Resolve 97402 User Manual

Page 1
Carpet cleaning (liquids)
SAFETY DATA SHEET
Product name
Distributed by
1. Product and company identification
:
:
D0039585 v.4
:
SDS #
Formulation #:
:
0077294
Professional Resolve Spot & Stain Carpet Cleaner
Relevant identified uses of the substance or mixture and uses advised against
Not applicable.
:
Website:
http://www.rbnainfo.com
Emergency telephone number (Medical)
Emergency telephone number (Transport)
:
1-800-338-6167
1-800-424-9300 (U.S. & Canada) CHEMTREC Outside U.S. and Canada (North America), call Chemtrec:703-527-3887
:
This SDS is designed for workplace employees, emergency personnel and for other conditions and situations where there is greater potential for large-scale or prolonged exposure, in accordance with the requirements of USDOL Occupational Safety and Health Administration.
This SDS is not applicable for consumer use of our products. For consumer use, all precautionary and first aid language is provided on the product label in accordance with the applicable government regulations, and shown in Section 15 of this SDS.
Reckitt Benckiser LLC. Morris Corporate Center IV 399 Interpace Parkway (P.O. Box 225) Parsippany, New Jersey 07054-0225 +1 973 404 2600
Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM
2. Hazards identification
Classification of the substance or mixture
SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A
:
Signal word
:
Warning
Hazard statements
:
Causes serious eye irritation.
Hazard pictograms
:
GHS label elements
General Prevention
:
Wear eye or face protection. Wash hands thoroughly after handling.
:
Read label before use. Keep out of reach of children. If medical advice is needed, have product container or label at hand.
Precautionary statements
1/11
10/10/2014.
Date of issue
:
SDS #
FF0077294_4
:
Code #
D0039585 v.4
:
Professional Resolve Spot & Stain Carpet Cleaner
Page 2
D0039585 v.4
Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM
2. Hazards identification
Supplemental label elements
:
None known.
Hazards not otherwise classified
:
None known.
Response
:
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention.
Storage
:
Not applicable.
Disposal
:
Not applicable.
3. Composition/information on ingredients
Mixture
:
Substance/mixture
sodium dodecyl sulphate
1 - 2.5
151-21-3
Ingredient name
CAS number %
There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section.
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
4. First aid measures
Wash out mouth with water. Remove dentures if any. Move to fresh air. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention if adverse health effects persist or are severe. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway.
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention.
Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Get medical attention if symptoms occur.
Remove victim to fresh air and keep at rest in a position comfortable for breathing. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention if adverse health effects persist or are severe. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway.
Eye contact Skin contact
Inhalation
Ingestion
:
:
:
:
Description of necessary first aid measures
Most important symptoms/effects, acute and delayed
Inhalation
:
No known significant effects or critical hazards.
Irritating to mouth, throat and stomach.
:
Ingestion
Skin contact
:
No known significant effects or critical hazards.
Causes serious eye irritation.
:
Eye contact
Over-exposure signs/symptoms
Potential acute health effects
2/11
10/10/2014.
Date of issue
:
SDS #
FF0077294_4
:
Code #
D0039585 v.4
:
Page 3
D0039585 v.4
Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM
4. First aid measures
Protection of first-aiders
:
No action shall be taken involving any personal risk or without suitable training. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Notes to physician
:
Treat symptomatically.
Specific treatments
:
No specific treatment.
Skin contact
Ingestion
Inhalation
No specific data.
No specific data.
No specific data.
:
:
:
Eye contact
:
Adverse symptoms may include the following: pain or irritation watering redness
See toxicological information (Section 11)
Indication of immediate medical attention and special treatment needed, if necessary
5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training.
Hazardous thermal decomposition products
Specific hazards arising from the chemical
Decomposition products may include the following materials: carbon dioxide carbon monoxide sulfur oxides metal oxide/oxides
In a fire or if heated, a pressure increase will occur and the container may burst.
Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective equipment for fire-fighters
Use an extinguishing agent suitable for the surrounding fire.
Extinguishing media
:
:
:
None known.
Suitable extinguishing media
:
Unsuitable extinguishing media
:
Special protective actions for fire-fighters
:
6. Accidental release measures
Personal precautions, protective equipment and emergency procedures
:
No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment.
For non-emergency personnel For emergency responders
:
If specialised clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non­emergency personnel".
3/11
10/10/2014.
Date of issue
:
SDS #
FF0077294_4
:
Code #
D0039585 v.4
:
Page 4
D0039585 v.4
Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM
6. Accidental release measures
Environmental precautions
Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal.
:
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).
Large spill
:
Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.
Small spill
:
Methods and materials for containment and cleaning up
7. Handling and storage
Conditions for safe storage, including any incompatibilities
Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination.
:
Protective measures
Put on appropriate personal protective equipment (see Section 8). Do not ingest. Avoid contact with eyes, skin and clothing. Avoid breathing vapor or mist. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container.
:
Precautions for safe handling
Not applicable.
8. Exposure controls/personal protection
Environmental exposure controls
:
Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.
Appropriate engineering controls
:
Good general ventilation should be sufficient to control worker exposure to airborne contaminants.
Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.
Hygiene measures
:
Control
Individual protection measures
Occupational exposure limits
4/11
10/10/2014.
Date of issue
:
SDS #
FF0077294_4
:
Code #
D0039585 v.4
:
Page 5
D0039585 v.4
Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM
8. Exposure controls/personal protection
Hand protection
Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator.
Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated.
Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles.
Eye/face protection
Respiratory protection
:
:
:
Body protection
Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.
:
Skin protection
Other skin protection
:
Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.
9. Physical and chemical properties
Physical state
Melting point
Vapor pressure
Relative density
Vapor density
Solubility
Liquid.
Not available.
1 to 1.03
Not available.
Not available.
Easily soluble in the following materials: cold water and hot water.
Citrus Herbaceous
Odor
pH
Amber.
Color
Evaporation rate
Not available.
Auto-ignition temperature
Flash point
Not available.
Closed cup: >93.3°C (>199.9°F)
Not available.
6.35 to 6.85
Viscosity
Not available.
Not available.
Odor threshold
Partition coefficient: n­octanol/water
:::
:
:
:
:::
: :
:
:
:
:
Appearance
Boiling point
:
Not available.
Flammability (solid, gas)
:
Not available.
Lower and upper explosive (flammable) limits
:
Not available.
Decomposition temperature
:
Not available.
5/11
10/10/2014.
Date of issue
:
SDS #
FF0077294_4
:
Code #
D0039585 v.4
:
Page 6
D0039585 v.4
Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM
10. Stability and reactivity
Hazardous decomposition products
Conditions to avoid
No specific data.
Hazardous decomposition products : carbon oxides , Various Organic chemicals. The product is stable.
Chemical stability
Do not mix with household chemicals
:
:
:
Incompatible materials
:
Possibility of hazardous reactions
:
Under normal conditions of storage and use, hazardous reactions will not occur. Polymerization. : There are no data available on the mixture itself.
Reactivity
:
No specific test data related to reactivity available for this product or its ingredients.
11. Toxicological information
Acute toxicity
Product/ingredient name
Result
Species
Dose
Exposure
Irritation/Corrosion
sodium dodecyl sulphate
Eyes - Mild irritant
Rabbit
-
250 Micrograms
-
Eyes - Moderate irritant
Rabbit
-
24 hours 100 milligrams
-
Eyes - Moderate irritant
Rabbit
-
10 milligrams
-
Skin - Mild irritant
Dog
-
24 hours 25 milligrams
-
Skin - Mild irritant
Guinea pig
-
24 hours 25 milligrams
-
Skin - Mild irritant
Human
-
2 hours 2 Percent
-
Skin - Mild irritant
Human
-
504 hours 0.3 Percent
-
Skin - Mild irritant
Human
-
24 hours 0.06 Percent
-
Skin - Mild irritant
Human
-
22 hours 10 Percent
-
Skin - Mild irritant
Human
-
47 hours 0.5 Percent
-
Skin - Mild irritant
Human
-
18 hours 2 Percent
-
Skin - Moderate irritant
Human
-
48 hours 3 Percent
-
Skin - Moderate irritant
Human
-
24 hours 0.1 Percent
-
Skin - Moderate irritant
Mouse
-
24 hours 25 milligrams
-
Skin - Mild irritant
Pig
-
24 hours 25 milligrams
-
Skin - Mild irritant
Rabbit
-
24 hours 50 milligrams
-
Skin - Moderate irritant
Rabbit
-
24 hours 25 milligrams
-
Product/ingredient name
Result
Score
Exposure
Observation
Species
Information on toxicological effects
Sensitization
Not available.
sodium dodecyl sulphate
LD50 Oral
Rat
1288 mg/kg
-
6/11
10/10/2014.
Date of issue
:
SDS #
FF0077294_4
:
Code #
D0039585 v.4
:
Page 7
D0039585 v.4
Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM
11. Toxicological information
Carcinogenicity
Not available.
Mutagenicity
Not available.
Teratogenicity
Not available.
Reproductive toxicity
Not available.
Specific target organ toxicity (single exposure)
Specific target organ toxicity (repeated exposure)
Not available.
Not available.
Aspiration hazard
Not available.
Not available.
Information on the likely routes of exposure
Inhalation
:
No known significant effects or critical hazards.
Irritating to mouth, throat and stomach.
:
Ingestion
Skin contact
:
No known significant effects or critical hazards.
Causes serious eye irritation.
:
Eye contact
Symptoms related to the physical, chemical and toxicological characteristics
Skin contact
Ingestion
Inhalation
No specific data.
No specific data.
No specific data.
:
:
:
Eye contact
:
Adverse symptoms may include the following: pain or irritation watering redness
Potential chronic health effects
Delayed and immediate effects and also chronic effects from short and long term exposure
:
Not available.
Potential acute health effects
Potential immediate effects
:
Not available.
Short term exposure
Potential delayed effects
:
Not available.
Potential immediate effects
:
Not available.
Long term exposure
Potential delayed effects
:
Not available.
7/11
10/10/2014.
Date of issue
:
SDS #
FF0077294_4
:
Code #
D0039585 v.4
:
Page 8
D0039585 v.4
Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM
11. Toxicological information
No known significant effects or critical hazards.
General
:
No known significant effects or critical hazards.
Carcinogenicity
:
No known significant effects or critical hazards.
Mutagenicity
:
No known significant effects or critical hazards.
Teratogenicity
:
Developmental effects
:
No known significant effects or critical hazards.
Fertility effects
:
No known significant effects or critical hazards.
Numerical measures of toxicity
Oral
112440 mg/kg
Route
ATE value
Acute toxicity estimates
12. Ecological information
Toxicity
sodium dodecyl sulphate
Acute EC50 1200 µg/l Marine water
Algae - Skeletonema costatum
96 hours
Acute LC50 900 µg/l Marine water
Crustaceans - Artemia salina ­Adult
48 hours
Acute LC50 1400 µg/l Fresh water
Daphnia - Daphnia pulex ­Neonate
48 hours
Acute LC50 590 µg/l Fresh water
Fish - Cirrhinus mrigala - Larvae
96 hours
Chronic NOEC 1.25 mg/l Marine water
Algae - Ulva fasciata - Zoea
96 hours
Chronic NOEC 3.2 mg/l Fresh water
Daphnia - Daphnia magna ­Neonate
21 days
Chronic NOEC >1357 µg/l Fresh water
Fish - Pimephales promelas
42 days
Product/ingredient name
Species
Result
Exposure
LogP
ow
BCF
Potential
Bioaccumulative potential
Other adverse effects
:
No known significant effects or critical hazards.
Product/ingredient name
sodium dodecyl sulphate
-2.03
-
low
Persistence and degradability
Soil/water partition coefficient (KOC)
:
Not available.
Mobility in soil
Not available.
8/11
10/10/2014.
Date of issue
:
SDS #
FF0077294_4
:
Code #
D0039585 v.4
:
Page 9
D0039585 v.4
Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM
13. Disposal considerations
Waste packaging should be recycled. Waste must be disposed of in accordance with federal, state and local environmental control regulations.
:
Disposal methods
14. Transport information
Not a DOT controlled material (United States). Not a TDG-controlled material. This preparation is not classified as dangerous according to international transport regulations (ADR/RID, IMDG or ICAO/IATA).
15. Regulatory information
U.S. Federal regulations
:
TSCA 8(a) PAIR
: 1-phenoxypropan-2-ol; 4-(4-hydroxy-4-methylpentyl)cyclohex-3­enecarbaldehyde; α-hexylcinnamaldehyde; bornan-2-one; phenylacetaldehyde; 2­benzylideneheptanal
TSCA 8(a) CDR Exempt/Partial exemption
: Not determined
United States inventory (TSCA 8b)
: Not determined.
Clean Air Act Section 112 (b) Hazardous Air Pollutants (HAPs)
:
Not listed
Clean Air Act Section 602 Class I Substances
:
Not listed
Clean Air Act Section 602 Class II Substances
:
Not listed
DEA List I Chemicals (Precursor Chemicals)
:
Not listed
DEA List II Chemicals (Essential Chemicals)
:
Not listed None of the components are listed.
Massachusetts
:
New York
:
None of the components are listed.
New Jersey
:
None of the components are listed.
Pennsylvania
:
None of the components are listed.
State regulations
SARA 302/304
SARA 304 RQ
:
Not applicable.
No products were found.
Composition/information on ingredients
SARA 311/312
Classification
:
Immediate (acute) health hazard
sodium dodecyl sulphate
1 - 2.5
No.
No.
No.
Yes.
No.
Name
%
Fire hazard
Sudden release of pressure
Reactive
Immediate (acute) health hazard
Delayed (chronic) health hazard
Composition/information on ingredients
9/11
10/10/2014.
Date of issue
:
SDS #
FF0077294_4
:
Code #
D0039585 v.4
:
Page 10
D0039585 v.4
Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM
15. Regulatory information
Label elements
16. Other information
Hazardous Material Information System (U.S.A.)
0
0
0
012
National Fire Protection Association (U.S.A.)
Health
Special
Instability/Reactivity
Flammability
Health
Flammability
Physical hazards
Date of issue
Date of previous issue
Version
:::
:
:
Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks Although HMIS® ratings are not required on MSDSs under 29 CFR 1910. 1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may be purchased exclusively from J. J. Keller (800) 327-6868.
The customer is responsible for determining the PPE code for this material.
Indicates information that has changed from previously issued version.
10/10/2014.
No previous validation.
4
Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency Response Copyright ©1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is not the complete and official position of the National Fire Protection Association, on the referenced subject which is represented only by the standard in its entirety.
Copyright ©2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of chemicals. The user is referred to certain limited number of chemicals with recommended classifications in NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA or not, anyone using the 704 systems to classify chemicals does so at their own risk.
Personal protection
Prepared by
:
Reckitt Benckiser Italy Via Sant'Antonio, 5 30034 MIRA, VENICE ITALY ++39 041 5629211
B
10/11
10/10/2014.
Date of issue
:
SDS #
FF0077294_4
:
Code #
D0039585 v.4
:
Page 11
D0039585 v.4
Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM
16. Other information
Notice to reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.
RB is a member of the CSPA Product Care Product Stewardship Program.
11/11
10/10/2014.
Date of issue
:
SDS #
FF0077294_4
:
Code #
D0039585 v.4
:
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