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MATERIAL SAFETY DATA SHEET
Product number
152-000P
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1. Product and Company Identification
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Product name Cirque de Citron
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Effective date
24-Jun-2011
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Company information
Claire Manufacturing Co.
1005 S. Westgate Drive
Addison, IL 60101 United States
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Company phone
General Assistance 630-543-7600
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Emergency telephone US
800-424-9300
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Emergency telephone outside US
703-527-3887
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Version #
01
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Emergency overview
Flammable. Aerosol. CONTENTS UNDER PRESSURE.
Will be easily ignited by heat, spark or flames. Harmful in contact with eyes.
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2. Hazards Identification
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Eyes
Contact may irritate or burn eyes. Health injuries are not known or expected under
normal use.
Potential health effects
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Skin
Health injuries are not known or expected under normal use.
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Inhalation
Intentional misuse by concentrating and inhaling the product can be harmful or fatal.
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Ingestion
Exposure by ingestion of an aerosol is unlikely.
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Target organs
Central nervous system.
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Chronic effects
May cause central nervous system disorder (e.g., narcosis involving a loss of
coordination, weakness, fatigue, mental confusion and blurred vision) and/or damage.
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Signs and symptoms
Narcosis.
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CAS # Percent
60 - 7067-64-1
Components
Acetone
10 - 1574-98-6Propane
10 - 15106-97-8n-Butane
2.5 - 10Non-hazardous and other components below reportable levels
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3. Composition / Information on Ingredients
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Eye contact
Immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention
immediately.
First aid procedures
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4. First Aid Measures
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Skin contact
Immediately take off all contaminated clothing. Wash off with soap and water. Get
medical attention if irritation develops or persists.
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Inhalation
If symptoms develop move victim to fresh air. Get medical attention if symptoms persist.
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Ingestion
In the unlikely event of swallowing contact a physician or poison control center.
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Notes to physician
Symptoms may be delayed.
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Flammable properties
Vapor or gas may spread to distant ignition sources and flash back. Runoff to sewer may
cause fire or explosion hazard.
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5. Fire Fighting Measures
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Suitable extinguishing media
Water fog. Foam. Alcohol foam. Dry chemical. Carbon dioxide (CO2).
Extinguishing media
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Product name: Cirque de Cit ron
Product #: 152-000P Revision date: 24-JUN-2011 Print date: 24-JUN-2011
MSDS US
1 / 5
13611
Pro Link Citron Metered Air Freshener
Pro Link Inc
Canton, MA 02021 United States
1.800.74.LINKS
Pro Link Citron Metered Air Freshener
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Protective equipment and
precautions for firefighters
In case of fire and/or explosion do not breathe fumes. Containers should be cooled with
water to prevent vapor pressure build up.
Protection of firefighters
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Methods for containment
Stop leak if you can do so without risk. Move the cylinder to a safe and open area if the
leak is irreparable. Stop the flow of material, if this is without risk.
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6. Accidental Release Measures
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Methods for cleaning up
Use a non-combustible material like vermiculite, sand or earth to soak up the product
and place into a container for later disposal.
Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface
thoroughly to remove residual contamination.
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Handling
Pressurized container: Do not pierce or burn, even after use. Do not smoke while using
or until sprayed surface is thoroughly dry. Use only in area provided with appropriate
exhaust ventilation. Do not use if spray button is missing or defective. Do not re-use
empty containers. Avoid prolonged exposure.
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7. Handling and Storage
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Storage
Contents under pressure. Do not puncture, incinerate or crush. The pressure in sealed
containers can increase under the influence of heat. Keep away from heat, sparks, and
flame. Avoid exposure to long periods of sunlight. Store in cool place. Keep in an area
equipped with sprinklers. Keep out of the reach of children. Keep away from food, drink
and animal feedingstuffs. Level 3 Aerosol.
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Exposure limits
ACGIH
Components
CAS #
Acetone 67-64-1
TWA
500 ppm
STEL
750 ppm
Ceiling
Not established
Propane 74-98-6 1000 ppm Not established Not established
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n-Butane 106-97-8 1000 ppm Not established Not established
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8. Exposure Controls / Personal Protection
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OSHA
Components
CAS #
Acetone 67-64-1
TWA
1000 ppm
STEL
Not established
Ceiling
Not established
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Propane 74-98-6 1000 ppm Not established Not established
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Eye / face protection
Do not get in eyes. Wear safety glasses with side shields (or goggles).
Personal protective equipment
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Skin protection
Not normally needed.
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Respiratory protection
When workers are facing concentrations above the exposure limit they must use
appropriate certified respirators. If permissible levels are exceeded use NIOSH
mechanical filter / organic vapor cartridge or an air-supplied respirator.
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Appearance
Compressed liquefied gas.
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9. Physical & Chemical Properties
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Boiling point
82.4 °F (27.8 °C) estimated
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Color
Clear.
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Density
0.7197 g/cm3 estimated
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Flammability (HOC)
32.5503 kJ/g estimated
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Flash back
No
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Flash point
-156 °F (-104.4 °C) Propellant
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Form
Aerosol.
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Freezing point
Not available
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Odor
Pleasant.
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pH
Not applicable
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Product name: Cirque de Cit ron
Product #: 152-000P Revision date: 24-JUN-2011 Print date: 24-JUN-2011
MSDS US
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Pro Link Citron Metered Air Freshener
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Physical state
Liquid.
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Pressure
45 - 65 psig @ 70F
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Solubility
Partially
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Specific gravity
0.7198 estimated
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Chemical stability
Stable at normal conditions. Risk of ignition.
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10. Chemical Stability & Reactivity Information
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Conditions to avoid
Heat, flames and sparks.
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Incompatible materials
Strong oxidizing agents.
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Hazardous decomposition products
May include oxides of carbon.
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Acute effects
Acute LD50: 28718 mg/kg estimated, Rat, Dermal
Acute LC50: 105 mg/l/4h estimated, Rat, Inhalation
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11. Toxicological Information
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Component analysis - LD50
Toxicology Data - Selected LD50s and LC50s
67-64-1 Oral LD50 Rat 5800 mg/kg
A
cetone
106-97-8 Inhalation LC50 Rat 658 mg/L 4 hn-Butane
74-98-6 Inhalation LC50 Rat 658 mg/L 4 hPropane
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Sensitization
Not expected to be hazardous by OSHA criteria.
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Teratogenicity
Not expected to be hazardous by OSHA criteria.
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Ecotoxicity
LC50 7790 mg/L, Fish, 96.00 Hours,
EC50 19011 mg/L, Daphnia, 48.00 Hours,
Components of this product have been identified as having potential environmental
concerns.
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12. Ecological Information
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Waste codes
D001: Waste Flammable material with a flash point <140 F
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13. Disposal Considerations
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Disposal instructions
Contents under pressure. Dispose of this material and its container to hazardous or
special waste collection point. Do not incinerate sealed containers. If discarded, this
product is considered a RCRA ignitable waste, D001. Dispose in accordance with all
applicable regulations.
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Department of Transportation (DOT) Requirements
Consumer commodity
ORM-D
None
Hazard class
Subsidiary hazard class
Proper shipping name
Basic shipping requirements:
156, 306
156, 306
None
Packaging exceptions
Packaging non bulk
Packaging bulk
Additional information:
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14. Transport Information
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Product name: Cirque de Cit ron
Product #: 152-000P Revision date: 24-JUN-2011 Print date: 24-JUN-2011
MSDS US
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Pro Link Citron Metered Air Freshener
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IMDG
AEROSOLS
2.1
1950
Hazard class
UN number
Proper shipping name
Basic shipping requirements:
LTD QTY
5F
None
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Packaging exceptions
Item
Labels required
Transport Category
Additional information:
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IATA
Aerosols, flammable
2.1
1950
Hazard class
UN number
Proper shipping name
Basic shipping requirements:
LTD QTY
2.1
Packaging exceptions
Labels required
Additional information:
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US federal regulations
This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.
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15. Regulatory Information
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29 CFR 1910.1200 hazardous
chemical
Yes
Occupational Safety and Health Administration (OSHA)
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Acetone: 5000.0000
CERCLA (Superfund) reportable quantity
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Section 302 extremely
hazardous substance
No
Superfund Amendments and Reauthorization Act of 1986 (SARA)
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Section 311 hazardous chemical
Yes
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Hazard categories (311/312)
Immediate Hazard - Yes
Delayed Hazard - No
Fire Hazard - Yes
Pressure Hazard - Yes
Reactivity Hazard - No
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Inventory status
Country(s) or region Inventory name On inventory (yes/no)*
No
No
No
No
No
China
Europe
Europe
Japan
Korea
Inventory of Existing Chemical Substances in China (IECSC)
European Inventory of New and Existing Chemicals (EINECS)
European List of Notified Chemical Substances (ELINCS)
Inventory of Existing and New Chemical Substances (ENCS)
Existing Chemicals List (ECL)
Yes
A
"Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)
United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory
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State regulations
U.S. - Pennsylvania - RTK (Right to Know) List
67-64-1 Environmental hazard
A
cetone
106-97-8 Presentn-Butane
74-98-6 PresentPropane
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Further information
HMIS® is a registered trade and service mark of the NPCA.
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16. Other Information
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Product name: Cirque de Cit ron
Product #: 152-000P Revision date: 24-JUN-2011 Print date: 24-JUN-2011
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Pro Link Citron Metered Air Freshener
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HMIS® ratings
Health: 1
Flammability: 4
Physical hazard: 0
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Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our
knowledge, information and belief at the date of its publication. The information given is
designed only as a guidance for safe handling, use, processing, storage, transportation,
disposal and release and is not to be considered a warranty or quality specification. The
information relates only to the specific material designated and may not be valid for such
material used in combination with any other materials or in any process, unless specified
in the text. The information in the sheet was written based on the best knowledge and
experience currently available.
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Prepared by
Regulatory Compliance
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Product name: Cirque de Cit ron
Product #: 152-000P Revision date: 24-JUN-2011 Print date: 24-JUN-2011
MSDS US
5 / 5
Pro Link Citron Metered Air Freshener
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