Rosemount 399VP General Purpose pH/ORP Sensor Abridged Manuals & Guides

Model 399VP

General Purpose pH/ORP Sensor

Instruction Sheet

PN 51A-399VP/rev.J
January 2011

MODEL 399VP

Insertion/Submersion Sensor

with new VP8 connector

(uses mating VP8 cable)

CAUTION

The solution used during calibration is an acid and
should be handled with care. Follow the directions of
the acid manufacturer. Wear the proper protective
equipment. Do not let the solution come in contact
with skin or clothing. If contact with skin is made,
immediately rinse with clean water.

The wetted sensor materials may not be compatible
with process com position and operating conditions.
Application compat ibility is entirely the

responsi-

bility of the user.

CAUTION

SENSOR/PROCESS APPLICATION COMPATIBILITY

SPECIFICATIONS

Sensor Type: General purpose 399VP
Measured Range: pH: A

CCUGLASS 0-14

ORP: -1500 to +1500 mV

Percent Linearity Over pH Range:

Operating Temperature: 0° to 85°C (32° to 185°F)

Au tomatic temperature compensation 0° to 85°C (32°
to 185°F), Temperature compensation is not required for
399 ORP when used with Models 1060, or 1181 ORP

Maximum Pressure: 790 kPa [abs] (100 psig) at 65°C (see

Graph 1 below)

Flow Rate: up to 2 ft/sec
Materials of Construction: Tefzel, glass, ceramic, & Viton
Materials of ORP: Platinum
Process Connections: 1 in. MNPT, 2 places
VP8 Cable: use PN 24281-00
Weight/Shipping Weight: 0.45 kg/0.9 kg (1 lb/2 lb)

• High pH glass provides greater accuracy over 12.5 pH

• HF glass provides improved resistance to hydrofluoric acid up to
300 ppm

GPLR Hemi Bulb Flat Bulb

1-2 pH 94% 93%

2-12 pH 99% 98%

12-13 pH 97% 95%

13-14 pH 92% –

For additional information, please visit our website at

www.emersonprocess.com/raihome/liquid/.

ATEX DIRECTIVE

Special Conditions for safe use

1. All pH/ORP sensors have a plastic enclosure
which must only be cleaned with a damp cloth to
avoid the danger due to a build up of an electro­static charge.

2. All pH/ORP sensor Models are intended to be in
contact with the process fluid and may not meet
the 500V r.m.s. a.c. test to earth. This must be
taken into consideration at installation.

WARNING

Before removing the sensor, be absolutely certain
that the process pressure is reduced to 0 psig and
the process temperature is lowered to a safe level!

2

STORAGE

1. It is recommended that electrodes be stored in their
original shipping containers until needed.

2. Do not store at temperatures below -5°C (23°F).

3. Electrodes should be stored with a protective cap
containing KCl solution (PN 9210342).

4. For overnight storage, immerse the sensor in tap
water or 4 pH buffer solution.

5. A pH glass electrode has a limited shelf life of one
year.

ELECTRODE PREPARATION

1. Remove electrode from shipping container.

2. Remove the protective boot covering the electrode
bulb.

3. Rinse away salt film with clean water, then shake
the electrode so that the internal solution fills the
bulb, thus removing any air trapped there.

NOTE

Do not allow lubricant to coat electrode bulb or
reference junction. If it does, wipe it clean before
installation.

INSTALLATION

For sensor orientation, see Figure 1.

For sensor dimensions, see Figure 2.

For wiring, see Figure 3 - 40.

TWO POINT BUFFER CALIBRATION

Select two stable buffer solutions, preferably pH 4.0
and 10.0 (pH buffers other than pH 4.0 and pH 10.0 can
be used as long as the pH values are at least two pH
units apart).

NOTE

A pH 7 buffer solution reads a mV value of
approx. zero, and pH buffers read approximately
± 59.1 mV for each pH unit above or below pH 7.
Check the pH buffer manufacturer specifications
for millivolt values at various temperatures since
it may affect the actual value of the buffer
solution mV/pH value.

1. Immerse sensor in the first buffer solution. Allow
sensor to equilibrate to the buffer temperature (to
avoid errors due to temperature differences
between the buffer solution and sensor tempera­ture) and wait for reading to stabilize. Value of buffer
can now be acknowledged by analyzer/ transmitter.

2. Once the first buffer has been acknowledged by the
analyzer/transmitter, rinse the buffer solution off of
the sensor with distilled or deionized water.

3. Repeat steps 1 and 2 using the second buffer
solution.

4. The theoretical slope value, according to the Nernst
equation for calculating pH, is approximately 59.17
mV/pH. Over time the sensor will age, both in the
process and in storage, and will result in reduced
slope values. To ensure accurate readings, it is
recommended that the electrode be replaced when
the slope value falls below 47 to 49 mV/pH.

RECOMMENDED pH SENSOR
STANDARDIZATION

For maximum accuracy, the sensor can be standard­ized on-line or with a process grab sample after a buffer
calibration has been performed and the sensor has
been conditioned to the process. Standardization
accounts for the sensor junction potential and other
interferences. Standardization will not change the
sensor’s slope but will simply adjust the analyzer’s
reading to match that of the known process pH.

MAINTENANCE FOR pH ELECTRODE

Electrodes should respond rapidly. Sluggishness,
offsets, and erratic readings are indicators that the
electrodes may need cleaning or replacement.

1. To remove oil deposit, clean the electrode with a
mild non-abrasive detergent.

2. To remove scale deposits, soak electrodes for 30 to
60 minutes in a 5% hydrochloric acid solution.

3. Temperature effect on life expectancy: If glass
electrode life expectancy is 100% @ 25°C (77°F),
then it will be approximately 25% @ 80°C (176°F),
and approximately 5% @ 120°C (248°F).

MODEL 399VP INSTALLATION

3

MODEL 399VP INSTALLATION

FIGURE 2. Sensor Dimensions

DWG. NO. REV.

40399VP01 A

INCH

MILLIMETER

INSTALLATION

FIGURE 1. Sensor Orientation

MODEL 399VP INSTALLATION

4

ORP CALIBRATION

1. After making an electrical connection between the
sensor and the instrument, obtain a standard
solution of saturated quinhydrone (PN R508-8OZ).
This can also be made quite simply by adding a
few crystals of quinhydrone to either pH 4 or pH 7
buffer. Quinhydrone is only slightly soluble, there­fore only a few crystals will be required.

2. Immerse the sensor in the standard solution. Allow
1-2 minutes for the ORP sensor to stabilize.

3. Adjust the standardize control of the instrument to
the solution value shown in the table below. The
resulting potentials, measured with a clean plat­inum electrode and saturated KCl/AgCl reference
electrode, should be within +/- 20 millivolts of the
value shown in the table below. Solution temperature

must be noted to ensure accurate interpretation of
results. The ORP value of saturated quinhydrone
solution is not stable over long periods of time.
Therefore, these standards should be made up
fresh each time they are used.

4. Remove the sensor from the buffer, rinse, and
install in the process.

MAINTENANCE FOR ORP ELECTRODE

Electrodes should respond rapidly. Sluggishness, off­sets, and erratic readings are indicators that the elec­trodes may need cleaning or replacement.

1. To remove oil deposit, clean the electrode with a

mild non-abrasive detergent.

2. To remove scale deposits, soak electrodes for 30 to

60 minutes in a 5% hydrochloric acid solution.

3. ORP (metallic) electrodes should be polished with

moistened baking soda.

pH 4 Solution pH 7 Solution

Temp °C 20 25 30 20 25 30

mV Potential 268 264 260 94 87 80

ORP of Saturated Quinhydrone Solution (millivolts)

CAUTION

Hydrofluoric acid and the mixture of Hydrochloric
acid and thiourea is toxic and highly corrosive. Avoid
skin contact, wear protective gloves. Use only in a
well ventilated area. Do not inhale fumes. In case of
an accident, consult a doctor immediately.

FIGURE 5. VP8 Cable, instrument end

FIGURE 4. VP8 Cable, sensor end

MODEL 399VP WIRING

5

WIRING

FIGURE 7. Model 81 VP Wiring FIGURE 8. Model 1181 VP Wiring

FIGURE 9. Model 54 VP Wiring through Remote Junction Box

GREEN

VP6

(PN 24281-00) VP8

GREEN

VP6 cable

VP8 cable (PN 24281-00)

FIGURE 6. Model 1056. This is the standard wiring for VP8 cable assembly. VP8 cable works both with

VP8 and VP6 sensor connector. VP8 cable is required for SMART communication.

6

MODEL 399VP WIRING

FIGURE 11. Model 2081 VP Wiring

FIGURE 13. Model 2081 VP Wiring through

Remote Junction Box

FIGURE 12. Model 1181, 1050/1060, and 1003/1023

VP6 Wiring through Remote Junction Box

FIGURE 10. Model 54 and 54e VP6 Wiring

GREEN

GREEN

7

MODEL 399VP WIRING

FIGURE 16. Model 54/54e VP8 Wiring

FIGURE 14. Model 81 VP6 Wiring through

Remote Junction Box

FIGURE 15. Model 3081, 4081, and 5081 VP

Wiring through Remote Junction Box

VP6

VP6

399VP

(PN 24281-00) VP8

MODEL 399VP WIRING

8

FIGURE 18. Model 3081, 4081, and 5081 Wiring. This

is standard VP8 wiring for 399VP. VP8 cable works

with both VP6 and VP8 sensor connector. VP8 cable

is required for SMART communication.

FIGURE 17. Model 1055-22-32 VP6 Wiring

FIGURE 19. Model 1054 VP Wiring

FIGURE 20. Model 1054A/B and 2054 VP6 Wiring

399VP

VP6

(PN 24281-00) VP8

9

FIGURE 22. Model 1054A/B & 2054 VP6 Wiring

through a Remote Junction Box

FIGURE 21. Model 1054 VP6 Wiring through

a Remote Junction Box

MODEL 399VP WIRING

FIGURE 23. Model 1055 -01 -10 -22 Wiring.

This is standard VP8 wiring for 399VP. VP8 cable works with both VP6 and VP8 sensor connector

Note: Place RC jumper (P/N 23988-00)
across “Reference In” to “Solution
Ground” when using dual sensor
inputs and the pH sensor doesn’t
have a solution ground.

10

MODEL 399VP WIRING

FIGURE 25. Model Xmt Wiring. This is standard VP8

wiring for 399VP. VP8 cable assembly works with both

VP8 and VP6 assembly

FIGURE 24. Model SCL-(P/Q) VP6 Wiring

FIGURE 26. Model 1055-22-32 integral cable and VP6 Wiring through Remote Junction Boxes

399VP

FIGURE 27. Wiring Model 399VP-09, 400, 401, 402, 403, and 404 to Model 1055 (Pipe/Wall Mount).

DWG. NO. REV.

41055107 C

11

MODEL 399VP WIRING

FIGURE 29. Model 399VP-09 to Model 6081 VP6 Wiring

(no reference diagnostics)

FIGURE 28. Model 399VP-09 to Model 6081 VP8 Wiring

(no reference diagnostics)

Note: Do not connect the
Blue wire to Solution Ground
but Instead terminate with a
wire nut and jumper Solution
Ground to Reference In. For
models Xmt and 1056 termi­nate Inner Drain with a wire
nut.

Note: Do not connect the
Blue wire to Solution Ground
but Instead terminate with a
wire nut and jumper Solution
Ground to Reference In. For
models Xmt and 1056 termi­nate Inner Drain with a wire
nut.

Credit Cards for U.S. Purchases Only.

The right people,
the right answers,
right now.

ON-LINE ORDERING NOW AVAILABLE ON OUR WEB SITE

http://www.raihome.com

Specifications subject to change without notice.

Emerson Process Management

2400 Barranca Parkway
Irvine, CA 92606 USA
Tel: [phone]
Fax: [phone]

http://www.raihome.com

© Rosemount Analytical Inc. 2011

Sira MC070110/00

ACCESSORIES

PART NUMBER DESCRIPTION

23645-06 15 ft cable with mating VP6 connector, prepped with BNC on analyzer end
23645-07 15 ft cable with mating VP6 connector, prepped without BNC on analyzer end
24281-00 15 ft. cable with mating VP8 connector
24281-01 25 ft. cable with mating VP8 connector
24281-02 2.5 ft. cable with mating VP8 connector
24281-03 50 ft. cable with mating VP8 connector
24281-04 100 ft. cable with mating VP8 connector
24281-05 4 ft. cable with mating VP8 connector
24281-06 10 ft. cable with mating VP8 connector
24281-07 20 ft. cable with mating VP8 connector
24281-08 30 ft. cable with mating VP8 connector

915240-03 Process tee with NPT connection threads

22719-02 Junction box
12707-00 Jet cleaner
23242-02 Insertion adapter
24091-00 Low flow cell

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