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! 1. Identification of the substance/preparation
Name of product GranQuartz 357E Venezian Stone Sealer
Manufacturer/distributor
Safety data-sheet (91/155 EEC)
Printed 25.05.2004
Revision 28.03.2003 (GB) Version 1.3
GranQuartz 357E Venezian Stone Sealer
GranQuartz Stone Care Systems
4963 S.Royal Atlanta Dr., Tucker, GA 30084
Phone 1-800-458-6222
Advice
Recommended intended purpose(s)
Sealer
Techn. Department
Phone 1-800-458-6222
2. Composition/information on ingredients
Chemical characterization
Solvent based sealer
Hazardous ingredients
CAS-No. EC-No. Name [% weight] Classification
001330-20-7 215-535-7 xylene < 20 R10; Xn R20/21; Xi R38
064742-95-6 265-199-0 Solvent naphtha (petroleum), light arom. > 25 Carc.Cat.2 R45; Xn R65
Additional advice
Benzene < 0,1 %
3. Special hazards information for man and environment
R-phrases
10 Flammable.
20/21 Harmful by inhalation and in contact with skin.
37 Irritating to respiratory system.
51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
4. First aid measures
General information
Remove contaminated soaked clothing immediately.
In case of inhalation
Ensure of fresh air.
In the event of symptoms refer for medical treatment.
In case of skin contact
In case of contact with skin wash off immediately with soap and water.
In case of eye contact
In case of contact with eyes rinse thoroughly with plenty of water and seek medical advice.
In case of ingestion
Do not induce vomitting.
If swallowed by mistake drink plenty of water and seek medical treatment.
5. Fire-fighting measures
Suitable extinguishing material
Foam
Dry powder
Carbon dioxide
sand
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Extinguishing material that may not be used for safety reasons
Full water jet
Special exposure hazards arising from the substance, combustible products or resulting gases
In case of fire formation of dangerous gases possible.
6. Accidental release measures
Personal precautions
Ensure adequate ventilation.
Use personal protective clothing.
Environmental precautions
Do not discharge into the drains/surface waters/groundwater.
Methods for cleaning up/taking up
Take up with absorbent material (e.g. sand, sawdust, general-purpose binder).
7. Handling and storage
Advice on safe handling
Use only in thoroughly ventilated areas.
Use solvent-resistant equipment.
Take the usual precautions when handling with chemicals.
Safety data-sheet (91/155 EEC)
Printed 25.05.2004
Revision 28.03.2003 (GB) Version 1.3
GranQuartz 357E Venezian Stone Sealer
Advice on protection against fire and explosion
Keep away from sources of ignition - No smoking
Take precautionary measures against static discharges.
Further information on storage conditions
Keep container dry, tightly closed and store at cool and aired place.
8. Exposure controls / personal protection
Ingredients with occupational exposure limits to be monitored
CAS-No. Name Code [mg/m³] [ml/m³] Remark
naphtha (petroleum), arom. > 25 % MAK 200 50 31, TRGS 901-
001330-20-7 Xylol (alle Isomeren) MAK 440 100 H
Respiratory protection
Breathing apparatus in the event of high concentrations.
Short term: filter apparatus, filter A
Hand protection
chemical-resistant gloves
Eye protection
safety goggles
General protective measures
Avoid contact with eyes and skin
Hygiene measures
At work do not eat, drink and smoke.
72
9. Physical and chemical properties
Form
liquid
Colour
colourless, clear
Odour
aromatic
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Data relevant for safety
pH value in delivery state
Safety data-sheet (91/155 EEC)
Printed 25.05.2004
Revision 28.03.2003 (GB) Version 1.3
GranQuartz 357E Venezian Stone Sealer
Value Temperature at Method Remark
not applicable
starts to boil
Flash point
Lower explosion limit
Upper explosion limit
Density
Solubility in water
Viscosity 1 Outflow time
10. Stability and reactivity
Conditions to avoid
No hazardous reactions known.
11. Toxicological information
Acute toxicity/Irritability/Sensitization
> 130 °C
> 23 °C
ca. 0,6 Vol-%
ca. 8 Vol-%
ca. 0,9 g/cm3
more or
less
insoluble
> 30 s ISO 2431/3 mm
LD 50 acute oral
LD 50 acute dermal
LC 50 acute
inhalation
12. Ecological information
Data on elimination (persistence and degradability)
Physico-chemical
degradability
Biological
degradability
! 13. Disposal considerations
! Waste code No. Name of waste
07 01 04* other organic solvents, washing liquids and mother liquors
Value/Validation Species Method Remark
not determined
not determined
not determined
Elimination rate Method of analysis Method Validation
not determined
not determined
Recommendations for the product
In accordance with regulations for special waste, must be taken to a special waste disposal.
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Recommendations for packaging
Totally emptied packaging may be taken for recycling.
14. Transport information
Land and inland navigation transport (ADR/RID/GGVS/GGVE/ADNR)
Identification
UN-No.
Class
PG
Hazard No.
Marine transport IMDG/GGV See
Proper shipping name
UN-No.
Class
PG
Marine pollutant
EmS-No.
Air transport ICAO/IATA
Proper shipping name
UN/ID-No.
Class
PG
Safety data-sheet (91/155 EEC)
Printed 25.05.2004
Revision 28.03.2003 (GB) Version 1.3
GranQuartz 357E Venezian Stone Sealer
Flammable liquid, n.o.s. (White spirit) special provision 640
1993
3
III
30
Flammable liquid, n.o.s., (White spirit)
1993
3
III
No
3-07
Flammable liquid, n.o.s. (White Spirit)
1993
3
III
15. Regulatory information
Remarks for classification
The product is classified and labelled in accordance with EC directives.
Classification
Harmful
Xn
Dangerous for the environment
N
R-phrases
10 Flammable.
20/21 Harmful by inhalation and in contact with skin.
37 Irritating to respiratory system.
51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
S-phrases
2 Keep out of the reach of children.
23.3 Do not breathe vapour.
24 Avoid contact with skin.
46 If swallowed, seek medical advice immediately and show this container or lable.
Hazardous ingredients for labeling
xylene
National regulations
Classification according to VbF/
remarks
AII
Water hazard class
2 VwVwS (17. 05. 1999)
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16. Other information
Further information
The information contained herein is based on the state of our knowledge. It characterizes the product with
regard to the appropriate safety precautions. It does not represent a guarantee of the poperties of the product.
Wording of the R-phrases specified in chapter 2 (not the classification of the formulation!)
R 10 Flammable.
R 20/21 Harmful by inhalation and in contact with skin.
R 38 Irritating to skin.
R 45 May cause cancer.
R 65 Harmful: may cause lung damage if swallowed.
Safety data-sheet (91/155 EEC)
Printed 25.05.2004
Revision 28.03.2003 (GB) Version 1.3
GranQuartz 357E Venezian Stone Sealer
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