Fisher-Rosemount GmbH & Co assumes no liability for any omissions or errors in this manual.
Any liability for direct or indirect damages, which might occur in connection with the deliv ery or the use of
this manual, is expressly e xcluded to the extend permitted by applicable law.
This instrument has left the works in good order according to safety regulations.
T o maintain this operating condition, the user must strictly follow the instructions and consider the warnings
in this manual or provided on the instrument.
Troub leshooting, component replacement and internal adjustments must be made by qualified
service personnel only.
According to the report No. “IBS/PFG-No. 41300392” about the approval of “DMT - Gesellschaft für
Forschung und Prüfung mbh, F achstelle für Sicherheit - Prüfstelle für Grubenbewetterung”, the stationary
®
gas analyzer BINOS
and of carbon dioxide between 0 and 80 % CO2. The system control with serial interfaces as described
CH
4
100 is suitable for measuring the concentrations of methane between 0 and 80 %
in this operation manual have not been subject to the DMT-approval. The DMT -in vestigation has no validity
®
for BINOS
100 M (combined NDIR / Oxygen measurement).
According to the report No. 95CU054/B about the appro val of “TÜV Nord mbH” the gas analyzer BINOS
100(M) is suitable for CO measuring according to TI Air and 13. BlmSchV (large furnaces order) and for
measuring according to TI Air , 13th BlmSchV (large furnaces order) and 17th BlmSchV (incineration).
Read this operation manual carefully before attempting to operate the analyzer !
For expedient handling of reports of defects , please include the model and serial number which
can be read on the instrument identity plate.
Look for the error check list please too (see Item 29. of this manual)
Fisher - Rosemount GmbH & Co.
®
Industriestrasse 1
D - 63594 Hasselroth
Phone + 49 60 55 / 884 - 0
Telefax + 49 60 55 / 884 - 209
90002953(2) BINOS® 100(M) e [4.10] 19.11.97
Page 3
CONTENTS
CONTENTS
INTRODUCTIONE - 1
SAFETY SUMMARYS - 1
GeneralS - 1
Gases and Gas Conditionning (Sample Handling)S - 2
Supply VoltageS - 3
Connection CablesS - 3
Electrostatic DischargeS - 4
Operating Conditions according to DMT - ApprovalS - 5
23.Check and Replacement of the Oxygen Sensor23 - 1
23.1Check of the Sensor23 - 2
23.2Replacement of the Sensor23 - 3
23.2.1Removal of the Sensor23 - 3
23.2.2Exchange of the Sensor23 - 4
23.2.3Reinstalling of the Sensor23 - 4
23.2.4Basic conditions for the Oxygen Sensor23 - 5
90002953(2) BINOS® 100(M) e [4.10] 19.11.97
V
Page 8
CONTENTS
TECHNICAL DATA24 - 1
24.1Voltage Supply24 - 4
24.1.1Electrical Safety24 - 4
24.1.2Power Supply24 - 4
SUPPLEMENT
25.Replacing the EPROM25 - 1
26.Pin - Assignments26 - 1
27.Connection Cable27 - 1
28.Open
29.Failure Check List29 - 1
INDEXR - 1
List of FiguresR - 7
VI
90002953(2) BINOS® 100(M) e [4.10] 19.11.97
Page 9
INTRODUCTION
Introduction
The BINOS® 100 gas analyzer is a member of the 100 series of our gas analyzers program. It is
designed for the continuous monitoring of gas concentrations and uses infrared absorption for its
operation.
The BINOS® 100 M analyzer includes both, one infrared channel and one electrochemical
channel for oxygen measurement.
The compactness of the BINOS® 100 (M) permits its use in a wide variety of applications in industry
and research. Energy conservation, occupational safety, and quality assurance are the major
areas addressed.
Some typical specific applications are:
❏Flue gas analyses for combustion efficiency in firing systems, gas cleaning systems
and legislation compliance (CO / CO2 or CO / O2)
❏Analysing landfill gas for ex protection (CH4 / CO2, CO2 / O2, CH4 / O2 combinations)
❏Monitoring metallurgical processes in metals refining and processing (CO / CO2 / HC)
❏Quality monitoring of natural gas (CO2)
❏Monitoring fermentation and sewages processes in biotechnology (CO2)
❏Motor vehicle exhaust gas analyses (Internal Combustion Engine Emissions)
❏Air quality monitoring [vehicular tunnel, gas production, personal protection (CO / CO2 / HC)]
❏Food industry
❏Universities and Research Institutes
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E - 1
Page 10
INTRODUCTION
The analyzers of the BINOS® 100 (M) series are complete, ready - to - use, gas analyzers which
may be directly inserted into existing or planned gas lines.
Since BINOS® 100 (M) is working according to the extractive measuring method an adequate
sample handling system has to be provided.
The analyzer is microprocessor controlled.
Programming available with use of optional, external solenoid valves permit fully automatic
calibration of the analyzer.
All inputs required may be activated by a host computer via an optional serial interface
(RS 232 C / 485), for networking applications.
Note:
Read this operation manual carefully before attempting to operate the analyzer !
For single - channel analyzers:
The display, entries and error messages for the second channel described
in this manual are inapplicable.
E - 2
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Safety Summary
In this manual we hav e used the following safety symbols
to draw y our attention to strictly f ollow these instructions !
1.General
SAFETY SUMMARY
GENERAL
◆The follo wing general safety precautions must be observed during all phases of operation,
service and repair of this instrument !
Failure to comply with these precautions or with specific w arnings elsewhere in this manual
violates safety standards of design, manuf acture and intended use of this instrument !
Failure to comply with these precautions may lead to personal injury and damage to this
instrument !
◆Fisher-Rosemount GmbH & Co . assume no liability for the customer´s f ailure to comply with
these requirements !
◆Do not attempt internal service or adjustment unless other person, capable of rendering first
aid and resuscitation, is present !
◆Because of the danger of introducing additional hazards, do not perform any unauthorized
modification to the instrument !
Return the instrument to a Fisher-Rosemount Sales and Service office for service or repair
to ensure that safety f eatures are maintained !
◆Operating personnel must not remove instrument covers !
Component replacement and internal adjustments must be made by qualified service
personnel only !
◆Instruments which appear damaged or defective should be made inoperativ e and secured
against unintended operation until they can be repaired by qualified service personnel.
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S - 1
Page 12
SAFETY SUMMARY
GENERAL / GASES AND GAS CONNECTIONS
Read this operation manual carefully before attempting to operate with the
instrument !
Do not operate the instrument in the presence of flammable gases, explosive
atmosphere or furnes without supplementary protective measures !
The installation site for the instrument has to be dry and remain above freezingpoint at all times.
The instrument must be exposed neither to direct sunlight nor to strong sources
of heat. Be sure to observe the permissible ambient temperature !
For outdoor sites, we recommend to install the instrument in a protective cabinet.
At least, the instrument has to be protected against rain (e.g., shelter).
Due to the high temperatures of photometer or heated components there is a
danger of burns to the operators.
2.Gases and Gas Conditionning (Sample Handling)
Do not interchange gas inlets and gas outlets !
All gases have to be supplied to the system as conditionned gases !
When the instrument is used with corrosive gases, it is to be verified that there
are no gas components which may damage the gas path components.
The exhaust gas lines have to be mounted in a declining, descending,pressureless and frost-free and according to the valid emission legislation !
Be sure to observe the safety regulations for the respective gases
(sample gas and test gases / span gases) and the gas bottles !
S - 2
Inflammable or explosiv e gas mixtures must not be purged into the instrument
without supplementary protective measures !
To avoid a danger to the operators by explosive, toxic or unhealthy gas
components, first purge the gas lines with ambient air or nitrogen (N2) before
cleaning or exchange parts of the gas paths.
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Page 13
SAFETY SUMMARY
SUPPLY VOLTAGE
3.Supply Voltage
◆Verify correct polarity for 24 V DC - operation !
◆This product is a Safety Class 1 instrument (provided with a protective earth terminal).
To prevent shock hazard, the instrument chassis and cabinet must be connected to an
electrical ground. The instrument must be connected to the AC power supply mains through
a three-conductor power cable , with the third wire firmly connected to an electrical ground
(safety ground) at the po wer outlet. If the instrument is to be energized via an external power
supply, that goes f or the power supply too.
Any interruption of the protective (grounding) conductor or disconnection of the protectiv e
earth terminal will cause a potential shock hazard that could result in personal injury.
Deliberate disconnection is inadmissible / prohibited !
◆Use only power supply VSE 2000 or equiv alent power supplys to be in agreement with the
CE - conformity.
◆In case of exchanging fuses the customer has to be certain that fuses of specified type and
rated current are used. It is prohibited to use repaired fuses or def ective fuse holders or to
short-circuit fuse carriers (fire hazard).
◆Always disconnect po wer, discharge circuits and remove e xternal voltage sources before
troubleshooting, repair or replacement of any component !
Any work inside the instrument without switching off the power must be
performed by a specialist, who is familiar with the related danger, only !
4.Connection Cables
◆Use only from our factory optional delivered cables or equivalent shielded cables to be in
agreement with the CE - conformity.
The customer has to guarantee, that the shield is be connected bothsided.
◆By using of optional delivering terminal strip adapters the analyzer is not be in agreement
with the CE - conformity. In this case CE - conformity is to be declared by customer as
“manufacturer of system”.
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S - 3
Page 14
SAFETY SUMMARY
ELECTROSTATIC DISCHARGE
5.Electrostatic Discharge
The electronic parts of the analyzer can be irreparably damaged if exposed to electrostatic
discharge (ESD).
The instrument is ESD protected when the covers have been secured and safety precautions
observed. When the housing is open, the internal components are not ESD protected anymore.
Although the electronic parts are reasonably safe to handle, you should be aw are of the following
considerations:
Best ESD example is when you walk ed across a carpet and then touched an electrically grounded
metal doorknob. The tiny spark which has jumped is the result of electrostatic discharge (ESD).
You prevent ESD by doing the following:
Remove the charge from your body before opening the housing and maintain during work with
opened housing, that no electrostatic charge can be built up.
Ideally you are opening the housing and working at an ESD - protecting workstation.
Here you can wear a wrist trap.
However , if y ou do not have such a workstation, be sure to do the following procedure exactly:
Discharge the electric charge from your body. Do this by touching a device that is electrically
grounded (any device that has a three - prong plug is electrically grounded when it is plugged into
a power receptacle).
This should be done several times during the operation with opened housing (especially after
leaving the service site because the movement on a low conducting floors or in the air might cause
additional ESDs).
S - 4
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Page 15
SAFETY SUMMARY
OPERATING CONDITIONS ACCORDING TO DMT - APPROVAL
6.Operating Conditions according to DMT - Approval
(Chapter 6 of the supplement I to the DMT - report No. “IBS/PFG-No. 41300392” about the
®
performance test of the stationary gas analyzer BINOS
100.
According to the system version and measuring results included in this report, the stationary gas
analyzer BINOS® 100 from Rosemount GmbH & Co. is suitable for measuring the concentrations
of methane between 0 and 80 % CH4 and of carbon dioxide between 0 and 80 % CO2, if the features
and system version go conform with the details contained in the enclosed documents as stated
in this report, if the analysis system is operated accordingly and if the following requirements are
met:
◆When using the gas warning system, it must be ensured that the permissible variations will
not be exceeded, taking into account the systematics f ailures of the measuring signals (as
indicated in this report) and the local operating conditions. Consider the Code of Pratice No .
T032 of the Labor Association of the Chemical Industry "Usage of stationary gas warning
systems for explosion protection".
◆Verify that the explosion protection requirements are met when using the gas warning
system.
◆Depending on the situation, it must be verified that the preset values are lo w enough to allow
the system to activate the necessary protection and emergency measures and, thus, to
prev ent an y critical situations in a minimum period of time.
◆When at system installation, a release of one or both measuring components in the ambient
air might occur, its influence on the measuring result should be prov ed. A sealed cell or an
external housing purging with sample-free air of measuring gases can be used, if required.
◆The operatability of the alarms and the displays of each system should be tested with clean
air and test gas after the initial operation, after each long-time interruption, and periodically .
The tightness of gas pathes should also be tested. The tests must be documented by
keeping accounts.
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S - 5
Page 16
SAFETY SUMMARY
OPERATING CONDITIONS ACCORDING TO DMT - APPROVAL
◆The intervals for the periodical tests must be settled by the person being responsib le for the
system´s security and in accordance with the Code of Pratice No. T023 of the Labor
Association of the Chemical Industry "Maintenance of stationary gas warning systems for
explosion protection".
◆Consider the superproportional dependency of the barometric pressure on the measured
value f or CO2.
◆The system control with serial interfaces described in this operation manual hav e not been
subject to this investigation.
◆Sample gas condensation in analyzer (components) must be prevented by taking the
necessary steps.
◆When the system is used with aggressive gases, it is to be verified that there are no gas
components which might damage the gas path components.
◆Appropriate dust filters must precede the used systems.
◆The pressure and flow values recommended b y the manufacturer should be observed. An
external monitoring of the sample gas flow through the analyzer should be provided.
◆The results of this investigation are based on the systems using software versions "3.03" and
"4.00" and "4.01". A change of the software version used must be certified by the Testing
Association.
◆It should be ensured that the system parameters for the analog output ha ve been correctly
adjusted. End of range of low concentration should not be identical or low er than the begin
of range. Disregarding these versions, the measurement range should be adjusted between
0 to 80 % CH4 and 0 to 80 % CO2 when the systems are used for e xplosion protection.
◆Read and follow the operation and maintenance manual supplied to and certified by PFG.
It is important that the temperature is kept between 5 and 45 °C.
S - 6
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Page 17
SAFETY SUMMARY
OPERATING CONDITIONS ACCORDING TO DMT - APPROVAL
◆The analyzer housings must be pro vided with a permanent type plate indicating the name
of the manufacturer , model number , serial number, and the f ollowing ref erence and date of
testing:
"IBS/PFG-Nr. 41300392"
Other designation requirements, such as these according to Ele xV, are still valid. With this
type plate, the manuf acturer conformes that the features and technical data of the delivered
system are identical with those described in this report. Any system which is not provided
with such a type plate does not go conform with this report.
◆The chapter 6 of this report must be included in the operation and maintenance manual.
◆The manufacturer has to supply the customer with a copy of this report, if required.
◆A print of the report in an abridged version requires the agreement of PFG.
◆The results included in this report may not be altered in publications produced by the
manufacturer.
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S - 7
Page 18
SAFETY SUMMARY
S - 8
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Page 19
SETUP
FRONT PANEL
1.Setup
The analyzer it incorporated in a 1/4 19" rack-mounting housing, 3 height units.
The optional table-top housing is fitted with a carrying strap and rubber feets additional.
1.1Front Panel
The front panel (see Fig. A-1) includes the LED - displays and all of the analyzer operating controls.
1.2Rear Panel
The rear panel (Fig. A-2) includes
❏the gas line fittings
❏the plug for the electrical supply input
❏the sub-miniature “D” mating socket for the analog signal outputs
❏the sub-miniature “D” plug for the digital outputs (concentration limits and valve control)
❏optionally the sub-miniature “D” mating socket for the RS 232 C / 485 - interface
❏optionally the sub-miniature “D” plug for the status signals (relay outputs)
90002953(2) BINOS® 100(M) e [4.10] 19.11.97
1 - 1
Page 20
SETUP
REAR PANEL
1.3Inside View
The inside view is shown in Fig. 1-1 and Fig 1-2.
❏Depending of analyzer
-one IR - photometer
-two IR - Photometer
-one O2 - sensor (electrochemical) and one IR - Photometer
{no DMT - certification)
-one pressure sensor (optional)
1 - 2
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Page 21
Cover metal plate
SETUP
INSIDE VIEW
Gas line fittings
PCB BKS
(channel 2)
Front panel
IR-Photometer
(depending on analyzer)
(channel 1)
Pressure sensor
(option)
(1 IR - channel analyzer, high measuring range with gas detector)
90002953(2) BINOS® 100(M) e [4.10] 19.11.97
Fig. 1-1: Inside View BINOS® 100
1 - 3
Page 22
SETUP
INSIDE VIEW
Gas line fittings
Cover metal plate
PCB BKS
IR - Photometer
(depending on analyzer)
(channel 2)
electrochemical
Oxygen sensor
with PCB “OXS”
(channel 1)
Pressure sensor
(option)
1 - 4
Front panel
Fig. 1-2: Inside View BINOS® 100 M
(IR - channel / electrochemical oxygen measurement, no DMT - certification)
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Page 23
PHOTOMETER ASSEMBLY
PYROELECTRICAL DETECTOR
2.Photometer Assembly
Depending on gas component and measuring range, different photometer assemblies will be
realized in BINOS® 100 (M).
Optional the photometer can be sealed to ambient air. In this case all parts are sealed with O rings.
The entire photometer assembly is mounted as a unit on the main circuit board (BKS) by means
of a bracket. The main circuit board is inserted into guide rails in the analyzer housing, to which
the front panel (membrane keypad) and the rear panel are assembled.
2.1Photometer with Pyroelectrical Detector (Solid-state detector)
Fig. 2-1 shows the schematical photometer assembly for dual - channel operation.
The base element for the photometer assembly is the chopper housing (03), upon which the light
source (thermal radiator, 07), the analysis cell (cuvette , 09), and the signal detection unit [filter cell
(14/15), pyroelectrical (solid-state) detector with integrated preamplifier (16)] are all mounted.
The chopper housing also incorporates the duplex filters (04/05) for the selection of spectral bandpass ranges from the broadband emission of the light sources.
Between the two halves of the chopper housing (03), which are sealed together with an O-ring,
is the chopper blade, driven by a stepping motor. Both the chopper housing and the motor
encapsulation are hermetically sealed with respect to the ambient in order to prevent entry of
gases, such as atmospheric CO2, which could produce background absorptivity (preabsorption)
leading to drift effects. An absorber material provides f or constant remo v al of an y tr aces of CO
which may enter the interior of the chopper housing via diffusion.
2
The chopper housing additionally incorporates a photoelectric gate for providing a reference
signal for the phase angle of the chopper blade, plus a temperature sensor (28) for monitoring
continuously the photometer assembly temperature. This temperature information is used by the
signal processing electronics for the compensation of thermal effects .
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2 - 1
Page 24
PHOTOMETER ASSEMBLY
PYROELECTRICAL DETECTOR
The analysis cells are merely aluminum tubes equipped with sample gas inlet and outlet fittings.
This extremely simple and windowless design enab les easy cleaning of the cells in the e v ent of
contamination.
The only optical surfaces which also might become contaminated are the chopper windows and
the windows of the filter cells; these are accessible upon removal of the cell body.
The filter cell (14/15) has a necked conical shape f or optimal adaptation of the analysis cell beam
cross - sectional profile to the active area of the detectors.
For high measurement ranges (up to 100 %), an adapter cell (10) is required.
The use of a spacer ring (08) creates an analysis cell in the space between the exit window of the
adapter cell and the entrance window of the filter cell.
2 - 2
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Page 25
PHOTOMETER ASSEMBLY
PYROELECTRICAL DETECTOR
Legends:
03Chopper Housing
04 / 05Duplex Filter Disc
06Zero - Adjustment Baffle (not for sealed photometer)
07Light Source (thermal radiator)
08Analysis Cell 1 - 7 mm (spacer ring)
09Analysis Cell 50 - 200 mm
10Adapter Cell
14/15Filter Cell
16Detector
17Flange (light source)
18-21O - Rings
22Clamp (analysis cells 1-7 mm)
23 (24)Clamping Collar (analysis cells 1-7 mm)
25Clamp (analysis cells 10-200 mm)
26Light Source Mounting Screws
27Mounting Screws for Analysis Cells/Adapter Cells
28Temperature Sensor
Fig. 2-1: Photometer Assembly with Pyroelectrical Detector
90002953(1) BINOS® 100(M) e [4.01] 25.09.96
2 - 3
Page 26
PHOTOMETER ASSEMBLY
GAS - DETECTOR
2.2Photometer with Gas Detector
Fig. 2-2 shows schematically the photometer assembly.
This assembly is similar to the assembly with p yroelectrical detector.
The analysis cells are separated into two halves b y means of an internal wall along its axis and
both ends are sealed with windows. This divided the analysis cell in measuring side and reference
side.
Sample gas is flowing through measuring side while the closed reference side contains inert gas
(N2).
To prevent measuring errors by preabsorption, two absorber , fitted to the gas connections of the
reference side, absorb CO2 - parts.
The filter cell has a single - stage conical shape.
The gas detector is connected by a shielded cable to the separate preamplifier.
For small measuring ranges the preamplifier is mounted at the analysis cell.
For high measuring ranges the preamplifier is mounted at two holding clamps.
2 - 4
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Page 27
PHOTOMETER ASSEMBLY
GAS - DETECTOR
3521
Fig. 2-2: Photometer Assembly BINOS® 100 with Gas Detector
[example above: high measuring ranges, example below: small measuring ranges
90002953(1) BINOS® 100(M) e [4.01] 25.09.96
1654 623
(only one measuring channel without O2 measurement).
Depending on analyzer model different measuring methods will be used.
3.1IR - Measurement
The analyzers are non - dispersive infrared photometers (NDIR) using measurement of selectiv e
radiation in a column of gas.
The measuring effect devided from absorption of infra - red radiation is due to the gas being
measured. The gas - specific wavelengths of the absorption bands characterize the type of gas
while the strength of the absorption gives a measure of the concentration of the component
measured. Due to a rotation chopper wheel, the r adiation intensities coming from measuring and
reference side of the analysis cell produce periodically changing signals within the detector.
The detector signal amplitude thus alternates between concentration - dependent and concentration - independent values. The difference between the two is a reliable measure of the
concentration of the absorbing gas component.
Dependent on measuring component and measuring concentration, two different measuring
methods will be used.
The undivided analysis cell is alternately illuminated with filtered light concentrated in one of two
spectral separated wav e length ranges. One of these two spectrally separ ated wave length bands
is chosen to coincide with an absorption band of the sample gas, and the other is chosen such
that none of the gas constituents expected to be encountered in practice absorbs anywhere within
the band.
The spectral transmittance curves of the interference filters used in the BINOS® 100 analyzer and
the spectral absorption of the gases CO and CO2 are shown in Fig. 3-1. It can be seen that the
absorption bands of these gases each coincide with the passbands of one of the interference
filters. The fourth interference filter , used for generating a ref erence signal, has its passband in a
spectral region where none of these gases absorb. Most of the other gases of interest also do not
absorb within the passband of this reference filter.
Fig. 3-1: Absorption Bands of Sample Gases and Transmittance of the
Interference Filters used
The signal generation happens by a pyroelectrical (solid-state) detector.
The detector records the incoming IR - radiation. This radiation intensity is reduced by the
absorption of the gas at the according wave lengths. By comparing the measuring and reference
wave length an alternating voltage signal is developed. This signal results from cooling and heating
of the pyroelectrical material of the detector.
3 - 2
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Page 31
MEASURING PRINCIPLE
IR - MEASUREMENT
3.1.2Opto - Pneumatic Measuring Principle
A thermal radiator generates the infrared radiation passing through a chopper wheel. This
radiation alternately passes through a filter cell and reaches reaches the measuring and reference
side of the analysis cell with equal intensity.
After passing another filter cell the radiation reaches the pneumatic detector.
The pneumatic detector compares and ev aluates the radiation from the measuring and reference
sides and converts them into voltage signals proportional to their intensity via a preamplifier.
The detector consists of a gas-filled absorption and a compensation chamber which are
interconnected via a flow channel.
Absorption chamber
Flow channel with
Microflow sensor
CaF2 Window
Gas intake connection
Compensation chamber
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Fig. 3-2: Principle Design of Gas Detector
3 - 3
Page 32
MEASURING PRINCIPLE
IR - MEASUREMENT
In principle the detector is filled with the infrared active gas to be measured and is only sensitive
to this distinct gas with its characteristic absorption spectrum. The absorption chamber is sealed
with a window which are transparent for infrared r adiation [usually CaF2 (Calcium fluoride)].
When the IR - radiation passes through the reference side of the analysis cell into the detector,
no preabsorption occurs. Thus the gas inside the absorption chamber is heated, expands and
some of it passes through the flow channel into the compensation chamber .
When the IR - radiation passes through the open measurement side of the analysis cell into the
detector, a part of it is absorbed depending on gas concentration. The gas in the absorption
chamber then is heated less than in the case of radiation coming from reference side. Absorption
chamber gas become colder, gas pressure in the absorption chamber is reduced and some gas
of compensation chamber passes through the flow channel into the absorption chamber.
The flow channel geometry is designed in such a way that it hardly impedes the gas flow by
restriction. Due to the radiation of chopper wheel, the different radiation intensities lead to
periodically repeated flow pulses within the detector.
The microflow sensor ev aluates this flow and converts it into electrical voltages.
The electronics, which follow , evaluate the signals and convert them into the corresponding display
format.
3 - 4
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Page 33
MEASURING PRINCIPLE
123
123
IR - MEASUREMENT
3.1.3Technique
The broadband emission from two IR sources (in the case of dual - channel analyzers) passes
through the chopper blade, then, if IFC, through combinations of interference filters, if
optopneumatic principle depending on application through an optical filter (reduction of influences) and enters the analysis cells. The light transmitted through these cells is f ocused by filter
cells onto the according detector. The preamplified detector output signal is sent to microprocessor
circuitry , which converts the analytical signals to results expressed directly in physical concentr ation units (Vol.-%, ppm, mg/Nm3 etc.).
Light source
Analysis cell measuring side
Analysis cell reference side
MOTOR
Duplex filter disc
Adapter cell
(high measuring range)
Analysis cell
(undivided)
Filter cell
Preamplifier
Filter cell
Gas detector
90002953(1) BINOS® 100(M) e [4.01] 25.09.96
Pyroelectrical detector
(solid-state detector)
Preamplifier
Chopper blade
Fig. 3-3: Principle Representation
3 - 5
Page 34
MEASURING PRINCIPLE
OXYGEN MEASUREMENT (ELECTROCHEMICAL PRINCIPLE)
3.2Oxygen Measurement (Electrochemical Principle)
The determination of O2 - concentrations is based on the principle of a galvanic cell.
The principle structure of the oxygen sensor is shown in Fig. 3-4.
Lead wire (Anode)
Lead wire (Cathode)
Anode
O - ring (8)
Plastic disc (9)
Plastic top (10)
(1)
(Lead)
(Black)
Thermistor (5)
Acid electrolyte (3)
Sponge disc (7)
Cathode
(2)
Teflon membrane (4)
(Red)
Resistor (6)
(Gold film)
Fig. 3-4: Structure of electrochemical Oxygen Sensor
The oxygen senor incorporate a lead/gold oxygen cell with a lead anode (1) and a gold cathode
(2), using a specific acid electrolyte. T o avoide moisture losses at the gold electrode a sponge sheet
is inserted on the purged side.
Oxygen molecules diffuse through a non-porous T eflon membrane (4) into the electrochemical cell
and are reduced at the gold-cathode. Water results from this reaction.
On the anode lead oxide is formed which is transferred into the electrolyte. The lead anode is
regenerated continuously and the electrode potential therefore remains unchanged for a long
time.
The rate of diffusion and so the response time (t90) of the sensor is dependent on the thickness
of the Teflon membrane.
3 - 6
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MEASURING PRINCIPLE
OXYGEN MEASUREMENT
(Red)(Black)
Thermistor (5)
(-)
Gold-
Cathode (2)
O2 + 4 H+ + 4 e- → 2 H2O
Summary reaktion O
(11)
Resistor (6)
Electrolyte (3)
(ph 6)
+ 2 Pb → 2 PbO
2
2 Pb + 2 H2O → 2 PbO + 4 H+ + 4 e
Fig. 3-5: Reaction of galvanic cell
(+)
Lead-
Anode (1)
-
The electric current between the electrodes is propor tional to the O2 concentration in the gas
mixture to be measured. The signals are measured as terminal voltages of the resistor (6) and the
thermistor (5) for temperature compensation.
The change in output voltages (mV) of the senor (11) represents the o xygen concentration.
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MEASURING PRINCIPLE
3 - 8
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MAIN FEATURES
4.Main Features
◆1/4 19" housing, 3 HU
◆Possibility of two measuring components (2-channel analyzer). Depending of analyzer
-one IR - photometer
-two IR - Photometer
-one O2 - sensor (electrochemical) and one IR - Photometer {no DMT - certification)
◆4 - digit LED - measuring value display and operators prompting via this displa ys for each
measuring channel
◆The response time (t90 - time) can be adjusted separately for each measuring channel
◆Plausibility checks
◆Temperature compensations
◆Interference compansation f or reduction of disturbing effects due to extr aneous absorption
◆Monitoring of two free adjustable concentration limits for each measuring channel
(max. 30 V DC / 30 mA, “Open Collector”, optically isolated)
◆Automatic calibration using z eroing and spanning at preselected intervals
(external solenoid valv es are required for this)
◆RS 232 C/485 serial interface for data intercommunications with host computers (optional)
◆Status signals as option (Non-voltage-carrying contacts, max. 42 V / 1 A)
◆Self - diagnostic procedures, plus maintenance and servicing support functions
◆Operator prompting for the avoidance of operator errors
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Page 38
MAIN FEATURES
4 - 2
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Page 39
PREPARATION
INSTALLATION SITE
5.Preparation
Please check the packing and its contents immediately upon arrival.
If any damage or missing items are found, then we request that you notify the forwarder to
undertake a damage surve y and report the loss or damage to us immediately.
5.1Installation
The analyzer must not operate in explosive atmosphere without supplementary protective
measures !
The installation site for the analyzer has to be dry and remain above freezing point at all times.
The analyzer must be exposed neither to direct sunlight nor to strong sources of heat.
Be sure to observe the permissible ambient temperatures (c.f. Item 24: Technical Data).
For outdoor installation, we recommend to install the analyzer in a protectiv e cabinet. At least, the
analyzer has to be protected against rain (e.g., shelter).
The analyzer has to be installed as near as possible to the sample point, in order to av oid low
response time caused by long sample gas lines.
In order to decrease the response time, a sample gas pump with a matching high pumping rate
may be used. Ev entually, the analyzer has to be operated in the bypass mode or by an ov erflow
valve to prevent too high flow and too high pressure (Fig. 5-1).
Exhaust
Bypass valve
Gas sampling pump
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Analyzer
Flow meter
Filter
Fig. 5-1: BINOS® 100 (M), Bypass installation
Exhaust
5 - 1
Page 40
PREPARATION
GAS CONDITIONNING (SAMPLE HANDLING)
5.2Gas Conditionning (Sample Handling)
The conditionning of the sample gas is of greatest importance for the successful operation of any
analyzer according to extractiv e method.
Only conditionned gas has to be supplied to the analyzer !
The gas has to fullfil the following conditions:
It must be
❏free of condensable constituents
❏free of dust
❏free of aggressive constituents which are not compatible with the material of the gas
paths.
❏have temperatures and pressures which are within the specifications stated in “Technical
Data” of this manual.
Inflammable or explosive gas mixtures may not be intr oduced into the analyzer
without supplementary protective measures !
When analysing vapours, the dewpoint of the sample gas has to be at least 10 °C below the
ambient temperature in order to avoid the precipitation of condensate in the gas paths .
Suitable gas conditionning hardware may be supplied or recommended for specific analytical
problems and operating conditions.
5.2.1Gas Flow Rate
The gas flow rate should be within the range 0.2 l/min to maxi. 1.5 l/min !
A constant flow rate of about 1 l/min is recommended.
5 - 2
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PREPARATION
GAS CONNECTIONS
5.3Gas Connections
All the fittings for gas line connections are placed just on the rear panel of the analyzer and are
clearly marked:
IN = gas inlet (Fig. 5-2 and Fig. A-2, Item 1)
Out = gas outlet (Fig. 5-2 and Fig. A-2, Item 5)
For one-channel analyzer and dual-channel analyz ers tubed in series, only the 2 gas line fittings
for channel 1 are present. If the two channels are tube parallel, then all 4 fittings will be present.
Do not interchange gas inlets and gas outlets !
The exhaust gas lines have to be mounted in a declining, pressureless and frost-free way and
according to the valid emission legislation!
Zero gas and span gas are introduced directly via the gas inlet. The test gas containers have to
be set up according to the current legislation.
Be sure to observe the safety regulations f or the respective gases !
K1K2K1K2
Gas inlets
IN
OUT
Gas outlets
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X1 OUTPUT
INTERFACE
Fig. 5-2: Gas Connections BINOS® 100 (M)
5 - 3
Page 42
PREPARATION
5 - 4
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SWITCHING ON
6.Switching On
Once the analyzer has been correctly assembled and installed in accordance with the general
instructions of section “5. Preparation”, the analyzer is ready for operation.
The analyzer is specified for an operating voltage of 24 V DC (+ 20 % / - 50 %).
Operation from 230 / 115 V AC requires the 24 V DC supply via VSE 2000 or equivalent power
supply.
X1 OUTPUT
INTERFACE
X2 OUTPUT
24 VDC
MADE IN GERMANY
Fig. 6-1: Supply Voltage BINOS® 100 (M)
X3 OUTPUT
plug
24 V DC
6.1Battery Operation
❍Connect battery and analyzer (Fig. 6-1, Plug 24 V DC).
Verify beforehand that the battery voltage agrees with the allowed supply
voltage of the analyzer ! Verify correct polarity before operation !
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SWITCHING ON
6.2Power Supply Operation
❍Connect mains line and power supply.
Verify beforehand that the line voltage stated on the power supply agrees
with that of your power supply line !
❍Connect power supply and analyzer (Fig. 6-1, Plug 24 V DC).
Verify correct polarity bef ore operation !
The presence of the supply voltage will be indicated by the illumination of the LED displa ys.
Upon connection of the supply voltage, the analyzer will perform a self - diagnostic test routine.
First the actual program version will be shown.
Finally either concentration values or error messages will be displayed
If as a result of a battery fault the default values were charged, this will be shown by a flushing “batt.”
This message will disappear after depressing any key.
Analyzer warming-up takes about 15 to 50 minutes, depending on the
installed detectors !
Before starting an analysis, however, the following should be performed:
❏entry of the desired system parameters,
❏calibration of the analyzer.
NOTE:
The "X’s" shown in the display indicate a number or combinations of numbers.
6 - 2
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KEY FUNCTIONS
7.Key Functions
The operation and programming of the analyzer is perf ormed using the membrane - type keypad
with its four ke ys (see Fig. A-1, Item 3 - 6).
Operator guidance prompts will appear on the 4 - digit LED - displays.
Battery - buffering of the stored parameters prevents their loss in the absense of a po wer supply
failure.
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Page 46
KEY FUNCTIONS
FUNCTION
7.1FUNCTION
Depressing this key (Fig. A-1, Item 3) addresses the individual analyzer functions in sequence.
Merely addressing an analyzer function will not initiate an analyzer action or operation. The
analyzer will continue to perform analysis throughout keypad entry procedures.
The following analyz er functions and their sequences (see also Fig. 7-1) are shown:
Zeroing channel 1
Zeroing channel 2
Spanning channel 1
Spanning channel 2
Interval Time for automatic Zeroing
Interval Time for automatic Spanning
Entry of concentration limits
Only in combination of digital
outputs and external solenoid
valves, and if Auto = 1
7 - 2
Entry of system parameters.
Entry of serial interface parameters
Only with Option RS 232 C/485 Serial
Interface
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KEY FUNCTIONS
ENTER
7.2ENTER
The ENTER - key (Fig. A-1, Item 4) is used for the transfer of (k eyed - in) numerical data to the
corresponding operating parameters and for the initiation of certain operations, such as zeroing
and spanning.
Depressing within the function sequences (following the sequences from "Zeroing (0 - 1)" to the
"interface - parameter (SIP.) using the FUNCTION - key) the first time only the ENTER - key
will appear on the display.
This indicates that - for safety - a pass word (user code) must be entered in order to enable the entry
level.
If an incorrect password is entered, the CODE displa y will remain, and the entry displayed will be
reset to the value “0”.
When the correct password has been entered, a transfer to the protected entr y level will be
effected.
This password has been set to the v alue “1” in our plant bef ore shipment.
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Page 48
KEY FUNCTIONS
KEY FUNCTION OVERVIEW
7 - 4
Fig. 7-1: BINOS® 100 (M) Operating Function Matrix
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KEY FUNCTIONS
INPUT - CONTROL
7.3INPUT - CONTROL
This keys (Fig. A-1, Item 5 and 6) are used for the adjustment of the individual entry parameter
values. Momentary depressions of either key will alter current values by +/- 1.
UPincrease current value by 1
DOWNdecrease current value by 1
If either of these keys is held depressed, the v alue will be altered continuously . Altering rate starts
with the slower rate, and shifts automatically to the f aster rate. When the minimal v alue is reached,
the analyzer will automatically revert to the slower rate in order to f acilitate entry of the minimal
value .
Each of the entry parameters is assigned an accepted tolerance range which must be observed
when entering parameter values. In addition, all entries are subjected to a plausibility check as
added protection against operator errors.
If within about 60 - 120 seconds no further keys have been depressed,
the analyzer will automatically revert to the “analysis display”.
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Page 50
KEY FUNCTIONS
7 - 6
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ENTRY OF SYSTEM PARAMETERS
8.Entry of System Parameters
Depress the key
until the textappears.
Depress the key
If the Code had not already been entered, there
will appear
Use the keysto select the Code
and then using
The display will now sho w:
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Page 52
ENTRY OF SYSTEM PARAMETERS
PRESSURE CORRECTION / CROSS COMPENSATION
8.1Pressure Correction
T o eliminate faulty measurements due to changes in barometric pressure or sample gas pressure,
the operator is offered the opportunity to enter the current pressure expressed in hP a (mbar) in
a range of 800 to 1300 hPa. The concentration values computed by the analyzer will then be
corrected to reflect the barometric pressure or sample gas pressure resp. entry.
The entry is effected using
and
It is possible to integrate a pressure sensor with a range of 800 - 1100 hPa.
The concentration values computed b y the analyzer will then be corrected to reflect the
barometric pressure to eliminate faulty measurements due to changes in barometric
pressure (see technical data). .
In this case it is not possible to enter pressure value manually. In attempting to enter
pressure value manually , the analyzer will automatically rev ert to the display of measured
pressure value.
8.2Cross - Compensation
This control permits switching the electronic cross - compensation feature on and off.
The cross - compensation feature is designed minimize mutual interferences between the two
gases (e. g., CO2 and CO) measured by the analyzer.
Entry of 0:cross - compensation is disabled
Entry of 1:cross - compensation is enabled
Effect the entry using
and
8 - 2
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ENTRY OF SYSTEM PARAMETERS
CROSS COMPENSATION CALIBRATION
8.3Cross - Compensation Calibration
Determination of cross - compensation correction factors is performed during the span adjustment. Pure test gases are required f or this operation. Once cross - compensation corrections have
been determined, span adjustments may be performed using test gas mixtures.
Entry of 0:spanning without cross-compensation correction (test gas mixtures)
Entry of 1:spanning with cross - compensation correction (pure test gases)
Effect the entry using
and
To perform a calibration with cross - compensation correction, proceed as follows:
First perform a zeroing f or both analysis channels (see 9.1.1).
Then perform a spanning for both analysis channels as described in section 9.1.2.
The spanning for the first of the analysis channels calibrated must then be repeated.
Note :
The entries described in sections 8.2 and 8.3 must be “1” f or performance of
a calibration with cross compensation correction !
Use only pure test gases !
When using test gas mixtures, “C.Cal” must be set to “0” !
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Page 54
ENTRY OF SYSTEM PARAMETERS
HOLD / AUTOMATIC CALIBRATION
8.4Hold
The analyzer function HOLD permits keeping the analog signal outputs and the concentration
limits locked at the last v alues measured during a calibration procedure.
Entry of 0:The outputs remain unlocked.
Entry of 1:The outputs will be locked.
Use the keys
andfor the entry.
8.5Automatic Calibration
For operation with optional, external solenoid valves it can be selected, if there is a time - controlled
(automatic) calibration possible or not (in combination with digital outputs).
Entry of 0:Time - controlled calibration is not possible
Entry of 1:Time - controlled calibration is possible
Use the keys
andfor the entry.
8 - 4
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ENTRY OF SYSTEM PARAMETERS
TOLERANCE CHECK
8.6Tolerance Check
The tolerance function is for the activation and deactiv ation of the tolerance check procedure for
various calibration gases.
If the tolerance check procedure has been activated, the microprocessor will verify during
calibration procedures whether the used calibration gas shows a deviation of more than 10 %
from measuring range of zero (zero - lev el) or more than 10 % of the nominal concentration value
entered resp. (span).
If this tolerance is exceeded, no calibration will be performed, and an error message will
appear (see Section 13).
Entry of 0:Tolerance check is deactivated.
Entry of 1:Tolerance check is activated.
Perform the entry using
and
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ENTRY OF SYSTEM PARAMETERS
DISPLAY OFF / ANALOG SIGNAL OUTPUTS
8.7Display Off
If 1 is entered, the DISPLA Y will be deactivated about 1 to 2 minutes after the last ke y depression.
If any key is depressed while the DISPLAY is deactivated, all display elements will be reactivated
without any further operation being initiated.
Entry of 0:Display is activated
Entry of 1:Display is deactivated
Entry is performed using
followed by
8.8Analog Signal Outputs
The analog signal outputs (optically isolated) are brought out to the 9 - pin sub - miniature
D- connector X2 on the analyzer rear panel.
Entry of 0:Output signal of 0 - 10 V (Option: 0 - 1 V) / 0 - 20 mA.
Entry of 1:Output signal of 2 - 10 V (Option: 0.2 - 1 V) / 4 - 20 mA. (lif e ze r o mode)
Use the keys
andfor entry .
Note:
The begin of range concentration (OFS.) and the end of range concentration (END) are free
programmable (see Item 8.12 and 8.13).
For type of voltage output (standard or option) look at order confirmation or identify plate resp .,
please.
8 - 6
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ENTRY OF SYSTEM PARAMETERS
K1K2K1K2
ANALOG SIGNAL OUTPUTS
Mating socket X 2
X1 OUTPUT
INTERFACE
X2 OUTPUT
IN
24 VDC
OUT
X3 OUTPUT
MADE IN GERMANY
Fig. 8-2: Pin assignments X 2 (analog signal outputs)
90002953(2) BINOS® 100(M) e [4.10] 19.11.97
Fig. 8-1: Mating socket X 2 (analog signal outputs)
5
1
6
9
1
20 (2) - 10 V DC [Option: 0 (0,2) - 1 V DC], Kanal 1
30 (4) - 20 mA, Kanal 1 (R
40 (2) - 10 V DC [Option: 0 (0,2) - 1 V DC], Kanal 2
50 (4) - 20 mA, Kanal 2 (R
6
7
8
9
⊥⊥
⊥ (V DC)
⊥⊥
⊥⊥
⊥ (mA)
⊥⊥
≤ 500 Ω)
B
≤ 500 Ω)
B
8 - 7
Page 58
ENTRY OF SYSTEM PARAMETERS
FLUSHING PERIOD / USER CODE
8.9Flushing Period
For calibration, the gas paths must be supplied with sufficient calibration gas . The flushing period
has to be fixed adequate; perf orm calibration only after a suitable flushing period (the calibration
gas flow should be identical with sample gas flow).
This period may be selected in the range 0 - 99 sec. depending on calibration conditions.
Use the keys
andfor entry.
8.10User Code
The value 1 has been set in our plant.
To prevent parameter alterations by unauthorized persons, the operator may specify another
password (user code).
Use the keys
andfor entry .
Please take care f or filing the user code .
8 - 8
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ENTRY OF SYSTEM PARAMETERS
RESPONSE TIME (T90)
8.11Response Time (t90)
For some types of analysis an alteration of the analyzer damping factor , i.e. its electrical response
time, t90, may be required. The operator is offered the option of selecting a response time optimal
for each application.
The range of accepted entries is 2 - 60 sec..
Use the keys
andfor the entry.
Entry possibility for channel 2
Use the keys
andfor the entry.
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ENTRY OF SYSTEM PARAMETERS
OFFSET (BEGIN OF RANGE)
8.12Offset (Begin of range)
The operator is here offered the opportunity to introduce a scale offset for the analog signal output
(begin of range).
Example:
For an analyzer concentration range of 0 - 25 % it is desired to measure only concentr ations in
the range 10 - 25 %. If the operator enters here the value 10 %, the analog signal outputs of
0 V / 0 mA or 2 (0.2) V / 4 mA will then correspond to a gas concentration of 10 %.
The displayed values are not affected.
Effect the entry using
and
Entry possibility for channel 2
Use the keys
andfor the entry.
Note:
The specifications of the analyzer written in the data sheet are only for OFS. = 0 and
END = full - scale range set in our factory !
It is part of customer to enter logical values for OFS. and END !
8 - 10
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ENTRY OF SYSTEM PARAMETERS
END OF RANGE VALUE
8.13End of Range Value
The operator is here offered the opportunity to introduce a full - scale range for the analog signal
output.
Example:
For an analyzer concentration range of 0 - 25 % it is desired to measure only concentr ations in
the range 0 - 15 %. If the operator enters here the value 15 %, the analog signal outputs of
10 (1) V / 20 mA will then correspond to a gas concentr ation of 15 %.
The displayed values are not affected.
Use the keys
andfor the entry.
Entry possibility for channel 2
Use the keys
andfor the entry.
Note:
The specifications of the analyzer written in the data sheet are only for OFS. = 0 and
END = full - scale range set in our factory !
It is part of customer to enter logical values for OFS. and END !
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Page 62
ENTRY OF SYSTEM PARAMETERS
RESET
8.14Reset
The reset operation restores the settings of the analyzer to the parameters and calibration f actors
set in our factory at the time of its manufacture .
This is equivalent to switching off the electrical supply line and s witching off the battery buffering
of the RAM’s b y remo ving the battery jumper, J7.
All parameters and calibration factors entered by the user will be lost whenever a reset
operation is performed.
The currently valid user identification code must be entered before a reset will be e x ecuted; this
will prevent inadvertent resets.
Entry is performed using
followed by
Whenever a reset operation is initiated, the analyz er operating program will be restarted, just as
it is when the instrument is first switched on (see Section 6).
Jumper J6, which activ ates the watc hdog circuitry must be inserted if the
reset operation is to be correctly executed.
8 - 12
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ENTRY OF SYSTEM PARAMETERS
8.15Program Version
The Program Version (No. of the installed softw are - version) will be displayed.
Depress the key
8.16Serial - No.
The Serial - No. will be displayed. (Please note this number for further contact with our factorymaintenace, service, etc.)
Depress the key
Continuation of Serial - No.
Depress the key
8.17Copy - No.
The EPROM Cop y - No. will be displayed.
Depress the key
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Page 64
ENTRY OF SYSTEM PARAMETERS
ABSORBER
8.18Absorber
This display will be shown onl y with “solenoid valve option”, if AUTO = 1.
For this parameter the entry is set to “0”.
Entry is performed using
followed by
Depress the keyuntil
the displays show
The analyzer now is back in the analysis mode .
8 - 14
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Page 65
CALIBRATION
9.Calibration
T o insure correct measurement results, zeroing and spanning should be carried out once a week.
Spanning can be performed only after zeroing before .
For the calibration procedure the required test gases hav e to be f ed to the analyz er through the
respective gas inlets (cf . section 5.3) with a no - back - pressure gas flo w rate of about 1 l/min (the
same as with sample gas) !
After switching on the analyzer, wait at least approx. 15 to 50 minutes
(depending on installed detectors) before admit gas to the analyzer !
Note !
For operation with optional, e xternal solenoid valves the solenoid v alves are activ ated automatically by the respective function (via digital outputs). If the analyzer is in “calibration mode”, a digital
status signal “calibration” can given optional (see Item 10.3).
Zeroing
For zeroing, the analyz er has to be flushed with nitrogen (N2) or adequate zerogas
(e. g. synth. air or conditionned air).
Spanning
The span gas concentration should be in a range of 80 % - 110 % of full - scale range !
For low er span gas concentrations the measuring accuracy could be lo wer for sample
gas concentrations, which are higher than the span gas concentration !
Spanning for o xygen measurement can be done using ambient air as span gas, if the
oxygen concentration is known and constant.
When using span gas mixtures the entry for “C.Cal” must be set to “0”
(see section 8.3) !
If there is no built-in pressure sensor , the correct pressure m ust be entered
before performing the calibration, if you want to have the possibility of
pressure correction (see 8.1) !
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Page 66
CALIBRATION
MANUAL ZEROING
9.1Manual Calibration
9.1.1Zer oing
Zeroing will set the actually measured gas concentration to “z ero”.
Depress the key
until the display shows(Zeroing channel 1) or
(Zeroing channel 2) resp.
Depress the key
There will appear
Use the keysto select the correct user - code
and enter using.
The displays will now showorresp.
The actual zero - lev el will be displayed.
Wait at least the entered flushing - period and t
9 - 2
- time.
90
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CALIBRATION
MANUAL ZEROING
Depress the key
The nominal valueorwill be displayed.
If the actual and nominal zero - levels agree, the next function can then be selected using the
FUNCTION - key (without zeroing).
If the two values disagree, then
depress the key
The actual measuring valueorwill be displayed
To start zeroing pressagain.
As soon as zeroing has finished, the display indicates
the actual measuring valueorresp. will be displayed.
The keyboard will only be released after another flushing - period and t
- time.
90
The analog signal outputs and the concentration limits are released too, if Hold = 1.
To leave “calibration mode” press
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CALIBRATION
MANUAL SPANNING
9.1.2Spanning
Verification of the span calibration is essential for accurate concentration measurement.
Spanning can be performed only after zeroing before .
Spanning will set the actually measured gas concentration to the entered “span gas setpoint”.
Note:The span gas concentration should be in a range of 80 % - 110 % of full - scale range !
For lower span gas concentrations the measuring accuracy could be lower for sample gas
concentrations, which are higher than the span gas concentration !
Spanning for o xygen measurement can be done using ambient air as span gas, if the
oxygen concentration is known and constant.
When using span gas mixtures the entry for “C.Cal” must be set to “0”
(see section 8.3) !
If there is no built-in pressure sensor , the correct pressure m ust be entered
before performing the calibration, if you want to have the possibility of
pressure correction (see 8.1) !
9 - 4
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CALIBRATION
MANUAL SPANNING
Depress the key
until the display shows(Spanning channel 1) or
(Spanning channel 2) resp.
Depress the key
Enter the correct user code, if not already entered
The displays will now showorresp.
The actual concentration - level will be displayed.
Wait at least the entered flushing - period and t
- time.
90
Depress the key
The test gas setpointorresp. will be displayed.
If necessary , enter the true test gas setpoint value (taken from the manuf acturer’s certification on
the gas bottle)
using the key
andusing.
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Page 70
CALIBRATION
MANUAL SPANNING
The actual measuring valueorresp. will be displayed
Leave calibration mode b y pressing the FUNCTION - ke y (enter of nominal value without span
calibration)
or pressagain to start spanning .
As soon as spanning has finished, the display indicates
the actual measuring valueorresp. will be displayed.
The keyboard will only be released after another flushing - period and t
- time.
90
The analog signal outputs and the concentration limits are released too, if Hold = 1.
To leave calibration mode press
When using span gas mixtures the entry for “C.Cal” must be set to “0”
(see section 8.3) !
The correct pressure must be entered before perf orming the calibration,
9 - 6
if you want to have the possibility of pressure correction (see 8.1) !
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CALIBRATION
AUTOMATIC ZEROING (OPTION)
9.2A utomatic Calibration Mode (Option)
A time-controlled calibration only can be done with separate external solenoid valv es via digital
outputs. The automatic function of the analyz er must also be activated correctly (cf . Section 8.5).
With this function, the analyzer can perform an automatic calibration at preset time intervals.
The displays of the analyzer shows additional the functions t - A O and t - AS using the FUNCTION
- key.
Note !
For a time-controlled calibration procedure, the test gases m ust be fed through “solenoid valv es”
controlled by the analyzer in order to ensure the supply of test gases in due course .
If the test gas concentration has changed, the correct setpoint is to enter first (see 9.1.2 ).
9.2.1Zer oing
Depress the key
until the displays show
Depress the key
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Page 72
CALIBRATION
AUTOMATIC ZEROING (OPTION)
If the correct user code has not yet been entered,
the displays shows
Use the keysto select the correct user - code
and enter using.
It appears
You can enter a time interval (hours), when an automatic zeroing has to be perf ormed.
Point of reference is the real time of entry.
Range of accepted entries: 0 - 399 (hours)
Note !
If the entry is “0” (zero), the time - controlled calibration is switched off.
Entry is performed using
followed by
After entry of interval, zeroing will be done automatically at the end of the entered time interval.
9 - 8
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Page 73
AUTOMATIC ZEROING AND SPANNING (OPTION)
9.2.2Combined Zeroing and Spanning
With this function a span calibration will be performed after completion of zeroing.
Depress the key
until the messageappears
CALIBRATION
Depress the key
Enter the correct user code, if not already entered
The displays will now show
You can enter a time interval (hours), when a automatic zeroing and after that a spanning has to
be performed.
Point of reference is the real time of entry.
Range of accepted entries: 0 - 399 (hours)
Note !
If the entry is “0” (zero), the time - controlled calibration is switched off.
Entry is performed using
followed by
After entry of interval, calibration will be done automatically at the end of the entered time interval.
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9 - 9
Page 74
CALIBRATION
9 - 10
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Page 75
DIGITAL OUTPUTS
10.Digital Outputs
All analyzer standard digital outputs are brought out to plug X 3 on the rear panel.
The loading of the outputs (“Open Collector”) is max. 30 V DC / 30 mA.
K1K2K1K2
X1 OUTPUT
INTERFACE
X2 OUTPUT
IN
24 VDC
OUT
X3 OUTPUT
Plug X 3
MADE IN GERMANY
90002953(1) BINOS® 100(M) e [4.01] 25.09.96
Fig. 10-1: Plug X 3 (Digital Outputs)
69
5
1Limits channel 2 max.
2Limits channel 2 min.
3Limits channel 1 max.
4Limits channel 1 min.
5
6Valve control span gas 2
7Valve control span gas 1
8Valve control zero gas
9Valve control sample gas
⊥⊥
⊥
⊥⊥
1
Fig. 10-2: Pin - Assignments X 3 (Digital Outputs)
10 - 1
Page 76
DIGITAL OUTPUTS
CONCENTRATION LIMITS
10.1Concentration Limits
It may be assigned one upper and one lower concentration limit for each channel, freely selectable
by the operator within the available concentration range.
The rightmost decimal of the related display will start to blink whenever a limiting concentration
value is reached.
Additional digital signal outputs for the concentration limits are brought out to plug X 3 on the rear
panel.(“Open Collector”, max. 30 V DC / 30 mA).
Depress the keyuntil the text
appears.
Depress the key
If the correct user code has not yet been entered,
the messagewill appear.
Depress the keysto select the correct user code,
enter with thekey.
The displays will now showlower limit channel 1
Use the keysto set the limiting value.
Depress the keyto enter the value.
10 - 2
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Page 77
DIGITAL OUTPUTS
LIMIT VALUES
There will then appearupper limit channel 1
Use the keysto set the limiting value.
Depress the keyto enter the value.
The displays will now showlower limit channel 2
Use the keysto set the limiting value.
Depress the keyto enter the value.
There will then appearupper limit channel 2
Use the keysto set the limiting value.
Depress the keyto enter the value.
Depress the keyuntil
the displays show
The analyzer is now bac k in the analysis displa y.
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10 - 3
Page 78
DIGITAL OUTPUTS
VALVE CONTROL / STATUS SIGNALS (OPTION)
10.2Valve Control
The valve control f or operation with optional external solenoid valv es will be done via plug X 3 on
the rear panel, too (see Fig. 10-1 and 10-2).
10.3Status Signals (Option)
The analyzer has been optionally equipped with two status signal outputs. These are fed to the
9-pin subminiature D-plug X 1 on the rear panel of the analyzer (see Item 9. and 13., too).
These signals are non-voltage-carrying contacts with a maximal loading of 42 V / 1 A !.
The primary step in the measurement of the concentration of a gas component is the admission
of sample gas to the analyzer.
Analyzer warming-up after switching on takes about 15 to 50 minutes,
depending on the installed detectors !
❍Admit sample gas at the gas inlet fitting.
❍Set the gas flow rate to approx. 1 l/min.
The analyzer must be in the “analysis mode”, i. e. the displays must show
Note !
If some other mode has been selected, the analyzer will automatically return to the analysis display
when a period of 60 - 120 seconds has elapsed after the last key actuation or after the last
completion of an operation !
The analyzer will remain at analysis display, until some other mode has been selected.
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11 - 1
Page 80
MEASUREMENT/SWITCHING OFF
SWITCHING OFF
11.2Switching Off
Before s witching off the analyzer, we recommend first flushing the gas lines for about 5 minutes
with zeroing gas (N2) or adequate conditionned air. The full procedure for shutting down the
analyzer is as follows:
❍Admit zeroing gas at the gas inlet fitting.
❍Set the gas flow rate to allowable rate.
After 5 minutes have elapsed:
❍Shut Off the zeroing gas supply.
❍Switch Off the analyzer by disconnecting the voltage supply.
❍Close all gas line fittings immediately.
11 - 2
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Page 81
12.Serial Interface (Option)
123456
123456
12
12
12
12
12
12
123456
123456
12.1Retrofitting of Serial Interface / Status Signals
❍Connect circuit board to the threated bolts at the rear panel and mounting with the
washers and the screws.
❍Connect cable subject to code pin to BKS - pin connector J9 .
Rear panel
Threated bolt
Rear panel
PCB BSI 10
J 9
J 9
Code pin
1
Fig. 12-1: Installation of PCB BSI 10
❍For retrofitting serial interface insert enclosed EPROM (see Item 25.).
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12 - 1
Page 82
SERIAL INTERFACE (OPTION)
GENERAL
12.2General
The analyzer is equipped with a serial interface enabling communications with a host computer .
The host computer can call up, prescribe, or alter parameters, as well as initiate analyzer
operations, using standardized protocols. The optional BSI 10 plug in circuit board constitutes the
hardware interface. This may be configured as RS 232 C or RS 485 interface. The RS 485 interface
permits networking several analyzers. Each analyzer may then be addressed using an assignment numerical ID - code.
Communications are always initiated b y the host computer; i.e ., analyzer beha ve passiv ely until
the host computer requests information from them or demands commencement of an action.
Communications use so - called “telegrams” being exchanged between the host computer and
the analyzer(s). Syntax for these telegrams is established in protocols.
T elegrams alwa ys commence with the "$" start character, immediately follow ed by a three - digit
instruction code.
Subsequent elements of telegrams are segregated by the ";" h yphen c haracter .
The final element of all telegrams transmitted must be the “CR” termination character .
Upon receipt of the terminate character, the analyzer attempts to e valuate the current contents
of its input buffer as a valid telegram. If the syntax of the transmitted telegram is correct, the
analyzer will transmit a response telegram to the host computer. This consists of the start
character, an instruction code, requested data, a bloc k - parity byte, and the termination character.
If the syntax of the transmitted telegram was not correct, the analyzer will transmit a status telegram
containing an error message to the host computer. Each terminate character reception thus
initiates an analyzer response.
12 - 2
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Page 83
SERIAL INTERFACE (OPTION)
GENERAL
T o avoid detecting transmission errors, the host computer can insert a message -length parity byte
immediately preceding the terminate character for verification by the analyzer.
The elapsed time between the reception of star t characters and termination characters is not
limited by the analyzer; i.e ., there are no “time - out” periods.
If the host computer transmits any new characters before the analyzer has responded to the
preceding telegram, the analyzer’s input buffer will reject them; i.e., these characters will be
ignored by the analyzer.
The transmission rate may be set between 600 and 4.800 baud.
An echo - mode may also be activ ated.
The analyzer software is configured such as that telegrams ma y be sent to the host computer at
time intervals of 150 ms and greater.
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12 - 3
Page 84
SERIAL INTERFACE (OPTION)
START UP
12.3Start Up
The analyzer has been set in our factory to RS 232 C or RS 485 interface via the plugged PCB
SIF 232 or SIF 485 on the PCB BSI 10.
The parameter 232c has also been set to 0 = NO or 1 = YES in the SIP (Serial Interface Parameters)
line.
Interconnection to the interface is via the 9 - pin sock et „Interface“ on the analyzer rear panel
(Fig. 12-2).
Socket
“Interface”
K1K2K1K2
IN
X1 OUTPUT
INTERFACE
X2 OUTPUT
24 VDC
OUT
MADE IN GERMANY
X3 OUTPUT
12 - 4
Fig. 12-2: Socket “Interface” (Serial Interface)
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Page 85
SERIAL INTERFACE (OPTION)
12.3.1RS 232 C
This interface requires a shielded cable having at least three internal conductors.
START UP
5
1
6
9
1GND
2RxD
3TxD
4not used
5GND
6not used
7not used
8not used
9not used
Fig. 12-3: Pin - Assignments “RS 232 Interface”
12.3.2RS 485
Configure 2- or 4-wire operation via solder bridge LB 1 of PCB SIF 485 before mounting the PCB.
Connecting of [1 - 2] 2-wire-operation is selcted. Connecting of [2 - 3] 4-wire-operation is active .
Connect Jumper P2 at both ends of interface connection (termination). For network operation with
several analyzers via RS485 interface, termination has to be done at both ends of network
connection only. F or the other analyzers remove the J umper.
5
1
69
1GND
2RxD3RxD+
4TxD+
5TxD6not used
7not used
8not used
9not used
Fig. 12-4: Pin - Assignments “RS 485 Interface”
In contrast to RS 232 C operation, simultaneous transmission and reception is not implemented
in this standard. This would not result in damage to the electronics, but could lead to destroy of
data. The analyzer behav es passively in this mode of operation; i.e., it keeps its transceiver set f or
reception whenever it is not transmitting. Since the time periods for transmission and reception are
controlled by protocols, “data collisions” are excluded.
90002953(1) BINOS® 100(M) e [4.01] 25.09.96
12 - 5
Page 86
SERIAL INTERFACE (OPTION)
START UP (INTERFACE - PARAMETER)
12.3.3Switching ON/OFF Interface Operation
The analyzer may be set to either “on - line” or “off - line” status. This setting may be perf ormed
either from the keypad or via telegram input.
Ke yboard setting:
SIP - parameter On.-L. = 1for on - line status
SIP - parameter On.-L. = 0for off - line status
Telegram setting:
Instruction code 6:sets analyzer on - line status
Instruction code 7:sets analyzer off - line status
If the analyzer is set to off - line status, it will accept only instruction code 6. All other instructions
will be ignored and result in transmission of appropriate status telegrams.
12.3.4Setting Interface Parameters
Agreement of interface parameters between analyzer and host computer is a fundamental
requirement for communication without errors.
The following analyzer parameters are concerned:
❏baud rate:600 / 1.200 / 2.400 / 4.800 bits/s
❏data bits:8
❏stop bits:2
❏parity bit:none
❏echo mode:on / off (received characters will be retransmitted immediately)
❏LPB-test:on / off (message - length parity check)
❏ID-no.:0 to 99 (device ID - no. in RS 485 mode)
12 - 6
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Page 87
SERIAL INTERFACE (OPTION)
START UP (INTERFACE - PARAMETER)
All entries are made using the keys
and
Depress the key
untilappears,
then depress the key
The unit is now ready for code entry, if such has not already been performed.
0 = off - line status
1 = on - line status
Each device is assigned a de vice number for operation
through the RS 485 interface (0 - 99).
Select interface type:
0 = RS 4851 = RS 232 C
Set baud rate:
0 = 4.800 1 = 2.400
90002953(1) BINOS® 100(M) e [4.01] 25.09.96
2 = 1.200 3 = 600
Echo-mode operation:
0 = OFF1 = ON
Message - block parity check
0 = OFF1 = ON
12 - 7
Page 88
SERIAL INTERFACE (OPTION)
TELEGRAM SYNTAX
12.4Telegram Syntax
Telegrams are assembled as f ollows:
12.4.1Start Character ( “$” = Hex 24)
If the start character is missing, this will result in transmission of an appropriate status telegram
by the analyzer.
12.4.2Terminate Character ( “CR” = Hex OD)
If the terminate character is missing, no decoding of the transmitted information will be performed,
and the analyzer will not respond. No response message will be transmitted.
12.4.3Instruction Code
Each instruction is assigned a unique three digit numerical instruction code. If a received
instruction code should be other than three - digits in length or contain non - numerical ASCIIcharacters, the analyzer will transmit an appropriate status telegram. Reception of unassigned
instruction codes will also result in the transmittal of a status telegram.
In the RS 232 C mode of operation, the instruction code immediately follows the start character;
in the RS 485 mode of operation, the start character is followed by a two - digit de vice identification
code, the separator character. “;”, and a three - digit instruction code, in this order.
12.4.4Hyphen Character ( “;” = Hex 3B)
Individual elements of a telegram line are separated by this hyphen character. Missing hyphen
characters can lead to misinterpretations of telegrams, and will result in transmission of an
appropriate status telegram.
12 - 8
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Page 89
SERIAL INTERFACE (OPTION)
STATUS TELEGRAM
12.4.5Status Telegram
If telegram syntax is faulty, or analyzer is unable to act upon an instruction received, then the
analyzer will transmit a status telegram to the host computer .
These status telegrams are listed here for ref erence:
$ID;000;S100;LPB<CR>unrecognized instruction code
$ID;000;S101;LPB<CR>LP - byte in error
$ID;000;S102;LPB<CR>start character missing
$ID;000;S103;LPB<CR>input buffer overflow
$ID;xxx;S104;LPB<CR>analyzer off - line status
$ID;xxx;S105;LPB<CR>text line too long
$ID;xxx;S106;LPB<CR>undefined instruction
$ID;xxx;S107;LPB<CR>invalid integer value
$ID;xxx;S108;LPB<CR>numerical value outside defined range
$ID;xxx;S109;LPB<CR>invalid failure/status code
$ID;xxx;S110;LPB<CR>instruction can not be done here
$ID;xxx;S111;LPB<CR>failure in transmitted character
$ID;xxx;S112;LPB<CR>zeroing running
$ID;xxx;S113;LPB<CR>spanning running
$ID;xxx;S114;LPB<CR>invalid real number
$ID;xxx;S115;LPB<CR>automatic calibration mode off
$ID;xxx;S116;LPB<CR>parameter outside defined range
$ID;xxx;S117;LPB<CR>preflushing period is running
xxx:instruction code
ID:device ID - no. in RS 485 mode
LPB:message - length parity byte
<CR>:terminate character
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12 - 9
Page 90
SERIAL INTERFACE (OPTION)
NUMERICAL REPRESENTATION / BLOCK PARITY CHECK
12.4.6Numerical Representations
Telegrams may contain integers or real numbers. The f ormats for these numbers are subject to
the following restrictions.
Integers:- maximum value = 216 - 1
- positive numbers only accepted
- no decimal points allowed
Real:- maxim um of 6 digits accepted
- no alphabetic characters (e.g. 2.2E-6) allowed
- analyzer output is 6 - digit real numbers
12.4.7Block Parity Check
The master control computer may insert a message - length parity byte into telegrams. These
invariably consist of tw o characters .
The message - length parity byte is the cumulatively EXCLUSIVE - OR correlation of all pre viously
transmitted characters of the telegram line. Representation is in hexadecimal format. For example,
if the decimal value should be decimal 13, this will be represented by the two characters “OD”, i.e.,
030H and 044H.
The verification procedure may be enabled or disabled at the analyzer (see Section 12.3.4).
12 - 10
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Page 91
SERIAL INTERFACE (OPTION)
12.5Instruction Syntax
Code definitions:
RP:receive parametersanalyzer is accepting values
SP:send parametersanalyzer is sending values
RI:receive instructions
k:channel numbers 0 to 1
m:r ange number (for BINOS® 100 is invariably 1)
w:value
INSTRUCTION SYNTAX
<ID>:analyzer ID - no. for RS 485 mode of operation; follows start character
LPB:message - length parity byte
<CR>: terminate character
Receipt of any instruction codes not listed in the following section will be acknowledged by
transmittal of status code 106. Future expansions will make use of code numbers not currently in
use.
90002953(2) BINOS® 100(M) e [4.10] 19.11.97
12 - 11
Page 92
SERIAL INTERFACE (OPTION)
INSTRUCTION LIST
12.5.1Instruction Listing
Instruction syntax:Instruction description:
$ID;001;k;LPB<CR>RI stand-by status
$ID;002;k;LPB<CR>RI sample gas valve open
$ID;003;k;LPB<CR>RI zeroing gas valve open
$ID;005;m;k;LPB<CR>RI span gas valve open
$ID;006;LPB<CR>RI on - line status
$ID;007;LPB<CR>RI off - line status
$ID;011;m;k;LPB<CR>SP at full scale range
$ID;013;k;LPB<CR>SP t
$ID;014;w;k;LPB<CR>RP t
(response time)
90
(response time)
90
$ID;017;k;LPB<CR>SP preflushing period
$ID;018;w;k;LPB<CR>RP preflushing period
$ID;019;k;LPB<CR>SP preflushing period
$ID;020;w;k;LPB<CR>RP preflushing period
$ID;023;k;LPB<CR>SP concentration
$ID;028;m;k;LPB<CR>SP span gas concentration
$ID;029;w;m;k;LPB<CR>RP span gas concentration
$ID;030;LPB<CR>SP status messages
$ID;603;k;LPB<CR>SP gas component
$ID;604;k;LPB<CR>RI automatic zeroing
$ID;605;k;LPB<CR>RI automatic spanning
$ID;606;0;LPB<CR>RI automatic zeroing & spanning
$ID;607;LPB<CR>SP absorber recovery cycles
$ID;627;LPB<CR>SP failure message (possib le error batt. is
clearing by read out)
$ID;645;0;LPB<CR>SP pressure value
12 - 12
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Page 93
SERIAL INTERFACE (OPTION)
12.5.2Response Telegrams
Response telegrams follow with the same syntax as the appropiate (SP-) commands (see 12.5).
The response telegram for instruction
“$ID;030;LPB<CR> SP Status messages”
shows as follows:
$ID;030;a;b;c;LPB<CR>
This means:
a: OK-Status0 = Relay without power 1 = Relay activ e
b: Value of v a riable “calibration”0 = Relay without po wer >0 = Relay active
bMeaning
0No Calibration
1Zeroing channel 1
2Zeroing channel 2
3Zeroing channel 1 + 2
4Spanning channel 1
5Spanning channel 2
6Spanning channel 1 + 2
7Spanning channel 1 first, then channel 2
8reserved
9reserved
10Waiting for flushing time and t90 response time
c: Relay 30 = Relay without power 1 = Relay active
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12 - 13
Page 94
SERIAL INTERFACE (OPTION)
12 - 14
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Page 95
ERROR LIST
Error CodePossible ReasonsCheck / Correct
13.Error List
Some of the failures which may arise during measurement will be reported on the displays in forms
of error codes.
When such a failure arises, the display's will show the concentr ation value
alternating with(E = ERROR).
Note !
If there is an "error message", a digital status signal "Failure" can be given optional (see Item 10.3)!
Be sure to observe the safety measures for all workings at the anal yzer!
Error CodePossible ReasonsCheck / Correct
1. Displays are “switched OFF”
No Display
1. Press any key.
Check parameter dOFF
(see 8.7).
90002953(2) BINOS® 100(M) e [4.10] 19.11.97
2. Voltage supply absent.
3. Connection front panel /BKS
absent.
2. Check electrical supply
(see Fig. A-2, Item 3).
3. Check connection
BKB - BKS (X1) (see 15.1).
13 - 1
Page 96
ERROR LIST
Error CodePossible ReasonsCheck / Correct
Flushing
Battery buffer faulty.
Check, if Jumper J 7
is plugged (see 16.).
Channel 1
Channel 2
A/D-Conversion-End-Signal
absent
The EPROM - default
values were charged.
1. Jumper not or incorrect
plugged.
2. Positive or negative
reference voltage absent.
3. Light barrier signal absent.
Exchange battery,
if battery voltage < 3,5 V
(BKS - Jumper J7 plugged).
The error is clearing after depressing
any key or with serial interface
instruction $627.
Light source is cold:
For dual-IR-channel analyzer
interchange the two light-sources.
7. Faulty analog
preamplifiering.
8. Contamination of the gas
paths.
Replace the suspect light source
(see 23.2).
7. Check measuring point 14.1.7 or
14.2.1 resp.
8. Check analysis cell and windows for
contamination.
Cleaning of contaminated parts
(see 22.3).
Check gas paths and gas
conditionning to contamination.
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13 - 5
Page 100
ERROR LIST
Error CodePossible ReasonsCheck / Correct
Fluctuating or
erroneous display
Response - time too long
(t
- time)
90
9. Barometric pressure
effects.
10. Temperature below the
dew point in the gas paths.
11. Faulty A/D - converter.
1. Incorrect response time
( t
- time).
90
2. Pumping rate inadequate.
9. Enter the correct value for
barometric pressure (see 8.1).
Pressure sensor faulty (E.37).
10. Check the temperature of the gas
paths and eliminate any reason of
condensation,
Maintain all temperatures at values
at least 10 °C above the dew point of
sample gas.
11. Exchange BKS.
1. Check the value for t
- time
90
(see 8.11).
2. The feeder line between the
sampling point and the analyzer is
too long.
Use a larger, external pump;
consider adding a bypass line to the
process stream for sampling
purposes (see 5.1).
13 - 6
3. Contamination of the gas
paths.
3. Check gas paths and gas
conditionning to contamination.
Clean gas paths and exchange the
filter elements.
90002953(2) BINOS® 100(M) e [4.10] 19.11.97
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