Section 1 - Product and Company Identification
Rev：CD-0010
Product Name:
Lithium Manganese Dioxide Button Batteries(CR)
Company:
Camelion Battery Co. Ltd
Address：Unit 705, Cyber Timers Tower A, Tian’an Cyber Park,
Shenzhen,china
Sizes:
All
Date of preparation:
1. 1, 2018
Telephone:
(86) 0755-83618088
Fax:
(86)0755-83475720
Section 2 - Composition/Information on Ingredients
3
)
ACGIN TLV
(mg/m3)
Content
Ingredient CAS#
(wt%)
RTECS#
OSHA PEL
(mg/m
Lithium metal 7439-93-2 1~3 OJ5540000 - -
Manganese Dioxide 1313-13-9 14.5~33.5 OP0350000 5 5
Graphite 7782-42-5 0.6~1.5 MD9659600 - 2
Carbon Black 1333-86-4 0.9~2.2 FF5800000 3.5 3.5
Teflon 116-14-3 1.9~4.5 KX4025000 15 10
1,2-Dimethoxyethane 110-71-4 3.5~6.5 KI1451000 - 3(ppm)
Propylene Carbonate 108-32-7 1.2~1.9 FF9650000 - -
Lithium Perchlorate 7791-03-9 0.4~0.9 - - -
Section 3 - Hazards Summarizing
Routes of Entry: Inhalation: NO Skin: NO Ingestion: YES
Reports of Carcinogenicity: NTP: NO IARC: NO OSHA: NO
Health Hazards Acute and Chronic: These chemicals are in a sealed can. Risk of exposure occurs
only if the battery is mechanically or electrically abused. The
most likely risk is acute exp osure when a cell vents. PC is
mildly irritating on eye and skin contact. DME is believed to
be slightly to moderately irritant. Contact of electrolyte and
extruded lithium with skin and eyes should be avoided.
Effects of Overexposure: Irritation of skin or eyes. Lithium can cause thermal &
chemical burns upon contact with skin.
Rev：CD-0010
Section 4 - First-aid Measures
None unless internal materials exposure. If contents are leaked out, observe following
instructions
Inhalation Fumes can cause respiratory irritation. Remove to fresh air and consult a physician.
Skin Immediately flush skin with plenty of water. If itch or irritation by chemical burn
Persists, consult a physician.
Eyes Immediately flush eye with plenty of water for at least 15 minutes. Consult a
physician immediately.
Ingestion If swallowing a battery, consult a physician immediately.
If contents come into mouth, immediately rinse by plenty of water and consult a
physician.
Section 5 - Fire-fighting Measures
Extinguishing Media Extinguisher of alkaline metal fire is effective.
Plenty of cold water is also effective to cool the surrounding area and
control the spread fire. But hydrogen gas may be evolved by the
reaction of water and lithium and it can form an explosive mixture.
Therefore in the case that lots of lithium batteries are burning in a
confined space, use a smothering agent.
Fire fighting procedure Use self-contained breathing apparatus and full protective gear not to
inhale harmful gas.
Section 6 - Accidental Release Measures
Spill release Procedures: If cell vents or is punctured, ventilate area well. Wear eye and skin
protection. Respiratory protection may be necessary in confined spaces.
Absorb liquid with suitable material such as sand or clay. Transfer to
container for later disposal.
Neutralizing Agent: Not relevant.
Section 7- Handling and Storage
Rev：CD-0010
Never swallow. Never charge. Never heat. Never expose to open flame. Never disassemble.
Never reverse the positive and negative terminals when mounting. Never short-circuit the battery.
Never weld the terminal or wire to the body of the battery directly. Never use different batteries
together. Never touch the liquid leaked out of battery. Never bring fire close to battery liquid.
Store in cool, dry place.
Section 8 - Exposure Controls/Personal Pr otection
Respiratory Protection: SCBA(fire); Full-face respirator with particulate/organic cartridge(spill).
Ventilation: In case of venting, provide as much ventilation as possible.
Protective Gloves: Natural or Butyl rubber gloves.
Eye Protection: Chem workers goggles
Work Hygienic Practices: Avoid exposure, wash hands after handling.
Section 9 - Physical and Chemical Properties
N/A
Section 10 - Stability and Reactivity
Stability Stable
Incompatibility Water
Hazardous Polymerization Will not occur
Condition to avoid See section 7
Hazardous Decomposition or Byproducts Hydrogen
Section 11 - Toxicological Information
N/A
Section 12 - Ecological Information
Do not let the internal ingredients contact water. Avoid emit to the ditch, waste ditch and the
earth's surface.
Section 13 - Disposal
Rev：CD-0010
All the lithium battery disposed by certified tools.
Section 14 - Transport Information
The battery has passed the test of UN38.3 ( No.UN08-0440 ) by Guangzhou MCM
Certification & Testing Co., ltd. The battery is non-restricted goods.
UN numbers and proper shipping names:
UN 3090: Lithium metal batteries
UN 3091: Lithium metal batteries contained in equipment
Lithium metal batteries packed with equipment
Organizations governing the transport of lithium batteries
Area Method Organization Special Provision
International Air IATA, ICAO Section Ⅱ of PI 968-970
International Marine IMO SP188,SP230,SP310 and SP957
U.S.A Air, Rail, Road, Marine DOT 49 CFR Section 173.185
Their regulations are based on the UN Recommendations. Each special provision provides
specifications on exceptions and packaging for lithium batteries shipping.
Ref) Summary of Packing Instruction (IATA Dangerous Goods Regulations 59th Edition) 2018
The minimum requirements necessary to transport as non-restricted goods are as follows:
1) For a lithium metal or lithium alloy cell, the lithium content is not more than 1g. For a
lithium metal or lithium alloy battery, the aggregate lithium content is not more than 2g.
Our products all accords this standard.
2) Each cell or battery is of the type proven to meet the requirement of each test in the UN
Manual of Tests and Criteria, Part III, sub-section 38.3.
3) Each package must be displayed a battery handling label. (Telephone number must be printed
for emergency call on the handling label.)
4) Each consignment must be accompanied with a declaration of non-dangerous goods
document. (Telephone number must be printed for emergency call on the document.)
5) Each package must be capable of withstanding a 1.2 m drop test.
In addition,
a) Transportation of batteries installed in equipment as non-restricted goods
If each package contains no more than 4 cells or 2 batteries, the requirement is the same as
current. But for other cases of cell or battery quantity, the requirements are 1), 2), 3) and 4).
Rev：CD-0010
b) Transport of batteries packed with equipment as non-restricted goods. Regardless of the
battery quantity, the requirements 1) to 5) shall be satisfied.
c) Transportation of batteries only as non-restricted goods. Regardless of the battery quantity,
the requirements 1) to 5) shall be satisfied.
Also the maximum weight of one package is restricted in air transport, 2.5kg or less for lithium
metal cells or batteries.
Section 15 - Regulatory Information
IATA Dangerous Goods Regulations 59th Edition (2018)
ICAO Technical Instructions for the safe transport of dangerous goods by air.
Safety regulations for dangerous chemical goods.
Our products all follows above-mentioned regulations.
Section 16 - Other Information
If you want further information, please contact Camelion sales representative.
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