Date of last issue: 12/12/2014
Date of first issue: 12/12/2014
Product name
:
PURELL® Advanced Instant Hand Sanitizer
Company name of supplier
:
GOJO Industries, Inc.
Address
:
One GOJO Plaza, Suite 500
Akron OH 44311
Telephone
:
1 (330) 255-6000
Emergency telephone
:
1-800-424-9300 CHEMTREC
Recommended use
:
Hand Sanitizer
Restrictions on use
:
This is a personal care or cosmetic product that is safe for
consumers and other users under normal and reasonably
foreseeable use. Cosmetics and consumer products,
specifically defined by regulations around the world, are
exempt from the requirement of an SDS for the consumer.
While this material is not considered hazardous, this SDS
contains valuable information critical to the safe handling and
proper use of the product for industrial workplace conditions
as well as unusual and unintended exposures such as large
spills. This SDS should be retained and available for
employees and other users of this product. For specific
intended-use guidance, please refer to the information
provided on the package or instruction sheet.
Flammable liquids
:
Category 3
Eye irritation
:
Category 2A
Hazard pictograms
:
Signal Word
:
Warning
Hazard Statements
:
H226 Flammable liquid and vapor.
H319 Causes serious eye irritation.
SECTION 1. IDENTIFICATION
Manufacturer or supplier's details
Recommended use of the chemical and restrictions on use
SECTION 2. HAZARDS IDENTIFICATION
GHS Classification
GHS Label element
1 / 15
Page 2
SAFETY DATA SHEET
PURELL® Advanced Instant Hand Sanitizer
Version
1.1
Revision Date:
02/10/2015
MSDS Number:
36779-00002
Date of last issue: 12/12/2014
Date of first issue: 12/12/2014
Precautionary Statements
:
Prevention:
P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking.
P233 Keep container tightly closed.
P241 Use explosion-proof electrical/ ventilating/ lighting/
equipment.
P242 Use only non-sparking tools.
P243 Take precautionary measures against static discharge.
P264 Wash skin thoroughly after handling.
P280 Wear protective gloves/ eye protection/ face protection.
Response:
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately
all contaminated clothing. Rinse skin with water/shower.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water
for several minutes. Remove contact lenses, if present and easy
to do. Continue rinsing.
P337 + P313 If eye irritation persists: Get medical advice/
attention.
Storage:
P403 + P235 Store in a well-ventilated place. Keep cool.
Disposal:
P501 Dispose of contents/ container to an approved waste
disposal plant.
Substance / Mixture
:
Mixture
Chemical Name
CAS-No.
Concentration (%)
Ethanol
64-17-5
>=50
- <70
Propan-2-ol
67-63-0
>=1
- <5
General advice
:
In the case of accident or if you feel unwell, seek medical
advice immediately.
When symptoms persist or in all cases of doubt seek medical
advice.
If inhaled
:
If inhaled, remove to fresh air.
Get medical attention if symptoms occur.
In case of skin contact
:
Wash with water and soap as a precaution.
Get medical attention if symptoms occur.
In case of eye contact
:
In case of contact, immediately flush eyes with plenty of water
for at least 15 minutes.
If easy to do, remove contact lens, if worn.
Other hazards
Vapors may form explosive mixture with air.
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous ingredients
SECTION 4. FIRST AID MEASURES
2 / 15
Page 3
SAFETY DATA SHEET
PURELL® Advanced Instant Hand Sanitizer
Version
1.1
Revision Date:
02/10/2015
MSDS Number:
36779-00002
Date of last issue: 12/12/2014
Date of first issue: 12/12/2014
Get medical attention.
If swallowed
:
If swallowed, DO NOT induce vomiting.
Get medical attention if symptoms occur.
Rinse mouth thoroughly with water.
Most important symptoms
and effects, both acute and
delayed
:
Causes serious eye irritation.
Protection of first-aiders
:
First Aid responders should pay attention to self-protection,
and use the recommended personal protective equipment
when the potential for exposure exists.
Notes to physician
:
Treat symptomatically and supportively.
Suitable extinguishing media
:
Water spray
Alcohol-resistant foam
Dry chemical
Carbon dioxide (CO2)
Unsuitable extinguishing
media
:
High volume water jet
Specific hazards during fire
fighting
:
Do not use a solid water stream as it may scatter and spread
fire.
Flash back possible over considerable distance.
Vapors may form explosive mixtures with air.
Exposure to combustion products may be a hazard to health.
Hazardous combustion products
:
Carbon oxides
Specific extinguishing
methods
:
Use extinguishing measures that are appropriate to local
circumstances and the surrounding environment.
Use water spray to cool unopened containers.
Remove undamaged containers from fire area if it is safe to do
so.
Evacuate area.
Special protective equipment
for fire-fighters
:
In the event of fire, wear self-contained breathing apparatus.
Use personal protective equipment.
Personal precautions,
protective equipment and
emergency procedures
:
Remove all sources of ignition.
Use personal protective equipment.
Follow safe handling advice and personal protective
equipment recommendations.
Environmental precautions
:
Discharge into the environment must be avoided.
SECTION 5. FIRE-FIGHTING MEASURES
SECTION 6. ACCIDENTAL RELEASE MEASURES
3 / 15
Page 4
SAFETY DATA SHEET
PURELL® Advanced Instant Hand Sanitizer
Version
1.1
Revision Date:
02/10/2015
MSDS Number:
36779-00002
Date of last issue: 12/12/2014
Date of first issue: 12/12/2014
Prevent further leakage or spillage if safe to do so.
Prevent spreading over a wide area (e.g. by containment or oil
barriers).
Retain and dispose of contaminated wash water.
Local authorities should be advised if significant spillages
cannot be contained.
Methods and materials for
containment and cleaning up
:
Non-sparking tools should be used.
Soak up with inert absorbent material.
Suppress (knock down) gases/vapors/mists with a water spray
jet.
For large spills, provide diking or other appropriate
containment to keep material from spreading. If diked material
can be pumped, store recovered material in appropriate
container.
Clean up remaining materials from spill with suitable
absorbent.
Local or national regulations may apply to releases and
disposal of this material, as well as those materials and items
employed in the cleanup of releases. You will need to
determine which regulations are applicable.
Sections 13 and 15 of this SDS provide information regarding
certain local or national requirements.
Technical measures
:
See Engineering measures under EXPOSURE
CONTROLS/PERSONAL PROTECTION section.
Local/Total ventilation
:
Use with local exhaust ventilation.
Use only in an area equipped with explosion proof exhaust
ventilation.
Advice on safe handling
:
Do not breathe vapors or spray mist.
Do not swallow.
Do not get in eyes.
Avoid prolonged or repeated contact with skin.
Handle in accordance with good industrial hygiene and safety
practice.
Non-sparking tools should be used.
Keep container tightly closed.
Keep away from heat and sources of ignition.
Take precautionary measures against static discharges.
Take care to prevent spills, waste and minimize release to the
environment.
Conditions for safe storage
:
Keep in properly labeled containers.
Keep tightly closed.
Keep in a cool, well-ventilated place.
Store in accordance with the particular national regulations.
Keep away from heat and sources of ignition.
Materials to avoid
:
Do not store with the following product types:
Strong oxidizing agents
SECTION 7. HANDLING AND STORAGE
4 / 15
Page 5
SAFETY DATA SHEET
PURELL® Advanced Instant Hand Sanitizer
Version
1.1
Revision Date:
02/10/2015
MSDS Number:
36779-00002
Date of last issue: 12/12/2014
Date of first issue: 12/12/2014
Organic peroxides
Flammable solids
Pyrophoric liquids
Pyrophoric solids
Self-heating substances and mixtures
Substances and mixtures which in contact with water emit
flammable gases
Explosives
Gases
Ingredients
CAS-No.
Value type
(Form of
exposure)
Control
parameters /
Permissible
concentration
Basis
Ethanol
64-17-5
TWA
1,000 ppm
1,900 mg/m3
NIOSH REL
TWA
1,000 ppm
1,900 mg/m3
OSHA Z-1
STEL
1,000 ppm
ACGIH
Propan-2-ol
67-63-0
TWA
200 ppm
ACGIH
STEL
400 ppm
ACGIH
TWA
400 ppm
980 mg/m3
NIOSH REL
ST
500 ppm
1,225 mg/m3
NIOSH REL
TWA
400 ppm
980 mg/m3
OSHA Z-1
Ingredients
CAS-No.
Control
parameters
Biological
specimen
Sampling
time
Permissible
concentratio
n
Basis
Propan-2-ol
67-63-0
Acetone
Urine
End of
shift at
end of
workweek
40 mg/l
ACGIH
BEI
Engineering measures
:
Minimize workplace exposure concentrations.
Use only in an area equipped with explosion proof exhaust
ventilation.
Use with local exhaust ventilation.
Respiratory protection
:
General and local exhaust ventilation is recommended to
maintain vapor exposures below recommended limits. Where
concentrations are above recommended limits or are
unknown, appropriate respiratory protection should be worn.
Follow OSHA respirator regulations (29 CFR 1910.134) and
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Ingredients with workplace control parameters
Biological occupational exposure limits
Personal protective equipment
5 / 15
Page 6
SAFETY DATA SHEET
PURELL® Advanced Instant Hand Sanitizer
Version
1.1
Revision Date:
02/10/2015
MSDS Number:
36779-00002
Date of last issue: 12/12/2014
Date of first issue: 12/12/2014
use NIOSH/MSHA approved respirators. Protection provided
by air purifying respirators against exposure to any
hazardous chemical is limited. Use a positive pressure air
supplied respirator if there is any potential for uncontrolled
release, exposure levels are unknown, or any other
circumstance where air purifying respirators may not provide
adequate protection.
Material
:
Impervious gloves
Material
:
Flame retardant gloves
Remarks
:
Choose gloves to protect hands against chemicals depending
on the concentration specific to place of work. Breakthrough
time is not determined for the product. Change gloves often!
For special applications, we recommend clarifying the
resistance to chemicals of the aforementioned protective
gloves with the glove manufacturer. Wash hands before
breaks and at the end of workday.
Eye protection
:
Wear the following personal protective equipment:
Safety goggles
Skin and body protection
:
Select appropriate protective clothing based on chemical
resistance data and an assessment of the local exposure
potential.
Wear the following personal protective equipment:
Flame retardant antistatic protective clothing.
Skin contact must be avoided by using impervious protective
clothing (gloves, aprons, boots, etc).
Hygiene measures
:
Ensure that eye flushing systems and safety showers are
located close to the working place.
When using do not eat, drink or smoke.
Wash contaminated clothing before re-use.
Appearance
:
liquid
Color
:
clear, Colorless to pale yellow
Odor
:
citrus
Odor Threshold
:
No data available
pH :
6.5 - 8.5
Melting point/freezing point
:
No data available
Initial boiling point and boiling
range
:
70 °C
Hand protection
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
6 / 15
Page 7
SAFETY DATA SHEET
PURELL® Advanced Instant Hand Sanitizer
Version
1.1
Revision Date:
02/10/2015
MSDS Number:
36779-00002
Date of last issue: 12/12/2014
Date of first issue: 12/12/2014
Flash point
:
25 °C
Evaporation rate
:
No data available
Flammability (solid, gas)
:
Not applicable
Upper explosion limit
:
No data available
Lower explosion limit
:
No data available
Vapor pressure
:
No data available
Relative vapor density
:
No data available
Density
:
0.8750 g/cm3
Water solubility
:
soluble
Partition coefficient: noctanol/water
:
Not applicable
Autoignition temperature
:
No data available
Decomposition temperature
:
The substance or mixture is not classified self-reactive.
Viscosity, kinematic
:
3,500 - 23,000 mm2/s (20 °C)
Explosive properties
:
Not explosive
Oxidizing properties
:
The substance or mixture is not classified as oxidizing.
Reactivity
:
Not classified as a reactivity hazard.
Chemical stability
:
Stable under normal conditions.
Possibility of hazardous reactions
:
Flammable liquid and vapor.
Vapors may form explosive mixture with air.
Can react with strong oxidizing agents.
Conditions to avoid
:
Heat, flames and sparks.
Incompatible materials
:
Oxidizing agents
Hazardous decomposition
products
:
No hazardous decomposition products are known.
Solubility(ies)
Viscosity
SECTION 10. STABILITY AND REACTIVITY
7 / 15
Page 8
SAFETY DATA SHEET
PURELL® Advanced Instant Hand Sanitizer
Version
1.1
Revision Date:
02/10/2015
MSDS Number:
36779-00002
Date of last issue: 12/12/2014
Date of first issue: 12/12/2014
LC50 (Rat): 124.7 mg/l
Exposure time: 4 h
Test atmosphere: vapor
Acute oral toxicity
:
LD50 (Rat): > 5,000 mg/kg
Acute inhalation toxicity
:
LC50 (Rat): 72.6 mg/l
Exposure time: 4 h
Test atmosphere: vapor
Acute dermal toxicity
:
LD50 (Rat): > 5,000 mg/kg
Result: No skin irritation
Species: Rabbit
Method: OECD Test Guideline 404
Result: No skin irritation
Species: Rabbit
Result: No skin irritation
SECTION 11. TOXICOLOGICAL INFORMATION
Information on likely routes of exposure
Inhalation
Skin contact
Ingestion
Eye contact
Acute toxicity
Not classified based on available information.
Product:
Ingredients:
Ethanol:
Propan-2-ol:
Skin corrosion/irritation
Not classified based on available information.
Product:
Ingredients:
Ethanol:
Propan-2-ol:
Serious eye damage/eye irritation
Causes serious eye irritation.
Ingredients:
8 / 15
Page 9
SAFETY DATA SHEET
PURELL® Advanced Instant Hand Sanitizer
Version
1.1
Revision Date:
02/10/2015
MSDS Number:
36779-00002
Date of last issue: 12/12/2014
Date of first issue: 12/12/2014
Species: Rabbit
Result: Irritation to eyes, reversing within 21 days
Method: OECD Test Guideline 405
Species: Rabbit
Result: Irritation to eyes, reversing within 21 days
Assessment: Does not cause skin sensitization.
Test Type: Local lymph node assay (LLNA)
Routes of exposure: Skin contact
Species: Mouse
Result: negative
Test Type: Buehler Test
Routes of exposure: Skin contact
Species: Guinea pig
Method: OECD Test Guideline 406
Result: negative
Genotoxicity in vitro
:
Test Type: In vitro mammalian cell gene mutation test
Result: negative
Genotoxicity in vivo
:
Test Type: Rodent dominant lethal test (germ cell) (in vivo)
Species: Mouse
Application Route: Ingestion
Result: negative
Genotoxicity in vitro
:
Test Type: Bacterial reverse mutation assay (AMES)
Result: negative
Genotoxicity in vivo
:
Test Type: Mammalian erythrocyte micronucleus test (in vivo
cytogenetic assay)
Species: Mouse
Application Route: Intraperitoneal injection
Result: negative
Ethanol:
Propan-2-ol:
Respiratory or skin sensitization
Skin sensitization: Not classified based on available information.
Respiratory sensitization: Not classified based on available information.
Product:
Ingredients:
Ethanol:
Propan-2-ol:
Germ cell mutagenicity
Not classified based on available information.
Ingredients:
Ethanol:
Propan-2-ol:
9 / 15
Page 10
SAFETY DATA SHEET
PURELL® Advanced Instant Hand Sanitizer
Version
1.1
Revision Date:
02/10/2015
MSDS Number:
36779-00002
Date of last issue: 12/12/2014
Date of first issue: 12/12/2014
Species: Rat
Application Route: inhalation (vapor)
Exposure time: 104 weeks
Method: OECD Test Guideline 451
Result: negative
IARC
No ingredient of this product present at levels greater than or
equal to 0.1% is identified as probable, possible or confirmed
human carcinogen by IARC.
OSHA
No ingredient of this product present at levels greater than or
equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA.
NTP
No ingredient of this product present at levels greater than or
equal to 0.1% is identified as a known or anticipated carcinogen
by NTP.
Effects on fertility
:
Test Type: Two-generation reproduction toxicity study
Species: Mouse
Application Route: Ingestion
Method: OECD Test Guideline 416
Result: negative
Effects on fertility
:
Test Type: Two-generation reproduction toxicity study
Species: Rat
Application Route: Ingestion
Result: negative
Effects on fetal development
:
Test Type: Embryo-fetal development
Species: Rat
Application Route: Ingestion
Result: negative
Assessment: May cause drowsiness or dizziness.
Carcinogenicity
Not classified based on available information.
Ingredients:
Propan-2-ol:
Reproductive toxicity
Not classified based on available information.
Ingredients:
Ethanol:
Propan-2-ol:
STOT-single exposure
Not classified based on available information.
Ingredients:
Propan-2-ol:
10 / 15
Page 11
SAFETY DATA SHEET
PURELL® Advanced Instant Hand Sanitizer
Version
1.1
Revision Date:
02/10/2015
MSDS Number:
36779-00002
Date of last issue: 12/12/2014
Date of first issue: 12/12/2014
Species: Rat
NOAEL: 2,400 mg/kg
Application Route: Ingestion
Exposure time: 2 y
Species: Rat
NOAEL: 5000 ppm
Application Route: inhalation (vapor)
Exposure time: 104 w
Method: OECD Test Guideline 413
Date of last issue: 12/12/2014
Date of first issue: 12/12/2014
Exposure time: 8 d
Toxicity to bacteria
:
EC50 (Pseudomonas putida): > 1,050 mg/l
Exposure time: 16 h
Biodegradability
:
Result: Readily biodegradable.
Biodegradation: 84 %
Exposure time: 20 d
Biodegradability
:
Result: rapidly degradable
Partition coefficient: noctanol/water
:
log Pow: -0.35
Partition coefficient: noctanol/water
:
log Pow: 0.05
Waste from residues
:
Dispose of in accordance with local regulations.
Contaminated packaging
:
Dispose of as unused product.
Empty containers should be taken to an approved waste
handling site for recycling or disposal.
Do not burn, or use a cutting torch on, the empty drum.
UNRTDG
UN number
:
UN 1987
Proper shipping name
:
ALCOHOLS, N.O.S.
Persistence and degradability
Ingredients:
Ethanol:
Propan-2-ol:
Bioaccumulative potential
Ingredients:
Ethanol:
Propan-2-ol:
Mobility in soil
No data available
Other adverse effects
No data available
SECTION 13. DISPOSAL CONSIDERATIONS
Disposal methods
SECTION 14. TRANSPORT INFORMATION
International Regulation
12 / 15
Page 13
SAFETY DATA SHEET
PURELL® Advanced Instant Hand Sanitizer
Version
1.1
Revision Date:
02/10/2015
MSDS Number:
36779-00002
Date of last issue: 12/12/2014
Date of first issue: 12/12/2014
(Ethanol, Propan-2-ol)
Class
:
3
Packing group
:
III
Labels
:
3
IATA-DGR
UN/ID No.
:
UN 1987
Proper shipping name
:
Alcohols, n.o.s.
(Ethanol, Propan-2-ol)
Class
:
3
Packing group
:
III
Labels
:
Flammable Liquids
Packing instruction (cargo
aircraft)
:
366
Packing instruction
(passenger aircraft)
:
355
IMDG-Code
UN number
:
UN 1987
Proper shipping name
:
ALCOHOLS, N.O.S.
(Ethanol, Propan-2-ol)
Class
:
3
Packing group
:
III
Labels
:
3
EmS Code
:
F-E, S-D
Marine pollutant
:
no
49 CFR
UN/ID/NA number
:
UN 1987
Proper shipping name
:
ALCOHOLS, N.O.S.
Class
:
3
Packing group
:
III
Labels
:
FLAMMABLE LIQUID
ERG Code
:
127
Marine pollutant
:
no
SARA 311/312 Hazards
:
Fire Hazard
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable for product as supplied.
Domestic regulation
SECTION 15. REGULATORY INFORMATION
EPCRA - Emergency Planning and Community Right-to-Know
CERCLA Reportable Quantity
This material does not contain any components with a CERCLA RQ.
SARA 304 Extremely Hazardous Substances Reportable Quantity
This material does not contain any components with a section 304 EHS RQ.
13 / 15
Page 14
SAFETY DATA SHEET
PURELL® Advanced Instant Hand Sanitizer
Version
1.1
Revision Date:
02/10/2015
MSDS Number:
36779-00002
Date of last issue: 12/12/2014
Date of first issue: 12/12/2014
Acute Health Hazard
SARA 302
:
No chemicals in this material are subject to the reporting
requirements of SARA Title III, Section 302.
SARA 313
:
The following components are subject to reporting levels
established by SARA Title III, Section 313:
Propan-2-ol
67-63-0
3.4086 %
Ethanol
64-17-5
50 - 70 %
Water
7732-18-5
30 - 50 %
Propan-2-ol
67-63-0
1 - 5 %
Ethanol
64-17-5
50 - 70 %
Water
7732-18-5
30 - 50 %
Propan-2-ol
67-63-0
1 - 5 %
California Prop 65
This product does not contain any chemicals known to the
State of California to cause cancer, birth, or any other
reproductive defects.
AICS
:
All ingredients listed or exempt.
US State Regulations
Pennsylvania Right To Know
New Jersey Right To Know
The ingredients of this product are reported in the following inventories:
Date of last issue: 12/12/2014
Date of first issue: 12/12/2014
NFPA:
HMIS III:
ACGIH
:
USA. ACGIH Threshold Limit Values (TLV)
ACGIH BEI
:
ACGIH - Biological Exposure Indices (BEI)
NIOSH REL
:
USA. NIOSH Recommended Exposure Limits
OSHA Z-1
:
USA. Occupational Exposure Limits (OSHA) - Table Z-1 Limits for Air Contaminants
ACGIH / TWA
:
8-hour, time-weighted average
ACGIH / STEL
:
Short-term exposure limit
NIOSH REL / TWA
:
Time-weighted average concentration for up to a 10-hour
workday during a 40-hour workweek
NIOSH REL / ST
:
STEL - 15-minute TWA exposure that should not be exceeded
at any time during a workday
OSHA Z-1 / TWA
:
8-hour time weighted average
Sources of key data used to
compile the Material Safety
Data Sheet
:
Internal technical data, data from raw material SDSs, OECD
eChem Portal search results and European Chemicals Agency, http://echa.europa.eu/
Revision Date
:
02/10/2015
Flammability
Health
Instability
2
3
0
FLAMMABILITY
PHYSICAL HAZARD
HEALTH
3
0
2
Special hazard.
0 = not significant, 1 =Slight,
2 = Moderate, 3 = High
4 = Extreme, * = Chronic
SECTION 16. OTHER INFORMATION
Further information
Full text of other abbreviations
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and
shall not be considered a warranty or quality specification of any type. The information provided relates only to the specific material identified at the top of this SDS and may not be valid
when the SDS material is used in combination with any other materials or in any process, unless specified in the text. Material users should review the information and recommendations
in the specific context of their intended manner of handling, use, processing and storage, in-
cluding an assessment of the appropriateness of the SDS material in the user’s end product, if
applicable.
US / Z8
15 / 15
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