Purell 5072-02, 6472-02, 7772-02 User Manual

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SAFETY DATA SHEET
PURELL® Healthcare HEALTHY SOAP™ Gentle & Free Foam
Version 1.0
Revision Date: 05/01/2017
1 / 11
SECTION 1. IDENTIFICATION
Product name
:
PURELL® Healthcare HEALTHY SOAP™ Gentle & Free
Foam
Manufacturer or supplier's details
Company name of supplier
:
GOJO Industries, Inc.
Address
:
One GOJO Plaza, Suite 500 Akron, Ohio 44311
Telephone
:
1 (330) 255-6000
Emergency telephone number
:
1-800-424-9300 CHEMTREC
Recommended use of the chemical and restrictions on use
Recommended use
:
Skin-care
Restrictions on use
:
This is a personal care or cosmetic product that is safe for consumers and other users under normal and reasonably foreseeable use. Cosmetics and consumer products, specifically defined by regulations around the world, are exempt from the requirement of an SDS for the consumer. While this material is not considered hazardous, this SDS contains valuable information critical to the safe handling and proper use of the product for industrial workplace conditions as well as unusual and unintended exposures such as large spills. This SDS should be retained and available for employees and other users of this product. For specific intended-use guidance, please refer to the information provided on the package or instruction sheet.
SECTION 2. HAZARDS IDENTIFICATION
GHS Classification
Eye irritation
:
Category 2B
GHS label elements
Signal word
:
Warning
Hazard statements
:
H320 Causes eye irritation.
Precautionary statements
:
Response:
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337 + P313 If eye irritation persists: Get medical advice/ attention.
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SAFETY DATA SHEET
PURELL® Healthcare HEALTHY SOAP™ Gentle & Free Foam
Version 1.0
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Other hazards
None known.
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous components
Chemical name
CAS-No.
Concentration (%)
Sodium Laureth Sulfate
68585-34-2
>= 1
- < 5
Glycerin
56-81-5
>= 1
- < 5
SECTION 4. FIRST AID MEASURES
General advice
:
In the case of accident or if you feel unwell, seek medical advice immediately. When symptoms persist or in all cases of doubt seek medical advice.
If inhaled
:
If inhaled, remove to fresh air. If symptoms persist, call a physician.
In case of skin contact
:
Wash with water and soap as a precaution. Get medical attention if irritation develops and persists.
In case of eye contact
:
Immediately flush eye(s) with plenty of water. If easy to do, remove contact lens, if worn. Seek medical advice.
If swallowed
:
If swallowed, DO NOT induce vomiting. Rinse mouth with water. Obtain medical attention.
Most important symptoms and effects, both acute and delayed
:
Causes eye irritation. Protection of first-aiders
:
First Aid responders should pay attention to self-protection and use the recommended protective clothing
SECTION 5. FIREFIGHTING MEASURES
Suitable extinguishing media
:
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Unsuitable extinguishing media
:
None known.
Hazardous combustion products
:
Sulphur oxides Carbon oxides Nitrogen oxides (NOx) Metal oxides Specific extinguishing
:
Use extinguishing measures that are appropriate to local
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SAFETY DATA SHEET
PURELL® Healthcare HEALTHY SOAP™ Gentle & Free Foam
Version 1.0
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methods
circumstances and the surrounding environment. Use a water spray to cool fully closed containers.
Further information
:
Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations.
Special protective equipment for firefighters
:
In the event of fire, wear self-contained breathing apparatus. Use personal protective equipment.
SECTION 6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
:
Use personal protective equipment. Ensure adequate ventilation. Evacuate personnel to safe areas. Material can create slippery conditions.
Environmental precautions
:
Discharge into the environment must be avoided. Prevent further leakage or spillage if safe to do so. Prevent spreading over a wide area (e.g. by containment or oil barriers). Retain and dispose of contaminated wash water. Local authorities should be advised if significant spillages cannot be contained.
Methods and materials for containment and cleaning up
:
Contain spillage, and then collect with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13). Keep in suitable, closed containers for disposal. Clean contaminated floors and objects thoroughly while observing environmental regulations.
SECTION 7. HANDLING AND STORAGE
Advice on safe handling
:
For personal protection see section 8. Do not swallow. Avoid contact with eyes. Keep container closed when not in use.
Conditions for safe storage
:
Keep in properly labelled containers. Keep container tightly closed in a dry and well-ventilated place. Store in accordance with the particular national regulations.
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Components with workplace control parameters
Components
CAS-No.
Value type (Form of exposure)
Control parameters / Permissible
Basis
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SAFETY DATA SHEET
PURELL® Healthcare HEALTHY SOAP™ Gentle & Free Foam
Version 1.0
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concentration
Glycerin
56-81-5
TWA (mist, respirable fraction)
5 mg/m3
OSHA Z-1 TWA (mist, total dust)
15 mg/m3
OSHA Z-1
Personal protective equipment
Respiratory protection
:
No personal respiratory protective equipment normally required.
Eye protection
:
No special measures necessary provided product is used correctly. Wear face-shield and protective suit for abnormal processing problems.
Skin and body protection
:
No special measures necessary provided product is used correctly.
Protective measures
:
Choose body protection in relation to its type, to the concentration and amount of dangerous substances, and to the specific work-place. Ensure that eye flushing systems and safety showers are located close to the working place.
Hygiene measures
:
Handle in accordance with good industrial hygiene and safety practice. Avoid contact with eyes.
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance
:
liquid
Colour
:
clear, colourless, light yellow
Odour
:
like soap
Odour Threshold
:
No data available
pH :
5.3 - 6.7, (20 °C)
Solidification / Setting point
:
1.4 °C
Initial boiling point and boiling range
:
98 °C Flash point
:
> 100 °C
Evaporation rate
:
No data available
Flammability (solid, gas)
:
Not applicable
Upper explosion limit
:
No data available
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SAFETY DATA SHEET
PURELL® Healthcare HEALTHY SOAP™ Gentle & Free Foam
Version 1.0
Revision Date: 05/01/2017
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Lower explosion limit
:
No data available
Vapour pressure
:
No data available
Relative vapour density
:
No data available
Density
:
1.012 g/cm3
Solubility(ies)
Water solubility
:
soluble
Partition coefficient: n­octanol/water
:
Not applicable Auto-ignition temperature
:
not determined
Thermal decomposition
:
The substance or mixture is not classified self-reactive.
Viscosity
Viscosity, kinematic
:
10 - 20 mm2/s (20 °C) Explosive properties
:
Not explosive
Oxidizing properties
:
The substance or mixture is not classified as oxidizing.
SECTION 10. STABILITY AND REACTIVITY
Reactivity
:
Not classified as a reactivity hazard.
Chemical stability
:
Stable under normal conditions.
Possibility of hazardous reactions
:
No dangerous reaction known under conditions of normal use. Incompatible materials
:
Strong oxidizing agents
Hazardous decomposition products
:
No hazardous decomposition products are known.
SECTION 11. TOXICOLOGICAL INFORMATION
Information on likely routes of exposure
Skin contact Eye contact Inhalation
Acute toxicity
Not classified based on available information.
Product:
Acute oral toxicity
:
Acute toxicity estimate : > 5,000 mg/kg Method: Calculation method
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Version 1.0
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Components:
Sodium Laureth Sulfate:
Acute oral toxicity
:
LD50 (Rat): > 2,000 mg/kg Assessment: The substance or mixture has no acute oral toxicity
Glycerin:
Acute oral toxicity
:
LD50 (Rat): > 5,000 mg/kg
Skin corrosion/irritation
Not classified based on available information.
Product:
Assessment: Not irritating when applied to human skin. Result: No skin irritation
Components:
Sodium Laureth Sulfate:
Result: Skin irritation
Glycerin:
Result: No skin irritation
Serious eye damage/eye irritation
Causes eye irritation.
Product:
Result: Mild eye irritation
Components:
Sodium Laureth Sulfate:
Result: Eye irritation Remarks: Severe eye irritation
Glycerin:
Result: No eye irritation
Respiratory or skin sensitisation
Skin sensitisation: Not classified based on available information. Respiratory sensitisation: Not classified based on available information.
Germ cell mutagenicity
Not classified based on available information.
Components:
Glycerin:
Genotoxicity in vitro
:
Test Type: In vitro mammalian cell gene mutation test Method: OECD Test Guideline 476 Result: negative
Carcinogenicity
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Version 1.0
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Not classified based on available information.
Components:
Glycerin:
Species: Rat Application Route: Ingestion Exposure time: 2 Years Result: negative
IARC
No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC.
ACGIH
No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by ACGIH.
OSHA
No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA.
NTP
No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP.
Reproductive toxicity
Not classified based on available information.
Components:
Glycerin:
Effects on fertility
:
Test Type: Two-generation reproduction toxicity study Species: Rat Application Route: Ingestion Result: negative
Effects on foetal development
:
Test Type: Embryo-foetal development Species: Rabbit Application Route: Ingestion Result: negative
STOT - single exposure
Not classified based on available information.
STOT - repeated exposure
Not classified based on available information.
Repeated dose toxicity
Components:
Sodium Laureth Sulfate:
Repeated dose toxicity ­Assessment
:
Causes serious eye irritation.
Glycerin:
Species: Rat
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Version 1.0
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NOAEL: 167 mg/m3 LOAEL: 660 mg/m3 Application Route: inhalation (dust/mist/fume) Exposure time: 13 w Symptoms: Local irritation
Aspiration toxicity
Not classified based on available information.
SECTION 12. ECOLOGICAL INFORMATION
Ecotoxicity Components:
Glycerin:
Toxicity to fish
:
LC50 (Oncorhynchus mykiss (rainbow trout)): 54,000 mg/l Exposure time: 96 h
Toxicity to daphnia and other aquatic invertebrates
:
EC50 (Daphnia magna (Water flea)): 1,955 mg/l Exposure time: 48 h
Toxicity to bacteria
:
NOEC (Pseudomonas putida): > 10,000 mg/l Exposure time: 16 h
Persistence and degradability Components:
Sodium Laureth Sulfate:
Biodegradability
:
Result: Readily biodegradable.
Glycerin:
Biodegradability
:
Result: Readily biodegradable. Biodegradation: 94 % Exposure time: 1 d
Bioaccumulative potential Components:
Glycerin:
Partition coefficient: n­octanol/water
:
log Pow: -1.76
Mobility in soil
No data available
Other adverse effects
No data available
Product:
Regulation
40 CFR Protection of Environment; Part 82 Protection of Stratospheric Ozone - CAA Section 602 Class I Substances
Remarks
This product neither contains, nor was manufactured with a
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SAFETY DATA SHEET
PURELL® Healthcare HEALTHY SOAP™ Gentle & Free Foam
Version 1.0
Revision Date: 05/01/2017
9 / 11 Class I or Class II ODS as defined by the U.S. Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + B).
SECTION 13. DISPOSAL CONSIDERATIONS
Disposal methods
Waste from residues
:
Dispose of in accordance with local regulations.
Contaminated packaging
:
Dispose of as unused product. Empty containers should be taken to an approved waste handling site for recycling or disposal.
SECTION 14. TRANSPORT INFORMATION
International Regulation
IATA-DGR
Not regulated as a dangerous good
IMDG-Code
Not regulated as a dangerous good
National Regulations
49 CFR
Not regulated as a dangerous good
SECTION 15. REGULATORY INFORMATION
EPCRA - Emergency Planning and Community Right-to-Know Act CERCLA Reportable Quantity
This material does not contain any components with a CERCLA RQ.
SARA 304 Extremely Hazardous Substances Reportable Quantity
This material does not contain any components with a section 304 EHS RQ.
SARA 311/312 Hazards
:
Acute Health Hazard
SARA 302
:
No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
SARA 313
:
This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313.
Clean Air Act
This product does not contain any hazardous air pollutants (HAP), as defined by the U.S. Clean Air Act Section 12 (40 CFR 61). This product does not contain any chemicals listed under the U.S. Clean Air Act Section 112(r) for Accidental Release Prevention (40 CFR 68.130, Subpart F). The following chemical(s) are listed under the U.S. Clean Air Act Section 111 SOCMI Intermediate or Final VOC's (40 CFR 60.489):
Glycerin
56-81-5
1.75 %
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Version 1.0
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This product does not contain any VOC exemptions listed under the U.S. Clean Air Act Section
450.
Clean Water Act
This product does not contain any Hazardous Substances listed under the U.S. CleanWater Act, Section 311, Table 116.4A. This product does not contain any Hazardous Chemicals listed under the U.S. CleanWater Act, Section 311, Table 117.3. This product does not contain any toxic pollutants listed under the U.S. Clean Water Act Section 307
Massachusetts Right To Know
Glycerin
56-81-5
1 - 5 %
Pennsylvania Right To Know
Water (Aqua)
7732-18-5
90 - 100 %
Glycerin
56-81-5
1 - 5 %
New Jersey Right To Know
Water (Aqua)
7732-18-5
90 - 100 %
Sodium Laureth Sulfate
68585-34-2
1 - 5 %
Glycerin
56-81-5
1 - 5 %
California Prop 65
This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.
The components of this product are reported in the following inventories:
CH INV
:
On the inventory, or in compliance with the inventory
TSCA
:
On the inventory, or in compliance with the inventory
DSL :
All components of this product are on the Canadian DSL.
AICS
:
On the inventory, or in compliance with the inventory
NZIoC
:
On the inventory, or in compliance with the inventory
ENCS
:
On the inventory, or in compliance with the inventory
ISHL
:
On the inventory, or in compliance with the inventory
KECI
:
On the inventory, or in compliance with the inventory
PICCS
:
On the inventory, or in compliance with the inventory
IECSC
:
On the inventory, or in compliance with the inventory
Inventories
AICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan), ISHL (Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), TCSI (Taiwan), TSCA (USA)
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SAFETY DATA SHEET
PURELL® Healthcare HEALTHY SOAP™ Gentle & Free Foam
Version 1.0
Revision Date: 05/01/2017
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SECTION 16. OTHER INFORMATION
Further information
NFPA:
HMIS III:
Revision Date
:
05/01/2017
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.
Flammability
Health
Instability
1
0
0
FLAMMABILITY
PHYSICAL HAZARD
HEALTH
0
0
1
Special hazard.
0 = not significant, 1 =Slight, 2 = Moderate, 3 = High 4 = Extreme, * = Chronic
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