MATERIAL SAFETY DATA SHEET
1. Product and Company Identification
Material name
Version #
Issue date
Revision date
Supersedes date
CAS #
Manufacturer/Supplier
A354T Sparkling Wind
01
05-15-2012
-
-
Mixture
Pro-Link, Inc.
500 Chapman Street
Canton, MA 02021
Telephone number:
Emergency
(781) 828-9550
24-Hour Emergency: PROSAR: (866) 303-6948
2. Hazards Identification
Physical state
Appearance
Emergency overview
OSHA regulatory status
Potential health effects
Routes of exposure
Eyes
Skin
Inhalation
Ingestion
Potential environmental effects
Liquid.
Clear yellow liquid.
WARNING
Combustible liquid and vapor.
Causes skin irritation. May cause an allergic skin reaction. Harmful if swallowed - may enter lungs
if swallowed or vomited.
This product is hazardous according to OSHA 29 CFR 1910.1200.
Inhalation. Eye contact. Skin contact.
Direct contact with eyes may cause temporary irritation.
Causes skin irritation. May cause allergic skin reaction.
In high concentrations, vapors may be irritating to the respiratory system.
Harmful if swallowed - may enter lungs if swallowed or vomited.
The product contains a substance which is very toxic to aquatic organisms and which may cause
long-term adverse effects in the aquatic environment.
3. Composition / Information on Ingredients
Components CAS # Percent
76-22-2 10 - 20Campher
80-56-8 1 - 5Alpha-pinene
586-62-9 1 - 5Terpinolene
99-87-6 1 - 3p-Cymene
5989-27-5 0.5 - 3Limonene
Composition comments
All concentrations are in percent by weight.
4. First Aid Measures
First aid procedures
Eye contact
Skin contact
Inhalation
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Immediately flush with plenty of water for up to 15 minutes. Remove any contact lenses and open
eyelids wide apart. In case of irritation from airborne exposure, move to fresh air. Get medical
attention if symptoms persist.
Wash with soap and water. Get medical attention if symptoms occur after washing.
If symptomatic, move to fresh air. Get medical attention if symptoms persist.
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Ingestion
without risk. Dike the spilled material, where this is possible.
US. ACGIH Threshold Limit Values
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
Canada. Alberta OELs (Occupational Health & Safety Code, Schedule 1, Table 2)
Call a physician or poison control center immediately. DO NOT induce vomiting. If victim is fully
conscious, give a cupful of water. Never give anything by mouth to an unconscious person. If
vomiting occurs, keep head lower than the hips to help prevent aspiration.
5. Fire Fighting Measures
Flammable properties
Extinguishing media
Suitable extinguishing
media
Unsuitable extinguishing
media
Protection of firefighters
Protective equipment and
precautions for firefighters
Fire fighting
equipment/instructions
Hazardous combustion
products
The product is combustible, but not flammable.
Water fog. Carbon dioxide (CO2). Dry chemical. Foam.
Do not use water jet as an extinguisher, as this will spread the fire.
Self-contained breathing apparatus and full protective clothing must be worn in case of fire.
Use water spray to cool unopened containers. Cool containers with flooding quantities of water
until well after fire is out.
Carbon oxides.
6. Accidental Release Measures
Personal precautions
Environmental precautions
Methods for cleaning up
Ensure adequate ventilation. Eliminate all ignition sources (no smoking, flares, sparks or flames in
immediate area). Avoid contact with skin. See Section 8 of the MSDS for Personal Protective
Equipment.
Do not contaminate water. Contact local authorities in case of spillage to drain/aquatic
environment.
Remove sources of ignition. Beware of the explosion danger. Stop the flow of material, if this is
Small Spills: Absorb spillage with non-combustible, absorbent material.
Large Spills: Use a non-combustible material like vermiculite, sand or earth to soak up the product
and place into a container for later disposal.
7. Handling and Storage
Handling
Storage
Wear appropriate personal protective equipment. Provide adequate ventilation. Avoid contact with
eyes, skin, and clothing. Do not taste or swallow. Wash thoroughly after handling.
Do not handle or store near an open flame, heat or other sources of ignition. Protect against direct
sunlight. Store in tightly closed original container in a dry, cool and well-ventilated place. Keep
away from food, drink and animal feeding stuffs. Store away from incompatible materials. Avoid
uncoated metal containers. Minimize exposure to air.
8. Exposure Controls / Personal Protection
Occupational exposure limits
TypeComponents
TWAAlpha-pine ne (80-56-8) 20 ppm
STELCampher (76-22-2) 3 ppm
TWA 2 ppm
TypeComponents
PELCampher (76-22-2) 2 mg/m3
TypeComponents
STELCampher (76-22-2) 19 mg/m3
TWA 12 mg/m3
Value
Value
Value
3 ppm
2 ppm
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Canada. British Columbia OELs. (Occupational Exposure Limits for Chemical Substances, Occupational Health and
Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents)
Canada. Quebec OELS. (Ministry of Labor - Regulation Respecting the Quality of the Work Environment)
Mexico. Occupational Exposure Limit Values
Safety Regulation 296/97, as amended)
TypeComponents
Value
TWAAlpha-pine ne (80-56-8) 20 ppm
STELCampher (76-22-2) 3 ppm
TWA 2 ppm
Engineering controls
Personal protective equipment
Eye / face protection
Skin protection
Respiratory protection
General hygiene
considerations
TypeComponents
Value
TWAAlpha-pine ne (80-56-8) 20 ppm
STELCampher (76-22-2) 3 ppm
TWA 2 ppm
TWAp-Cymene (99-87-6) 274 mg/m3
50 ppm
TypeComponents
Value
STELCampher (76-22-2) 19 mg/m3
3 ppm
TWA 12 mg/m3
2 ppm
TypeComponents
Value
STELCampher (76-22-2) 19 mg/m3
3 ppm
TWA 12 mg/m3
2 ppm
Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates
should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation,
or other engineering controls to maintain airborne levels below recommended exposure limits. If
exposure limits have not been established, maintain airborne levels to an acceptable level.
Wear safety glasses with side shields (or goggles).
Wear chemical-resistant gloves, footwear and protective clothing appropriate for risk of exposure.
Contact glove manufacturer for specific information.
In case of inadequate ventilation use suitable respirator.
Always observe good personal hygiene measures, such as washing after handling the material
and before eating, drinking, and/or smoking. Routinely wash work clothing and protective
equipment to remove contaminants.
9. Physical & Chemical Properties
Appearance
Physical state
Form
Color
Odor
Odor threshold
pH
Vapor pressure
Vapor density
Boiling point
Melting point/Freezing point
Solubility (water)
Specific gravity
Flash point
Flammability limits in air,
upper, % by volume
Flammability limits in air,
lower, % by volume
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Clear yellow liquid.
Liquid.
Liquid.
Clear to yellow.
Not assigned.
Not available.
Not available.
Not available.
Not available.
Not available.
Not available.
Not available.
Not available.
131 °F (55 °C)
Not available.
Not available.
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Auto-ignition temperature
Acute effects
Chronic effects
Carcinogenicity
Partition coefficient
Not available.
No data available.
(n-octanol/water)
10. Chemical Stability & Reactivity Information
Chemical stability
Conditions to avoid
Incompatible materials
Hazardous decomposition
products
Possibility of hazardous
reactions
Material is stable under normal conditions.
Contact with incompatible materials. Keep away from heat, sparks, and flame.
Strong oxidizing agents. Strong acids. Alkalis.
Carbon oxides. Unidentified organic compounds.
Will not occur.
11. Toxicological Information
Toxicological data
Components Species
Alpha-pinene (80-56-8)
Acute
Oral
LD50 Rat
Campher (76-22-2)
Acute
Oral
LD50 Mouse
Other
LD50 Mouse
Rat 70 mg/kg
Limonene (5989-27-5)
Acute
Dermal
LD50 Rabbit
Oral
LD50 Rat
p-Cymene (99-87-6)
Acute
Oral
LD50 Rat
Terpinolene (586-62-9)
Acute
Dermal
LD50 Rabbit
Rat > 5 ml/kg
Oral
LD50 Mouse
Test Results
3700 mg/kg
1310 mg/kg
3000 mg/kg
5 g/kg
4400 mg/kg
3669 mg/kg
> 5000 mg/kg
> 4000 mg/kg
Sensitization
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May cause allergic skin disorders in sensitive individuals.
ACGIH Sensitizer
Alpha-pinene (CAS 80-56-8) Sensitizer.
Causes skin irritation. Harmful if swallowed - may enter lungs if swallowed or vomited.
Chronic effects are not expected when this product is used as intended.
None known.
ACGIH Carcinogens
Alpha-pinene (CAS 80-56-8)
A4 Not classifiable as a human carcinogen.
Campher (CAS 76-22-2) A4 Not classifiable as a human carcinogen.
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IARC Monographs. Overall Evaluation of Carcinogenicity
Environmental effects
Partition coefficient
Limonene (CAS 5989-27-5) 3 Not classifiable as to carcinogenicity to humans.
12. Ecological Information
Ecotoxicological data
Components Test ResultsSpecies
Limonene (5989-27-5)
Aquatic
EC50Crustacea 0.42 mg/l, 48 HoursDaphnia
LC50Fish 0.619 - 0.796 mg/l, 96 hoursFathead minnow (Pimephales promelas)
Ecotoxicity
The product contains a substance which is very toxic to aquatic organisms and which may cause
long-term adverse effects in the aquatic environment.
An environmental hazard cannot be excluded in the event of unprofessional handling or disposal.
Persistence and degradability
Bioaccumulation /
No data available.
No data available.
Accumulation
No data available.
p-Cymene 4.1
Terpinolene 4.23
Limonene 4.232
Alpha-pinene 4.83
Mobility in environmental
No data available.
media
13. Disposal Considerations
Disposal instructions
Waste from residues / unused
products
Contaminated packaging
Dispose of contents/container in accordance with local/regional/national/internat ional regulations.
Do not allow this material to drain into sewers/water supplies.
Dispose of waste and residues in accordance with local authority requirements.
Since emptied containers retain product residue, follow label warnings even after container is
emptied.
14. Transport Information
DOT
Basic shipping requirements:
UN number
Proper shipping name
Hazard class
Packing group
Environmental hazards
Marine pollutant
Additional information:
Special provisions
Packaging exceptions
Packaging non bulk
Packaging bulk
IATA
UN number
UN proper shipping name
Transport hazard class(es)
Packing group
Environmental hazards
ERG code
IMDG
UN number
UN proper shipping name
Transport hazard class(es)
Packing group
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UN1169
Extracts, aromatic, liquid, MARINE POLLUTANT
3
III
Yes
B1, IB3, T2, TP1
150
203
242
UN1169
Extracts, aromatic, liquid
3
III
Yes
3L
UN1169
EXTRACTS, AROMATIC, LIQUID, MARINE POLLUTANT
3
III
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Environmental hazards
Marine pollutant
EmS No.
Yes
F-E, S-D
TDG
Proper shipping name
Hazard class
UN number
Packing group
Marine pollutant
EXTRACTS, AROMATIC, LIQUID, MARINE POLLUTANT
3
UN1169
III
Yes
15. Regulatory Information
US federal regulations
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
CERCLA (Superfund) reportable quantity (lbs) (40 CFR 302.4)
Alpha-pinene: 100
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Hazard categories
Section 302 extremely
hazardous substance (40
CRF 355, Appendix A)
Section 311/312 (40 CFR
370)
Drug Enforcement
Administration (DEA) (21 CFR
1308.11-15)
Canadian regulations
WHMIS status
WHMIS classification
WHMIS labeling
This product is hazardous according to OSHA 29 CFR 1910.1200.
Immediate Hazard - Yes
Delayed Hazard - No
Fire Hazard - Yes
Pressure Hazard - No
Reactivity Hazard - No
No
Yes
Not controlled
This product has been classified in accordance with the hazard criteria of the CPR and the MSDS
contains all the information required by the CPR.
Controlled
B3 - Combustible Liquids
D2B - Other Toxic Effects-TOXIC
Inventory status
Country(s) or region Inventory name On inventory (yes/no)*
Australian Inventory of Chemical Substances (AICS) YesAustralia
Domestic Substances List (DSL) YesCanada
Non-Domestic Substances List (NDSL) NoCanada
Inventory of Existing Chemical Substances in China (IECSC) YesChina
European Inventory of Existing Commercial Chemical
Substances (EINECS)
European List of Notified Chemical Substances (ELINCS) NoEurope
Inventory of Existing and New Chemical Substances (ENCS) YesJapan
Existing Chemicals List (ECL) YesKorea
New Zealand Inventory YesNew Zealand
Philippine Inventory of Chemicals and Chemical Substances
(PICCS)
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YesEurope
YesPhilippines
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Country(s) or region Inventory name On inventory (yes/no)*
workers and the environment
Toxic Substances Control Act (TSCA) Inventory YesUnited States & Puerto Rico
*A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s)
State regulations
US - California Hazardous Substances (Director's): Listed substance
Campher (CAS 76-22-2) Listed.
US - California Proposition 65 - Carcinogens & Reproductive Toxicity (CRT): Listed substance
Not listed.
US - New Jersey RTK - Substances: Listed substance
Alpha-pinene (CAS 80-56-8) Listed.
Campher (CAS 76-22-2) Listed.
Limonene (CAS 5989-27-5) Listed.
p-Cymene (CAS 99-87-6) Listed.
Terpinolene (CAS 586-62-9) Listed.
US. Massachusetts RTK - Substance List
Alpha-pinene (CAS 80-56-8) Listed.
Campher (CAS 76-22-2) Listed.
p-Cymene (CAS 99-87-6) Listed.
US. New Jersey Worker and Community Right-to-Know Act
Not regulated.
US. Pennsylvania RTK - Hazardous Substances
Alpha-pinene (CAS 80-56-8) Listed.
Campher (CAS 76-22-2) Listed.
p-Cymene (CAS 99-87-6) Listed.
Mexico regulations
This safety data sheet was prepared in accordance with the Official Mexican Standard
(NOM-018-STPS-2000).
16. Other Information
Further information
HMIS® ratings
NFPA ratings
Disclaimer
HMIS® is a registered trade and service mark of the NPCA.
Health: 2
Flammability: 2
Physical hazard: 0
Health: 2
Flammability: 2
Instability: 0
This information is provided without warranty. The information is believed to be correct. This
information should be used to make an independent determination of the methods to safeguard
.
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