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MATERIAL SAFETY DATA SHEET
Product number
173-002
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1. Product and Company Identification
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Product name Autumn Leaves Air Freshener & Deodorizer
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Effective date
11-Aug-2009
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Company information
Claire Manufacturing Co.
500 Vista Ave.
Addison, IL 60101 United States
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Company phone
General Assistance 630-543-7600
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Emergency telephone US
800-424-9300
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Emergency telephone outside US
703-527-3887
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Version #
02
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Supersedes date
04-Aug-2009
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Emergency overview
CONTENTS UNDER PRESSURE. Aerosol.
Prolonged exposure may cause chronic effects.
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2. Hazards Identification
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Routes of exposure
Ingestion. Skin contact.
Potential health effects
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Eyes
Health injuries are not known or expected under normal use.
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Skin
Prolonged or repeated contact can result in defatting and drying of the skin which may
result in skin irritation and dermatitis (rash).
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Inhalation
Intentional misuse by concentrating and inhaling the product can be harmful or fatal.
Prolonged inhalation may be harmful.
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Ingestion
Exposure by ingestion of an aerosol is unlikely. May cause delayed lung damage.
Components of the product may be absorbed into the body by ingestion.
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Target organs
Central nervous system. Lungs.
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Chronic effects
May cause central nervous system disorder (e.g., narcosis involving a loss of
coordination, weakness, fatigue, mental confusion, and blurred vision) and/or damage.
May cause delayed lung damage.
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Signs and symptoms
Discomfort in the chest. Narcosis. Defatting of the skin. Irritation.
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CAS # Percent
10 - 1574-98-6
Components
Propane
8 - 10106-97-8n-Butane
3 - 564-17-5Ethyl Alcohol
60 - 80Non-hazardous and other components below reportable levels
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3. Composition / Information on Ingredients
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Eye contact
Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact
lenses, if present and easy to do. Continue rinsing. Get medical attention if irritation
develops or persists.
First aid procedures
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4. First Aid Measures
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Skin contact
Immediately take off all contaminated clothing. Wash off with warm water and soap. Get
medical attention if irritation develops or persists.
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Inhalation
Move to fresh air. Call a physician if symptoms develop or persist.
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Ingestion
If material is ingested, immediately contact a poison control center. Have victim rinse
mouth thoroughly with water. Do not induce vomiting without advice from poison control
center. If vomiting occurs naturally, have victim lean forward to reduce risk of aspiration.
Do not use mouth-to-mouth method if victim ingested the substance. Induce artificial
respiration with the aid of a pocket mask equipped with a one-way valve or other proper
respiratory medical device.
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Product #: 173-002 Revision date: 11-AUG-2009 Print date: 11-AUG-2009
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Flammable properties
Vapor or gas may spread to distant ignition sources and flash back. Runoff to sewer may
cause fire or explosion hazard.
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5. Fire Fighting Measures
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Suitable extinguishing media
Water fog. Dry chemical. Carbon dioxide (CO2).
Extinguishing media
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Protective equipment and
precautions for firefighters
In the event of fire and/or explosion do not breathe fumes. Wear full protective clothing,
including helmet, self-contained positive pressure or pressure demand breathing
apparatus, protective clothing and face mask. Containers should be cooled with water to
prevent vapor pressure build up. For massive fire, use unmanned hose holders or
monitor nozzles; if this is impossible, withdraw from area and let fire burn.
Protection of firefighters
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Methods for containment
Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area).
Stop leak if you can do so without risk. Move the cylinder to a safe and open area if the
leak is irreparable. Stop the flow of material, if this is without risk. Prevent entry into
waterways, sewers, basements or confined areas.
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6. Accidental Release Measures
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Methods for cleaning up
Should not be released into the environment. Use a non-combustible material like
vermiculite, sand or earth to soak up the product and place into a container for later
disposal.
Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean contaminated
surface thoroughly.
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Handling
Pressurized container: Do not pierce or burn, even after use. Do not handle or store near
an open flame, heat or other sources of ignition. Do not use if spray button is missing or
defective. Use only with adequate ventilation. Do not get this material in contact with
eyes. Do not get this material in contact with skin. Avoid prolonged exposure.
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7. Handling and Storage
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Storage
Level 1 Aerosol.
Contents under pressure. Do not puncture, incinerate or crush. The pressure in sealed
containers can increase under the influence of heat. Do not handle or store near an open
flame, heat or other sources of ignition. Do not expose to heat or store at temperatures
above 120°F/49°C as can may burst. Avoid exposure to long periods of sunlight. Keep
out of the reach of children. Do not store, incinerate, or heat this material above 120
degrees Fahrenheit.
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Exposure limits
ACGIH
Components
CAS #
Propane 74-98-6
TWA
1000 ppm
STEL
Not established
Ceiling
Not established
n-Butane 106-97-8 1000 ppm Not established Not established
space
Ethyl Alcohol 64-17-5 1000 ppm Not established Not established
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8. Exposure Controls / Personal Protection
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OSHA
Components
CAS #
Propane 74-98-6
TWA
1000 ppm
STEL
Not established
Ceiling
Not established
space
Ethyl Alcohol 64-17-5 1000 ppm Not established Not established
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Eye / face protection
Wear chemical goggles.
Personal protective equipment
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Skin protection
Wear appropriate chemical resistant clothing. Protective gloves.
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Respiratory protection
When workers are facing concentrations above the exposure limit they must use
appropriate certified respirators. If permissible levels are exceeded use NIOSH
mechanical filter / organic vapor cartridge or an air-supplied respirator.
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Product #: 173-002 Revision date: 11-AUG-2009 Print date: 11-AUG-2009
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Appearance
Compressed liquefied gas.
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9. Physical & Chemical Properties
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Boiling point
158 °F (70 °C) estimated
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Color
White.
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Flammability (HOC)
10.1142 kJ/g estimated
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Flash back
No
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Flash point
-156 °F (-104.4 °C) Propellant
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Form
Aerosol.
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Odor
Characteristic.
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pH
10 - 11
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Physical state
Liquid.
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Pressure
72 - 92 psig @70F
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Solubility
Partially
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Specific gravity
0.8438 estimated
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Conditions to avoid
Heat, flames and sparks.
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10. Chemical Stability & Reactivity Information
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Hazardous decomposition products
No hazardous decomposition products are known.
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Acute effects
Acute LC50: 974 mg/l/4h estimated, Rat, Inhalation
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11. Toxicological Information
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Sensitization
Not expected to be hazardous by OSHA criteria.
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Teratogenicity
Not expected to be hazardous by OSHA criteria.
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Ecotoxicity
Components of this product have been identified as having potential environmental
concerns.
LC50 2882 mg/L estimated, Fish, 96.00 Hours,
EC50 50285 mg/L estimated, Daphnia, 48.00 Hours,
IC50 7500 mg/L estimated, Algae, 72.00 Hours,
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12. Ecological Information
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Waste codes
D001: Waste Flammable material with a flash point <140 F
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13. Disposal Considerations
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Disposal instructions
Contents under pressure. Dispose of this material and its container at hazardous or
special waste collection point. Do not incinerate sealed containers. Do not allow this
material to drain into sewers/water supplies. If discarded, this product is considered a
RCRA ignitable waste, D001. Dispose in accordance with all applicable regulations.
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Department of Transportation (DOT) Requirements
Consumer commodity
ORM-D
None
Hazard class
Subsidiary hazard class
Proper shipping name
Basic shipping requirements:
156, 306
156, 306
None
Packaging exceptions
Packaging non bulk
Packaging bulk
Additional information:
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14. Transport Information
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Product #: 173-002 Revision date: 11-AUG-2009 Print date: 11-AUG-2009
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IMDG
AEROSOLS
2.1
1950
Hazard class
UN number
Proper shipping name
Basic shipping requirements:
LTD QTY
None
Packaging exceptions
Labels required
Additional information:
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IATA
Aerosols, flammable
2.1
1950
Hazard class
UN number
Proper shipping name
Basic shipping requirements:
LTD QTY
2.1
Packaging exceptions
Labels required
Additional information:
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US federal regulations
This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.
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15. Regulatory Information
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29 CFR 1910.1200 hazardous
chemical
Yes
Occupational Safety and Health Administration (OSHA)
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None
CERCLA (Superfund) reportable quantity
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Hazard categories
Immediate Hazard - Yes
Delayed Hazard - Yes
Fire Hazard - Yes
Pressure Hazard - Yes
Reactivity Hazard - No
Superfund Amendments and Reauthorization Act of 1986 (SARA)
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Section 302 extremely
hazardous substance
No
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Section 311 hazardous chemical
Yes
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Inventory status
Country(s) or region Inventory name On inventory (yes/no)*
No
Yes
Yes
No
No
China
Europe
Europe
Japan
Korea
Inventory of Existing Chemical Substances in China (IECSC)
European Inventory of New and Existing Chemicals (EINECS)
European List of Notified Chemical Substances (ELINCS)
Inventory of Existing and New Chemical Substances (ENCS)
Existing Chemicals List (ECL)
Yes
A
"Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)
United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory
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State regulations
U.S. - Pennsylvania - RTK (Right to Know) List
64-17-5 PresentEthyl Alcohol
106-97-8 Presentn-Butane
74-98-6 PresentPropane
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Further information
HMIS® is a registered trade and service mark of the NPCA.
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16. Other Information
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HMIS® ratings
Health: 1
Flammability: 2
Physical hazard: 0
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Product #: 173-002 Revision date: 11-AUG-2009 Print date: 11-AUG-2009
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Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our
knowledge, information and belief at the date of its publication. The information given is
designed only as a guidance for safe handling, use, processing, storage, transportation,
disposal and release and is not to be considered a warranty or quality specification. The
information relates only to the specific material designated and may not be valid for such
material used in combination with any other materials or in any process, unless specified
in the text.
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MSDS sections updated
Product and Company Identification: Product and Company Identification
Physical & Chemical Properties: Fire Fighting Measures
Transport Information: Agency Name and Packaging Type/Transport Mode Selection
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Prepared by
Regulatory Compliance
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Product #: 173-002 Revision date: 11-AUG-2009 Print date: 11-AUG-2009
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Fall Harvest Air Freshener & Deodorizer
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