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RECOMMENDED pH SENSOR
STANDARDIZATION
For maximum accuracy, the sensor can be standardized on-line or with a process grab sample after a
buffer calibration has been performed and the sensor
has been conditioned to the process. Standardization
accounts for the sensor junction potential and other
interferences. Standardization will not change the sensor’s slope but will simply adjust the analyzer’s reading
to match that of the known process pH.
MAINTENANCE
Electrodes should respond rapidly. Sluggishness, offsets, and erratic readings are indicators that the electrodes may need cleaning or replacement.
1. To remove oil deposit, clean the electrode with a
mild non-abrasive detergent.
2. To remove scale deposits, soak electrodes for 30 to
60 minutes in a 5% hydrochloric acid solution.
3. Temperature effect on life expectancy: If glass electrode life expectancy is 100% @ 25°C (77°F), then
it will be approximately 25% @ 80°C (176°F), and
approximately 5% @ 120°C (248°F).
TWO POINT BUFFER CALIBRATION
Select two stable buffer solutions, preferably pH 4.0 and 10.0 (pH buffers other than pH 4.0 and pH 10.0 can be
used as long as the pH values are at least two pH units apart).
NOTE
A pH 7 buffer solution reads a mV value of approx. zero, and pH buffers read approximately ± 59.1
mV for each pH unit above or below pH 7. Check the pH buffer manufacturer specifications for millivolt values at various temperatures since it may affect the actual value of the buffer solution
mV/pH value.
1. Immerse sensor in the first buffer solution. Allow sensor to equilibrate to the buffer temperature (to avoid errors
due to temperature differences between the buffer solution and sensor temperature) and wait for reading to
stabilize. Value of buffer can now be acknowledged by analyzer/transmitter.
2. Once the first buffer has been acknowledged by the analyzer/transmitter, rinse the buffer solution off of the
sensor with distilled or deionized water.
3. Repeat steps 1 and 2 using the second buffer solution.
4. The theoretical slope value, according to the Nernst equation for calculating pH, is approximately 59.17 mV/pH.
Over time the sensor will age, both in the process and in storage, and will result in reduced slope values. To
ensure accurate readings, it is recommended that the electrode be replaced when the slope value falls below
47 to 49 mV/pH.