Page 1
Safety Data Sheet
Version 1.1
Print Date 04/27/2015
Revision Date 02/24/2015
SDS Number 350000011484
Product name
:
RAID® ANT & ROACH KILLER 17 (OUTDOOR FRESH®)
Recommended use
:
Insecticide
Manufacturer, importer,
:
S.C. Johnson & Son, Inc.
Racine WI 53403-2236
Telephone
:
+18005585252
Emergency telephone
:
24 Hour Medical Emergency Phone: (866)231-5406
Hazard classification
Hazard category
Hazards identification
Aerosol
Category 2
Flammable aerosol.
Gases under pressure
Liquefied gas
Contains gas under pressure;
may explode if heated.
according to Hazard Communication Standard; 29 CFR 1910.1200
RAID® ANT & ROACH KILLER 17 (OUTDOOR FRESH®)
1. PRODUCT AND COMPANY IDENTIFICATION
Product information
supplier
number
2. HAZARDS IDENTIFICATION
Classification of the substance or mixture
Globally Harmonized System (GHS) Classification
Labelling
Hazard symbols
Flame
Gas cylinder
Signal word
Warning
Hazard statements
Flammable aerosol.
Contains gas under pressure; may explode if heated.
Precautionary statements
Protect from sunlight. Do not expose to temperatures exceeding 50 °C/ 122 °F.
Protect from sunlight. Store in a well-ventilated place.
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
Do not spray on an open flame or other ignition source.
Do not pierce or burn, even after use.
1525 Howe Street
24 Hour International Emergency Phone: (703)527-3887
24 Hour Transport Emergency Phone: (800)424-9300
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Safety Data Sheet
Version 1.1
Print Date 04/27/2015
Revision Date 02/24/2015
SDS Number 350000011484
Other hazards
:
None identified
Chemical Name
CAS-No.
Weight percent
Alkanes, C14-16
90622-46-1
10.00 - 30.00
Isobutane
75-28-5
5.00 - 10.00
Propane
74-98-6
1.00 - 5.00
Isopropanol
67-63-0
1.00 - 5.00
Imiprothrin
72963-72-5
0.10 - 1.00
Cypermethrin
52315-07-8
0.10 - 1.00
Eye contact
:
No special requirements
Skin contact
:
No special requirements
Inhalation
:
No special requirements.
Ingestion
:
No special requirements
Suitable extinguishing
media
:
Use water spray, alcohol-resistant foam, dry chemical or
carbon dioxide.
Specific hazards during
:
Aerosol Product - Containers may rocket or explode in heat of
water courses.
Further information
:
Fight fire from maximum distance or protected area. Cool and
containers. Wear full protective clothing and pos it i ve pres sur e
according to Hazard Communication Standard; 29 CFR 1910.1200
RAID® ANT & ROACH KILLER 17 (OUTDOOR FRESH®)
3. COMPOSITION/INFORMATION ON INGREDIENTS
The specific chemical identity and/or exact percentage (concentration) of this composition has been
withheld as a trade secret.
For additional information on product ingredients, see www.whatsinsidescjohnson.com.
4. FIRST AID MEASURES
5. FIREFIGHTING MEASURES
firefighting
fire. Do not allow run-off from fire fighting to enter drains or
use caution when approaching or handling fire-exposed
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Safety Data Sheet
Version 1.1
Print Date 04/27/2015
Revision Date 02/24/2015
SDS Number 350000011484
self-contained breathing apparatus. In case of fire and/or
explosion do not breathe fumes.
NFPA Classification
:
NFPA Level 1 Aerosol
Personal precautions
:
Remove all sources of ignition.
Environmental
:
Do not flush into surface water or sanitary sewer system.
Methods and materials
:
If damage occurs to aerosol can:
Precautions for safe
:
Avoid contact with skin, eyes and clothing.
Advice on protection
:
Keep away from sources of ignition - No smoking.
according to Hazard Communication Standard; 29 CFR 1910.1200
RAID® ANT & ROACH KILLER 17 (OUTDOOR FRESH®)
6. ACCIDENTAL RELEASE MEASURES
Wear personal protective equipment.
Wash thoroughly after handling.
precautions
for containment and
cleaning up
7. HANDLING AND STORAGE
Handling
handling
Use appropriate containment to avoid environmental
contamination.
Outside of normal use, avoid release to the environment.
Contain spillage, soak up with non-combustible absorbent
material, (e.g. sand, earth, diatomaceous earth, vermiculite)
and transfer to a container for disposal according to local /
national regulations (see section 13).
Use only non-sparking equipment.
Dike large spills.
Clean residue from spill site.
Do not enter places where used or stored until adequately
ventilated.
For personal protection see section 8.
Use only as directed.
KEEP OUT OF REACH OF CHILDREN AND PETS.
Pressurized container.
Do not pierce or burn, even after use.
against fire and explosion
Storage
Do not spray on an open flame or other ignition source.
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Safety Data Sheet
Version 1.1
Print Date 04/27/2015
Revision Date 02/24/2015
SDS Number 350000011484
Requirements for storage
:
Protect from sunlight. Do not expose to temperatures
Components
CAS-No.
mg/m3
ppm
Nonunits
Basis
Isobutane
75-28-5
-
1,000 ppm
- ACGIH
Propane
74-98-6
-
1,000 ppm
- ACGIH
Propane
74-98-6
1,800 mg/m3
1,000 ppm
-
OSHA TWA
Isopropanol
67-63-0
980 mg/m3
400 ppm
-
OSHA TWA
Isopropanol
67-63-0
-
400 ppm
- ACGIH
Isopropanol
67-63-0
-
200 ppm
- ACGIH
Respiratory protection
:
Do not spray in enclosed areas.
Hand protection
:
No special requirements.
Eye protection
:
No special requirements.
Skin and body protection
:
No special requirements.
Hygiene measures
:
Handle in accordance with good indus tri al h ygie ne and saf et y
according to Hazard Communication Standard; 29 CFR 1910.1200
RAID® ANT & ROACH KILLER 17 (OUTDOOR FRESH®)
areas and containers
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Occupational Exposure Limits
exceeding 50 °C/ 122 °F.
Keep away from food, drink and animal feedingstuffs.
Keep in a dry, cool and well-ventilated place.
standard
STEL
TWA
STEL
Personal protective equipment
practice. Wash thoroughly after handling.
9. PHYSICAL AND CHEMICAL PROPERTIES
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TWA
Page 5
Safety Data Sheet
Version 1.1
Print Date 04/27/2015
Revision Date 02/24/2015
SDS Number 350000011484
Form
:
aerosol
Form
:
Compressed gas
Color
:
clear
Odor
:
pleasant
Odour Threshold
:
No data available
pH
:
No data available
Melting point/freezing point
:
No data available
Initial boiling point and
boiling range
:
No data available
Flash point
:
< -7 °C
Evaporation rate
:
No data available
Flammability (solid, gas)
:
No data available
Upper/lower flammability or
:
No data available
Vapour pressure
:
No data available
Vapour density
:
No data available
Relative density
:
0.877 g/cm3 at 70 °F
Solubility(ies)
:
partly soluble
according to Hazard Communication Standard; 29 CFR 1910.1200
RAID® ANT & ROACH KILLER 17 (OUTDOOR FRESH®)
explosive limits
< 19.4 °F
Propellant
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Safety Data Sheet
Version 1.1
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Revision Date 02/24/2015
SDS Number 350000011484
Partition coefficient: n-
:
No data available
Auto-ignition temperature
:
No data available
Decomposition temperature
:
No data available
Viscosity, dynamic
:
No data available
Viscosity, kinematic
:
No data available
Oxidizing properties
:
No data available
Volatile Organic
Total VOC (wt. %)*
:
12.1 % - additional exemptions may apply
Regulations
Other information
:
None identified
:
Possibility of hazardous
reactions
:
Stable under recommended storage conditions.
Conditions to avoid
:
Heat, flames and sparks.
Incompatible materials
:
Strong oxidizing agents
Hazardous decomposition
:
Thermal decomposition can lead to release of irritating gases
according to Hazard Communication Standard; 29 CFR 1910.1200
RAID® ANT & ROACH KILLER 17 (OUTDOOR FRESH®)
octanol/water
Compounds
10. STABILITY AND REACTIVITY
*as defined by US Federal and State Consumer Product
products
11. TOXICOLOGICAL INFORMATION
and vapours.
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Safety Data Sheet
Version 1.1
Print Date 04/27/2015
Revision Date 02/24/2015
SDS Number 350000011484
Emergency Overview
:
Warning
Acute oral toxicity
:
NA GHS LD50
Acute inhalation toxicity
:
NA GHS LC50 (dust and mist)
Acute dermal toxicity
:
NA GHS LD50
GHS Properties
Classification
Routes of entry
Acute toxicity
No classification proposed
-
Skin corrosion/irritation
No classification proposed
-
Serious eye
damage/eye irritation
No classification proposed
-
Skin sensitisation
No classification proposed
-
Respiratory
sensitisation
No classification proposed
-
Germ cell mutagenicity
No classification proposed
-
Carcinogenicity
No classification proposed
-
Reproductive toxicity
No classification proposed
-
Specific target organ
exposure
No classification proposed
-
Specific target organ
exposure
No classification proposed
-
Aspiration hazard
No classification proposed
-
Aggravated Medical
Condition
:
None known.
according to Hazard Communication Standard; 29 CFR 1910.1200
RAID® ANT & ROACH KILLER 17 (OUTDOOR FRESH®)
estimated
> 5,000 mg/kg
estimated
> 5.1 mg/l
toxicity - single
estimated
> 5,000 mg/kg
toxicity - repeated
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Safety Data Sheet
Version 1.1
Print Date 04/27/2015
Revision Date 02/24/2015
SDS Number 350000011484
Alkanes, C14-16
No data
available
Isobutane
LC50
Fish
27.98 mg/l
96 h
Propane
LC50
Fish
27.98 mg/l
96 h
Isopropanol
LC50
Pimephales promelas
9,640 mg/l
96 h
Imiprothrin
LC50
Oncorhynchus mykiss
0.038 mg/l
96 h
Cypermethrin
LC50
Oncorhynchus mykiss
0.00283
96 h
NOEC
Pimephales promelas
0.00001
28 d
Alkanes, C14-16
No data
Components
End point
Species
Value
Exposure
time
Components
End point
Species
Value
Exposure
time
according to Hazard Communication Standard; 29 CFR 1910.1200
RAID® ANT & ROACH KILLER 17 (OUTDOOR FRESH®)
12. ECOLOGICAL INFORMATION
Product : The product itself has not been tested.
Toxicity
The ingredients in this formula have been reviewed and no adverse impact to the environment is
expected when used according to label directions.
Toxicity to fish
Toxicity to aquatic invertebrates
(fathead minnow)
(rainbow trout)
(rainbow trout)
(fathead minnow)
mg/l
mg/l
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Safety Data Sheet
Version 1.1
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Revision Date 02/24/2015
SDS Number 350000011484
available
Isobutane
LC50
Daphnid
16.33 mg/l
48 h
Propane
LC50
Daphnid
14.22 mg/l
48 h
Isopropanol
EC50
Daphnia magna (Water
13,299
48 h
Imiprothrin
EC50
Daphnia magna (Water
0.051 mg/l
48 h
Cypermethrin
EC50
Daphnia magna (Water
0.00471
48 h
NOEC
Daphnia magna (Water
0.00004
21 d
Alkanes, C14-16
No data
available
Isobutane
EC50
Green algea
8.57 mg/l
96 h
Propane
No data
available
Isopropanol
EC50
Desmodesmus
> 1,000
72 h
Imiprothrin
NOEC
Pseudokirchneriella
1.3 mg/l
72 h
Components
End point
Species
Value
Exposure
time
according to Hazard Communication Standard; 29 CFR 1910.1200
RAID® ANT & ROACH KILLER 17 (OUTDOOR FRESH®)
flea)
flea)
flea)
flea)
mg/l
mg/l
mg/l
Toxicity to aquatic plants
subspicatus (green algae)
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mg/l
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Safety Data Sheet
Version 1.1
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Revision Date 02/24/2015
SDS Number 350000011484
subcapitata (green algae)
Cypermethrin
ErC50
available
> 0.0033
72 h
Component
Biodegradation
Exposure
time
Summary
Alkanes, C14-16
82 %
28 d
Readily biodegradable
Isobutane
70 %
< 10 d
Readily biodegradable
Propane
70 %
< 10 d
Readily biodegradable
Isopropanol
53 %
5 d
Readily biodegradable
Imiprothrin
58 %
28 d
Not readily
Cypermethrin
0.6 - 1.4 %
33 d
Not readily
Component
Bioconcentration
factor (BCF)
Partition Coefficient nOctanol/water (log)
Alkanes, C14-16
No data available
No data available
Isobutane
1.57 - 1.97
2.8
Propane
No data available
2.36
Isopropanol
0.96 estimated
0.05
Imiprothrin
58.2 Calculated
2.9
Cypermethrin
373.4 Measured
5.3 - 5.6
according to Hazard Communication Standard; 29 CFR 1910.1200
RAID® ANT & ROACH KILLER 17 (OUTDOOR FRESH®)
Persistence and degradability
Bioaccumulative potential
No data
mg/l
biodegradable.
biodegradable.
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Safety Data Sheet
Version 1.1
Print Date 04/27/2015
Revision Date 02/24/2015
SDS Number 350000011484
Component
End point
Value
Alkanes, C14-16
No data available
Isobutane
No data available
Propane
No data available
Isopropanol
No data available
Imiprothrin
Koc 268
Cypermethrin
Koc 80653 - 574360
Component
Results
Alkanes, C14-16
Not fulfilling PBT and vPvB criteria
Isobutane
Not fulfilling PBT and vPvB criteria
Propane
Not fulfilling PBT and vPvB criteria
Isopropanol
Not fulfilling PBT and vPvB criteria
Imiprothrin
Not fulfilling PBT and vPvB criteria
Cypermethrin
Not fulfilling PBT and vPvB criteria
Other adverse effects
:
None known.
PESTICIDAL WASTE:
according to Hazard Communication Standard; 29 CFR 1910.1200
RAID® ANT & ROACH KILLER 17 (OUTDOOR FRESH®)
Mobility
PBT and vPvB assessment
13. DISPOSAL CONSIDERATIONS
For disposal information, please read and follow Disposal
instructions on the pesticide label.
Consumer may discard empty container in trash, or recycle
where facilities exist.
14. TRANSPORT INFORMATION
Please refer to the Bill of Lading/receiving documents for up-to-date shipping information.
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Safety Data Sheet
Version 1.1
Print Date 04/27/2015
Revision Date 02/24/2015
SDS Number 350000011484
Land transport
Sea transport
Air transport
UN number
1950
1950
1950
UN proper
shipping name
AEROSOLS,
Flammable, 2.1
AEROSOLS,
Flammable, 2.1
AEROSOLS,
Flammable, 2.1
Transport hazard
class(es)
2.1 2 2.1
Packing group
- - -
Environmental
hazards
-
- -
Special
Limited quantities
Limited quantities
documents.
Limited quantities
Notification status
:
All ingredients of this product are listed or are excluded from
California Prop. 65
:
This product does not contain any chemicals known to State of
according to Hazard Communication Standard; 29 CFR 1910.1200
RAID® ANT & ROACH KILLER 17 (OUTDOOR FRESH®)
precautions for
user
15. REGULATORY INFORMATION
FIFRA Labeling
This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to
certain labeling requirements under federal pesticide law. These requirements differ from the
classification criteria and hazard information required for safety data sheets, and for workplace labels of
non-pesticide chemicals.
Following is the hazard information as required on the pesticide label:
CAUTION:
CONTENTS UNDER PRESSURE.
Flammable.
Exposure to temperatures above 130° F may cause bursting.
derogation may be
applicable to this
product, please check
transport documents.
listing on the U.S. Toxic Substances Control Act (TSCA)
Chemical Substance Inventory.
derogation may be
applicable to this
product, please
check transport
derogation may be
applicable to this
product, please check
transport documents.
California to cause cancer, birth defects, or any other
reproductive harm.
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Safety Data Sheet
Version 1.1
Print Date 04/27/2015
Revision Date 02/24/2015
SDS Number 350000011484
Registration # / Agency
4822-447/US/EPA
Health
2
Flammability
4
Reactivity
0
Health
2
Fire
4
Reactivity
0
Special
-
Prepared by
SC Johnson Global Safety Assessment &
Regulatory Affair s (GSARA)
according to Hazard Communication Standard; 29 CFR 1910.1200
RAID® ANT & ROACH KILLER 17 (OUTDOOR FRESH®)
16. OTHER INFORMATION
HMIS Ratings
NFPA Ratings
This information is being provided in accordance with the Occupational Safety and Health Administration
(OSHA) regulation (29 CFR 1910.1200). The information supplied is designed for workplaces where
product use and frequency of exposure exceeds that established for the labeled consumer use.
Further information
This document has been prepared using data from sources considered to be technically reliable. It does
not constitute a warranty, expressed or implied, as to the accuracy of the information contained herein.
Actual conditions of use are beyond the seller's control. User is responsible to evaluate all available
information when using product for any particular use and to comply with all Federal, State, Provincial
and Local laws and regulations.
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Page 14
Safety Data Sheet
Version 1.1
Print Date 04/27/2015
Revision Date 02/24/2015
SDS Number 350000011484
according to Hazard Communication Standard; 29 CFR 1910.1200
RAID® ANT & ROACH KILLER 17 (OUTDOOR FRESH®)
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