MATERIAL SAFETY DATA SHEET
1. Product and Company Identification
Material name
Version #
Issue date
Revision date
Supersedes date
CAS #
Manufacturer/Supplier
A358T Cool Cucumber
01
05-15-2012
-
-
Mixture
Pro-Link, Inc.
500 Chapman Street
Canton, MA 02021
Telephone number:
Emergency
(781) 828-9550
24-Hour Emergency: PROSAR: (866) 303-6948
2. Hazards Identification
Physical state
Appearance
Emergency overview
OSHA regulatory status
Potential health effects
Routes of exposure
Eyes
Skin
Inhalation
Ingestion
Potential environmental effects
Liquid.
Clear, pale yellow liquid.
WARNING
Combustible liquid and vapor.
Causes skin irritation.
This product is hazardous according to OSHA 29 CFR 1910.1200.
Inhalation. Eye contact. Skin contact.
Direct contact with eyes may cause temporary irritation.
Causes skin irritation.
In high concentrations, vapors may be irritating to the respiratory system.
No harmful effects expected in amounts likely to be ingested by accident.
The product is not classified as environmentally hazardous. However, this does not exclude the
possibility that large or frequent spills can have a harmful or damaging effect on the environment.
3. Composition / Information on Ingredients
Components CAS # Percent
142-92-7 15 - 25Hexyl Acetate
78-70-6 5 - 15Linalool
Composition comments
All concentrations are in percent by weight.
4. First Aid Measures
First aid procedures
Eye contact
Skin contact
Inhalation
Ingestion
Immediately flush with plenty of water for up to 15 minutes. Remove any contact lenses and open
eyelids wide apart. In case of irritation from airborne exposure, move to fresh air. Get medical
attention if symptoms persist.
Wash with soap and water. Get medical attention if symptoms occur after washing.
If symptomatic, move to fresh air. Get medical attention if symptoms persist.
Rinse mouth thoroughly. Seek medical advice. Only induce vomiting at the instruction of medical
personnel.
5. Fire Fighting Measures
Flammable properties
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The product is combustible, but not flammable.
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Extinguishing media
without risk. Dike the spilled material, where this is possible.
Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents)
Suitable extinguishing
media
Unsuitable extinguishing
media
Protection of firefighters
Protective equipment and
precautions for firefighters
Fire fighting
equipment/instructions
Hazardous combustion
products
Water fog. Carbon dioxide (CO2). Dry chemical. Foam.
Do not use water jet as an extinguisher, as this will spread the fire.
Self-contained breathing apparatus and full protective clothing must be worn in case of fire.
Use water spray to cool unopened containers. Cool containers with flooding quantities of water
until well after fire is out.
Carbon oxides.
6. Accidental Release Measures
Personal precautions
Environmental precautions
Methods for cleaning up
Ensure adequate ventilation. Eliminate all ignition sources (no smoking, flares, sparks or flames in
immediate area). Avoid contact with skin. See Section 8 of the MSDS for Personal Protective
Equipment.
Do not contaminate water. Contact local authorities in case of spillage to drain/aquatic
environment.
Remove sources of ignition. Beware of the explosion danger. Stop the flow of material, if this is
Small Spills: Absorb spillage with non-combustible, absorbent material.
Large Spills: Use a non-combustible material like vermiculite, sand or earth to soak up the product
and place into a container for later disposal.
7. Handling and Storage
Handling
Storage
Wear appropriate personal protective equipment. Provide adequate ventilation. Avoid contact with
eyes, skin, and clothing. Do not taste or swallow. Wash thoroughly after handling.
Do not handle or store near an open flame, heat or other sources of ignition. Protect against direct
sunlight. Store in tightly closed original container in a dry, cool and well-ventilated place. Keep
away from food, drink and animal feeding stuffs. Store away from incompatible materials. Avoid
uncoated metal containers. Minimize exposure to air.
8. Exposure Controls / Personal Protection
Occupational exposure limits
TypeComponents
TWAHexyl Acetate (142-92-7) 294 mg/m3
Engineering controls
Personal protective equipment
Eye / face protection
Skin protection
Respiratory protection
General hygiene
considerations
Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates
should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation,
or other engineering controls to maintain airborne levels below recommended exposure limits. If
exposure limits have not been established, maintain airborne levels to an acceptable level.
Wear safety glasses with side shields (or goggles).
Wear chemical-resistant gloves, footwear and protective clothing appropriate for risk of exposure.
Contact glove manufacturer for specific information.
In case of inadequate ventilation use suitable respirator.
Always observe good personal hygiene measures, such as washing after handling the material
and before eating, drinking, and/or smoking. Routinely wash work clothing and protective
equipment to remove contaminants.
Value
50 ppm
9. Physical & Chemical Properties
Appearance
Physical state
Form
Color
A358T Cool Cucumber
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Clear, pale yellow liquid.
Liquid.
Liquid.
Colorless to pale yellow.
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Odor
Acute effects
Chronic effects
Carcinogenicity
Environmental effects
Odor threshold
pH
Vapor pressure
Vapor density
Boiling point
Melting point/Freezing point
Solubility (water)
Specific gravity
Flash point
Flammability limits in air,
Not assigned.
Not available.
Not available.
Not available.
Not available.
Not available.
Not available.
Not available.
Not available.
156.20 °F (69.00 °C)
Not available.
upper, % by volume
Flammability limits in air,
Not available.
lower, % by volume
Auto-ignition temperature
Partition coefficient
Not available.
No data available.
(n-octanol/water)
10. Chemical Stability & Reactivity Information
Chemical stability
Conditions to avoid
Incompatible materials
Hazardous decomposition
products
Possibility of hazardous
reactions
Material is stable under normal conditions.
Contact with incompatible materials. Keep away from heat, sparks, and flame.
Strong oxidizing agents. Strong acids. Alkalis.
Carbon oxides. Unidentified organic compounds.
Will not occur.
11. Toxicological Information
Toxicological data
Components Species
Linalool (78-70-6)
Acute
Dermal
LD50 Rabbit
Rat 5610 mg/kg
Oral
LD50 Mouse
Sensitization
No sensitizing effects known.
Causes skin irritation.
Chronic effects are not expected when this product is used as intended.
None known.
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not available.
12. Ecological Information
Ecotoxicological data
Components Test ResultsSpecies
Hexyl Acetate (142-92-7)
Aquatic
LC50Fish 3.7 - 4.4 mg/l, 96 hoursFathead minnow (Pimephales promelas)
Test Results
2000 mg/kg
3000 mg/kg
Ecotoxicity
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The product is not classified as environmentally hazardous. However, this does not exclude the
possibility that large or frequent spills can have a harmful or damaging effect on the environment.
An environmental hazard cannot be excluded in the event of unprofessional handling or disposal.
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Persistence and degradability
Partition coefficient
Bioaccumulation /
No data available.
No data available.
Accumulation
No data available.
Linalool 2.97
Mobility in environmental
No data available.
media
13. Disposal Considerations
Disposal instructions
Waste from residues / unused
products
Contaminated packaging
Dispose of contents/container in accordance with local/regional/national/internat ional regulations.
Do not allow this material to drain into sewers/water supplies.
Dispose of waste and residues in accordance with local authority requirements.
Since emptied containers retain product residue, follow label warnings even after container is
emptied.
14. Transport Information
DOT
Basic shipping requirements:
UN number
Proper shipping name
Hazard class
Packing group
Additional information:
Special provisions
Packaging exceptions
Packaging non bulk
Packaging bulk
IATA
UN number
UN proper shipping name
Transport hazard class(es)
Packing group
Labels required
IMDG
UN number
UN proper shipping name
Transport hazard class(es)
Packing group
Labels required
TDG
Proper shipping name
Hazard class
UN number
Packing group
Special provisions
Labels required
Packaging exceptions
Packaging non bulk
Packaging bulk
UN3082
Environmentally hazardous substances, liquid, n.o.s. (Limonene, Hexyl Acetate)
9
III
8, 146, 173, 335, IB3, T4, TP1, TP29
155
203
241
UN3082
Environmentally hazardous substances, liquid, n.o.s. (Limonene, Hexyl Acetate)
9
III
9
UN3082
Environmentally hazardous substances, liquid, n.o.s. (Limonene, Hexyl Acetate)
9
III
9
Environmentally hazardous substances, liquid, n.o.s. (Limonene, Hexyl Acetate)
9
UN3082
III
8, 146, 173, 335, IB3, T4, TP1, TP29
9
155
203
241
15. Regulatory Information
US federal regulations
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
CERCLA (Superfund) reportable quantity (lbs) (40 CFR 302.4)
None
A358T Cool Cucumber
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Not regulated.
This product is hazardous according to OSHA 29 CFR 1910.1200.
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Superfund Amendments and Reauthorization Act of 1986 (SARA)
Hazard categories
Immediate Hazard - Yes
Delayed Hazard - No
Fire Hazard - Yes
Pressure Hazard - No
Reactivity Hazard - No
Section 302 extremely
No
hazardous substance (40
CRF 355, Appendix A)
Section 311/312 (40 CFR
Yes
370)
Drug Enforcement
Not controlled
Administration (DEA) (21 CFR
1308.11-15)
Canadian regulations
This product has been classified in accordance with the hazard criteria of the CPR and the MSDS
contains all the information required by the CPR.
WHMIS status
WHMIS classification
Controlled
B3 - Combustible Liquids
D2B - Other Toxic Effects-TOXIC
WHMIS labeling
Inventory status
Country(s) or region Inventory name On inventory (yes/no)*
Australian Inventory of Chemical Substances (AICS) YesAustralia
Domestic Substances List (DSL) YesCanada
Non-Domestic Substances List (NDSL) NoCanada
Inventory of Existing Chemical Substances in China (IECSC) YesChina
European Inventory of Existing Commercial Chemical
Substances (EINECS)
European List of Notified Chemical Substances (ELINCS) NoEurope
Inventory of Existing and New Chemical Substances (ENCS) NoJapan
Existing Chemicals List (ECL) YesKorea
New Zealand Inventory YesNew Zealand
Philippine Inventory of Chemicals and Chemical Substances
(PICCS)
Toxic Substances Control Act (TSCA) Inventory YesUnited States & Puerto Rico
*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)
State regulations
US - California Proposition 65 - Carcinogens & Reproductive Toxicity (CRT): Listed substance
Not listed.
US. Massachusetts RTK - Substance List
Not regulated.
US. New Jersey Worker and Community Right-to-Know Act
Not regulated.
US. Pennsylvania RTK - Hazardous Substances
Not regulated.
Mexico regulations
This safety data sheet was prepared in accordance with the Official Mexican Standard
(NOM-018-STPS-2000).
YesEurope
YesPhilippines
16. Other Information
Further information
HMIS® ratings
A358T Cool Cucumber
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HMIS® is a registered trade and service mark of the NPCA.
Health: 2
Flammability: 2
Physical hazard: 0
CPH MSDS NA
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NFPA ratings
workers and the environment
Disclaimer
Health: 2
Flammability: 2
Instability: 0
This information is provided without warranty. The information is believed to be correct. This
information should be used to make an independent determination of the methods to safeguard
.
A358T Cool Cucumber
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