! 1. Identification of the substance/preparation
Name of product GranQuartz 207R Marble Polishing Powder
Manufacturer/distributor
Safety data-sheet (91/155 EEC)
Printed 25.05.2004
Revision 23.01.2004 (GB) Version 1.5
GranQuartz 207R Marble Polishing Powder
GranQuartz Stone Care Systems
4963 S.Royal Atlanta Dr., Tucker, GA 30084
Phone 1-800-458-6222
Advice
Techn. Department
Phone 1-800-458-6222
2. Composition/information on ingredients
Chemical characterization
Oxalate based polishing powder
Hazardous ingredients
CAS-No. EC-No. Name [% weight] Classification
000144-62-7 205-634-3 oxalic-acid > 5 Xn R21/22
Additional advice
Benzene < 0,1 %
3. Special hazards information for man and environment
R-phrases
21/22 Harmful in contact with skin and if swallowed.
4. First aid measures
General information
Remove contaminated soaked clothing immediately.
In case of inhalation
Ensure of fresh air.
In the event of symptoms refer for medical treatment.
In case of skin contact
In case of contact with skin wash off immediately with soap and water.
In case of eye contact
In case of contact with eyes rinse thoroughly with plenty of water and seek medical advice.
In case of ingestion
Do not induce vomitting.
If swallowed by mistake drink plenty of water and seek medical treatment.
5. Fire-fighting measures
Suitable extinguishing material
Foam
Dry powder
Carbon dioxide
sand
Extinguishing material that may not be used for safety reasons
Full water jet
Special exposure hazards arising from the substance, combustible products or resulting gases
In case of fire formation of dangerous gases possible.
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6. Accidental release measures
Personal precautions
Ensure adequate ventilation.
Use personal protective clothing.
Environmental precautions
Do not discharge into the drains/surface waters/groundwater.
Methods for cleaning up/taking up
Take up mechanically.
7. Handling and storage
Advice on safe handling
Avoid the formation of dust.
Use only in thoroughly ventilated areas.
Take the usual precautions when handling with chemicals.
Advice on protection against fire and explosion
Keep away from sources of ignition - No smoking
Further information on storage conditions
Keep container dry, tightly closed and store at cool and aired place.
Safety data-sheet (91/155 EEC)
Printed 25.05.2004
Revision 23.01.2004 (GB) Version 1.5
GranQuartz 207R Marble Polishing Powder
8. Exposure controls / personal protection
Ingredients with occupational exposure limits to be monitored
CAS-No. Name Code [mg/m³] [ml/m³] Remark
000144-62-7 oxalic-acid MAK, EU 1 E H
Respiratory protection
Breathing apparatus in the event of high concentrations.
Short term: filter apparatus, Filter P2
Hand protection
chemical-resistant gloves
Eye protection
safety goggles
Skin protection
Acid-resistant protective clothing
General protective measures
Avoid contact with eyes and skin
Hygiene measures
At work do not eat, drink and smoke.
9. Physical and chemical properties
Form
powder
Colour
whitish
Odour
pungent
Data relevant for safety
pH value in delivery state
decomposition point
Value Temperature at Method Remark
not applicable
ab 102 °C
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Flash point
Safety data-sheet (91/155 EEC)
Printed 25.05.2004
Revision 23.01.2004 (GB) Version 1.5
GranQuartz 207R Marble Polishing Powder
Value Temperature at Method Remark
not applicable
Bulk density
Solubility in water
10. Stability and reactivity
Conditions to avoid
No hazardous reactions known.
Materials to avoid
Reactions with oxidising agents.
Risk of dust explosions
Reactions with alkalies.
Hazardous decomposition products
Carbon monoxide
Carbon dioxide
11. Toxicological information
Acute toxicity/Irritability/Sensitization
LD 50 acute oral
ca. 1 kg/m3
partially
soluble
Value/Validation Species Method Remark
not determined
LD 50 acute dermal
LC 50 acute
inhalation
12. Ecological information
Data on elimination (persistence and degradability)
Physico-chemical
degradability
Biological
degradability
13. Disposal considerations
Waste code No. Name of waste
06 01 06* other acids
Recommendations for the product
In accordance with regulations for special waste, must be taken to a special waste disposal.
not determined
not determined
Elimination rate Method of analysis Method Validation
not determined
not determined
Recommendations for packaging
Totally emptied packaging may be taken for recycling.
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14. Transport information
Land and inland navigation transport (ADR/RID/GGVS/GGVE/ADNR)
Identification
Marine transport IMDG/GGV See
Proper shipping name
Air transport ICAO/IATA
Proper shipping name
15. Regulatory information
Remarks for classification
The product is classified and labelled in accordance with EC directives.
Classification
Harmful
Xn
R-phrases
21/22 Harmful in contact with skin and if swallowed.
S-phrases
2 Keep out of the reach of children.
24/25 Avoid contact with skin and eyes.
36/37/39 Wear suitable protective clothing, gloves and eye/face protection.
46 If swallowed, seek medical advice immediately and show this container or lable.
Safety data-sheet (91/155 EEC)
Printed 25.05.2004
Revision 23.01.2004 (GB) Version 1.5
GranQuartz 207R Marble Polishing Powder
no dangerous good
no dangerous good
no dangerous good
Hazardous ingredients for labeling
oxalic-acid
National regulations
Classification according to VbF/
remarks
Water hazard class
16. Other information
Further information
The information contained herein is based on the state of our knowledge. It characterizes the product with
regard to the appropriate safety precautions. It does not represent a guarantee of the poperties of the product.
Wording of the R-phrases specified in chapter 2 (not the classification of the formulation!)
R 21/22 Harmful in contact with skin and if swallowed.
VbF: is not subject to decree for combustible liquids.
1 VwVwS (17. 05. 1999)
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