Purex 06355 User Manual

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F-143

Safety Data Sheet

Revision Number: 011.0

Issue Date: 03/04/2015

The Dial Corporation, a Henkel Company; 7201 E. Henkel Way; Scottsdale, AZ 85255-9672

Classic and Ultra Dry Detergents

Page 1 of 6

HAZARD CLASS

HAZARD CATEGORY

SKIN IRRITATION

EYE IRRITATION

The hazards described in this OSHA Globally Harmonized System Safety Data Sheet (SDS) are not intended for consumers, and does not address consumer use of the product. For information regarding consumer applications of this product, refer to the product label.

1. IDENTIFICATION OF THE SUBSTANCE OR MIXTURE AND OF THE SUPPLIER

Product identifier used on the label:

Other means of identification:

Recommended use of the chemical and restrictions on use: Heavy duty detergent, No restrictions on use. Name, address and telephone number of the chemical manufacturer:

Emergency telephone number: Medical Emergencies: 1-888-689-9082

Dry Purex® Classic All Temperature Laundry Detergent — Original Fresh Scent, Mountain Breeze, Mountain Breeze w/Renuzit Super Odor Neutralizer, After The Rain Dry Purex® Classic All Temperature Laundry Detergent with Bleach Alternative— Original Fresh Scent Dry Purex® Ultra Laundry Detergent—Original Fresh Scent, Mountain Breeze, Mountain Breeze w/Renuzit Super Odor Neutralizer Dry Purex® with Color Safe Bleach Ultra Laundry Detergent—Original Fresh Scent Dry Purex® Ultra Laundry Detergent—For Bucket Production (Summit Advantage) Dry Trend® Classic All Temperature Laundry Detergent Dry Trend® Classic All Temperature Laundry Detergent with Bleach Alternative Dry Purex® Classic Detergent with Crystals Fragrance— Lavender, Fresh Spring Waters Dry Purex® Ultra Detergent with Crystals Fragrance— Lavender, Fresh Spring Waters Purex® with Bleach Alternative Powder Laundry Detergent – Fresh Mountain Breeze, Lavender Blossom Purex® with Oxi Powder Laundry Detergent – Fresh Morning Burst

99103058, 99103059, 99103065 (Classic Purex – Original Fresh Scent); 99103062, 99103067, 99103070 (Classic Purex – Mountain Breeze); 99103064, 99103069, 99102921 (Classic Purex Mountain Breeze w/Renuzit); 99101679, 99102836 (Classic Purex – After The Rain); 99103060, 99103061, 99103066 (Classic Purex w/BA – Original Fresh Scent); IDH#1266148 (Ultra Purex Fresh Scent); 99103072 (Ultra Purex – Original Fresh Scent); 99103074 (Ultra Purex Mountain Breeze); 88101543, 99103076, IDH# 1267197 (Ultra Purex Mountain Breeze w/Renuzit SON); 99103073 (Ultra Purex with Color Safe Bleach- Original Fresh Scent); 99103095 (Ultra Purex Dry Detergent for Bucket Production (Summit Advantage); 99103077, 99103078, 99103083 (Classic Trend); 99103081, 99103082, 99103084 (Classic Trend w/BA); 99103089 (Ultra Purex with Color Safe Bleach–Mountain Breeze); 1692111 (Classic Lavender); 1692121 (Classic Fresh Spring Waters); 1692122 (Ultra Lavender); 1692123 (Ultra Fresh Spring Waters); 1948488 (Purex w/Bleach Alt Fresh Mt Breeze); 1948792 (Purex w/Bleach Alt Lavender Blossom); 1951197 (Purex w/Oxi Fresh Morning Burst)

The Dial Corporation, a Henkel Company 7201 E. Henkel Way Scottsdale, AZ 85255-9672 USA

CHEMTREC: 1-800-424-9300 (24 hours daily) Internet: www.henkelna.com

2. HAZARD IDENTIFICATION

Classification of the substance or mixture in accordance with paragraph (d) of §1910.1200

Signal word: WARNING Hazard Statement(s): Causes skin irritation.

Symbol(s):

Causes serious eye irritation.

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The Dial Corporation, a Henkel Company; 7201 E. Henkel Way; Scottsdale, AZ 85255-9672

Classic and Ultra Dry Detergents

Page 2 of 6

Precautionary Statements:

Chemical Name*

CAS Number (Unique Identifier)

Concentration

Classification §1910.1200

Sodium carbonate

497-19-8

30 – 60 %

Eye irritation 2A

Skin irritation 2

Benzenesulfonic acid, 4-C10-13-

sec-alkyl derivs.

85536-14-7

10 – 30 %

Acute toxicity 4; Oral

Skin corrosion 1C; Dermal

Chronic hazards to the aquatic environment 3

Sodium silicate

1344-09-8

5 – 10 %

Serious eye damage 1

Skin corrosion 1C

Acute toxicity 4; Oral

Fatty alcohol ethoxylate C12-15

68131-39-5

1 – 5 %

Acute hazards to the aquatic environment 1

Disodium carbonate, compound

with hydrogen peroxide (2:3)

15630-89-4

1 – 5 % Oxidizing Solid 3

Acute toxicity 4; Oral Acute toxicity 4; Oral

Eye irritation 1

Serious eye damage 1

Prevention: Wash thoroughly after handling.

Response: IF ON SKIN: Wash with plenty of soap and water.

Storage: Not prescribed Disposal: Not prescribed

Hazards not otherwise classified: Not available.

Classification complies with OSHA Hazard Communication Standard (29 CFR 1910.1200) and is consistent with the provisions of the United Nations Globally Harmonized System of Classification and Labeling of Chemicals (GHS).

See Section 11 for additional toxicological information.

Wear eye and face protection. Wear protective gloves.

IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to remove. Continue rinsing. If skin irritation occurs: Get medical attention. If eye irritation persists: Get medical attention. Take off contaminated clothing.

3. COMPOSITION / INFORMATION ON INGREDIENTS

The following chemicals are classified as health hazards in accordance with paragraph (d) of § 1910.1200.

*The specific chemical identity and/or exact percentage (concentration) of composition has been withheld because a trade secret is claimed in accordance with paragraph (i) of §1910.1200.

4. FIRST AID MEASURES

Description of necessary measures

Most important symptoms and effects, both acute and delayed

Indication of any immediate medical attention and special treatment needed

Inhalation: Remove from exposure area to fresh air. Keep affected person warm and at rest. Treat symptomatically and supportively. Skin contact: Rinse affected area with large amounts of water until no evidence of product remains. Get medical attention if irritation persists. Eye contact: Immediately rinse eyes with plenty of water for at least 15 minutes while holding eyelids open. Get medical attention if pain or

irritation persist. Ingestion: Dilution by rinsing the mouth and giving water or milk to drink is generally recommended. If unconscious, the victim should not be given anything to drink. Contact physician or local poison control center.

After eye contact: May cause moderate to severe irritation. After skin contact: Repeated or prolonged exposure may cause irritation. After Ingestion: Ingestion may cause pain, burning, swelling and redness in the mouth and throat. Nausea and vomiting may occur. After inhalation: Irritation of the respiratory tract, coughing. Inhalation of larger amounts may cause laryngospasm with shortness of breath.

After eye contact: Rinse eyes immediately with plenty of water, occasionally lifting upper and lower lids, until no evidence of product remains. After skin contact: Rinse affected area with large amounts of water until no evidence of product remains. After ingestion: Do not induce vomiting. Dilution by rinsing the mouth and giving a glass of water to drink is generally recommended. After inhalation: Remove from exposure area to fresh air immediately. Contact physician or local poison control center.

5. FIRE FIGHTING MEASURES

Suitable (and unsuitable) extinguishing media

Suitable extinguishing media: Dry chemical, carbon dioxide, water spray or regular foam. Unsuitable extinguishing media: None known

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The Dial Corporation, a Henkel Company; 7201 E. Henkel Way; Scottsdale, AZ 85255-9672

Classic and Ultra Dry Detergents

Page 3 of 6

Specific hazards arising from the chemical

Hazardous Component(s)

ACGIH

OSHA PEL

AIHA WEEL

OTHER

Sodium carbonate

None

Sodium silicate

None

Fatty alcohol ethoxylate C12-15

None

Thermal decomposition may release toxic and/or hazardous gases, including toxic oxides of carbon and sulfur.

Special protective equipment and precautions for fire-fighters

In case of fire, wear a full-face positive-pressure self-contained breathing apparatus and protective suit. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Avoid breathing vapors, keep upwind. Isolate area. Keep unnecessary personnel away.

6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures Wear skin, eye and respiratory protection as recommended in Section 8. Stop leak if you can do it without risk. Spills present a slipping hazard. Keep unnecessary personnel away. Ventilate spill area if possible. Make sure area is slip-free before re-opening to traffic.

Environmental Precautions

Small or household quantities may be disposed in regular domestic trash. For larger quantities check with your local disposal authorities. Methods and materials for containment and cleaning up

SMALL SPILLS: Sweep or scoop up and place into containers for later disposal. Wash site of spillage thoroughly with water. LARGE SPILLS: Sweep or scoop up and place into suitable clean, dry containers for reclamation or later disposal. Dispose in suitable waste container. Keep unnecessary people away from spill.

7. HANDLING AND STORAGE

Precautions for safe handling

Do not get in eyes, on skin, on clothing. Do not take internally. Use with adequate ventilation. Avoid generating dusts.

Conditions for safe storage, including any incompatibilities

Store in original containers in a cool dry area. Storage areas for large quantities (warehouse) should be well ventilated. Keep the containers tightly closed when not in use.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

OSHA permissible exposure limit (PEL), American Conference of Governmental Industrial Hygienists (ACGIH) Threshold Limit Value (TLV), and any other exposure limit used or recommended by the chemical manufacturer, importer, or employer preparing the safety data sheet, where available.

Appropriate engineering controls

Provide local exhaust or general dilution ventilation to keep potential exposure to airborne contaminants below the permissible exposure limits where mists or vapors may be generated.

Individual protection measures

Respiratory: If respiratory protection is required, it must be based on the contamination levels found in the workplace, must not exceed the

working limits of the respirator and be jointly approved by the National Institute for Occupational Safety and Health and the Mine Safety and Health Administration (NIOSH-MSHA).

Eye: Safety glasses are required to prevent eye contact where dusty conditions may occur. Hand/Body: Protective gloves are required where repeated or prolonged skin contact may occur. Protective clothing is required where

repeated or prolonged skin contact may occur.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance: powder, white Odor: floral, spicy, green Odor threshold: Not available. pH: Not available. Melting point/ range: Not available. Boiling point/range: Not available. Flash point: Not applicable Evaporation rate: Not available. Flammable/Explosive limits - lower: Not available. Flammable/Explosive limits - upper: Not available. Vapor pressure: Not available. Vapor density: Not available. Solubility in water: Soluble Partition coefficient (n-octanol/water): Not available. Autoignition temperature: Not available.

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The Dial Corporation, a Henkel Company; 7201 E. Henkel Way; Scottsdale, AZ 85255-9672

Classic and Ultra Dry Detergents

Page 4 of 6

Decomposition temperature: Not available.

Hazardous Component(s)

LD50s and LC50s

Immediate and Delayed Health Effects

Sodium carbonate

Oral LD50 (RAT) = 4.090 mg/kg Inhalation LC50 (RAT, 2 h) = 2,3 mg/l

Irritant, Sensory Benzenesulfonic acid, 4-C10-13-sec-alkyl derivs.

None

No Data

Sodium silicate

Oral LD50 (RAT) = 1.100 - 1.600 mg/kg Oral LD50 (RAT) = 1,1 g/kg

Corrosive, Irritant Fatty alcohol ethoxylate C12-15

None

No Target Organs

Disodium carbonate, compound with hydrogen peroxide (2:3)

None

No Data

Hazardous Component(s)

NTP Carcinogen

IARC Carcinogen

OSHA Carcinogen

Sodium carbonate

No No No

Benzenesulfonic acid, 4-C10-13-sec-alkyl derivs.

Sodium silicate

Fatty alcohol ethoxylate C12-15

Disodium carbonate, compound with hydrogen peroxide (2:3)

Viscosity: Not available. VOC content: Not available. Specific gravity: Not available.

10. STABILITY AND REACTIVITY

Reactivity: This product may react with strong reducing agents. Chemical stability: Stable under normal ambient temperature (70°F, 21°C) and pressure (1 atm). Possibility of hazardous reactions: Hazardous polymerization has not been reported to occur under normal temperatures and pressures. Conditions to avoid: Avoid storing in direct sunlight, avoid extremes of temperature, avoid contact with incompatible substances. Incompatible materials: Strong reducing agents, acids. Hazardous decomposition products: Thermal decomposition may produce irritating smoke, carbon monoxide, and carbon dioxide.

11. TOXICOLOGICAL INFORMATION

Likely routes of exposure including symptoms related to characteristics

Other relevant toxicity information:

This product is a laundry care product. The use of this product by consumers is safe under normal and reasonable foreseen use.

Numerical measures of toxicity, including delayed and immediate effect

Inhalation: Dust may cause mucous membrane irritation with coughing, dryness and sore throat. Skin contact: May cause skin irritation. Eye contact: May cause moderate to severe irritation. Ingestion: May cause mild gastrointestinal irritation with nausea, vomiting, diarrhea and abdominal pain. Physical/Chemical: Repeated or prolonged excessive exposure with skin may cause irritation.

Carcinogenicity None of the ingredients in this product are listed as carcinogens by the International Agency for Research on Cancer Mutagenicity None of the ingredients in this product are known to cause mutagenicity.

Toxicity for reproduction None of the ingredients in this product are known as reproductive, fetal, or developmental hazards.

(IARC), the National Toxicology Program (NTP) or the Occupational Safety and Health Administration (OSHA).

12. ECOLOGICAL INFORMATION

Aquatic Toxicity:

This product is anticipated to be safe for the environment at concentrations predicted in household settings under normal use conditions. The following toxicity information is available for the hazardous ingredient(s) when used as technical grade and is provided as reference for the occupational settings.

Toxicity to fish:

The aquatic toxicity profile of this product has not been determined.

Toxicity to aquatic invertebrates:

The aquatic toxicity profile of this product has not been determined.

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The Dial Corporation, a Henkel Company; 7201 E. Henkel Way; Scottsdale, AZ 85255-9672

Classic and Ultra Dry Detergents

Page 5 of 6

Hazardous substances

Result value

Route of application

Species

Method

Benzenesulfonic acid, 4-C10-13-sec-alkyl derivs.

readily biodegradable

no data

> 60 %

OECD 301

Fatty alcohol ethoxylate C12-15

readily biodegradable

aerobic

81 %

EU Method C.4-E

Toxicity to algae:

The aquatic toxicity profile of this product has not been determined.

Persistence and degradability:

The persistence and degradability of this product has not been determined. The hazardous ingredients are readily biodegradable.

Bioaccumulation Potential: The bioaccumulation potential of this product has not been determined. Mobility: The mobility of this product (in soil and water) has not been determined.

13. DISPOSAL CONSIDERATIONS

Waste Number and Description: Not applicable Disposal Considerations: Not regulated

Disposal of products: This product is not a RCRA hazardous waste and can be disposed of in accordance with federal, state and local

Disposal of packages: Place in trash.

regulations.

14. TRANSPORT INFORMATION

The information in this section is for reference only and should not take the place of a shipping paper (bill of lading) specific to an order. Please note that the proper shipping classification may vary by packaging, properties, and mode of transportation.

U.S. Department of Transportation Ground (49 CFR)

International Air Transportation (ICAO/IATA)

Water Transportation (IMO/IMDG)

Proper shipping name: Not regulated Hazard class or division: None Identification number: None Packing group: None

15. REGULATORY INFORMATION

Occupational Safety and Health Act: Hazard Communication Rule, 29 CFR 1910.1200: The Occupational Safety and Health Administration (OSHA) require Material Safety Data Sheets (MSDSs) to provide information about any hazard that may be associated with the product and make this information available in the workplace. Since the use pattern and exposure in the workplace are generally not consistent with those experienced by consumers, this MSDS may contain health hazard information not relevant to consumer use.

United States Regulatory Information:

Canada Regulatory Information

TSCA 8 (b) Inventory Status: All components of this product are either listed on or exempt from the U.S. Toxic Substances Control Act

(TSCA) chemical substance inventory.

TSCA 12 (b) Export Notification: None above reporting de minimis CERCLA/SARA Section 302 EHS: None above reporting de minimis CERCLA/SARA Section 311/312: Not available. CERCLA/SARA Section 313: None above reporting de minimis California Proposition 65: No California Proposition 65 listed chemicals are known to be present.

CEPA DSL/NDSL Status: One or more components are not listed on, and are not exempt from listing on either the Domestic Substances List

or the Non-Domestic Substances List.

16. OTHER INFORMATION

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The Dial Corporation, a Henkel Company; 7201 E. Henkel Way; Scottsdale, AZ 85255-9672

Classic and Ultra Dry Detergents

Page 6 of 6

DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel Corporation and its

affiliates (“Henkel”) does not assume responsibility for any results obtained by persons over whose methods Henkel has no control. It is the user’s

responsibility to determine the suitability of Henkel’s products or any production methods mentioned herein for a particular purpose, and to adopt such

precautions as may be advisable for the protection of property and persons against any hazards that may be involved in the handling and use of any

Henkel’s products. In light of the foregoing, Henkel specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular purpose, arising from sale or use of Henkel’s products. Henkel further disclaims any liability for consequential or incidental

damages of any kind, including lost profits.

This safety data sheet contains changes from the previous version in sections: 2, 4, 11, 12 Prepared by: R&D Support Services Issue date: 03/04/2015 Supercedes: Rev. 10, 10/27/2014