Page 1
HT SIlica Reference Gel
Safety Data Sheet
According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations
Revision Date: 04/10/2015
Date of issue: 11/19/2014 Version: 1.0
04/10/2015
EN (English US) 1/9
Product Form: Mixture
Product Name: HT SIlica Reference Gel
Part Number: 1700625, 9210392-9210395
Use of the Substance/Mixture: No use is specified.
1.3. Name, Address, and Telephone of the Responsible Party
Company
Rosemount Analytical Inc.
2400 Barranca Parkway
Irvine, CA 92606
USA
949-757-8500
Emergency Number
:
949-757-8500
Flam. Liq. 3
H226
Hazard Pictograms (GHS-US)
:
GHS02
Signal Word (GHS-US)
:
Warning
Hazard Statements (GHS-US)
:
H226 - Flammable liquid and vapor.
Precautionary Statements (GHS-US)
:
P210 - Keep away from heat, hot surfaces, open flames, sparks. - No smoking.
P233 - Keep container tightly closed.
P240 - Ground/bond container and receiving equipment.
P241 - Use explosion-proof electrical, lighting, ventilating equipment.
P242 - Use only non-sparking tools.
P243 - Take precautionary measures against static discharge.
P280 - Wear eye protection, face protection, protective gloves.
P303+P361+P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing.
Rinse skin with water/shower.
P370+P378 - In case of fire: Use foam, dry chemical extinguishing powder, carbon dioxide
(CO2) to extinguish.
P403+P235 - Store in a well-ventilated place. Keep cool.
P501 - Dispose of contents/container in accordance with local, regional, national,
provincial, and international regulations.
SECTION 1: IDENTIFICATION
1.1. Product Identifier
1.2. Intended Use of the Product
1.4. Emergency Telephone Number
SECTION 2: HAZARDS IDENTIFICATION
2.1. Classification of the Substance or Mixture
Classification (GHS-US)
Full text of H-phrases: see section 16
2.2. Label Elements
GHS-US Labeling
2.3. Other Hazards
Flammable vapors can accumulate in head space of closed systems. Exposure may aggravate those with pre-existing eye, skin, or
respiratory conditions.
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HT SIlica Reference Gel
Safety Data Sheet
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EN (English US)
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Name
Product Identifier
% (w/w)
Classification (GHS-US)
Potassium chloride*
(CAS No) 7447-40-7
27.3 - 40,
40 - 70,
70 - 94.75
Not classified
Silica, amorphous
(CAS No) 7631-86-9
5
Not classified
Isopropyl alcohol
(CAS No) 67-63-0
0.25
Flam. Liq. 2, H225
Eye Irrit. 2A, H319
STOT SE 3, H336
General: None expected under normal conditions of use.
Inhalation: Overexposure may be irritating to the respiratory system.
Skin Contact: Repeated or prolonged exposure is likely to cause irritation.
Eye Contact: Direct contact with the eyes is likely irritating.
Ingestion: If a large quantity has been ingested : may cause irritation of the linings of the mouth, throat, and gastrointestinal tract.
Chronic Symptoms: None expected under normal conditions of use.
If you feel unwell, seek medical advice (show the label where possible).
Precautionary Measures Fire: Exercise caution when fighting any chemical fire. Under fire conditions, hazardous fumes will be
present.
Firefighting Instructions: Use water spray or fog for cooling exposed containers. In case of major fire and large quantities: Evacuate
area. Fight fire remotely due to the risk of explosion.
Protection During Firefighting: Do not enter fire area without proper protective equipment, including respiratory protection.
Hazardous Combustion Products: Carbon oxides. Halogenated compounds. Potassium oxides. Silicon oxides.
Suitable Extinguishing Media: Alcohol foam, carbon dioxide, dry chemical.
Unsuitable Extinguishing Media: Do not use a heavy water stream. Use of heavy stream of water may spread fire.
Fire Hazard: Flammable liquid and vapor.
Explosion Hazard: May form flammable/explosive vapor-air mixture.
Reactivity: Reacts with (strong) oxidizers: (increased) risk of fire.
2.4. Unknown Acute Toxicity (GHS-US) No data available
SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS
3.1. Substances
Not applicable
3.2. Mixture
*More than one of the ranges of concentration prescribed by Controlled Products Regulations has been used where necessary due to
varying compostion.
Full text of H-phrases: see section 16
SECTION 4: FIRST AID MEASURES
4.1. Description of First Aid Measures
General: Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label if possible).
IF exposed or concerned: Get medical advice/attention.
Inhalation: Remove to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER/doctor/physician if
you feel unwell.
Skin Contact: Remove contaminated clothing. Gently wash with plenty of soap and water followed by rinsing with water for at least
15 minutes. Call a POISON CENTER or doctor/physician if you feel unwell. Wash contaminated clothing before reuse.
Eye Contact: Rinse cautiously with water for at least 15 minutes. Remove contact lenses, if present and easy to do so. Continue
rinsing. Obtain medical attention if irritation persists.
Ingestion: Rinse mouth thoroughly with water. Do NOT induce vomiting. Seek medical attention immediately.
4.2. Most Important Symptoms and Effects Both Acute and Delayed
4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed
SECTION 5: FIRE-FIGHTING MEASURES
5.1. Extinguishing Media
5.2. Special Hazards Arising From the Substance or Mixture
5.3. Advice for Firefighters
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HT SIlica Reference Gel
Safety Data Sheet
According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations
04/10/2015
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Reference to Other Sections
Refer to section 9 for flammability properties.
General Measures: Avoid breathing (vapor, mist, spray). Avoid all contact with skin, eyes, or clothing. Eliminate every possible
source of ignition.
Protective Equipment: Use appropriate personal protection equipment (PPE).
Emergency Procedures: Evacuate unnecessary personnel.
Protective Equipment: Equip cleanup crew with proper protection.
Emergency Procedures: Ventilate area. Stop leak if safe to do so. Eliminate ignition sources.
For Containment: Contain any spills with dikes or absorbents to prevent migration and entry into sewers or streams.
Methods for Cleaning Up: Absorb and/or contain spill with inert material. Collect absorbed material and place into a sealed, labeled
container for proper disposal. Do not take up in combustible material such as: saw dust or cellulosic material. Use only non-sparking
tools.
For further information refer to section 13. See heading 8, Exposure Controls and Personal Protection.
Additional Hazards When Processed: Any proposed use of this product in elevated-temperature processes should be thoroughly
evaluated to assure that safe operating conditions are established and maintained. Handle empty containers with care because
residual vapors are flammable.
Hygiene Measures: Handle in accordance with good industrial hygiene and safety procedures. Wash hands and other exposed areas
with mild soap and water before eating, drinking or smoking and when leaving work. Contaminated work clothing should not be
allowed out of the workplace.
Technical Measures: Ground/bond container and receiving equipment. Use explosion-proof ventilating, lighting, electrical
equipment.
Storage Conditions: Store in a cool, dry, well-ventilated place. Keep containers tightly closed. Do not store near heat, flame, or other
potential ignition sources. Do not store with oxidizers. Do not store in unlabeled containers. Ground all equipment containing this
material.
Incompatible Materials: Strong acids, strong bases, strong oxidizers.
No use is specified.
Silica, amorphous (7631-86-9)
USA OSHA
OSHA PEL (TWA) (mg/m³)
6 mg/m³
USA OSHA
OSHA PEL (TWA) (ppm)
20 mppcf (80mg/m3/%SiO2)
Nunavut
OEL TWA (mg/m³)
2 mg/m³ (respirable mass)
Northwest Territories
OEL TWA (mg/m³)
2 mg/m³ (respirable mass)
Yukon
OEL TWA (mg/m³)
300 particle/mL (as measured by Konimeter
instrumentation)
SECTION 6: ACCIDENTAL RELEASE MEASURES
6.1. Personal Precautions, Protective Equipment and Emergency Procedures
6.1.1. For Non-Emergency Personnel
6.1.2. For Emergency Personnel
6.2. Environmental Precautions
Contain any spills with dikes or absorbents to prevent migration and entry into sewers or streams. Do not allow to enter drains or
water courses. Contact competent authorities after a spill.
6.3. Methods and Material for Containment and Cleaning Up
6.4. Reference to Other Sections
SECTION 7: HANDLING AND STORAGE
7.1. Precautions for Safe Handling
7.2. Conditions for Safe Storage, Including Any Incompatibilities
7.3. Specific End Use(s)
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1. Control Parameters
For substances listed in section 3 that are not listed here, there are no established Exposure limits from the manufacturer, supplier,
importer, or the appropriate advisory agency including: ACGIH (TLV), NIOSH (REL), OSHA (PEL), Canadian provincial governments, or
the Mexican government.
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Isopropyl alcohol (67-63-0)
Mexico
OEL TWA (mg/m³)
980 mg/m³
Mexico
OEL TWA (ppm)
400 ppm
Mexico
OEL STEL (mg/m³)
1225 mg/m³
Mexico
OEL STEL (ppm)
500 ppm
USA ACGIH
ACGIH TWA (ppm)
200 ppm
USA ACGIH
ACGIH STEL (ppm)
400 ppm
USA OSHA
OSHA PEL (TWA) (mg/m³)
980 mg/m³
USA OSHA
OSHA PEL (TWA) (ppm)
400 ppm
USA NIOSH
NIOSH REL (TWA) (mg/m³)
980 mg/m³
USA NIOSH
NIOSH REL (TWA) (ppm)
400 ppm
USA NIOSH
NIOSH REL (STEL) (mg/m³)
1225 mg/m³
USA NIOSH
NIOSH REL (STEL) (ppm)
500 ppm
USA IDLH
US IDLH (ppm)
2000 ppm (10% LEL)
Alberta
OEL STEL (mg/m³)
984 mg/m³
Alberta
OEL STEL (ppm)
400 ppm
Alberta
OEL TWA (mg/m³)
492 mg/m³
Alberta
OEL TWA (ppm)
200 ppm
British Columbia
OEL STEL (ppm)
400 ppm
British Columbia
OEL TWA (ppm)
200 ppm
Manitoba
OEL STEL (ppm)
400 ppm
Manitoba
OEL TWA (ppm)
200 ppm
New Brunswick
OEL STEL (mg/m³)
1230 mg/m³
New Brunswick
OEL STEL (ppm)
500 ppm
New Brunswick
OEL TWA (mg/m³)
983 mg/m³
New Brunswick
OEL TWA (ppm)
400 ppm
Newfoundland & Labrador
OEL STEL (ppm)
400 ppm
Newfoundland & Labrador
OEL TWA (ppm)
200 ppm
Nova Scotia
OEL STEL (ppm)
400 ppm
Nova Scotia
OEL TWA (ppm)
200 ppm
Nunavut
OEL STEL (mg/m³)
1228 mg/m³
Nunavut
OEL STEL (ppm)
500 ppm
Nunavut
OEL TWA (mg/m³)
983 mg/m³
Nunavut
OEL TWA (ppm)
400 ppm
Northwest Territories
OEL STEL (mg/m³)
1228 mg/m³
Northwest Territories
OEL STEL (ppm)
500 ppm
Northwest Territories
OEL TWA (mg/m³)
983 mg/m³
Northwest Territories
OEL TWA (ppm)
400 ppm
Ontario
OEL STEL (ppm)
400 ppm
Ontario
OEL TWA (ppm)
200 ppm
Prince Edward Island
OEL STEL (ppm)
400 ppm
Prince Edward Island
OEL TWA (ppm)
200 ppm
Québec
VECD (mg/m³)
1230 mg/m³
Québec
VECD (ppm)
500 ppm
Québec
VEMP (mg/m³)
985 mg/m³
Québec
VEMP (ppm)
400 ppm
Saskatchewan
OEL STEL (ppm)
400 ppm
Saskatchewan
OEL TWA (ppm)
200 ppm
Yukon
OEL STEL (mg/m³)
1225 mg/m³
Yukon
OEL STEL (ppm)
500 ppm
Yukon
OEL TWA (mg/m³)
980 mg/m³
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Safety Data Sheet
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Yukon
OEL TWA (ppm)
400 ppm
Appropriate Engineering Controls: Gas detectors should be used when flammable gases/vapors may be released. Emergency eye
wash fountains and safety showers should be available in the immediate vicinity of any potential exposure. Ensure adequate
ventilation, especially in confined areas. Proper grounding procedures to avoid static electricity should be followed. Use explosionproof equipment. Ensure all national/local regulations are observed.
Personal Protective Equipment: Full protective flameproof clothing. Insufficient ventilation: wear respiratory protection. Protective
goggles. Gloves.
Materials for Protective Clothing: Wear fire/flame resistant/retardant clothing.
Hand Protection: Wear chemically resistant protective gloves.
Eye Protection: Chemical goggles or safety glasses.
Skin and Body Protection: Wear fireproof clothing.
Respiratory Protection: Use a NIOSH-approved respirator or self-contained breathing apparatus whenever exposure may exceed
established Occupational Exposure Limits.
Environmental Exposure Controls: Do not allow the product to be released into the environment.
Consumer Exposure Controls: Do not eat, drink or smoke during use.
Physical State
:
Liquid
Appearance
:
Not available
Odor
:
Not available
Odor Threshold
:
Not available
pH : Not available
Evaporation Rate
:
Not available
Melting Point
:
Not available
Freezing Point
:
Not available
Boiling Point
:
Not available
Flash Point
:
48 °C (118.4 °F) (Estimated Flash Point for 5% Isopropyl Alcohol Solution)
Auto-ignition Temperature
:
Not available
Decomposition Temperature
:
Not available
Flammability (solid, gas)
:
Not available
Lower Flammable Limit
:
Not available
Upper Flammable Limit
:
Not available
Vapor Pressure
:
Not available
Relative Vapor Density at 20 °C
:
Not available
Relative Density
:
Not available
Specific Gravity
:
Not available
Solubility
:
Not available
Partition Coefficient: N-Octanol/Water
:
Not available
Viscosity
:
Not available
Explosive Properties
:
Product is not explosive, however, formation of explosive air-vapor mixture
is possible
Explosion Data – Sensitivity to Mechanical Impact
:
Not expected to present an explosion hazard due to mechanical impact
Explosion Data – Sensitivity to Static Discharge
:
Not expected to present an explosion hazard due to static discharge
8.2. Exposure Controls
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
9.1. Information on Basic Physical and Chemical Properties
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Silica, amorphous (7631-86-9)
LD50 Oral Rat
> 5000 mg/kg
LD50 Dermal Rabbit
> 2000 mg/kg
LC50 Inhalation Rat
> 2.2 mg/l (Exposure time: 1 h)
Potassium chloride (7447-40-7)
LD50 Oral Rat
2600 mg/kg
Isopropyl alcohol (67-63-0)
LD50 Oral Rat
4710 mg/kg
LD50 Dermal Rabbit
4059 mg/kg
LC50 Inhalation Rat
72600 mg/m³ (Exposure time: 4 h)
Silica, amorphous (7631-86-9)
IARC Group
3
Isopropyl alcohol (67-63-0)
IARC Group
3
Acute Toxicity: Not classified
SECTION 10: STABILITY AND REACTIVITY
10.1. Reactivity: Reacts with (strong) oxidizers: (increased) risk of fire.
10.2. Chemical Stability: Stable under recommended handling and storage conditions (see section 7).
10.3. Possibility of Hazardous Reactions: Hazardous polymerization will not occur.
10.4. Conditions to Avoid: Direct sunlight, extremely high or low temperatures, open flames, sources of ignition and incompatible
materials.
10.5. Incompatible Materials: Strong acids, strong bases, strong oxidizers.
10.6. Hazardous Decomposition Products: Thermal decomposition generates : Oxides of silicon and carbon. Potassium oxides.
Halogenated compounds.
SECTION 11: TOXICOLOGICAL INFORMATION
11.1. Information on Toxicological Effects - Product
LD50 and LC50 Data: Not available
Skin Corrosion/Irritation: Not classified
Serious Eye Damage/Irritation: Not classified
Respiratory or Skin Sensitization: Not classified
Germ Cell Mutagenicity: Not classified
Teratogenicity: Not classified
Carcinogenicity: Not classified
Specific Target Organ Toxicity (Repeated Exposure): Not classified
Reproductive Toxicity: Not classified
Specific Target Organ Toxicity (Single Exposure): Not classified
Aspiration Hazard: Not classified
Symptoms/Injuries After Inhalation: Overexposure may be irritating to the respiratory system.
Symptoms/Injuries After Skin Contact: Repeated or prolonged exposure is likely to cause irritation.
Symptoms/Injuries After Eye Contact: Direct contact with the eyes is likely irritating.
Symptoms/Injuries After Ingestion: If a large quantity has been ingested : May cause irritation of the linings of the mouth, throat,
and gastrointestinal tract.
Chronic Symptoms: None expected under normal conditions of use.
11.2. Information on Toxicological Effects - Ingredient(s)
LD50 and LC50 Data:
SECTION 12: ECOLOGICAL INFORMATION
12.1. Toxicity
No additional information available
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Silica, amorphous (7631-86-9)
LC50 Fish 1
5000 mg/l (Exposure time: 96 h - Species: Brachydanio rerio [static])
EC50 Daphnia 1
7600 mg/l (Exposure time: 48 h - Species: Ceriodaphnia dubia)
Potassium chloride (7447-40-7)
LC50 Fish 1
1060 mg/l (Exposure time: 96 h - Species: Lepomis macrochirus [static])
EC50 Daphnia 1
825 mg/l (Exposure time: 48 h - Species: Daphnia magna)
LC 50 Fish 2
750 - 1020 mg/l (Exposure time: 96 h - Species: Pimephales promelas [static])
Isopropyl alcohol (67-63-0)
LC50 Fish 1
9640 mg/l (Exposure time: 96 h - Species: Pimephales promelas [flow-through])
EC50 Daphnia 1
13299 mg/l (Exposure time: 48 h - Species: Daphnia magna)
EC50 Other Aquatic Organisms 1
1000 mg/l (Exposure time: 96 h - Species: Desmodesmus subspicatus)
LC 50 Fish 2
11130 mg/l (Exposure time: 96 h - Species: Pimephales promelas [static])
EC50 Other Aquatic Organisms 2
1000 mg/l (Exposure time: 72 h - Species: Desmodesmus subspicatus)
Silica, amorphous (7631-86-9)
BCF Fish 1
(no bioaccumulation expected)
Isopropyl alcohol (67-63-0)
Log Pow
0.05 (at 25 °C)
Proper Shipping Name
:
FLAMMABLE LIQUIDS, N.O.S., (ISOPROPYL ALCOHOL / SILICA SOLUTION)
Hazard Class
:
3 Identification Number
:
UN1993
Label Codes
:
3
Packing Group
:
III
ERG Number
:
128
Proper Shipping Name
:
FLAMMABLE LIQUIDS, N.O.S., (ISOPROPYL ALCOHOL / SILICA SOLUTION)
Hazard Class
:
3
Identification Number
:
UN1993
Packing Group
:
III
Label Codes
:
3
EmS-No. (Fire)
:
F-E
EmS-No. (Spillage)
:
S-E
MFAG Number
:
130
12.2. Persistence and Degradability
Not available
12.3. Bioaccumulative Potential
12.4. Mobility in Soil
Not available
12.5. Other Adverse Effects
Other Information: Avoid release to the environment.
SECTION 13: DISPOSAL CONSIDERATIONS
13.1. Waste treatment methods
Sewage Disposal Recommendations: Do not dispose of waste into sewer. Do not empty into drains; dispose of this material and its
container in a safe way.
Waste Disposal Recommendations: Dispose of waste material in accordance with all local, regional, national, provincial, and
international regulations.
SECTION 14: TRANSPORT INFORMATION
14.1. In Accordance with DOT
14.2. In Accordance with IMDG
14.3. In Accordance with IATA
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Proper Shipping Name
:
FLAMMABLE LIQUIDS, N.O.S., (ISOPROPYL ALCOHOL / SILICA SOLUTION)
Packing Group
:
III
Identification Number
:
UN1993
Hazard Class
:
3
Label Codes
:
3
ERG Code (IATA)
:
3L
Proper Shipping Name
:
FLAMMABLE LIQUIDS, N.O.S., (ISOPROPYL ALCOHOL / SILICA SOLUTION)
Packing Group
:
III
Hazard Class
:
3 Identification Number
:
UN1993
Label Codes
:
3
Silica, amorphous (7631-86-9)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Potassium chloride (7447-40-7)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Isopropyl alcohol (67-63-0)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Listed on United States SARA Section 313
EPA TSCA Regulatory Flag
T - T - indicates a substance that is the subject of a Section 4 test
rule under TSCA.
SARA Section 313 - Emission Reporting
1.0 % (only if manufactured by the strong acid process, no supplier
notification)
Silica, amorphous (7631-86-9)
U.S. - Massachusetts - Right To Know List
U.S. - New Jersey - Right to Know Hazardous Substance List
U.S. - Pennsylvania - RTK (Right to Know) List
Isopropyl alcohol (67-63-0)
U.S. - Massachusetts - Right To Know List
U.S. - New Jersey - Right to Know Hazardous Substance List
U.S. - Pennsylvania - RTK (Right to Know) - Environmental Hazard List
U.S. - Pennsylvania - RTK (Right to Know) List
Silica, amorphous (7631-86-9)
Listed on the Canadian DSL (Domestic Substances List)
Listed on the Canadian IDL (Ingredient Disclosure List)
IDL Concentration 1 %
WHMIS Classification
Uncontrolled product according to WHMIS classification criteria
HT SIlica Reference Gel
SARA Section 311/312 Hazard Classes
Fire hazard
HT SIlica Reference Gel
WHMIS Classification
Class B Division 3 - Combustible Liquid
14.4. In Accordance with TDG
SECTION 15: REGULATORY INFORMATION
15.1. US Federal Regulations
15.2. US State Regulations
15.3. Canadian Regulations
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Potassium chloride (7447-40-7)
Listed on the Canadian DSL (Domestic Substances List)
WHMIS Classification
Uncontrolled product according to WHMIS classification criteria
Isopropyl alcohol (67-63-0)
Listed on the Canadian DSL (Domestic Substances List)
Listed on the Canadian IDL (Ingredient Disclosure List)
IDL Concentration 1 %
WHMIS Classification
Class B Division 2 - Flammable Liquid
Class D Division 2 Subdivision B - Toxic material causing other toxic effects
Revision Date
:
04/10/2015
Other Information
:
This document has been prepared in accordance with the SDS requirements of the OSHA
Hazard Communication Standard 29 CFR 1910.1200.
GHS Full Text Phrases:
------
Eye Irrit. 2A
Serious eye damage/eye irritation Category 2A
------
Flam. Liq. 2
Flammable liquids Category 2
------
Flam. Liq. 3
Flammable liquids Category 3
------
STOT SE 3
Specific target organ toxicity (single exposure) Category 3
------
H225
Highly flammable liquid and vapor
------
H226
Flammable liquid and vapor
------
H319
Causes serious eye irritation
------
H336
May cause drowsiness or dizziness
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the SDS
contains all of the information required by CPR.
SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION
Party Responsible for the Preparation of This Document
Rosemount Analytical Inc. 2400 Barranca Parkway Irvine, CA 92606
This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and
environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product.
North America GHS US 2012 & WHMIS 2
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