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Product Name : PRINT CARTRIDGE BLACK SP C310HA (Black toner) SDS
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Number : 406475
Date Prepared : 11/01/2008 Date Modified : 08/01/2014 Date Printed: 11/11/2016
Safety Data Sheet
Section1 : Chemical Product and Company Identification
(a) Product identifier used on the label
Product Name : PRINT CARTRIDGE BLACK SP C310HA (Black toner)
(b) Other means of identification
SDS Number : 406475
(c) Recommended use of the chemical and restrictions on use
General Use : The Image Formation of Printing Machine or Copier
(d) Name, address, and telephone number of the chemical manufacturer, importer, or other responsible party
Company Name : Ricoh USA, Inc.
Department : Environmental Sustainability and Product Compliance
Address : 5 Dedrick Place West Caldwell, NJ 07006 USA
(e) Emergency phone number.
Telephone Number : 1-973-882-2000 or 1-973-882-5218 (For product information) or
Telefax Number : 1-973-882-3959
E-mail : environmentinfo@ricoh-usa.com
1-800-336-6737 (for emergencies)
Section2 : Hazards Identification
Classification
EXPLOSIVES Not Applicable
FLAMMABLE GASES Not Applicable
FLAMMABLE AEROSOLS Not Applicable
OXIDIZING GASES Not Applicable
GASES UNDER PRESSURE Not Applicable
FLAMMABLE LIQUIDS Not Applicable
FLAMMABLE SOLIDS Classification not possible
SELF-REACTIVE SUBSTANCES AND
MIXTURES
PHYSICAL HAZARD(S)
HEALTH HAZARD(S) ACUTE TOXICITY(ORAL) Not Classified
PYROPHORIC LIQUIDS Not Applicable
PYROPHORIC SOLIDS Classification not possible
SELF-HEATING SUBSTANCES AND
MIXTURES
SUBSTANCES AND MIXTURES,
WHICH ON CONTACT WITH WATER,
EMIT FLAMMABLE GASES
OXIDIZING LIQUIDS Not Applicable
OXIDIZING SOLIDS Classification not possible
ORGANIC PEROXIDES Classification not possible
CORROSIVE TO METALS Classification not possible
ACUTE TOXICITY(DERMAL) Classification not possible
ACUTE TOXICITY
(INHALATION - GAS)
ACUTE TOXICITY
(INHALATION - VAPOUR)
ACUTE TOXICITY
(INHALATION - DUST AND MIST)
SKIN CORROSION/IRRITATION Not Classified
SERIOUS EYE DAMAGE/EYE
IRRITATION
RESPIRATORY SENSITIZER Classification not possible
SKIN SENSITIZER Not Classified
GERM CELL MUTAGENICITY Classification not possible
Not Applicable
Classification not possible
Classification not possible
Not Applicable
Not Applicable
Classification not possible
Classification not possible
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CARCINOGENICITY Classification not possible
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TOXIC TO REPRODUCTION Classification not possible
TARGET ORGAN SYSTEMIC
TOXICITY FOLLOWING SINGLE
EXPOSURE
TARGET ORGAN SYSTEMIC
TOXICITY FOLLOWING REPEAT
EXPOSURE
ASPIRATION HAZARD Classification not possible
ACUTE HAZARDS TO
THE AQUATIC ENVIRONMENT
ENVIRONMENTSL
HAZARD(S)
Label element
Pictogram：
Signal word(s)：
Hazard statement(s)：
Precautionary
statement(s) not applicable
CHRONIC HAZARDS TO
THE AQUATIC ENVIRONMENT
HAZARDOUS TO THE OZONE
LAYER
not applicable
not applicable
【Prevention】
【Response】
【Storage】
【Disposal】
not applicable
not applicable
not applicable
Classification not possible
Classification not possible
Classification not possible
Classification not possible
Classification not possible
Specific Hazards
Dust explosion (like most finely grained organic powders)
Section3 : Composition, Information on Ingredients
Ingredients Contents
CAS No./Chemical name (%)
Confidential
Polyester Resin 1
Confidential
Polyester Resin 2
Confidential
Wax
Confidential
Silica
Confidential
Organic Salt
Section4 : First Aid Measures
(a) Necessary measures
Inhalation :
Remove from exposure into fresh air and rinse mouth with water. Seek medical advice.
Skin Contact :
Wash thoroughly with soapy water.
40-60
20-40
1-5
1-5
1-5
Eye Contact :
Flush with a large amount of water until particles are removed. Seek medical advice.
Ingestion :
Drink several glasses of water to dilute ingested toner. Seek medical advice.
(b) Most important symptoms/effects, acute and delayed.
Not available
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(c) Indication of immediate medical attention and special treatment needed.
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Immediate edical Attention :
Immediate medical attention is not required.
Section5 : Fire Fighting Measures
(a) Suitable (and unsuitable) extinguishing media.
Extinguishing Media to Avoid :
Not applicable.
(b) Specific hazards arising from the chemical (e.g., nature of any hazardous combustion products).
Specific Hazards :
Can form explosive dust-air mixtures when finely dispersed in air.
(c) Special protective equipment and precautions for fire-fighters.
Fire-Fighting Instructions / Specific Method :
No special fire protecting method is required. Sprinkling or fire extinguishers can be used.
Protection of Firefighters :
Wear gloves, glasses, a mask if necessary.
Section6 : Accidental Release Measures
(a) Personal precautions, protective equipment, and emergency procedures.
Personal Precautions :
Do not breathe in dust.
Environment Precautions :
Do not flush into sewers or watercourses.
(b) Methods and materials for containment and cleaning up.
Methods for Cleaning Up :
Fine powder may form explosive dust-air mixture.Confirm there is no source of fire and if there is a
source,remove it.Sweep up spilled powder slowly and clean reminder with wet cloth.If a vacuum cleaner
is used,a dust explosion-proof type must be chosen.
Section7 : Handling and Storage
(a) Precautions for safe handling.
Handling :
Technical Measures/Precautions
Not applicable
Safe Handling Advice
Do not handle in areas where there is wind or draught, this may cause dust to get into eyes.
Avoid breathing in dust.
(b) Conditions for safe storage, including any incompatibilities.
Storage :
Technical Measures
Not applicable
Storage Conditions
Keep out of reach of children.
Store in dry, well-ventilated area, to maintain quality the temperature should not exceed 35degrees
centigrade for a long time. Avoid direct sunlight.
Packaging material
Not applicable
Specific Use(s) :
Image formation in printing machines or copiers.
Section8 : Exposure Controls/Personal Protection
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(a) OSHA permissible exposure limit (PEL), American Conference of Governmental Industrial Hygienists
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(ACGIH)
Threshold Limit Value (TLV), and any other exposure limit
Control Parameters
Exposure Limit Value ( I )
USA OSHA PEL
(TWA)
ACGIH TLV (TWA) : 10mg/m3 (Inhalable fraction) 3.0mg/m3 (Respirable fraction)
DFG MAK : 4.0mg/m3 (Total dust) 1.5mg/m3 (Respirable fraction)
Personal Protection
(b) Appropriate engineering controls.
Technical measures :
Use adequate ventilation. None required with intended use.
(c) Individual protection measures, such as personal protective equipment.
Respiratory Protections (Specify Type)
None required in normal use. If the limit of exposure concentration is exceeded, use authorised
respirator.
Eye Protection
Put on goggles if necessary.
Protective Gloves
Use vinyl or rubber gloves if necessary.
Protective Clothing or Equipment
Wear chemical-resistant apron or other impervious clothing if necessary.
: 15mg/m3 (Total dust) 5.0mg/m3 (Respirable fraction)
Hygiene Measures
Wash hands after handling.
Section9 : Physical and Chemical Properties
(a)Appearance (physical state, color, etc.)
Physical state : Solid
Form : Powder
Colour : Black
(b)Odor : Slightly plastic odor
(c)Odor threshold : Not available
(d)pH : Not applicable
(e)Melting point/freezing point
(degrees centigrade)
(f)Initial boiling point and boiling range : Not applicable
(g)Flash point : Not applicable
(h)Evaporation Rate (Butyl Acetate = 1) : Not applicable
(i)Flammability (solid, gas) : Not flammable
: (Softening point) Approx.110
(j)Upper/lower flammability or explosive
limits
(k)Vapor Pressure (Pa) : Not applicable
(l)Vapor Density (AIR=1) : Not applicable
(m)Relative density : Approx.1.2
: Upper Not available Lower Not available
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(n)Solubility(ies)
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Water Solubility (g/L) : Insoluble
Chloroform Solubility (g/L) : Slightly soluble
(o)Partition coefficient: n-octanol/water : Not available
(p)Auto-ignition temperature : Not available
(q)Decomposition temperature
(degrees centigrade)
(r)Viscosity (Pa・s) : Not applicable
: Not available
Section10 : Stability and Reactivity
(a)Reactivity
Hazardous Reaction :
Dust explosion, like most finely grained organic powders.
(b)Chemical stability :
Stable
(c)Possibility of hazardous reactions :
Not available
(d)Condition to Avoid :
Not applicable in normal use.
(e)Incompatible materials :
Not applicable in normal use.
(f)Hazardous decomposition products :
Decomposition products will not occur.
Section11 : Toxicological Information
(a)Information on the likely routes of exposure (inhalation, ingestion, skin and eye contact)
ingestion,skin,inhalation,eye contact
(b)Symptoms related to the physical, chemical and toxicological characteristics
Not available
(c)Delayed and immediate effects and also chronic effects from short- and long-term exposure
Not available
Acute Toxicity
Acute Oral Toxicity (LD50) :
5000 or over [mg/kg] (Rat) (Based on other product test results of similar ingredients.)
Acute Dermal Toxicity :
Not available
Acute Inhalation Toxicity :
Not available
Local effects
Acute Skin Irritation(PII) :
1.0 or below (Rabbit) (Based on other product test results of similar ingredients.)
Acute Eye Irritation :
Not available (Ingredients are not classified as dangerous according to Directive 67/548/EEC.)
Sensitization
Acute Allergenic Effects :
0 % (Marmot) (Based on other product test results of similar ingredients.)
Mutagenicity : Negative (Ames test)
Reproduction Toxicity : Does not contain substances listed as hazardous to reproductive health.
Teratogenic : Not available
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(d)Numerical measures of toxicity (such as acute toxicity estimates)
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Not available
(e)Whether the hazardous chemical is listed in the National Toxicology Program (NTP)
Report on Carcinogens (latest edition) or has been found to be a potential carcinogen
in the International Agency for Research on Cancer (IARC) Monographs (latest edition), or by OSHA.
Carbon black contained in this product is classified to Group 2B of IARC as the result of inhalation test
in use of rat.
But oral/skin test does not show carcinogenicity.
The toner containing carbon black did not show carcinogenicity in chronic inhalation exposure test in
use of rat.
Section12 : Ecological Information
Mobility : No data are available on any adverse effects on the environment.
Persistence/Degradability : Not available
Bioaccumulation : Not available
Ecotoxicity
Acute Toxicity for Fish (LC50) : Not classified as toxic (EU Directive 1999/45/EC)mg/l/96hr
Acute Toxicity for Daphnia (EC50) : Not classified as toxic (EU Directive 1999/45/EC)mg/l/48hr
Algae Inhibition Test (IC50) : Not classified as toxic (EU Directive 1999/45/EC)mg/l/72hr
General information:
Dispose of waste and residues in accordance with local authority requirements.
Disposal methods:
Disposal recommendations are based on material as supplied. Disposal must be in accordance with
current applicable laws and regulations, and material characteristics at time of disposal. Confirm disposal
procedures with local regulations.
Precautions
Do not throw the toner cartridge or toner into an open flame. Hot toner may scatter and cause burns or
other damage.
International Regulations
Land Transport
RID/ADR : Not applicable
DOT 49 CFR : Not applicable
ADNR : Not applicable
Sea Transport
IMDG Code : Not applicable
Air Transport
ICAO-TI/IATA-DGR : Not applicable
UN Number : Not applicable
Class : Not applicable
Section13 : Disposal Consideration
Section14 : Transport Information
Specific Precautionary Transport Measures and Conditions
Avoid direct sunlight in quality.
Section15 : Regulatory Information
Regulations
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US Information
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Information on the label :
Not required
TSCA (Toxic Substances Control Act) :
This toner complies with all applicable rules and regulations under TSCA.
SARA (Superfund Amendments and Reauthorization Act) Title III
313 Reportable Ingredients :
Not regulated
California Proposition 65
Not regulated
Canada Information
WHMIS Controlled product :
Not a controlled product
EU Information
Information on the label (EU Regulation (EC)No. 1272/2008)
Symbol & Indication : Not required
Hazard Statement : Not required
Precautionary statement : Not required
Special Precautions underEU Regulation 1272/2008 Annex II :
Not required
This product complies with applicable rules and regulations under 76/769/EEC
Section16 : Other Information
Explanation of Hazardous Materials Identification System [HMIS]& National Fire Protection Association
[NFPA] Hazard Rating Systems:
Both the HMIS and NFPA systems use number from "0" to "4" to show the degree of hazard in an
uncontrolled situation:
0=Minimum Hazard 1=Slight Hazard 2=Moderate Hazard 3=Serious Hazard 4=Severe Hazard
Colors may also be used in both systems:
Blue=Health Hazard Red=Fire Hazard Yellow=Reactivity Hazard White=Indicate a special hazard
HMIS will specify any Personal Protective Equipment reqired [PPE],
NFPA will specify OX(oxidizer), Acid(acid), ALK(Alkali), COR(Corrosive), W(use no water), xx(Radioactive).
Literature References :
ANSI Z400.1-1993
ISO 11014-1
Commission Directive 91/155/EEC
IARC (1996) "IARC Monograph on the Evaluation of the Carcinogenic Risk of Chemicals to Humans,
Vol.65, Printing Process and Printing Inks, Carbon Black and Some Nitro Compounds", Lyon, pp149-261
H.Muhle, B.Bellman, O.Creutzenberg, C.Dasenbrock, H.Emst, R.Kilpper, J.C.MacKenzie, P.Morrow, U.Mohr,
S.Takenaka and R.Mermelstein(1991) "Pulmonary Response to Toner upon Chronic Inhalation Exposure in
Rats" Fundamental and Applied Toxicology 17,pp280-299
IARC (2008) "IARC Monograph on the Evaluation of the Carcinogenic Risk of Chemicals to Humans,
Vol.93"
NIOSH CURRENT INTELLIGENCE BULLETIN "Evaluation of Health Hazard and Recommendation for
Occupational Exposure to Titanium Dioxide DRAFT"
ACGIH-TLV : Threshold Limit Values for Chemical Substances and Physical Agents
OSHA Z-Tables : US Department of Labor, 29CFR Part 1910 , Tables Z-1, Z-2, and Z-3
NTP (USA) : US Department of Health and Human Services National Toxicology
Symbol (EC) : Regulation (EC)No.1272/2008
91/155/ EEC : EU Directive 91/155/ EEC
1999/45/EC : EU Directive 1999/45/EC
CLP (EC)No.1272/2008 :
and Biological Exposure Indices
Program Annual Report on Carcinogens
DFG-MAK（GER）: DFG List of MAK and BAT Value
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Regulation (EC)No.1272/2008 of the European Parliamant and of the
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Council of 16 December 2008 on classification, labelling and packaging
of substances and mixtures,amending and repealing Directive
67/548/EEC and 1999/45/EC, and amending Regulation (EC)No.
1907/2006
EC 304/2003 : Regulation (EC) No 304/2003 of the European Parliament and of the
WHMIS Controlled
product
OELs-TWA (Australia) : Guidance Note on the Interpretation of Exposure Standards for
Abbreviations :
OSHA PEL PEL (Permissible Exposure Limit) under Occupational Safety and Health Act
ACGIH-TLV TLV (Threshold Limit Values) under American Conference of Governmental Industrial
Hygienists
REACH EC)No.1907/2006:Council Regulation concerning the Registration, Evaluation,
Authorization and Restriction of Chemicals
SVHC Substances of Very High Concern
ECHA The European Chemicals Agency
DFG-MAK MAK (Maximale Arbeitsplatz Konzentrationen) by Deutsche Forschungs Gemeinschaft
RoHS Restriction of the use of certain Hazardous Substances in Electrical and Electronic
Equipment
TWA Time Weighted Average
IARC International Agency for Research on Cancer
NTP National Toxicology Program
WHMIS Workplace Hazardous Information System
NOHSC National Occupational Health and Safety Commission Act 1985
Council of 28 January 2003 concerning the export and import of
dangerous chemicals
: Canada Workplace Hazardous Information System
Atmospheric Contaminants in the Occupational Environment [NOHSC:
3008 (1995)]
Disclaimer(S) :
This information is furnished without warranty, expressed or implied, except that it is accurate to the best
knowledge of Ricoh USA, Inc.
It relates only to the specific material designated herein, and does not relate to use in combination with
any other material or process.
Ricoh USA, Inc assumes no legal responsibility for use or reliance upon this information.
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