Repel CB003384 User Manual

Page 1
Safety Data Sheet
Repel Insect Repellent Sportsmen Max Formula 40% DEET
Section 1 - Product and Company Identification
Product Identifiers:
Details of the Supplier of the Safety Data Sheet:
Manufacturer/Supplier: Chemsico
Div. of United Industries Corp. P.O. Box 142642 St. Louis, MO 63114
For product information: 1-800-880-1181
For medical emergencies: 1-800-633-2873
Section 2 - Hazards Identification
Conforms to Hazard Communication Standard 29 CFR 1910.1200.
GHS Classification of Substance or Mixture:
GHS Label Elements:
Hazard pictogram(s):
Flammable aerosol - Category 2
Page 1 of 7
Revision date: 2/22/2016
Signal word: WARNING
Hazard statements: • Flammable aerosol
• Compressed gas – contents under pressure; may burst if heated
• Causes eye irritation
• Harmful if swallowed
• May cause an allergic skin reaction
Precautionary Statements:
• Contents under pressure.
• Do not use or store near heat or open flame.
• Do not puncture or incinerate container.
• Exposure to temperatures above 130°F may cause bursting.
• If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.
• Wash hands with soap and water after handling. Do not eat, drink or smoke when using this product. If swallowed: Call a poison control center or doctor for treatment advice if you feel unwell. Rinse mouth.
• If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash before reuse.
Page 2
Safety Data Sheet
Repel Insect Repellent Sportsmen Max Formula 40% DEET
Section 3 - Composition / Information on Ingredients
Chemical Name CAS# Weight Percent
DEET (N,N-Diethyl-m-toluamide) 134-62-3 40.0% Ethanol 64-17-5 20.0% Isobutane 75-28-5 10.0%
Note: Ingredients not identified are proprietary or non-hazardous. Values are not product specifications.
Section 4 - First Aid Measures
Eye contact: Hold eye open and rinse slowly and gently with water for
15-20 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing. Call a poison control center or doctor for treatment advice.
Skin contact: After returning indoors, wash treated skin with soap and
Inhalation: No special requirements
water. Discontinue use if irritation or rash occurs.
Ingestion: Call a poison control center or doctor immediately for
treatment advice. Have person sip if able to swallow. Do not induce vomiting unless told to do so by a poison control center or doctor. Do not give anything by mouth to
Note to Physician: None
an unconscious person.
General advice: If you feel unwell, seek medical advice (show the label
where possible). Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Keep out of reach of children.
Section 5 - Fire Fighting Measures
Flammable properties: Pressurized aerosol container
NFPA classification: NFPA level 1 aerosol
Suitable extinguishing media: Water fog, foam, CO2, dry chemical
Unsuitable extinguishing media: Not available
Specific hazards arising from the
chemical: Contents under pressure – container may burst in heat of
fire.
Protective equipment for firefighters: Firefighters should wear full protective clothing including self-contained breathing apparatus.
Hazardous combustion products: None known
Explosion data: Not available
Sensitivity to static discharge: Not available
Personal precautions: Keep unnecessary personnel away. Do not touch or walk
through spilled material.
Revision date: 2/22/2016
Page 2 of 7
Page 3
Exposure Limits
Chemical name
Safety Data Sheet
Repel Insect Repellent Sportsmen Max Formula 40% DEET
Section 6 - Accidental Release Measures
Personnel precautions: Remove all sources of ignition. Wear personnel protective
equipment as recommended in Section 8. Wash thoroughly after handling.
For emergency responders: If specialized clothing is required to deal with the spillage,
take note of any information in Section 8 on suitable and unsuitable materials.
Environmental precautions: Avoid dispersal of spilled material and runoff and contact
with soil, waterways, drains and sewers.
Methods for containment and cleaning up: Stop leak if without risk. Move containers from spill area.
Before attempting clean up, refer to hazard data given above. Small spills may be absorbed with earth, sand or absorbent material swept up and placed in suitable, covered, and labeled containers. Prevent large spills from entering sewers or waterways. Contact emergency services and supplier for advice. Never return spills in original containers for re-use.
Section 7 - Handling and Storage
Precautions for safe handling: Put on appropriate personal protective equipment as
recommended in Section 8. Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50°C (122°F). Do not pierce or burn, even after use. Do not ingest. Avoid contact with skin, eyes and clothing. Avoid breathing vapor or mist. Use only with adequate ventilation. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical equipment. Use only non­sparking tools. Empty containers retain product residue and can be hazardous.
Storage: Store in a cool, dry area away from open flame. Do not
store above 50°C (122°F).
Section 8 - Exposure Controls / Personal Protection
Exposure guidelines:
Components with Occupational Exposure Limits
OSHA PEL ACGIH TLV SupplierOEL
ppm mg/m
3
ppm mg/m3 ppm mg/m3
DEET TWA None None None Ethanol TWA 1000 1900 1000 ------ 1000 1900 Isobutane TWA Not established 1000 ------ Not established
Engineering controls:
Personal protective equipment:
Eye/Face protection: During application, prevent entry into eyes. Wear safety
General ventilation normally adequate.
glasses with side shields if using in large applications.
Revision date: 2/22/2016
Page 3 of 7
Page 4
Safety Data Sheet
Repel Insect Repellent Sportsmen Max Formula 40% DEET
Skin and body protection: After returning indoors, wash treated skin with soap and
water.
Respiratory protection: Where exposure guideline levels may be exceeded, use an
approved NIOSH respirator.
General hygiene considerations: Handle in accordance with good industrial hygiene and
safety practices. When using, do not eat or drink. Wash hands before breaks and immediately after handling the product.
Section 9 - Physical & Chemical Properties
Appearance: Clear
Color: Colorless to pale yellow
Physical state: Pressurized liquid
Odor: Ethanol & DEET
Odor threshold: No data available
pH: 8.3 (liquid portion)
Melting point: No data available
Freezing point: No data available
Boiling point: No data available
Flash point: 85°F (liquid portion)
Flame Extension 18” (level 1 aerosol)
Flammability limits in air, lower, % by volume: No data available
Flammability limits in air, upper, % by volume: No data available
Vapor pressure: No data available
Vapor density: No data available
Relative density @ 20°C: 0.922 (liquid portion)
Octanol/water coefficient: No data available
Auto-ignition temperature: No data available
Decomposition temperature: No data available
Solubility: Miscible in water
Evaporation rate: No data available
% Volatile organic compounds: 30.2
Section 10 - Chemical Stability & Reactivity Information
Reactivity
Conditions to avoid: Do not mix with other chemicals.
Incompatible materials: Avoid strong oxidizers.
Chemical stability
Product stability: Stable under recommended storage conditions.
Page 4 of 7
Revision date: 2/22/2016
Page 5
Safety Data Sheet
Repel Insect Repellent Sportsmen Max Formula 40% DEET
Other
Hazardous decomposition products: None known
Possibility of hazardous reactions: Hazardous polymerization does not occur.
Section 11 - Toxicological Information
Primary eye irritation: Causes substantial but temporary eye injury (EPA tox.
Primary skin irritation: Non-irritating (EPA tox. category IV)
Acute dermal: LD50 > 5000 mg/kg (EPA tox. category IV)
Acute inhalation: LC50 > 2 mg/L (EPA tox. category IV)
Acute oral: LD50 > 2000 mg/kg (EPA tox. category III)
Sensitization: Not a skin sensitizer.
Chronic effects/ Carcinogenicity: No data available
Mutagenicity: No data available
Reproductive effects: No data available
Teratogenicity: No data available
category II)
Ecotoxicity: No data available
Section 12 - Ecological Information
Environmental effects: No data available
Aquatic toxicity: None
Persistence / degradability: No data available
Bioaccumulation / accumulation: No data available
Partition coefficient: No data available
Mobility in environmental media: No data available
Chemical fate information: No data available
Section 13 - Disposal Considerations
Waste codes: Not available
Disposal instructions: Dispose in accordance with all applicable regulations.
Waste from residues / unused
products: Not available
Contaminated packaging: Not available
Section 14 - Transportation Information
U.S. Department of Transportation
(DOT): UN-1950, Aerosols, Flammable, 2.1, Limited Quantity
IATA: UN-1950, Aerosols, 2.1
IMDG: UN-1950, Aerosols, Flammable, Limited Quantity
Revision date: 2/22/2016
Page 5 of 7
Page 6
Safety Data Sheet
Repel Insect Repellent Sportsmen Max Formula 40% DEET
Section 15 - Regulatory Information
29 CFR 1910.1200 hazardous chemical Occupational Safety and Health Administration (OSHA): No
CERCLA (Superfund) reportable
quantity: Not available
Hazard categories
Superfund Amendments and Reauthorization Act of 1986 (SARA):
Immediate Hazard No Delayed Hazard No Fire Hazard No Pressure Hazard No
Section 302 extremely hazardous Substance: No
Section 311 hazardous chemical: No
Clean Air Act (CAA): Not available
Clean Water Act (CWA): Not available
State regulations:
FIFRA labeling:
Signal word: CAUTION
Precautionary statements: Causes substantial but temporary eye injury. Do not get in eyes. Harmful if
FLAMMABLE. Contents under pressure. Keep away from heat, sparks and open
Notification status:
California Prop. 65:
Disclaimer:
Reactivity Hazard No
This chemical is a pesticide product registered by the Environmental Protection
Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets, and for workplace non-pesticide chemicals. Following is the hazard information as required on the pesticide label:
swallowed. Use of this product may cause skin reactions in rare cases. Wash hands before eating, drinking, chewing gum, using tobacco or using the toilet.
flame. Do not puncture or incinerate container. Exposure to temperatures above 130°F may cause bursting. Do not apply to synthetic fabrics such as acetate, rayon or spandex. Will not damage cotton, wool or nylon. May damage furniture finishes, leather, plastics and painted and varnished surfaces, including watch crystals, guns, bows and automobiles.
All ingredients of this product are listed or are excluded from listing on the U.S.
Toxic Substances Control Act (TSCA) Chemical Substance Inventory.
This product does not contain any chemicals known to the state of California to
cause cancer, birth defects or any other reproductive harm.
Information contained herein was obtained from sources considered technically
accurate and reliable. While every effort has been made to ensure full disclosure of product hazards, in some cases data is not available and is so stated. Since conditions of actual product use are beyond control of the supplier, it is assumed that users of this material have been fully trained according to the requirements of all applicable legislation and regulatory instruments. No warranty, expressed or implied, is made and supplier will not be liable for any losses, injuries or
Revision date: 2/22/2016
Page 6 of 7
Page 7
Safety Data Sheet
Repel Insect Repellent Sportsmen Max Formula 40% DEET
consequential damages which may result from the use of or reliance on any information contained in this document.
Section 16 - Other Information
Item numbers: HG-33801; HG-83801; HG-94102
HMIS ratings: Health Hazard 1 Flammability 3 Physical Hazard 0
Issue date: 2/22/2016
Prepared by: WPC Brands, Inc.
P.O. Box 4406 Bridgeton, MO 63044-0406 (800) 242-1166
Page 7 of 7
Revision date: 2/22/2016
Loading...