Emerson designs, manufactures, and tests its products to meet many national and international standards. Because these
instruments are sophisticated technical products, you must properly install, use, and maintain them to ensure they continue to
operate within their normal specifications. You must adhere to the following instructions and integrate them into your safety
program when installing, using, and maintaining Emerson's Rosemount products. Failure to follow the proper instructions may
cause any one of the following situations to occur: loss of life, personal injury, property damage, damage to this instrument, and
warranty invalidation.
• Read all instructions prior to installing, operating, and servicing the product.
• If you do not understand any of the instructions, contact your Emerson representative for clarification.
• Follow all warnings, cautions, and instructions marked on and supplied with the product.
• Inform and educate your personnel in the proper installation, operation, and maintenance of the product.
• Install equipment as specified in the installation instructions of the appropriate Quick Start Guide and per applicable local and
national codes. Connect all products to the proper electrical and pressure sources.
• To ensure proper performance, use qualified personnel to install, operate, update, program, and maintain the product.
• When replacement parts are required, ensure that qualified people use replacement parts specified by Emerson.
Unauthorized parts and procedures can affect the product's performance, place the safe operation of your process at risk, and
may result in fire, electrical hazards, or improper operation.
• Ensure that all equipment doors are closed and protective covers are in place, except when maintenance is being performed
by qualified people, to prevent electrical shock and personal injury.
Note
The information contained in this document is subject to change without notice.
CAUTION
If a Model 275/375 HART® Communicator is used with this product, the software within the Model 275/375 may require
modification.
If a software modification is required, please contact your local Emerson Service Group or National Response Center at
1-800-422-6076 or 1-888-433-6829.
Safety instructions
The following safety instructions apply specifically to all EU member states. They should be strictly adhered to in order to ensure
compliance with the Low Voltage Directive. Non-EU states should also comply with the following unless superseded by local or
national standards.
2
WARNING
Adequate earth connections should be made to all earthing points, internal and external, where provided.
After installation or troubleshooting, all safety covers and safety grounds must be replaced. The integrity of all earth terminals
must be maintained at all times.
Main supply cords should comply with the requirements of IEC227 or IEC245.
All wiring shall be suitable for use in an ambient temperature of greater than 221 °F (105 °C).
All cable glands used should be of such internal dimensions as to provide adequate cable anchorage.
To ensure safe operation of this equipment, connection to the mains supply should only be made through a circuit breaker,
which will disconnect all circuits carrying conductors during a fault situation. The circuit breaker may also include a
mechanically operated isolating switch. If it does not, then another means of disconnecting the equipment from the supply
must be provided and clearly marked as such. Circuit breakers or switches must comply with a recognized standard, such as
IEC947. All wiring must conform with any local standards.
Where equipment or covers are marked with the symbol below, hazardous voltages are likely to be present beneath. These
covers should only be removed when power is removed from the equipment - and then only by trained service personnel.
Where equipment or covers are marked with the symbol below, there is a danger of hot surfaces beneath. These covers
should only be removed by trained service personnel when power is removed from the equipment. Certain surfaces may
remain hot to the touch.
Where equipment or covers are marked with the symbol below, refer to the reference manual for instructions.
All graphical symbols used in this product are from one or more of the following standards: EN61010, IEC417, and ISO3864.
Where equipment or labels are marked "Do Not Open While Energized" or similar, there is a danger of ignition in areas where
an explosive atmosphere is present. This equipment should only be opened when the power is removed and adequate time as
specified on the label or in the Reference Manual has been allowed for the equipment to cool down - and then only by trained
service personnel.
WARNING
Cable entry devices and blanking elements shall be Ex d certified. Cables or conductors in conduit, cable entry devices and
blanking elements must be rated for 176 °F (80 °C).
WARNING
Physical access
Unauthorized personnel may potentially cause significant damage to and/or misconfiguration of end users’ equipment. This could
be intentional or unintentional and needs to be protected against.
Physical security is an important part of any security program and fundamental to protecting your system. Restrict physical access
by unauthorized personnel to protect end users’ assets. This is true for all systems used within the facility.
Warranty
Rosemount™ warrants that the equipment manufactured and sold by it will, upon shipment, be free of defects in workmanship or
material. Should any failure to conform to this warranty become apparent during a period of one year after the date of shipment,
Rosemount shall, upon prompt written notice from the purchaser, correct such nonconformity by repair or replacement, F.O.B.
3
factory of the defective part or parts. Correction in the manner provided above shall constitute a fulfillment of all liabilities of
Rosemount with respect to the quality of the equipment.
THE FOREGOING WARRANTY IS EXCLUSIVE AND IN LIEU OF ALL OTHER WARRANTIES OF QUALITY WHETHER WRITTEN, ORAL, OR
IMPLIED (INCLUDING ANY WARRANTY OF MERCHANTABILITY OF FITNESS FOR PURPOSE).
The remedy(ies) provided above shall be purchaser’s sole remedy(ies) for any failure of Rosemount to comply with the warranty
provisions, whether claims by the purchaser are based in contract or in tort (including negligence).
Rosemount does not warrant equipment against normal deterioration due to environment. Factors, such as corrosive gases and
solid particulates, can be detrimental and can create the need for repair or replacement as part of normal wear and tear during the
warranty period.
Equipment supplied by Rosemount, Inc. but not manufactured by it will be subject to the same warranty as is extended to
Rosemount by the original manufacturer.
At the time of installation it is important that the required services are supplied to the system and that the electronic controller is
set up at least to the point where it is controlling the sensor heater. This will ensure, that should there be a delay between
installation and full commissioning that the sensor being supplied with ac power and reference air will not be subjected to
component deterioration.
Definitions
The following definitions apply to Warnings, Cautions, and Notes found throughout this publication.
WARNING
Highlights an operation or maintenance procedure, practice, condition, statement, etc., which if not strictly observed, could result
in injury, death, or long-term health hazards of personnel.
CAUTION
Highlights an operation or maintenance procedure, practice, condition, statement, etc., which if not strictly observed, could result
in damage to or destruction of equipment or loss of effectiveness.
Note
Highlights an essential operating procedure, condition, or statement.
Symbols
Earth (ground) terminal
Protective conductor terminal
Risk of electrical shock
Refer to reference manual.
4
Reference ManualContents
00809-0100-4340April 2022
Contents
Chapter 1Description and specifications....................................................................................9
A typical Rosemount™ Oxymitter 4000 should contain the items shown in Figure 1-1.
Record the part number, serial number, and order number for each component of your
system.
WARNING
The Rosemount Oxymitter 4000 is offered in both hazardous area and general
purpose configurations.
The hazardous area version has special markings on the approval label. The general
purpose version does not. If you received the general purpose version, ensure you do not
install it in a potentially explosive atmosphere.
Also use the following tables to compare your order number against your unit. The title of
the table defines the model. The rest of the table defines the various options and features
of the Rosemount Oxymitter 4000. Ensure the features and options specified by your
order number are on or included with the unit.
Rosemount Oxymitter 40009
Description and specificationsReference Manual
April 202200809-0100-4340
Figure 1-1: Typical System Package
A. Quick Start Guide
B. Rosemount IMPS 4000 Intelligent Multiprobe Test Gas Sequencer (optional)
C. Rosemount Oxymitter 4000 with integral electronics
D. Rosemount SPS 4001B Single Probe Autocalibration Sequencer (optional) (safe area
only)
E. HART® Communicator package (optional)
F. Mounting plate with mounting hardware and gasket
G. Rosemount Oxymitter 4000 with remote electronics (optional)
H. Reference air set (used if Rosemount SPS 4001B without reference air option or
Rosemount IMPS 4000 is not supplied)
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Table 1-1: Rosemount Oxymitter 4000 Ordering Information
CodeSensing probe type with flame arrestor
1Ceramic diffusion element probe (ANSI 3-in. 150 lb.)
2Snubber diffusion element (ANSI 3-in. 150 lb.)
3Ceramic diffusion element probe (DIN 2527): ¼-in. (6.35 mm)
tube fittings
4Snubber diffusion element (DIN 2527): ¼-in. (6.35 mm) tube
fittings
7Ceramic diffusion element (ANSI 3-in. 300 lb.)
8Ceramic diffusion element (ANSI 4-in. 300 lb.)
CodeProbe assembly
018 in. (457 mm) probe
33 ft. (0.91 m) probe
56 ft. (1.83 m) probe
CodeMounting adapter - stack side
0No adapter plate (0 must be chosen under Mounting adapter -
probe side below)
1New installation - square weld plate with studs
2Model 218 mounting plate (with Model 218 shield removed)
3Adapter plate required; must reference adapter plate part
number.
CodeMounting adapter - probe side
0No adapter plate
1Probe only (ANSI)
4Probe only (DIN)
CodeElectronic housing & filtered customer termination - Type
®
4X, IP66
12HART integral electronics, transient protected filtered
3Gas fluorescent LOI HART capable, glass window, English only
Rosemount Oxymitter 400011
Description and specificationsReference Manual
April 202200809-0100-4340
Table 1-1: Rosemount Oxymitter 4000 Ordering Information (continued)
CodeLanguage
1English
2German
3French
4Spanish
5Italian
CodeTermination filtering
00No option - specified as part of electronic housing
CodeCalibration accessories
00No hardware
01Cal/Ref flow meters and ref pressure regulator
CodeHazardous area approval
00Specified as part of electronics
(1)
(1)
(1)
(1)
CodeElectronics to probe cable
00No cable
1020 ft. (6 m) cable
1140 ft. (12 m) cable
1260 ft. (18 m) cable
1380 ft. (24 m) cable
14100 ft. (30 m) cable
15150 ft. (45 m) cable
16200 ft. (61 m) cable
(1) Membrane keypad only.
Note
1. Recommended uses: High velocity particulates in flue stream, installation within
11.5 ft. (3.5 m) of soot blowers or heavy salt cake buildup. Applications: pulverized
coal, recovery boilers, or lime kiln.
2. Where possible, specify ANSI or DIN designation; otherwise, provide details of
existing mounting plate as follows:
Plate with studs
Bolt circle diameter, number and arrangement of studs,
stud thread, and stud height above mounting plate
Plate without studsBolt circle diameter, number, and arrangement of holes,
threads, and depth of stud mounting plate with accessories
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3. You can use the membrane keypad to start up, calibrate, and operate the
transmitter. Remote access and additional functionality available via HART
Communications.
Table 1-2: Rosemount OXT4CDR Oxymitter Probes
CodeSensing probe type with flame arrestor
1Ceramic diffusion element probe (ANSI), 115 V heater
2Snubber diffusion element (ANSI), 115 V heater
3Ceramic diffusion element probe (DIN), 115 V heater
4Snubber diffusion element probe (DIN), 115 V heater
7Ceramic diffusion element probe (ANSI) 3-in. 300 lb. bolt circle,
115 V heater
8Snubber diffusion element probe (ANSI) 3-in. 300 lb. bolt circle,
115 V heater
ACeramic diffusion element probe (ANSI), 44 V heater
BSnubber diffusion element (ANSI), 44 V heater
CCeramic diffusion element probe (DIN), 44 V heater
DSnubber diffusion element (DIN), 44 V heater
CodeProbe assembly
018 in. (457 mm) probe
33 ft. (0.91 m) probe
56 ft. (1.83 m) probe
CodeMounting adapter - stack side
0No adapter plate
1Probe only (ANSI)
4Probe only (DIN)
CodeElectronic housing & filter customer termination - Type 4X,
IP66
12Transient protected filtered termination
CodeExisting electronics
03No hardware, for use with 218A Electronics, World Class IFT, or
Oxymitter or X, V Electronics
07Westinghouse/Rosemount digital 132 electronics
08Yokogawa ZA-8 series electronics - max. operating temp of
junction box is 149 °F (65 °C).
09Other competitive electronics - specify brand and model
A typical Rosemount™ Oxymitter 4000 should contain the items shown in Figure 1-1.
Record the part number, serial number, and order number of each component of your
system.
The transmitter comes with the following:
• Signal conditioning electronics that output a 4-20 mA signal representing an O2 value.
• A membrane keypad or full function local operator interface for setup, calibration, and
diagnostics.
You can also access information from the transmitter with a HART® handheld
communicator or Asset Management Solution (AMS) software.
1.3Measurement
Emerson designed the Rosemount™ Oxymitter 4000 to measure the net concentration of
oxygen in an industrial process (i.e., the oxygen remaining after all fuels have been
oxidized). The probe is permanently positioned within an exhaust duct or stack and
performs its task without a sampling system.
The equipment measures oxygen percentage by reading the voltage developed across a
heated electrochemical cell, which consists of a small yttria stabilized zirconia (YSZ) disc.
Both sides of the disc are coated with porous metal electrodes. When the equipment is
operated at the proper temperature, the following Nernst equation gives the millivolt
output of the cell:
EMF = KT log10(P1/P2) + C
Rosemount Oxymitter 400017
Description and specificationsReference Manual
April 202200809-0100-4340
Where:
• P2 is the partial pressure of the oxygen in the measured gas on one side of the cell.
• P1 is the partial pressure of the oxygen in the reference air on the opposite side of the
cell.
• T is the absolute temperature.
• C is the cell constant.
• K is an arithmetic constant.
Note
For best results, use clean, dry, instrument air (20.95 percent oxygen) as the reference air.
When the cell is at an operating temperature and there are unequal oxygen
concentrations across the cell, oxygen ions will travel from the high oxygen partial
pressure side to the low oxygen partial pressure side of the cell. The resulting logarithmic
output voltage is approximately 50 mV per decade. The output is proportional to the
inverse logarithm of the oxygen concentration. Therefore, the output signal increases as
the oxygen concentration of the sample gas decreases. This characteristic enables the
transmitter to provide exceptional sensitivity at low oxygen concentrations.
The transmitter measures net oxygen concentration in the presence of all the products of
combustion, including water vapor. Therefore, it may be considered an analysis on a "wet"
basis. In comparison with older methods, such as the portable apparatus, which analyze
on a "dry" basis, the "wet" analysis will, in general, indicate a lower percentage of oxygen.
The difference between the "dry" and "wet" analyses will be proportional to the water
content of the gas stream.
1.4Configuration
Rosemount™ Oxymitter 4000 Transmitters are available in three length options, giving the
operator flexibility to use an in situ penetration appropriate to the size of the stack or duct.
The options are:
• Length: 18 in. (457 mm), weight: 29 lb. (13.15 kg)
• Length: 3 ft. (0.91 m), weight: 34 lb. (15.42 kg)
• Length: 6 ft. (1.83 m), weight: 44 lb. (19.96 kg)
The electronics control probe temperature and provide an isolated output, 4-20 mA, that
is proportional to the measured oxygen concentration. The power supply can accept
voltages of 90 - 250 Vac and 48/62 Hz; no setup procedures are required. Modulating the
duty cycle of the probe heater portion of the electronics maintains the oxygen sensing cell
at a constant temperature. The electronics accepts millivolt signals generated by the
sensing cell and produces the outputs to be used by remotely connected devices. The
output is an isolated 4-20 mA current.
The transmitter is available with an integral or remote electronics package. Two
calibration gas sequencers are available, the Rosemount IMPS 4000 and the Rosemount
SPS 4001B (Figure 1-2). The operator must install the Rosemount IMPS 4000 and the
Rosemount SPS 4001B in a nonhazardous, explosive-free environment.
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Figure 1-2: Rosemount Oxymitter 4000 Autocalibration System Options
A. Rosemount Oxymitter 4000
B. Rosemount SPS 40001B (1 probe). Must be installed in a safe area.
C. Rosemount IMPS 4000 (1 to 4 probes). Must be installed in a safe area or be X- or Z-
purged by the customer.
Systems with multiprobe applications may employ an optional Rosemount IMPS 4000
Intelligent Multiprobe Test Gas Sequencer. The Rosemount IMPS 4000 provides automatic
calibration gas sequencing for up to four Rosemount Oxymitter 4000 units and
accommodates autocailibrations based on the CALIBRATION RECOMMENDED signal from
the transmitter, a timed interval set up in HART® or the Rosemount IMPS 4000, or
whenever a calibration request is initiated.
For systems with one or two transmitter units per combustion process, the operator can
use an optional Rosemount SPS 4001B Single Probe Autocalibration Sequencer with each
transmitter to provide automatic calibration gas sequencing. The sequencer performs
autocalibrations based on the CALIBRATION RECOMMENDED signal from the transmitter,
a timed interval set up in HART, or whenever a calibration request is initiated.
1.5Features
The cell output voltage and sensitivity increase as the oxygen concentration decreases.
The Rosemount™ Oxymitter 4000 includes:
• An optional local operator interface (LOI), which allows continual O2 display and full
interface capability.
• Field replaceable cell, heater, thermocouple, diffuser, and PC boards.
• Rugged 316L stainless steel wetted parts.
• Electronics adaptable for line voltages from 90 - 250 Vac; no configuration is necessary.
Rosemount Oxymitter 400019
Description and specificationsReference Manual
April 202200809-0100-4340
• Membrane keypad available in five languages: English, French, German, Italian, and
Spanish.
An operator can communicate with the transmitter in one of three ways:
• Membrane keypad
• Local operator interface (LOI)
• Optional HART® interface
1.5.1Membrane keypad
The membrane keypad and HART® communications are standard.
Figure 1-3: Membrane Keypad
WARNING
Accessing the probe keypad requires opening the electronics housing.
Opening the electronics housing will cause the loss of all hazardous permits. Opening the
electronics housing in hazardous areas may cause an explosion resulting in loss of
property, severe personal injury, or death.
You may need to get a hot work permit from your company safety officer before opening
the electronic housing.
The membrane keypad, housed within the right side of the electronics housing, provides
flashing LEDs to indicate faults. You can calibrate from the membrane keypad.
To use the HART capability, you must have either:
• HART handheld communicator.
• Asset Management Solution (AMS) software for the PC.
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1.5.2Local operator interface (LOI)
The optional LOI takes the place of the membrane keypad and allows local communication
with the electronics.
Figure 1-4: LOI
1.5.3Optional HART® interface
The transmitter's 4-20 mA output line transmits an analog signal proportional to the
oxygen level. The HART output is superimposed on the 4-20 mA output signal.
WARNING
The HART option is not protected by energy limiting barriers.
Do not interface with the HART option from within the hazardous area.
Route the 4-20 mA cables and make the connections outside the hazardous area.
This is the case even when using the intrinsically safe version of the handheld
communicator.
You can access HART information through the following:
• Handheld communicator: Requires device description (DD) software specific to the
Rosemount™ Oxymitter 4000. The DD software is supplied with many handheld
communicator units, but Emerson service technicians can also program it into existing
units.
• Personal computer (PC): Requires AMS software available from Emerson.
• Selected distributed control systems: Requires input/output (I/O) hardware and AMS
software.
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Description and specificationsReference Manual
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1.6System considerations
Prior to installing the transmitter, make sure you have all the components necessary for
installation. Ensure all the components are properly integrated to make the system
functional.
CAUTION
Handle with care
The Rosemount™ Hazardous Area Oxymitter 4000 is designed for industrial applications.
Some probe components are made from ceramics, which are susceptible to shock when
mishandled.
Take adequate antistatic precautions to prevent equipment damage when handling
printed circuit boards and integrated circuits.
Treat each component of the system with care to avoid physical damage.
After verifying that you have all the components, select mounting locations and
determine how each component will be placed in terms of available line voltage, ambient
temperatures, environmental considerations, convenience, and serviceability.
WARNING
The HART option is not protected by energy limiting barriers.
Do not interface with the HART option from within the hazardous area.
Route the 4-20 mA cables and make the connections outside the hazardous area.
This is the case even when using the intrinsically safe version of the handheld
communicator.
Figure 1-5 shows a typical system wiring. Figure 1-6 shows a typical system installation
with integral electronics. Figure 1-9 shows a typical installation with remote electronics.
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Figure 1-5: Rosemount Oxymitter 4000 HART® Connections and AMS Application
A. Rosemount Oxymitter 4000 with integral electronics
B. 4-20 mA output (twisted pairs)
C. HART handheld interface
D. Asset Management Solutions
E. Termination in control room
F. Line voltage
G. Two calibration gas lines by customer (300 ft. [90 m]) maximum
Rosemount Oxymitter 400023
Description and specificationsReference Manual
April 202200809-0100-4340
Figure 1-6: Standard Installation with Integral Electronics
A. Adapter plate
B. Instrument air supply (reference air)
C. Pressure regulator
D. Calibration gas
E. Flow meter
F. 4 to 20 mA signal
G. Logic I/O
H. Line voltage
I. Rosemount Oxymitter 4000
J. Stack
K. Gases
L. Duct
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Figure 1-7: Rosemount IMPS 4000 Multiprobe Autocalibration Option Installation
with Integral Electronics
A. Duct
B. Calibration gas
C. Rosemount IMPS 4000
D. Reference air
E. Logic I/O
F. 4 to 20 mA signal
G. Line voltage
H. Rosemount Oxymitter 4000
I. Adapter plate
J. Stack
K. Gases
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Description and specificationsReference Manual
April 202200809-0100-4340
Figure 1-8: Rosemount 4001B Single Probe Autocalibration Option (with Reference
Air Option) Installation with Integral Electronics
A. Duct
B. Calibration gas
C. Rosemount SPS 4001B
D. Reference air
E. Logic I/O
F. 4 to 20 mA signal
G. Line voltage
H. Rosemount Oxymitter 4000
I. Adapter plate
J. Stack
K. Gases
WARNING
Install the Rosemount IMPS 4000 and SPS 4001B in a non-hazardous, explosive-free
environment.
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Figure 1-9: Standard Installation with Remote Electronics
A. Duct
B. Adapter plate
C. Instrument air supply (reference air)
D. Pressure regulator
E. Flow meter
F. Calibration gas
G. Line voltage
H. 4 to 20 mA signal
Figure 1-11: Rosemount SPS 4001B Single Probe Autocalibration Option (with
Reference Air Option) Installation with Remote Electronics
A. Duct
B. Calibration gas
C. Reference air
D. Rosemount SPS 4001B
E. Line voltage
F. Logic I/O
G. 4 to 20 mA signal
H. Line voltage
I. Remote electronics
J. Rosemount Oxymitter 4000
K. Adapter plate
L. Stack
M. Gases
A source of instrument air is optional at the transmitter for reference air use. Since the unit
can be equipped with an in-place calibration feature, you can make provisions to
permanently connect calibration gas bottles to the transmitter. If you are permanently
connecting the calibration gas bottles, use a check valve next to the calibration fittings on
the integral electronics. The check valve is to prevent breathing of the calibration gas and
subsequent flue gas condensation and corrosion. The check valve is in addition to the stop
valve in the calibration gas kit and solenoid valves in the Rosemount IMPS 4000 or SPS
4001B.
Note
The integral electronics is rated Type 4X (IP66) and is capable of operation at
temperatures up to 185 °F (85 °C). The optional LOI is also rated for operation at
temperatures up to 185 °F (85 °C). The infrared keypad functionality will degrade at
temperatures above 158 °F (70 °C).
Retain the transmitter's original packaging in case you need to ship the components to
another site. This packaging is designed to protect the product.
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1.7Optional Rosemount IMPS 4000
The programmable lead controller (PLC) in the Rosemount IMPS 4000 provides fault
indications using flashing LEDs and LCD display messages.
WARNING
Install the Rosemount IMPS 4000 in a non-hazardous, explosive-free environment. Refer to
the Rosemount IMPS Intelligent Multiprobe Test Gas Sequencer Reference Manual for
more information.
1.8Optional Rosemount SPS 4001B
WARNING
Install the Rosemount SPS 4001B in a non-hazardous, explosive-free environment. For
further information, refer to the Rosemount SPS 4001B Single Probe Autocalibration
Sequencer Reference Manual.
1.9Rosemount 751 remote powered loop LCD
display
The optional Rosemount 751 remote mounted LCD display panel is loop driven by the
4-20 mA output signal representing the O2 percentage.
The display provides a simple, economical means to obtain accurate, reliable, and remote
indication of important process variables. This display operates on the 4-20 mA line from
the Rosemount Hazardous Area Oxymitter 4000.