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1. Identification of the substance/preparation
Name of product GranQuartz 901K Anti-Slip Fluid
Manufacturer/distributor
Safety data-sheet (91/155 EEC)
Printed 25.05.2004
Revision 28.03.2003 (GB) Version 1.1
GranQuartz 901K Anti-Slip Fluid
GranQuartz Stone Care Systems
4963 S.Royal Atlanta Dr., Tucker, GA 30084
Phone 1-800-458-6222
Advice
Recommended intended purpose(s)
Cleaner
Techn. Department
Phone 1-800-458-6222
2. Composition/information on ingredients
Chemical characterization
Produkt with fluorides
Hazardous ingredients
CAS-No. EC-No. Name [% weight] Classification
001341-49-7 215-676-4 ammonium-hydrogendifluoride < 10 T R25; C R34
3. Special hazards information for man and environment
R-phrases
22 Harmful if swallowed.
34 Causes burns.
4. First aid measures
General information
Remove contaminated soaked clothing immediately.
In case of inhalation
Ensure of fresh air.
In the event of symptoms refer for medical treatment.
In case of skin contact
In case of contact with skin wash off with Ca-Gluconate solution.
In case of contact with skin wash off immediately with soap and water.
In case of eye contact
In case of contact with eyes rinse thoroughly with plenty of water and seek medical advice.
In case of ingestion
Do not induce vomitting.
If swallowed by mistake drink plenty of water and seek medical treatment.
5. Fire-fighting measures
Suitable extinguishing material
Product does not burn, fire-extinguishing activities according to surrounding.
Special exposure hazards arising from the substance, combustible products or resulting gases
Hydrogen fluoride (HF)
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6. Accidental release measures
Personal precautions
Ensure adequate ventilation.
Use personal protective clothing.
Environmental precautions
Do not discharge into the drains/surface waters/groundwater.
Methods for cleaning up/taking up
Take up with absorbent material (e.g. general-purpose binder).
Neutralize with slaked lime.
7. Handling and storage
Advice on safe handling
Use only in well-ventilated areas.
Take the usual precautions when handling with chemicals.
Advice on protection against fire and explosion
No special measures necessary.
Requirements for storage rooms and vessels
Do not use glass containers.
Safety data-sheet (91/155 EEC)
Printed 25.05.2004
Revision 28.03.2003 (GB) Version 1.1
GranQuartz 901K Anti-Slip Fluid
Further information on storage conditions
Keep container dry, tightly closed and store at cool and aired place.
8. Exposure controls / personal protection
Respiratory protection
Short term: filter apparatus, filter E
Hand protection
Gloves (acid-resistant)
Eye protection
safety goggles
Skin protection
Acid-resistant protective clothing
General protective measures
Avoid contact with eyes and skin
Hygiene measures
At work do not eat, drink and smoke.
9. Physical and chemical properties
Form
liquid
Colour
colourless, clear
Odour
odourless
Data relevant for safety
pH value in delivery state
starts to boil
Flash point
Density
Value Temperature at Method Remark
ca. 1,5 - 4,5
> 90 °C
not applicable
ca. 1,0 g/cm3
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Solubility in water
10. Stability and reactivity
Conditions to avoid
Reactions with metals, with evolution of hydrogen.
Hazardous decomposition products
Hydrogen fluoride
11. Toxicological information
Acute toxicity/Irritability/Sensitization
LD 50 acute oral
Safety data-sheet (91/155 EEC)
Printed 25.05.2004
Revision 28.03.2003 (GB) Version 1.1
GranQuartz 901K Anti-Slip Fluid
Value Temperature at Method Remark
multimiscible
Value/Validation Species Method Remark
not determined
LD 50 acute dermal
LC 50 acute
inhalation
12. Ecological information
Data on elimination (persistence and degradability)
Physico-chemical
degradability
Biological
degradability
! 13. Disposal considerations
! Waste code No. Name of waste
16 03 03* inorganic wastes containing dangerous substances
Recommendations for the product
Neutralize with lime.
Remove in accordance with local offical regulations.
not determined
not determined
Elimination rate Method of analysis Method Validation
not determined
not determined
Recommendations for packaging
Totally emptied packaging may be taken for recycling.
14. Transport information
Land and inland navigation transport (ADR/RID/GGVS/GGVE/ADNR)
Identification
UN-No.
Class
PG
Hazard No.
Ammonium hydrogen difluoride solution
2817
8
III
86
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Marine transport IMDG/GGV See
Proper shipping name
UN-No.
Class
PG
Marine pollutant
EmS-No.
Air transport ICAO/IATA
Proper shipping name
UN/ID-No.
Class
PG
15. Regulatory information
Remarks for classification
The product is classified and labelled in accordance with EC directives.
Classification
Corrosive
C
Safety data-sheet (91/155 EEC)
Printed 25.05.2004
Revision 28.03.2003 (GB) Version 1.1
GranQuartz 901K Anti-Slip Fluid
Ammonium hydrogendifluoride solution
2817
8
III
No
8-06
Ammonium hydrogendifluoride solution
2817
8
III
R-phrases
22 Harmful if swallowed.
34 Causes burns.
S-phrases
1/2 Keep locked up and out of reach of children.
26 In case of contact with eyes, rinse immediately with plenty of water and seek medical
advice.
36/37/39 Wear suitable protective clothing, gloves and eye/face protection.
45 In case of accident or if you feel unwell, seek medical advice immediately (show the
lable where possible).
Hazardous ingredients for labeling
ammonium-hydrogendifluoride
National regulations
Classification according to VbF/
remarks
Water hazard class
Other regulations, restrictions and prohibition regulations
ZH 1/161 "Data Sheet: Hydrogen fluoride, hydrofluoric acid and inorganic fluorides (M 005)"
VbF: is not subject to decree for combustible liquids.
1 VwVwS (17. 05. 1999)
16. Other information
Further information
The information contained herein is based on the state of our knowledge. It characterizes the product with
regard to the appropriate safety precautions. It does not represent a guarantee of the poperties of the product.
Wording of the R-phrases specified in chapter 2 (not the classification of the formulation!)
R 25 Toxic if swallowed.
R 34 Causes burns.
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