Rosco Tough Prime Data Sheet

Material Safety Data Sheet
Revision Date: 01-Mar-2013 Revision Number: 5
1. PRODUCT AND COMPANY IDENTIFICATION
Product Name Product Code Product Class
Color
Manufacturer
Rosco Laboratories Inc. 52 Harbor View Avenue Stamford, CT 06902, USA Phone: (203)-708-8900 www.rosco.com
2. COMPOSITION INFORMATION ON COMPONENTS
Hazardous Components
Chemical Name CAS-No Weight % (max)
Limestone 1317-65-3 20
Titanium dioxide 13463-67-7 15
Kaolin 1332-58-7 10
Carbon black 1333-86-4 5
Glass, oxide 65997-17-3 5
TOUGH PRIME RF6050, RF6055
Emergency Telephone Number(s)
CHEMTREC (US): 800-424-9300 CHEMTREC (outside US): (703)-527-3887
3. HAZARDS IDENTIFICATION
Emergency Overview
Vapors may be irritating to eyes, nose, throat, and lungs. May cause skin irritation and/or dermatitis.
Appearance liquid Odor little or no odor Potential Health Effects
Principal Routes of Exposure Acute Effects
Eyes Skin Inhalation Ingestion
Chronic Effects
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Eye contact, skin contact and inhalation.
May cause slight irritation. Substance may cause slight skin irritation. May cause irritation of respiratory tract. Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea.
Repeated contact may cause allergic reactions in very susceptible persons.
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See Section 11 for additional Toxicological information.
Aggravated Medical Conditions HMIS
Health: 1* Flammability: 0 Reactivity: 0 PPE: -
None known
HMIS Legend
0 - Minimal Hazard 1 - Slight Hazard 2 - Moderate Hazard 3 - Serious Hazard 4 - Severe Hazard * - Chronic Hazard X - Consult your supervisor or S.O.P. for "Special" handling instructions.
Note: The PPE rating has intentionally been left blank. Choose appropriate PPE that will protect employees from the hazards the material will present under the actual normal conditions of use.
Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks. Although HMIS® ratings are not required on MSDSs under 29 CFR 1910.1200, the preparer, has chosen to provide them. HMIS® ratings are to be used only in conjunction with a fully implemented HMIS® program by workers who have received appropriate HMIS® training. HMIS® is a registered trade and service mark of the NPCA. HMIS® materials may be purchased exclusively from J. J. Keller (800) 327-6868.
4. FIRST AID MEASURES
General Advice Eye Contact
No hazards which require special first aid measures. Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
Skin Contact
Wash off immediately with soap and plenty of water removing all contaminated clothes and shoes.
Inhalation Ingestion
Move to fresh air. If symptoms persist, call a physician. Clean mouth with water and afterwards drink plenty of water. Consult a physician if
necessary.
Notes To Physician
Treat symptomatically
5. FIRE-FIGHTING MEASURES
Suitable Extinguishing Media
Protective Equipment And Precautions For Firefighters
Specific Hazards Arising From The Chemical
Sensitivity To Mechanical Impact
Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.
Closed containers may rupture if exposed to fire or extreme heat.
No
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Sensitivity To Static Discharge Flash Point Data
Flash Point (°F) Flash Point (°C) Flash Point Method
Flammability Limits In Air
Lower Explosion Limit Upper Explosion Limit
Health: 1
NFPA Legend
0 - Not Hazardous 1 - Slightly 2 - Moderate 3 - High 4 - Severe
The ratings assigned are only suggested ratings, the contractor/employer has ultimate responsibilities for NFPA ratings where this system is used. Additional information regarding the NFPA rating system is available from the National Fire Protection Agency (NFPA) at www.nfpa.org.
Flammability: 0 Instability: 0
No
Not applicable Not applicable Not applicable
Not applicable Not applicable
Special: Not ApplicableNFPA
6. ACCIDENTAL RELEASE MEASURES
Personal Precautions Environmental Precautions Methods For Clean-Up
Other Information
Handling
Storage
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Exposure Limits
Hazardous Components
Chemical Name ACGIH OSHA
Limestone N/E 15 mg/m3 - TWA total
Avoid contact with skin, eyes and clothing. Ensure adequate ventilation. Prevent further leakage or spillage if safe to do so. Soak up with inert absorbent material. Sweep up and shovel into suitable containers
for disposal. None known
7. HANDLING AND STORAGE
Avoid contact with skin, eyes and clothing. Avoid breathing vapors, spray mists or sanding dust. In case of insufficient ventilation, wear suitable respiratory equipment.
Keep container tightly closed. Keep out of the reach of children.
3
5 mg/m
- TWA
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Titanium dioxide 10 mg/m3 - TWA 15 mg/m3 - TWA total
Kaolin 2 mg/m
Carbon black 3.5 mg/m
Glass, oxide 1 fiber/cm3 - TWA
3
- TWA 15 mg/m3 - TWA total
3
- TWA 3.5 mg/m3 - TWA
5 mg/m3 - TWA
Legend
ACGIH - American Conference of Governmental Industrial Hygienists Exposure Limits OSHA - Occupational Safety & Health Administration Exposure Limits N/E - Not Established
Engineering Measures
Ensure adequate ventilation, especially in confined areas.
Personal Protective Equipment
Eye/Face Protection Skin Protection Respiratory Protection
Hygiene Measures
Safety glasses with side-shields. Protective gloves and impervious clothing In case of insufficient ventilation wear suitable respiratory equipment.
Avoid contact with skin, eyes and clothing. Remove and wash contaminated clothing before re-use. Wash thoroughly after handling.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance Odor Density (lbs/gal) Specific Gravity pH Viscosity (centistokes) Evaporation Rate Vapor Pressure Vapor Density Wt. % Solids Vol. % Solids Wt. % Volatiles Vol. % Volatiles VOC Regulatory Limit (g/L) Boiling Point (°F) Boiling Point (°C) Freezing Point (°F) Freezing Point (°C) Flash Point (°F) Flash Point (°C) Flash Point Method Upper Explosion Limit Lower Explosion Limit
liquid little or no odor
9.8 - 10.6
1.17 - 1.27 Not available Not available Not available Not available Not available 40 - 50 30 - 40 50 - 60 60 - 70 < 50 212 100 32 0 Not applicable Not applicable Not applicable Not applicable Not applicable
5 mg/m
3
N/E
- TWA
10. STABILITY AND REACTIVITY
Chemical Stability
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Stable under normal conditions.
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Conditions To Avoid Incompatible Materials Hazardous Decomposition Products Possibility Of Hazardous Reactions
11. TOXICOLOGICAL INFORMATION
Acute Toxicity Product
No information available
Component
Limestone LD50 Oral: 6,450 mg/kg (Rat) vendor data Sensitization: No sensitizing effects known.
Titanium dioxide LD50 Oral: > 10000 mg/kg (Rat) LD50 Dermal: > 10000 mg/m³ (Rabbit) LC50 Inhalation (Dust): > 6.82 mg/L (Rat, 4 hr.)
Prevent from freezing No materials to be especially mentioned. None under normal use. None under normal conditions of use.
Kaolin LD50 Oral: > 5000 mg/kg (Rat)
Carbon black LD50 Oral: > 15400 mg/kg (Rat) LD50 Dermal: > 3000 mg/kg (Rabbit)
Chronic Toxicity Carcinogenicity
The information below indicates whether each agency has listed any ingredient as a carcinogen:
Chemical Name ACGIH IARC NTP OSHA
Carcinogen
2B - Possible
Titanium dioxide
Carbon black
• Although IARC has classified titanium dioxide as possibly carcinogenic to humans (2B), their summary concludes: "No significant exposure to titanium dioxide is thought to occur during the use of products in which titanium dioxide is bound to other materials, such as paint."
Human
Carcinogen
2B - Possible
Human
Carcinogen
Listed
Listed
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Legend
ACGIH - American Conference of Governmental Industrial Hygienists IARC - International Agency for Research on Cancer NTP - National Toxicity Program OSHA - Occupational Safety & Health Administration
12. ECOLOGICAL INFORMATION
Ecotoxicity Effects
Product
Acute Toxicity to Fish
No information available
Acute Toxicity to Aquatic Invertebrates
No information available
Acute Toxicity to Aquatic Plants
No information available
Component
Acute Toxicity to Fish
Titanium dioxide LC50: >1000 mg/L (Fathead Minnow - 96 hr.)
Acute Toxicity to Aquatic Invertebrates
No information available
Acute Toxicity to Aquatic Plants
No information available
13. DISPOSAL CONSIDERATIONS
Waste Disposal Method
Dispose of in accordance with federal, state, and local regulations. Dry, empty containers may be recycled in a can recycling program. Local requirements may vary, consult your sanitation department or state-designated environmental protection agency for more disposal options.
14. TRANSPORT INFORMATION
DOT
Not regulated
ICAO / IATA
IMDG / IMO
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Not regulated
Not regulated
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15. REGULATORY INFORMATION
International Inventories
United States TSCA Canada DSL
Yes - All components are listed or exempt. Yes - All components are listed or exempt.
Federal Regulations
SARA 311/312 hazardous categorization
Acute Health Hazard No Chronic Health Hazard Yes Fire Hazard No Sudden Release of Pressure Hazard No Reactive Hazard No
SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372:
This product may contain trace amounts of (other) SARA reportable chemicals. Contact the preparer for further information.
Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) (see 40 CFR 61)
This product contains the following HAPs:
This product may contain trace amounts of (other) HAPs chemicals. Contact the preparer for further information.
State Regulations
California Proposition 65
This product may contain small amounts of materials known to the state of California to cause cancer or reproductive harm.
State Right-to-Know
Chemical Name Massachusetts New Jersey Pennsylvania Louisiana Rhode Island
Limestone X X X X
Titanium dioxide X X X X
Kaolin X X X X
Carbon black X X X X
Legend
X - Listed
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16. OTHER INFORMATION
WARNING! If you scrape, sand, or remove old paint, you may release lead dust. LEAD IS TOXIC. EXPOSURE TO
LEAD DUST CAN CAUSE SERIOUS ILLNESS, SUCH AS BRAIN DAMAGE, ESPECIALLY IN CHILDREN. PREGNANT WOMEN SHOULD ALSO AVOID EXPOSURE. Wear a NIOSH approved respirator to control lead exposure. Clean up carefully with a HEPA vacuum and a wet mop. Before you start, find out how to protect yourself and your family by contacting the National Lead Information Hotline at 1-800-424-LEAD or log on to www.epa.gov/lead.
Prepared By
Product Stewardship Department Complementary Coatings Corp. dba Insl-X 101 Paragon Drive Montvale, NJ 07645 Phone: 1-800-225-5554
Revision Date: Revision Summary
Disclaimer
The information contained herein is presented in good faith and believed to be accurate as of the effective date shown above. This information is furnished without warranty of any kind. Employers should use this information only as a supplement to other information gathered by them and must make independent determination of suitability and completeness of information from all sources to assure proper use of these materials and the safety and health of empl oyees. Any use of this data and information must be determined by the user to be in accordance with applicable federal, provincial, and local laws and regulations.
01-Mar-2013 Not available
End of MSDS
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