Material Safety Data Sheet
Printed: 13.06.2005
Revised: 13.06.2005
Lithofin OIL-EX
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1 Identification of substance:
Product details:
Trade name: Lithofin OIL-EX
Application of the substance / the preparation Cleaner
Distributor:
GranQuartz, L. P.
P.O. Box 2206
Tucker, GA 30085-2206/USA
Information Department:
see above
Emergency Information:
information department
24-Hour Emergency Telephone Number:
1-800-255-3924 (USA & Canada) or 813-248-0585
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2 Composition/Data on components:
Chemical characterization
Description: Solvent based cleaner
Dangerous components:
64742-82-1 Naphta, hydrodesulfurized heavy with < 1%benzene 90 %
1330-20-7 xylene, mixed isomers, pure 2.5-10 %
RTECS: ZE 2100000
95-63-6 1,2,4-trimethylbenzene < 2.5 %
100-41-4 ethylbenzene < 2.5 %
RTECS: DA 0700000
Additional information
Benzene < 0,1 %
For further components with limit values which require monitoring at the workplace please see chapter
8.
TSCA
1330-20-7 xylene, mixed isomers, pure
95-63-6 1,2,4-trimethylbenzene
100-41-4 ethylbenzene
112926-00-8 Silica, amorphous
64742-82-1 naphtha (petroleum), hydrodesulfurized heavy
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3 Hazards identification
Hazard description: Dangerous for the environment
Information pertaining to particular dangers for man and environment
Flammable.
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
Classification system
The classification is in line with internationally approved calculation standards. It is expanded,
however, by information from technical literature and by information furnished by supplier companies.
NFPA ratings (scale 0-4)
Health = 2
Fire = 3
Reactivity = 0
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4 First aid measures
1
Material Safety Data Sheet
Printed: 13.06.2005
Revised: 13.06.2005
Lithofin OIL-EX
General information
Immediately remove any clothing soiled by the product.
After inhalation
Remove victim from contaminated area. If breathing is difficult, give oxygen. If breathing stops, provide
artificial respiration. Call a doctor.
After skin contact
Clean effected skin thoroughly with water and a mild cleansing agent.
No residues shall remain on the skin.
After eye contact
Rinse opened eye for several minutes under running water.
Seek medical treatment.
After swallowing
Rinse mouth with water.
Do not induce vomiting
Seek medical treatment.
If vomiting occurs spontaneously: Hold the head of the casualty low with the body in a prone position
in order to avoid penetration of vomit into the air tube.
If babies/toddlers are concerned always consult a physician or the local Poison Information Centre.
Information for doctor
Treatment Symptomatic treatment
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5 Fire fighting measures
Suitable extinguishing agents
Foam
Extinguishing powder
Carbon dioxide
Sand
Use fire fighting measures that suit the environment.
For safety reasons unsuitable extinguishing agents Water with full jet.
Special hazards caused by the material, its products of combustion or resulting gases:
Dangerous decomposition products see chapter 10: stability and reactivity
Protective equipment:
Wear self-contained respiratory protective device.
Additional information
Dispose of fire debris and contaminated fire fighting water in accordance with official regulations.
Collect contaminated fire fighting water separately. It must not enter the sewage system.
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6 Accidental release measures
Person-related safety precautions:
Ensure adequate ventilation
Wear protective clothing.
Keep unprotected persons away.
Measures for environmental protection:
Do not allow product to reach sewage system or any water course.
Inform respective authorities in case of seepage into water course or sewage system.
Do not allow to penetrate the ground/soil.
In case of seepage into the ground inform responsible authorities.
Measures for cleaning/collecting:
Absorb with non-combustible material like sand, soil, diatomite.
Ensure adequate ventilation.
Send for recovery or disposal in suitable receptacles.
Dispose contaminated material as waste according to item 13.
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7 Handling and storage
Handling
Information for safe handling:
2
Material Safety Data Sheet
Printed: 13.06.2005
Revised: 13.06.2005
Lithofin OIL-EX
Use only in well ventilated areas.
Avoid contact with eyes and skin.
Keep receptacles tightly sealed.
Use solvent-proof equipment.
Avoid inhalation of vapours.
Information about protection against explosions and fires:
Keep ignition sources away - Do not smoke.
Protect against electrostatic charges.
Storage
Requirements to be met by storerooms and receptacles:
Store receptacles tightly closed at a cool and dry place with sufficient ventilation
Provide solvent resistant, sealed floor.
Prevent any seepage into the ground.
Information about storage in one common storage facility:
Store away from foodstuffs.
Store away from feed.
Further information about storage conditions: None.
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8 Exposure controls and personal protection
Additional information about design of technical systems:
No further data; see item 7.
Components with limit values that require monitoring at the workplace:
112926-00-8 Silica, amorphous
PEL: Short-term value: 80 mg/m³
as % SiO2
REL: 6 mg/m³
TLV: 10 mg/m³ (e)
1330-20-7 xylene, mixed isomers, pure
PEL: 435 mg/m³, 100 ppm
REL: Short-term value: 655 mg/m³, 150 ppm
Long-term value: 435 mg/m³, 100 ppm
(o-, m-, & p-isomers)
TLV: Short-term value: 651 mg/m³, 150 ppm
Long-term value: 434 mg/m³, 100 ppm
BEI
95-63-6 1,2,4-trimethylbenzene
REL: 125 mg/m³, 25 ppm
TLV: 123 mg/m³, 25 ppm
100-41-4 ethylbenzene
PEL: 435 mg/m³, 100 ppm
REL: Short-term value: 545 mg/m³, 125 ppm
Long-term value: 435 mg/m³, 100 ppm
TLV: Short-term value: 543 mg/m³, 125 ppm
Long-term value: 434 mg/m³, 100 ppm
BEI
Additional information:
The lists that were valid during the creation were used as basis.
Personal protective equipment
General protective and hygienic measures
Keep away from foodstuffs, beverages and feed.
Wash hands before breaks and at the end of work.
Avoid contact with the eyes and skin.
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Material Safety Data Sheet
Printed: 13.06.2005
Revised: 13.06.2005
Lithofin OIL-EX
Do not inhale dust / smoke / mist.
Do not eat or drink while working.
Use skin protection cream for skin protection.
The usual protective measures based on the application have to be followed.
All protective equipment used shall be according to 29 CFR.1910 Subpart I Personal Protective
Equipment
Breathing equipment:
Not necessary if room is well-ventilated.
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer
exposure use respiratory protective device that is independent of circulating air.
Short term filter device:
Filter A
NIOSH/MSHA-approved respirator
Protection of hands:
Wear chemically resistant protective gloves (tested according to DIN EN 374)
The glove material has to be impermeable and resistant to the product/ the substance/ the
preparation.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the
degradation. After use of gloves apply skin-cleaning agents and skin cosmetics.
Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of
quality and varies from manufacturer to manufacturer.
Penetration time of glove material
The exact break trough time has to be found out by the manufacturer of the protective gloves and has
to be observed.
Eye protection: Chemical safety goggles
Body protection: Protective work clothing.
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9 Physical and chemical properties:
General Information
Form: Pasty
Color: Whitish
Odor: Aromatic
Value/Range Unit Method
Change in condition
Melting point/Melting range: undetermined
Boiling point/Boiling range: > 130 ° C
Flash point: > 23 ° C
Auto igniting: Product is not self igniting.
Danger of explosion: Product is not explosive. However, formation of explosive
air/vapour mixtures are possible.
Explosion limits:
Lower: ~ 0.6 Vol %
Upper: ~ 8.0 Vol %
Density: at 20° C ~ 0.8 g/cm³
Solubility in / Miscibility with
Water: Insoluble
Viscosity:
dynamic: at 20° C > 30 s
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10 Stability and reactivity
4
Material Safety Data Sheet
Printed: 13.06.2005
Revised: 13.06.2005
Lithofin OIL-EX
Thermal decomposition / conditions to be avoided:
No decomposition if used and stored according to specifications.
Dangerous reactions No dangerous reactions known
Dangerous products of decomposition:
In the case of fire or at high temperatures the formation of the following decomposition products is
possible: Carbon monoxide and carbon dioxide
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11 Toxicological information
Acute toxicity:
LD/LC50 values that are relevant for classification:
100-41-4 ethylbenzene
Oral: LD50: 3500 mg/kg (rat)
Dermal: LD50: 17800 mg/kg (rabbit)
1330-20-7 xylene, mixed isomers, pure
Oral: LD50: 4300 mg/kg (rat)
Dermal: LD50: 2000 mg/kg (rabbit)
Inhalative: LC50/4 h: 6350 mg/l (rat)
Primary irritant effect:
on the skin:
Prolonged or repeated exposure may cause slight skin irritation.
on the eye: No irritating effect.
Sensitization: No sensitizing effects known.
Additional toxicological information:
Inhalation of concentrated vapours as well as oral intake will lead to anaesthesia-like conditions and
headache, dizziness, etc.
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12 Ecological information:
Ecotoxical effects:
Acquatic toxicity:
Presently there are no ecotoxicological values available.
Remark:
Toxic for fish
Toxic for water fleas
Toxic for algae
General notes:
Follow the instructions for use of the producer or supplier.
Do not allow product to reach ground water, water course or sewage system.
Danger to drinking water if even small quantities leak into the ground.
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13 Disposal considerations
Product:
Recommendation
Must not be disposed of together with household garbage. Do not allow product to reach sewage
system. Disposal according to instructions of local authorities.
Unclean packaging:
Recommendation:
Disposal must be made according to official regulations.
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14 Transport information
DOT regulations:
Hazard class: 3
Identification number: UN1993
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Material Safety Data Sheet
Printed: 13.06.2005
Revised: 13.06.2005
Lithofin OIL-EX
Packing group: III
Proper shipping name (technical name):
FLAMMABLE LIQUID, N.O.S. (naphtha (petroleum),
hydrodesulphurized heavy)
Label 3
Land transport ADR/RID (cross-border)
ADR/RID class: 3 (F1) Flammable liquids
Danger code (Kemler): 30
UN-Number: 1993
Packaging group: III
Label 3
Description of goods: 1993 FLAMMABLE LIQUID, N.O.S., special provision 640E (naphtha
(petroleum), hydrodesulphurized heavy)
Maritime transport IMDG:
IMDG Class: 3
UN Number: 1993
Label 3
Packaging group: III
EMS Number: F-E S-E
Marine pollutant: No
Proper shipping name: FLAMMABLE LIQUID, N.O.S. (naphtha (petroleum),
hydrodesulphurized heavy)
Air transport ICAO-TI and IATA-DGR:
ICAO/IATA Class: 3
UN/ID Number: 1993
Label 3
Packaging group: III
Proper shipping name: FLAMMABLE LIQUID, N.O.S. (naphtha (petroleum),
hydrodesulphurized heavy)
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15 Regulations
Cancerogenity categories
EPA (Environmental Protection Agency)
1330-20-7 xylene, mixed isomers, pure: D
100-41-4 ethylbenzene: D
IARC (International Agency for Research on Cancer)
112926-00-8 Silica, amorphous: 3
1330-20-7 xylene, mixed isomers, pure: 3
100-41-4 ethylbenzene: 2B
NTP (National Toxicology Program)
void
TLV (Threshold Limit Value established by ACGIH)
1330-20-7 xylene, mixed isomers, pure: A4
MAK (German Maximum Workplace Concentration)
void
NIOSH-Ca (National Institute for Occupational Safety and Health)
void
OSHA-Ca (Occupational Safety & Health Administration)
void
Markings according to EU guidelines:
The product has been classified and marked in accordance with directives on hazardous materials.
Code letter and hazard designation of product:
Dangerous for the environment
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Material Safety Data Sheet
Printed: 13.06.2005
Revised: 13.06.2005
Lithofin OIL-EX
Risk phrases:
Flammable.
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
Safety phrases:
Keep out of the reach of children.
Do not breathe fumes
Do not empty into drains, dispose of this material and its container at hazardous or special waste
collection point
Wear suitable protective clothing.
If swallowed, seek medical advice immediately and show this container or label.
Regulation or reporting requirements USA
Sara section 355
not listed
Sara section 313
1330-20-7 xylene, mixed isomers, pure
95-63-6 1,2,4-trimethylbenzene
100-41-4 ethylbenzene
Prop. 65 - Cancer
not listed
Prop. 65 - Repr. tox.
not listed
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16 Other information:
This information is based on our present knowledge. However, this shall not constitute a guarantee for
any specific product features and shall not establish a legally valid contractual relationship.
Department issuing MSDS:
KFT-Chemieservice Marienstr. 3 D-64347 Griesheim
Postfach 1451 D-64345 Griesheim
Tel.: +49-6155-823241
Fax: +49-6155-823246
Contact: Angelika Torges
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