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! 1. Identification of the substance/preparation
Name of product GranQuartz 539C Ceramic Tile Sanitary Cleaner
Manufacturer/distributor
Safety data-sheet (91/155 EEC)
Printed 25.05.2004
Revision 22.01.2004 (GB) Version 1.5
GranQuartz 539C Ceramic Tile Sanitary Cleaner
GranQuartz Stone Care Systems
4963 S.Royal Atlanta Dr., Tucker, GA 30084
Phone 1-800-458-6222
Advice
Recommended intended purpose(s)
Cleaner
Techn. Department
Phone 1-800-458-6222
2. Composition/information on ingredients
Chemical characterization
Acid cleaner
Hazardous ingredients
CAS-No. EC-No. Name [% weight] Classification
- - nonionic surfactants < 25 Xn R22-41
000067-63-0 200-661-7 propan-2-ol < 15 F R11; Xi R36; R67
007664-38-2 231-633-2 orthophosphoric-acid < 25 C R34
3. Special hazards information for man and environment
R-phrases
36/38 Irritating to eyes and skin.
4. First aid measures
General information
Remove contaminated soaked clothing immediately.
In case of inhalation
Ensure of fresh air.
In the event of symptoms refer for medical treatment.
In case of skin contact
In case of contact with skin wash off immediately with soap and water.
In case of eye contact
In case of contact with eyes rinse thoroughly with plenty of water and seek medical advice.
In case of ingestion
Do not induce vomitting.
If swallowed by mistake drink plenty of water and seek medical treatment.
5. Fire-fighting measures
Suitable extinguishing material
Product does not burn, fire-extinguishing activities according to surrounding.
6. Accidental release measures
Personal precautions
Ensure adequate ventilation.
Use personal protective clothing.
Environmental precautions
Do not discharge into the drains/surface waters/groundwater.
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Methods for cleaning up/taking up
Take up with absorbent material (e.g. sand, sawdust, general-purpose binder).
7. Handling and storage
Advice on safe handling
Use only in well-ventilated areas.
Take the usual precautions when handling with chemicals.
Advice on protection against fire and explosion
No special measures necessary.
Further information on storage conditions
Keep container dry, tightly closed and store at cool and aired place.
8. Exposure controls / personal protection
Ingredients with occupational exposure limits to be monitored
CAS-No. Name Code [mg/m³] [ml/m³] Remark
000067-63-0 propan-2-ol MAK 500 200 Y
Safety data-sheet (91/155 EEC)
Printed 25.05.2004
Revision 22.01.2004 (GB) Version 1.5
GranQuartz 539C Ceramic Tile Sanitary Cleaner
Hand protection
Gloves (acid-resistant)
Eye protection
safety goggles
Skin protection
Acid-resistant protective clothing
General protective measures
Avoid contact with eyes and skin
Hygiene measures
At work do not eat, drink and smoke.
9. Physical and chemical properties
Form
liquid
Data relevant for safety
Value Temperature at Method Remark
pH value in delivery state
starts to boil
Flash point
< 2
> 90 °C
> 65 °C
Colour
green
Odour
pleasant
Density
Solubility in water
10. Stability and reactivity
Conditions to avoid
Reactions with metals, with evolution of hydrogen.
ca. 1,1 g/cm3
multimiscible
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11. Toxicological information
Acute toxicity/Irritability/Sensitization
LD 50 acute oral
Safety data-sheet (91/155 EEC)
Printed 25.05.2004
Revision 22.01.2004 (GB) Version 1.5
GranQuartz 539C Ceramic Tile Sanitary Cleaner
Value/Validation Species Method Remark
not determined
LD 50 acute dermal
LC 50 acute
inhalation
12. Ecological information
Data on elimination (persistence and degradability)
Physico-chemical
degradability
Biological
degradability
13. Disposal considerations
Waste code No. Name of waste
06 01 06* other acids
Recommendations for the product
Remove in accordance with local offical regulations.
not determined
not determined
Elimination rate Method of analysis Method Validation
not determined
not determined
Recommendations for packaging
Totally emptied packaging may be taken for recycling.
14. Transport information
Land and inland navigation transport (ADR/RID/GGVS/GGVE/ADNR)
Identification
UN-No.
Class
PG
Hazard No.
Marine transport IMDG/GGV See
Proper shipping name
UN-No.
Class
PG
Marine pollutant
EmS-No.
Air transport ICAO/IATA
Proper shipping name
UN/ID-No.
Class
PG
corrosive liquid n.o.s. (Phosphoric acid)
1760
8
III
80
Corrosive liquid, n.o.s., (Phosphoric acid)
1760
8
III
No
8-15
Corrosive liquid, n.o.s., (Phosphoric acid; solution)
1760
8
III
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15. Regulatory information
Remarks for classification
The product is classified and labelled in accordance with EC directives.
Classification
Irritant
Xi
R-phrases
36/38 Irritating to eyes and skin.
S-phrases
2 Keep out of the reach of children.
46 If swallowed, seek medical advice immediately and show this container or lable.
National regulations
Classification according to VbF/
remarks
Safety data-sheet (91/155 EEC)
Printed 25.05.2004
Revision 22.01.2004 (GB) Version 1.5
GranQuartz 539C Ceramic Tile Sanitary Cleaner
VbF: is not subject to decree for combustible liquids.
Water hazard class
16. Other information
Further information
The information contained herein is based on the state of our knowledge. It characterizes the product with
regard to the appropriate safety precautions. It does not represent a guarantee of the poperties of the product.
Wording of the R-phrases specified in chapter 2 (not the classification of the formulation!)
R 11 Highly flammable.
R 22 Harmful if swallowed.
R 34 Causes burns.
R 36 Irritating to eyes.
R 41 Risk of serious damage to eyes.
R 67 Vapours may cause drowsiness and dizziness.
2 VwVwS (17. 05. 1999)
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