity
:
Not available
Solubility
:
Not available
Partition Coefficient: N-Octanol/Water
:
Not available
Viscosity
:
Not available
Potassium chloride (7447-40-7)
LD50 Oral Rat
2600 mg/kg
Sodium benzoate (532-32-1)
LD50 Oral Rat
4070 mg/kg
Xanthan gum (11138-66-2)
LD50 Oral Rat
> 45000 mg/kg
Acute Toxicity (Oral): Not classified
Acute Toxicity (Dermal): Not classified
Acute Toxicity (Inhalation): Not classified
1501085 REV 1
SECTION 10: STABILITY AND REACTIVITY
Reactivity: Hazardous reactions will not occur under normal conditions.
Chemical Stability: Stable under recommended handling and storage conditions (see section 7).
Possibility of Hazardous Reactions: Hazardous polymerization will not occur.
Conditions to Avoid: Direct sunlight, extremely high or low temperatures, and incompatible materials.
Incompatible Materials: Strong acids, strong bases, strong oxidizers.
Hazardous Decomposition Products: None known.
SECTION 11: TOXICOLOGICAL INFORMATION
Information on Toxicological Effects - Product
LD50 and LC50 Data: Not available
Skin Corrosion/Irritation: Not classified
Eye Damage/Irritation: Not classified
Respiratory or Skin Sensitization: Not classified
Germ Cell Mutagenicity: Not classified
Carcinogenicity: Not classified
Specific Target Organ Toxicity (Repeated Exposure): Not classified
Reproductive Toxicity: Not classified
Specific Target Organ Toxicity (Repeated Exposure): Not classified
Aspiration Hazard: Not classified
Symptoms/Injuries After Inhalation: Prolonged exposure may cause irritation.
Symptoms/Injuries After Skin Contact: Prolonged exposure may cause skin irritation.
Symptoms/Injuries After Eye Contact: May cause slight irritation to eyes.
Symptoms/Injuries After Ingestion: Ingestion may cause adverse effects.
Chronic Symptoms: None expected under normal conditions of use.
Information on Toxicological Effects - Ingredient(s)
LD50 and LC50 Data:
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Reference Cell Recharge, AgCl/KCl Gel
Safety Data Sheet
According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations And According To The Hazardous Products Regulation (February 11, 2015).
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Ecology - General: Toxic to aquatic life. Harmful to aquatic life with long lasting effects.
Silver chloride (7783-90-6)
LC50 Fish 1
1.2 μg/l
EC50 Daphnia 1
0.22 μg/l
Potassium chloride (7447-40-7)
LC50 Fish 1
1060 mg/l (Exposure time: 96 h - Species: Lepomis macrochirus [static])
EC50 Daphnia 1
825 mg/l (Exposure time: 48 h - Species: Daphnia magna)
LC50 Fish 2
750 (750 - 1020) mg/l (Exposure time: 96 h - Species: Pimephales promelas [static])
EC50 Daphnia 2
880 mg/l (Exposure time: 24 h - Species: Daphnia magna)
Sodium benzoate (532-32-1)
LC50 Fish 1
420 (420 - 558) mg/l (Exposure time: 96 h - Species: Pimephales promelas [flow-through])
EC50 Daphnia 1
650 mg/l (Exposure time: 48 h - Species: Daphnia magna)
LC50 Fish 2
> 100 mg/l (Exposure time: 96 h - Species: Pimephales promelas [static])
Reference Cell Recharge, AgCl/KCl Gel
Persistence and Degradability
May cause long-term adverse effects in the environment.
Reference Cell Recharge, AgCl/KCl Gel
Bioaccumulative Potential
Not established.
Sodium benzoate (532-32-1)
BCF Fish 1
(no bioaccumulation)
Log Pow
-2.13
Other Information: Avoid release to the environment.
Silver chloride (7783-90-6)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Potassium chloride (7447-40-7)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Sodium benzoate (532-32-1)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Xanthan gum (11138-66-2)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
1501085 REV 1
SECTION 12: ECOLOGICAL INFORMATION
Toxicity
Persistence and Degradability
Bioaccumulative Potential
Mobility in Soil Not available
Other Adverse Effects
SECTION 13: DISPOSAL CONSIDERATIONS
Waste Disposal Recommendations: Dispose of contents/container in accordance with local, regional, national, and international
regulations
Additional Information: Container may remain hazardous when empty. Continue to observe all precautions.
Ecology - Waste Materials: Avoid release to the environment. This material is hazardous to the aquatic environment. Keep out of
sewers and waterways.
SECTION 14: TRANSPORT INFORMATION
In Accordance with DOT Not regulated for transport.
In Accordance with IMDG Not regulated for transport.
In Accordance with IATA Not regulated for transport.
In Accordance with TDG Not regulated for transport.
SECTION 15: REGULATORY INFORMATION
US Federal Regulations
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Reference Cell Recharge, AgCl/KCl Gel
Safety Data Sheet
According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations And According To The Hazardous Products Regulation (February 11, 2015).
06/21/2016
EN (English US)
6/6
Water (7732-18-5)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Silver chloride (7783-90-6)
Listed on the Canadian DSL (Domestic Substances List)
Potassium chloride (7447-40-7)
Listed on the Canadian DSL (Domestic Substances List)
Sodium benzoate (532-32-1)
Listed on the Canadian DSL (Domestic Substances List)
Xanthan gum (11138-66-2)
Listed on the Canadian DSL (Domestic Substances List)
Water (7732-18-5)
Listed on the Canadian DSL (Domestic Substances List)
Revision Date
:
06/21/2016
Other Information
:
This document has been prepared in accordance with the SDS requirements of the OSHA
Hazard Communication Standard 29 CFR 1910.1200 and Canada’s Hazardous Products
Regulations (HPR).
GHS Full Text Phrases:
------
Aquatic Acute 1
Hazardous to the aquatic environment - Acute Hazard Category 1
------
Aquatic Acute 2
Hazardous to the aquatic environment - Acute Hazard Category 2
------
Aquatic Chronic 1
Hazardous to the aquatic environment - Chronic Hazard Category 1
------
Aquatic Chronic 3
Hazardous to the aquatic environment - Chronic Hazard Category 3
------
Comb. Dust
May form combustible dust concentrations in air
------
Eye Irrit. 2A
Serious eye damage/eye irritation Category 2A
------
Met. Corr. 1
Corrosive to metals Category 1
------
H290
May be corrosive to metals
------
H319
Causes serious eye irritation
------
H400
Very toxic to aquatic life
------
H401
Toxic to aquatic life
------
H410
Very toxic to aquatic life with long lasting effects
------
H412
Harmful to aquatic life with long lasting effects
1501085 REV 1
US State Regulations
Neither this product nor its chemical components appear on any US state lists.
Canadian Regulations
SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION
This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and
environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product.
NA GHS SDS 2015
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