! 1. Identification of the substance/preparation
Name of product GranQuartz 631C Heavy Duty Cleaner
Manufacturer/distributor
Safety data-sheet (91/155 EEC)
Printed 25.05.2004
Revision 23.01.2004 (GB) Version 1.5
GranQuartz 631C Heavy Duty Cleaner
GranQuartz Stone Care Systems
4963 S.Royal Atlanta Dr., Tucker, GA 30084
Phone 1-800-458-6222
Advice
! Recommended intended purpose(s)
Cleaner
Techn. Department
Phone 1-800-458-6222
2. Composition/information on ingredients
Chemical characterization
Alkaline cleaner
Hazardous ingredients
CAS-No. EC-No. Name [% weight] Classification
- anionic surfactants < 20 Xi R 38-41
000067-63-0 200-661-7 propan-2-ol < 15 F R11; Xi R36; R67
000111-76-2 203-905-0 ethylene glycol monobutyl ether; butylcellosolve < 20 Xn R20/21/22; Xi R36/38
001310-73-2 215-185-5 sodium-hydroxide > 5 C R35
3. Special hazards information for man and environment
R-phrases
35 Causes severe burns.
4. First aid measures
General information
Remove contaminated soaked clothing immediately.
In case of inhalation
Ensure of fresh air.
In the event of symptoms refer for medical treatment.
In case of skin contact
In case of contact with skin wash off immediately with soap and water.
In case of eye contact
In case of contact with eyes rinse thoroughly with plenty of water and seek medical advice.
In case of ingestion
Do not induce vomitting.
If swallowed by mistake drink plenty of water and seek medical treatment.
5. Fire-fighting measures
Suitable extinguishing material
Product does not burn, fire-extinguishing activities according to surrounding.
Extinguishing material that may not be used for safety reasons
Full water jet
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6. Accidental release measures
Personal precautions
Ensure adequate ventilation.
Use personal protective clothing.
Environmental precautions
Do not discharge into the drains/surface waters/groundwater.
Methods for cleaning up/taking up
Take up with absorbent material (e.g. sand, sawdust, general-purpose binder).
7. Handling and storage
Advice on safe handling
Take the usual precautions when handling with chemicals.
Advice on protection against fire and explosion
No special measures necessary.
Requirements for storage rooms and vessels
Do not use glass containers.
Safety data-sheet (91/155 EEC)
Printed 25.05.2004
Revision 23.01.2004 (GB) Version 1.5
GranQuartz 631C Heavy Duty Cleaner
Further information on storage conditions
Keep container dry, tightly closed and store at cool and aired place.
8. Exposure controls / personal protection
Ingredients with occupational exposure limits to be monitored
CAS-No. Name Code [mg/m³] [ml/m³] Remark
000067-63-0 propan-2-ol MAK 500 200 Y
000111-76-2 2-butoxyethanol MAK 98 20 H,Y
001310-73-2 sodium-hydroxide MAK 2 E Y, u.D.
Hand protection
Gloves (alkali-resistant)
Eye protection
safety goggles
Skin protection
Alkali-resistant protective clothing
General protective measures
Avoid contact with eyes and skin
Hygiene measures
At work do not eat, drink and smoke.
9. Physical and chemical properties
Form
liquid
Data relevant for safety
pH value in delivery state
starts to boil
Flash point
Colour
yellowish
Odour
characteristic
Value Temperature at Method Remark
> 12
> 90 °C
> 65 °C
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Density
Safety data-sheet (91/155 EEC)
Printed 25.05.2004
Revision 23.01.2004 (GB) Version 1.5
GranQuartz 631C Heavy Duty Cleaner
Value Temperature at Method Remark
ca. 1,1 g/cm3
Solubility in water
10. Stability and reactivity
Conditions to avoid
Reactions with light metals, with evolution of hydrogen.
Materials to avoid
Reactions with acids.
11. Toxicological information
Acute toxicity/Irritability/Sensitization
LD 50 acute oral
LD 50 acute dermal
LC 50 acute
inhalation
multimiscible
Value/Validation Species Method Remark
not determined
not determined
not determined
12. Ecological information
Data on elimination (persistence and degradability)
Physico-chemical
degradability
Biological
degradability
13. Disposal considerations
Waste code No. Name of waste
06 02 04* sodium and potassium hydroxide
Recommendations for the product
Remove in accordance with local offical regulations.
Recommendations for packaging
Totally emptied packaging may be taken for recycling.
14. Transport information
Land and inland navigation transport (ADR/RID/GGVS/GGVE/ADNR)
Identification
UN-No.
Class
PG
Hazard No.
Elimination rate Method of analysis Method Validation
not determined
not determined
Caustic alkali liquid, n.o.s. (Sodium hydroxide)
1719
8
III
80
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Marine transport IMDG/GGV See
Proper shipping name
UN-No.
Class
PG
Marine pollutant
EmS-No.
Air transport ICAO/IATA
Proper shipping name
UN/ID-No.
Class
PG
15. Regulatory information
Remarks for classification
The product is classified and labelled in accordance with EC directives.
Classification
Corrosive
C
Safety data-sheet (91/155 EEC)
Printed 25.05.2004
Revision 23.01.2004 (GB) Version 1.5
GranQuartz 631C Heavy Duty Cleaner
Caustic alkali liquid, n.o.s., (Sodium hxdroxide)
1719
8
III
No
8-06
Caustic alkali liquid, n.o.s., (Sodium hydroxide; solution)
1719
8
III
R-phrases
35 Causes severe burns.
S-phrases
1/2 Keep locked up and out of reach of children.
26 In case of contact with eyes, rinse immediately with plenty of water and seek medical
36/37/39 Wear suitable protective clothing, gloves and eye/face protection.
45 In case of accident or if you feel unwell, seek medical advice immediately (show the
Hazardous ingredients for labeling
sodium-hydroxide
National regulations
Classification according to VbF/
remarks
Water hazard class
16. Other information
Further information
The information contained herein is based on the state of our knowledge. It characterizes the product with
regard to the appropriate safety precautions. It does not represent a guarantee of the poperties of the product.
advice.
lable where possible).
VbF: is not subject to decree for combustible liquids.
2 VwVwS (17. 05. 1999)
Wording of the R-phrases specified in chapter 2 (not the classification of the formulation!)
R 11 Highly flammable.
R 20/21/22 Harmful by inhalation, in contact with skin and if swallowed.
R 35 Causes severe burns.
R 36 Irritating to eyes.
R 36/38 Irritating to eyes and skin.
R 38 Irritating to skin.
R 41 Risk of serious damage to eyes.
R 67 Vapours may cause drowsiness and dizziness.
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