F-152
Safety Data Sheet
Revision Number: 015.0
Issue Date: 04/20/2015
The Dial Corporation, a Henkel Company; 7201 E. Henkel Way; Scottsdale, AZ 85255-9672
Liquid Laundry Detergents
Page 1 of 5
HAZARD CLASS
HAZARD CATEGORY
SKIN IRRITATION
2
EYE IRRITATION
2A
1. IDENTIFICATION OF THE SUBSTANCE OR MIXTURE AND OF THE SUPPLIER
Product identifier used on the label: Purex® Liquid Laundry Detergent – Free & Clear, HE–Free & Clear, Original Fresh, Mountain Breeze, After the
Other means of identification: 1181714, 1187274, 1632226, 1692442, 1858933 (F&C, HE-F&C); 1181715, 1187271, 1632069, 1692432,
Recommended use of the chemical and restrictions on use: Universal, No restrictions on use.
Name, address and telephone number of the chemical manufacturer:
Emergency telephone number: Medical Emergencies: 1-888-689-9082
The Dial Corporation, a Henkel Company
7201 E. Henkel Way
Scottsdale, AZ 85255-9672 USA
CHEMTREC: 1-800-424-9300 (24 hours daily)
Internet: www.henkelna.com
Rain, HE – After The Rain, Lavender (Sunshine Clean Canada), Lemon Fresh, Baby (Purex Baby Soft)
Purex® with Color Safe Bleach Alternative Liquid Laundry Detergent – Original Fresh w/ BA (w/Color Safe BA),
Mountain Breeze w/BA (Mountain Breeze w/Color Safe BA)
Purex® with Crystals Fragrance / Purex® Detergent with Crystals and Fabric Softener – Fresh Spring Waters,
Fresh Lavender Blossom
1858930 (Original Fresh); 1187136, 1187139, 1632059 (Mountain Breeze); 1181717, 1187273, 1632058,
1692459, 1858935 (After the Rain, HE – After the Rain); 1187137, 1187140, 1632228 (Lavender, Lavender
Fresh, Sunshine Clean Canada); 1533605, 1187275, 1633998 (Lemon Fresh); 1533606, 1187276, 1634028
(Purex Baby Soft); 1187138, 1187272, 1632224 (Original Fresh w/ BA, Original Fresh w/Color Safe BA);
1181716, 1187277, 1632063 (Mountain Breeze w/BA, Mountain Breeze w/Color Safe BA); 1079495, 1079496,
1698997 (w/Crystals Fragrance & FS); 1835452, 1836444 (w/ Crystals Fragrance Fresh Spring Waters);
1835435, 1836442 (w/ Crystals Fragrance Fresh Lavender Blossom)
2. HAZARD IDENTIFICATION
Classification of the substance or mixture in accordance with paragraph (d) of §1910.1200
Signal word, hazard statement(s), symbol(s) and precautionary statement(s) in accordance with paragraph (f) of §1910.1200
Signal word: WARNING
Hazard Statement(s): Causes skin irritation.
Causes serious eye irritation.
Symbol(s):
Precautionary Statements:
Prevention: Wash thoroughly after handling.
Wear eye and face protection.
Wear protective gloves.
Response: IF ON SKIN: Wash with plenty of soap and water.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
remove. Continue rinsing.
If skin irritation occurs: Get medical attention.
If eye irritation persists: Get medical attention.
Take off contaminated clothing.
Storage: Not prescribed
Disposal: Not prescribed
The Dial Corporation, a Henkel Company; 7201 E. Henkel Way; Scottsdale, AZ 85255-9672
Liquid Laundry Detergents
Page 2 of 5
Hazards not otherwise classified: Not available.
Chemical Name*
CAS Number (Unique Identifier)
Concentration
Alcohols, C10-16, ethoxylated, sulfates, sodium
salts, 2EO
68081-91-4
5 - 10%
Benzenesulfonic acid, C10-13-alkyl derivs.,
sodium salts
68411-30-3
1 - 5%
Sodium carbonate
497-19-8
1 - 5%
Alcohols, C12-18, 7EO
68213-23-0
1 - 5%
Sodium chloride
7647-14-5
1 - 5%
Classification complies with OSHA Hazard Communication Standard (29 CFR 1910.1200) and is consistent with the provisions of the United
Nations Globally Harmonized System of Classification and Labeling of Chemicals (GHS).
See Section 11 for additional toxicological information.
3. COMPOSITION / INFORMATION ON INGREDIENTS
The following chemicals are classified as health hazards in accordance with paragraph (d) of § 1910.1200.
*The specific chemical identity and/or exact percentage (concentration) of composition has been withheld because a trade secret is claimed in
accordance with paragraph (i) of §1910.1200.
4. FIRST AID MEASURES
Description of necessary measures
Most important symptoms and effects, both acute and delayed
Indication of any immediate medical attention and special treatment needed
Inhalation: Remove from exposure area to fresh air. Contact physician or local poison control center.
Skin contact: Rinse affected area with large amounts of water until no evidence of product remains. Get medical attention if irritation
persists.
Eye contact: Rinse eyes immediately with plenty of water, occasionally lifting upper and lower lids, until no evidence of product
remains. Get medical attention if pain or irritation persist.
Ingestion: Dilution by rinsing the mouth and giving water or milk to drink is generally recommended. Contact physician or local
poison control center.
After eye contact: Moderate to severly irritating to the eyes (redness, swelling, burning, watering eyes). After skin contact: Temporary irritation
of the skin (redness, swelling, burning). After inhalation: Breathing high vapor concentrations may produce anesthetic effects, nausea,
dizziness, headache. After ingestion: Ingestion may cause irritation of mouth, throat, digestive tract, diarrhea and vomiting.
After eye contact: Hold eye open and rinse slowly and gently with water for 15 - 20 minutes. After skin contact: Rinse affected area with large
amounts of mild soap and water until no evidence of product remains. After inhalation: Remove from exposure area to fresh air. After
ingestion: Dilution by rinsing the mouth and giving water or milk to drink is generally recommended.
5. FIRE FIGHTING MEASURES
Suitable (and unsuitable) extinguishing media
Specific hazards arising from the chemical
Oxides of carbon and oxides of nitrogen.
Special protective equipment and precautions for fire-fighters
In case of fire, wear a full-face positive-pressure self-contained breathing apparatus and protective suit. Shut off all ignition sources Apply cooling water
to sides of containers that are exposed to flames until well after fire is out. Avoid breathing vapors, keep upwind. Keep unnecessary personnel away.
Suitable extinguishing media: Dry chemical, carbon dioxide, water spray or regular foam.
Unsuitable extinguishing media: None
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Wear skin, eye and respiratory protection as recommended in Section 8. Stop or reduce any leaks if it is safe to do so. Spills present a slipping hazard.
Keep unnecessary personnel away. Ensure clean-up is conducted by trained personnel only. Make sure area is slip-free before re-opening to traffic.
Environmental Precautions
Small or household quantities may be disposed in sewer or other liquid waste system. For larger quantities check with your local water treatment plant.
Methods and materials for containment and cleaning up
The Dial Corporation, a Henkel Company; 7201 E. Henkel Way; Scottsdale, AZ 85255-9672
Liquid Laundry Detergents
Page 3 of 5
Shut off ignition sources. No smoking, flames or flares in hazard area. Ventilate closed spaces before entering. SMALL SPILLS: Contain and absorb with
Hazardous Component(s)
ACGIH
OSHA PEL
AIHA WEEL
OTHER
Sodium carbonate
None
None
None
None
Sodium chloride
None
None
None
None
sand or other non-combustible absorbent material and place into containers for later disposal. Wash site of spillage thoroughly with water. LARGE
SPILLS: Dike far ahead of spill to prevent further movement. Recover by pumping or by using a suitable absorbent material and place into containers for
later disposal. Dispose in suitable waste container.
7. HANDLING AND STORAGE
Precautions for safe handling
Do not get in eyes or on skin. Do not ingest. Use with adequate ventilation. Avoid generating aerosols and mists. Keep the containers closed when not in
use.
Conditions for safe storage, including any incompatibilities
Store away from incompatible substances, excessive heat, flames, sparks or other ignition sources. Storage areas for large quantities (warehouse)
should be well ventilated. Keep the containers tightly closed when not in use.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
OSHA permissible exposure limit (PEL), American Conference of Governmental Industrial Hygienists (ACGIH) Threshold Limit Value (TLV),
and any other exposure limit used or recommended by the chemical manufacturer, importer, or employer preparing the safety data sheet,
where available.
Appropriate engineering controls
Provide local exhaust or general dilution ventilation to keep potential exposure to airborne contaminants below the permissible exposure limits where
mists or vapors may be generated.
Individual protection measures
Respiratory: If respiratory protection is required, it must be based on the contamination levels found in the workplace, must not exceed the
working limits of the respirator and be jointly approved by the National Institute for Occupational Safety and Health and the Mine Safety and
Health Administration (NIOSH-MSHA).
Eye: Splash-proof safety glasses are required to prevent eye contact where splashing of product may occur.
Hand/Body: Chemical-resistant gloves are required where repeated or prolonged skin contact may occur. Protective clothing is required
where repeated or prolonged skin contact may occur.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance: liquid, colored or colorless
Odor: distinct
Odor threshold: Not available.
pH: 10.2 - 12.2
Melting point/ range: Not available.
Boiling point/range: Not available.
Flash point: Not available.
Evaporation rate: Not available.
Flammable/Explosive limits - lower: Not available.
Flammable/Explosive limits - upper: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Solubility in water: Not available.
Partition coefficient (n-octanol/water): Not available.
Autoignition temperature: Not available.
Decomposition temperature: Not available.
Viscosity: 300 - 700 mPa.s
VOC content: Not available.
Specific gravity: 1.040 - 1.080 at 20 °C (68°F)
10. STABILITY AND REACTIVITY
Reactivity: This product may react with acids.
Chemical stability: Stable under normal ambient temperature (70°F, 21°C) and pressure (1 atm).
Possibility of hazardous reactions: Hazardous polymerization does not occur under normal temperatures and pressures.
Conditions to avoid: Avoid storing in direct sunlight, avoid extremes of temperature, avoid contact with incompatible substances.
The Dial Corporation, a Henkel Company; 7201 E. Henkel Way; Scottsdale, AZ 85255-9672
Liquid Laundry Detergents
Page 4 of 5
Hazardous Component(s)
LD50s and LC50s
Immediate and Delayed Health Effects
Alcohols, C10-16, ethoxylated, sulfates, sodium salts,
2EO
None
No Data
Benzenesulfonic acid, C10-13-alkyl derivs., sodium salts
None
Irritant
Sodium carbonate
Oral LD50 (RAT) = 4.090 mg/kg
Inhalation LC50 (RAT, 2 h) = 2,3 mg/l
Irritant, Sensory
Alcohols, C12-18, 7EO
None
Central nervous system, Irritant
Sodium chloride
Oral LD50 (RAT) = 3.000 mg/kg
Irritant
Hazardous Component(s)
NTP Carcinogen
IARC Carcinogen
OSHA Carcinogen
Alcohols, C10-16, ethoxylated, sulfates, sodium salts, 2EO
No
No
No
Benzenesulfonic acid, C10-13-alkyl derivs., sodium salts
No
No
No
Sodium carbonate
No
No
No
Alcohols, C12-18, 7EO
No
No
No
Sodium chloride
No
No
No
Hazardous substances
Result value
Route of
application
Species
Method
Benzenesulfonic acid, C10-13-alkyl
derivs., sodium salts
readily biodegradable
aerobic
85 %
OECD 301 B
Alcohols, C12-18, ethoxylated
readily biodegradable
aerobic
79 %
OECD 301 D
Incompatible materials: Strong oxidizers, acids.
Hazardous decomposition products: Thermal decomposition products may include oxides of carbon.
11. TOXICOLOGICAL INFORMATION
Likely routes of exposure including symptoms related to characteristics
Other relevant toxicity information:
This product is a laundry care product. The use of this product by consumers is safe under normal and reasonable foreseen use.
Numerical measures of toxicity, including delayed and immediate effect
Carcinogenicity information
Inhalation: Unlikely to occur due to the physical properties of the product. Inhalation of product mist may cause irritation of the nose,
throat, and respiratory tract.
Skin contact: Repeated or prolonged excessive exposure may cause irritation or dermatitis.
Eye contact: This product may cause irritation with stinging, tearing, and redness.
Ingestion: Ingestion of large quantities may cause gastrointestinal irritation with nausea, vomiting and diarrhea.
Physical/Chemical: No physical/chemical hazards are anticipated for this product.
Carcinogenicity None of the ingredients in this product are listed as carcinogens by the International Agency for Research on Cancer
(IARC), the National Toxicology Program (NTP) or the Occupational Safety and Health Administration (OSHA).
Mutagenicity None of the ingredients in this product are known to cause mutagenicity.
Toxicity for reproduction None of the ingredients in this product are known as reproductive, fetal, or developmental hazards.
12. ECOLOGICAL INFORMATION
Aquatic Toxicity:
The following toxicity information is available for the hazardous ingredient(s) when used as technical grade and is provided as reference for the
occupational settings. This product is anticipated to be safe for the environment at concentrations predicted in household settings under normal use
conditions.
Toxicity to fish:
The aquatic toxicity profile of this product has not been determined.
Toxicity to aquatic invertebrates:
The aquatic toxicity profile of this product has not been determined.
Toxicity to algae:
The aquatic toxicity profile of this product has not been determined.
Persistence and degradability:
Bioaccumulation Potential: The bioaccumulation potential of this product has not been determined.
Mobility: The mobility of this product (in soil and water) has not been determined.
The Dial Corporation, a Henkel Company; 7201 E. Henkel Way; Scottsdale, AZ 85255-9672
Liquid Laundry Detergents
Page 5 of 5
13. DISPOSAL CONSIDERATIONS
Description of waste residues:
Safe handling and disposal methods:
Hazardous waste number: Not regulated
Recommended method of disposal: This product is not a RCRA hazardous waste and can be disposed of in accordance with federal, state
and local regulations.
Disposal of packages: Dispose of container and unused contents in accordance with federal, state and local requirements.
14. TRANSPORT INFORMATION
The transport information provided in this section only applies to the material/formulation itself, and is not specific to any
package/configuration.
U.S. Department of Transportation Ground (49 CFR)
International Air Transportation (ICAO/IATA)
Water Transportation (IMO/IMDG)
Proper shipping name: Not regulated
Hazard class or division: None
Identification number: None
Packing group: None
Proper shipping name: Not regulated
Hazard class or division: None
Identification number: None
Packing group: None
Proper shipping name: Not regulated
Hazard class or division: None
Identification number: None
Packing group: None
15. REGULATORY INFORMATION
Occupational safety and health act: Hazard Communication Standard, 29 CFR 1910.1200(g) Appendix D: The Occupational Safety and Health
Administration (OSHA) require that the Safety Data Sheets (SDSs) are readily accessible to employees for all hazardous chemicals in the workplace.
Since the use pattern and exposure in the workplace are generally not consistent with those experienced by consumers, this SDS may contain health
hazard information not relevant to consumer use.
United States Regulatory Information
Canada Regulatory Information
TSCA 8 (b) Inventory Status All components of this product are either listed on or exempt from the U.S. Toxic Substances Control Act
(TSCA) chemical substance inventory.
TSCA 12 (b) Export Notification: None above reporting de minimis
CERCLA/SARA Section 302: None above reporting de minimis
CERCLA/SARA Section 311/312: Not available.
CERCLA/SARA Section 313: None above reporting de minimis
California Proposition 65: No California Proposition 65 listed chemicals are known to be present.
CEPA DSL/NDSL Status: One or more components are not listed on, and are not exempt from listing on either the Domestic Substances List
or the Non-Domestic Substances List.
16. OTHER INFORMATION
DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel Corporation and its
affiliates (“Henkel”) does not assume responsibility for any results obtained by persons over whose methods Henkel has no control. It is the user’s
responsibility to determine the suitability of Henkel’s products or any production methods mentioned herein for a particular purpose, and to adopt such
precautions as may be advisable for the protection of property and persons against any hazards that may be involved in the handling and use of any
Henkel’s products. In light of the foregoing, Henkel specifically disclaims all warranties, express or implied, including warranties of merchantability and
fitness for a particular purpose, arising from sale or use of Henkel’s products. Henkel further disclaims any liability for consequential or incidental
damages of any kind, including lost profits.
This safety data sheet contains changes from the previous version in sections: 12
Prepared by: R&D Support Services
Issue date: 04/20/2015 Supercedes: Rev. 14, 08/12/2014
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