PPG Industries LN-901 DATA SHEET

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LN-901 HEAVY DUTY AHE90112TN0

Not available. Liquid.

SAFETY DATA SHEET

Product name

Other means of identification

Product type

Section 1. Identification

: :

Product code

00407693

Date of issue/Date of revision

3 April 2019

Version

Relevant identified uses of the substance or mixture and uses advised against

Uses advised against

Not applicable.

Product use

Consumer applications, Professional applications.

Use of the substance/ mixture

Adhesive.

Manufacturer

PPG Industries, Inc. One PPG Place Pittsburgh, PA 15272

(412) 434-4515 (U.S.) (514) 645-1320 (Canada) 01-800-00-21-400 or + 52 55 5559 1588 (Mexico)

Emergency telephone number

Technical Phone Number

1-800-441-9695 (8:00 am to 5:00 pm EST)

Section 2. Hazards identification

FLAMMABLE LIQUIDS - Category 2 SKIN IRRITATION - Category 2 GERM CELL MUTAGENICITY - Category 1 CARCINOGENICITY - Category 1A TOXIC TO REPRODUCTION (Fertility) - Category 2 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2

Classification of the substance or mixture

Percentage of the mixture consisting of ingredient(s) of unknown toxicity: 7.8% (Oral),

96.5% (Dermal), 82.3% (Inhalation)

OSHA/HCS status

This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200).

This product contains TiO2 which has been classified as a GHS Carcinogen Category 2 based on its IARC 2B classification. For many PPG products, TiO2 is utilized as a raw material in a liquid coating formulation. In this case, the TiO2 particles are bound in a matrix with no meaningful potential for human exposure to unbound particles of TiO2 when the product is applied with a brush or roller. Sanding the coating surface or mist from spray applications may be harmful depending on the duration and level of exposure and require the use of appropriate personal protective equipment and/or engineering controls (see Section 8).

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Product name

Product code

Date of issue

Version

00407693

3 April 2019

Section 2. Hazards identification

Signal word

Danger

Hazard statements

Highly flammable liquid and vapor. Causes skin irritation. May cause genetic defects. May cause cancer. Suspected of damaging fertility. May cause damage to organs through prolonged or repeated exposure.

Hazard pictograms

Precautionary statements

Prevention

Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wear protective gloves. Wear eye or face protection. Wear protective clothing. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Use explosion-proof electrical, ventilating, lighting and all material-handling equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Keep container tightly closed. Do not breathe vapor. Wash hands thoroughly after handling.

Response

Get medical attention if you feel unwell. IF exposed or concerned: Get medical attention. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower. IF ON SKIN: Wash with plenty of soap and water. Take off contaminated clothing and wash it before reuse. If skin irritation occurs: Get medical attention.

Storage

Store locked up. Store in a well-ventilated place. Keep cool.

Disposal

Dispose of contents and container in accordance with all local, regional, national and international regulations.

GHS label elements

General

Read label before use. Keep out of reach of children. If medical advice is needed, have product container or label at hand.

Supplemental label elements

Sanding and grinding dusts may be harmful if inhaled. This product contains crystalline silica which can cause lung cancer or silicosis. The risk of cancer depends on the duration and level of exposure to dust from sanding surfaces or mist from spray applications. Repeated exposure to high vapor concentrations may cause irritation of the respiratory system and permanent brain and nervous system damage. Inhalation of vapor/aerosol concentrations above the recommended exposure limits causes headaches, drowsiness and nausea and may lead to unconsciousness or death. Avoid contact with skin and clothing. Wash thoroughly after handling. Emits toxic fumes when heated.

Hazards not otherwise classified

Prolonged or repeated contact may dry skin and cause irritation.

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Product name

Product code

Date of issue

Version

00407693

3 April 2019

Section 3. Composition/information on ingredients

Kaolin

≥20 - ≤50

1332-58-7

Distillates (petroleum), light distillate hydrotreating process, low-boiling

≥10 - ≤20

68410-97-9

Limestone

≥10 - ≤20

1317-65-3

cyclohexane

≥10 - <20

110-82-7

n-hexane

<1.0

110-54-3

titanium dioxide

≤1.0

13463-67-7

cristobalite (<10 microns)

<1.0

14464-46-1

crystalline silica, respirable powder (<10 microns)

<1.0

14808-60-7

crystalline silica, respirable powder (>10 microns)

≤1.0

14808-60-7

Ingredient name

CAS number

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section.

Substance/mixture

Occupational exposure limits, if available, are listed in Section 8.

Mixture

Any concentration shown as a range is to protect confidentiality or is due to batch variation.

Product name

LN-901 HEAVY DUTY AHE90112TN0

SUB codes represent substances without registered CAS Numbers.

Section 4. First aid measures

Eye contact

Skin contact

Inhalation Ingestion

: :

Description of necessary first aid measures

Most important symptoms/effects, acute and delayed

Inhalation

::Ingestion

Skin contact

Eye contact

Over-exposure signs/symptoms

Eye contact

Adverse symptoms may include the following: pain or irritation watering redness

Potential acute health effects

If ingestion, irritation, any type of overexposure or symptoms of overexposure occur during or persists after use of this product, contact a POISON CONTROL CENTER, EMERGENCY ROOM OR PHYSICIAN immediately; have Safety Data Sheet information available. Never give anything by mouth to an unconscious or convulsing person.

Remove contact lenses, irrigate copiously with clean, fresh water, holding the eyelids apart for at least 10 minutes and seek immediate medical advice.

Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel.

Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water or use recognized skin cleanser. Do NOT use solvents or thinners.

If swallowed, seek medical advice immediately and show this container or label. Keep person warm and at rest. Do NOT induce vomiting.

No known significant effects or critical hazards.

Causes skin irritation. Defatting to the skin.

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Product name

Product code

Date of issue

Version

00407693

3 April 2019

Section 4. First aid measures

Protection of first-aiders

No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves.

Notes to physician

Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled.

Specific treatments

No specific treatment.

Skin contact

Ingestion

Inhalation

Adverse symptoms may include the following: reduced fetal weight increase in fetal deaths skeletal malformations

Adverse symptoms may include the following: irritation redness dryness cracking reduced fetal weight increase in fetal deaths skeletal malformations

See toxicological information (Section 11)

Indication of immediate medical attention and special treatment needed, if necessary

Section 5. Fire-fighting measures

Hazardous thermal decomposition products

Specific hazards arising from the chemical

Decomposition products may include the following materials: carbon oxides metal oxide/oxides

Highly flammable liquid and vapor. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Vapors may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back. Runoff to sewer may create fire or explosion hazard. This material is toxic to aquatic life with long lasting effects. Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or drain.

Use dry chemical,

CO₂,

water spray (fog) or foam.

Extinguishing media

Do not use water jet.

Suitable extinguishing media

Unsuitable extinguishing media

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Product name

Product code

Date of issue

Version

00407693

3 April 2019

Section 5. Fire-fighting measures

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool.

Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.

Special protective equipment for fire-fighters

Special protective actions for fire-fighters

Section 6. Accidental release measures

Environmental precautions

Personal precautions, protective equipment and emergency procedures

Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal.

No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment.

Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).

Large spill

Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.

Small spill

Methods and materials for containment and cleaning up

For non-emergency personnel

For emergency responders

If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For nonemergency personnel".

Section 7. Handling and storage

Protective measures

Put on appropriate personal protective equipment (see Section 8). Avoid exposure obtain special instructions before use. Avoid exposure during pregnancy. Do not handle until all safety precautions have been read and understood. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not ingest. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and

Precautions for safe handling

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Product name

Product code

Date of issue

Version

00407693

3 April 2019

Section 7. Handling and storage

Advice on general occupational hygiene

Conditions for safe storage, including any incompatibilities

Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures.

Do not store above the following temperature: 50°C (122°F). Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination.

material handling) equipment. Use only non-sparking tools. Take precautionary measures against electrostatic discharges. Empty containers retain product residue and can be hazardous. Do not reuse container.

Special precautions

Vapors may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back. Vapors are heavier than air and may spread along floors. If this material is part of a multiple component system, read the Safety Data Sheet(s) for the other component or components before blending as the resulting mixture may have the hazards of all of its parts.

Kaolin

ACGIH TLV (United States, 3/2018).

TWA: 2 mg/m³ 8 hours. Form: Respirable fraction

OSHA PEL (United States, 5/2018).

TWA: 5 mg/m³ 8 hours. Form: Respirable fraction

TWA: 15 mg/m³ 8 hours. Form: Total dust

Distillates (petroleum), light distillate hydrotreating process, low-boiling

OSHA PEL (United States).

TWA: 500 ppm

Limestone

OSHA PEL (United States, 5/2018).

TWA: 5 mg/m³ 8 hours. Form: Respirable fraction

TWA: 15 mg/m³ 8 hours. Form: Total dust

cyclohexane

ACGIH TLV (United States, 3/2018).

TWA: 100 ppm 8 hours.

OSHA PEL (United States, 5/2018).

TWA: 1050 mg/m³ 8 hours.

TWA: 300 ppm 8 hours.

n-hexane

ACGIH TLV (United States, 3/2018). Absorbed through skin.

TWA: 50 ppm 8 hours.

OSHA PEL (United States, 5/2018).

TWA: 1800 mg/m³ 8 hours.

Section 8. Exposure controls/personal protection

Ingredient name

Exposure limits

Control parameters

Occupational exposure limits

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Section 8. Exposure controls/personal protection

TWA: 500 ppm 8 hours.

titanium dioxide

OSHA PEL (United States, 5/2018).

TWA: 15 mg/m³ 8 hours. Form: Total dust

ACGIH TLV (United States, 3/2018).

TWA: 10 mg/m³ 8 hours.

cristobalite (<10 microns)

OSHA PEL Z3 (United States, 6/2016).

TWA: 250 mppcf / 2 x (%SiO2+5) 8 hours. Form: Respirable

TWA: 10 mg/m³ / 2 x (%SiO2+2) 8 hours. Form: Respirable

TWA: 30 mg/m³ / 2 x (%SiO2+2) 8 hours. Form: Total dust

OSHA PEL (United States, 5/2018).

TWA: 50 µg/m³ 8 hours. Form: Respirable dust

ACGIH TLV (United States, 3/2018).

TWA: 0.025 mg/m³ 8 hours. Form: Respirable fraction

crystalline silica, respirable powder (<10 microns)

ACGIH TLV (United States, 3/2018).

TWA: 0.025 mg/m³ 8 hours. Form: Respirable

OSHA PEL Z3 (United States, 6/2016).

TWA: 10 mg/m³ / (%SiO2+2) 8 hours. Form: Respirable

TWA: 250 mppcf / (%SiO2+5) 8 hours. Form: Respirable

OSHA PEL (United States, 5/2018).

TWA: 50 µg/m³ 8 hours. Form: Respirable dust

crystalline silica, respirable powder (>10 microns)

OSHA PEL Z3 (United States, 6/2016).

TWA: 10 mg/m³ / (%SiO2+2) 8 hours. Form: Respirable

TWA: 250 mppcf / (%SiO2+5) 8 hours. Form: Respirable

OSHA PEL (United States, 5/2018).

TWA: 50 µg/m³ 8 hours. Form: Respirable dust

ACGIH TLV (United States, 3/2018).

TWA: 0.025 mg/m³ 8 hours. Form: Respirable fraction

Key to abbreviations

Acceptable Maximum Peak

ACGIH

American Conference of Governmental Industrial Hygienists.

Ceiling Limit

Potential skin absorption

Respiratory sensitization

Skin sensitization

Total dust

Consult local authorities for acceptable exposure limits.

Threshold Limit Value

TLV

TWA

Time Weighted Average

Fume=F

IPEL

Internal Permissible Exposure Limit

Occupational Safety and Health Administration.

OSHA

Respirable

OSHA 29 CFR 1910.1200 Subpart Z - Toxic and Hazardous Substances

STEL

==Short term Exposure limit values

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Product name

Product code

Date of issue

Version

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3 April 2019

Section 8. Exposure controls/personal protection

Hand protection

Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated.

Eye/face protection

Respiratory protection

Body protection

Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear antistatic protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves.

: Environmental exposure controls

Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.

Appropriate engineering controls

Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment.

Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.

Hygiene measures

Individual protection measures

Skin protection

Other skin protection

Recommended monitoring procedures

If this product contains ingredients with exposure limits, personal, workplace atmosphere or biological monitoring may be required to determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment. Reference should be made to appropriate monitoring standards. Reference to national guidance documents for methods for the determination of hazardous substances will also be required.

Chemical splash goggles.

Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.

Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. If workers are exposed to concentrations above the exposure limit, they must use appropriate, certified respirators. Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary.

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Product name

Product code

Date of issue

Version

00407693

3 April 2019

Section 9. Physical and chemical properties

Physical state

Melting point

Vapor pressure

Relative density

Vapor density

Solubility

Liquid.

Not available.

1.18

Not available.

Insoluble in the following materials: cold water.

Characteristic.

Odor

Not available.

Color

Evaporation rate

Not available.

Auto-ignition temperature

Flash point

Not available.

Closed cup: -17°C (1.4°F)

Not available. Not available.

Viscosity

Kinematic (40°C (104°F)): >0.21 cm2/s (>21 cSt)

Not available.

Odor threshold

Partition coefficient: noctanol/water

:::

:::::

:::

::Appearance

Boiling point

>37.78°C (>100°F)

Flammability (solid, gas)

Not available.

Lower and upper explosive (flammable) limits

Not available.

Decomposition temperature

Not available.

Yes.:Material supports

combustion.

% Solid. (w/w)

67.575

Density ( lbs / gal )

9.85

Volatility

53% (v/v), 32.425% (w/w)

Section 10. Stability and reactivity

Conditions to avoid

The product is stable.

Chemical stability

Incompatible materials

Possibility of hazardous reactions

Under normal conditions of storage and use, hazardous reactions will not occur.

Reactivity

No specific test data related to reactivity available for this product or its ingredients.

When exposed to high temperatures may produce hazardous decomposition products.

Keep away from the following materials to prevent strong exothermic reactions: oxidizing agents, strong alkalis, strong acids.

Refer to protective measures listed in sections 7 and 8.

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Product name

Product code

Date of issue

Version

00407693

3 April 2019

Section 10. Stability and reactivity

Hazardous decomposition products

Decomposition products may include the following materials: carbon monoxide, carbon dioxide, smoke, oxides of nitrogen.

Section 11. Toxicological information

Acute toxicity

Kaolin

LD50 Oral

Rat

>5000 mg/kg

Distillates (petroleum), light distillate hydrotreating process, low-boiling

LD50 Oral

Rat

5.17 g/kg

Limestone

LD50 Oral

Rat

6450 mg/kg

cyclohexane

LD50 Oral

Rat

6240 mg/kg

n-hexane

LC50 Inhalation Gas.

Rat

48000 ppm

4 hours

LD50 Oral

Rat

15840 mg/kg

titanium dioxide

LC50 Inhalation Dusts and mists

Rat

>6.82 mg/l

4 hours

LD50 Dermal

Rabbit

>5000 mg/kg

LD50 Oral

Rat

>5000 mg/kg

Product/ingredient name

Result

Species

Dose

Exposure

Conclusion/Summary

Carcinogenicity

Conclusion/Summary

Mutagenicity

Conclusion/Summary

Irritation/Corrosion

Conclusion/Summary

Skin

Eyes

Respiratory

Sensitization

Conclusion/Summary

Skin

Respiratory

Information on toxicological effects

Classification

titanium dioxide

-2B-

cristobalite (<10 microns)

-1Known to be a human carcinogen.

crystalline silica, respirable powder (<10 microns)

-1Known to be a human carcinogen.

crystalline silica, respirable powder (>10 microns)

-1Known to be a human carcinogen.

Product/ingredient name

NTP

IARC

OSHA

Carcinogen Classification code:

There are no data available on the mixture itself.

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Product name

Product code

Date of issue

Version

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Section 11. Toxicological information

Teratogenicity

Conclusion/Summary

Reproductive toxicity

Conclusion/Summary

Specific target organ toxicity (single exposure)

IARC: 1, 2A, 2B, 3, 4 NTP: Known to be a human carcinogen; Reasonably anticipated to be a human carcinogen OSHA: + Not listed/not regulated: -

There are no data available on the mixture itself.

Name

Information on the likely routes of exposure

Specific target organ toxicity (repeated exposure)

cyclohexane

Category 3

n-hexane

Category 3

Category

cyclohexane

Category 2

n-hexane

Category 2

cristobalite (<10 microns)

Category 1

crystalline silica, respirable powder (<10 microns)

Category 1

Aspiration hazard

Name

Result

Distillates (petroleum), light distillate hydrotreating process, low-boiling

ASPIRATION HAZARD - Category 1

cyclohexane

ASPIRATION HAZARD - Category 1

n-hexane

ASPIRATION HAZARD - Category 1

Potential acute health effects

Inhalation

No known significant effects or critical hazards.

Ingestion

Skin contact

Causes skin irritation. Defatting to the skin.

No known significant effects or critical hazards.

Eye contact

Over-exposure signs/symptoms

Inhalation

Adverse symptoms may include the following: reduced fetal weight increase in fetal deaths skeletal malformations

Eye contact

Adverse symptoms may include the following: pain or irritation watering redness

Target organs

Contains material which causes damage to the following organs: brain, eyes, central nervous system (CNS). Contains material which may cause damage to the following organs: lungs, cardiovascular system, upper respiratory tract, skin, stomach.

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Product name

Product code

Date of issue

Version

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Section 11. Toxicological information

Conclusion/Summary

General

Carcinogenicity

: Mutagenicity

Teratogenicity

Potential chronic health effects

Delayed and immediate effects and also chronic effects from short and long term exposure

Potential immediate effects

: Short term exposure

Potential delayed effects

Potential immediate effects

: Long term exposure

Potential delayed effects

Skin contact

Ingestion

Adverse symptoms may include the following: reduced fetal weight increase in fetal deaths skeletal malformations

Adverse symptoms may include the following: irritation redness dryness cracking reduced fetal weight increase in fetal deaths skeletal malformations

May cause cancer. Risk of cancer depends on duration and level of exposure.

There are no data available on the mixture itself. This product contains crystalline silica which can cause lung cancer or silicosis. The risk of cancer depends on the duration and level of exposure to dust from sanding surfaces or mist from spray applications. This product contains TiO2 which has been classified as a GHS Carcinogen Category 2 based on its IARC 2B classification. For many PPG products, TiO2 is utilized as a raw material in a liquid coating formulation. In this case, the TiO2 particles are bound in a matrix with no meaningful potential for human exposure to unbound particles of TiO2 when the product is applied with a brush or roller. Sanding the coating surface or mist from spray applications may be harmful depending on the duration and level of exposure and require the use of appropriate personal protective equipment and/or engineering controls (see Section 8). Exposure to component solvent vapor concentrations in excess of the stated occupational exposure limit may result in adverse health effects such as mucous membrane and respiratory system irritation and adverse effects on the kidneys, liver and central nervous system. Symptoms and signs include headache, dizziness, fatigue, muscular weakness, drowsiness and, in extreme cases, loss of consciousness. Solvents may cause some of the above effects by absorption through the skin. There is some evidence that repeated exposure to organic solvent vapors in combination with constant loud noise can cause greater hearing loss than expected from exposure to noise alone. If splashed in the eyes, the liquid may cause irritation and reversible damage. Ingestion may cause nausea, diarrhea and vomiting. This takes into account, where known, delayed and immediate effects and also chronic effects of components from short-term and long-term exposure by oral, inhalation and dermal routes of exposure and eye contact.

May cause damage to organs through prolonged or repeated exposure. Prolonged or repeated contact can defat the skin and lead to irritation, cracking and/or dermatitis.

No known significant effects or critical hazards.

May cause genetic defects.

There are no data available on the mixture itself.

There are no data available on the mixture itself. There are no data available on the mixture itself.

There are no data available on the mixture itself.

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Product name

Product code

Date of issue

Version

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Section 11. Toxicological information

Developmental effects

Fertility effects

No known significant effects or critical hazards.

Suspected of damaging fertility.

Section 12. Ecological information

LogP

BCF

Potential

Bioaccumulative potential

Product/ingredient name

cyclohexane

3.44

83.18

low

n-hexane

3.9-low

Toxicity

Limestone

Acute LC50 >56000 mg/l

Fish

96 hours

titanium dioxide

Acute LC50 >100 mg/l Fresh water

Daphnia - Daphnia magna

48 hours

Product/ingredient name

Species

Result

Exposure

Persistence and degradability

Soil/water partition coefficient (KOC)

Not available.

Mobility in soil

Not available.

Section 13. Disposal considerations

The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Vapor from product residues may create a highly flammable or explosive atmosphere inside the container. Do not cut, weld or grind used containers unless they have been cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.

Disposal methods

Disposal should be in accordance with applicable regional, national and local laws and regulations.

Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION for additional handling information and protection of employees. Section 6. Accidental release measures

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Product name

Product code

Date of issue

Version

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3 April 2019

14. Transport information

ADHESIVES

3IIADHESIVES

3IIADHESIVES UN1133

3 II

UN1133

DOT

IMDG

IATA

UN number

UN proper shipping name

Transport hazard class (es)

Packing group

Environmental hazards

No.

Yes.

Yes. The environmentally hazardous substance mark is not required.

Marine pollutant substances

Not applicable.

(cyclohexane)

RQ substances

8128.3

(cyclohexane)

Not applicable.

Special precautions for user

Transport within user’s premises:

always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.

Additional information

Package sizes shipped in quantities less than the product reportable quantity are not subject to the RQ (reportable quantity) transportation requirements.

The marine pollutant mark is not required when transported in sizes of ≤5 L or ≤5 kg.

DOT

IMDG::

IATA

The environmentally hazardous substance mark may appear if required by other transportation regulations.

Product RQ (lbs)

Section 15. Regulatory information

SARA 302/304

SARA 304 RQ

Not applicable.

Composition/information on ingredients

All components are listed or exempted.

United States inventory (TSCA 8b)

United States

United States - TSCA 5(a)2 - Final significant new use rules:

No products were found.

4-nonylphenol, branched

Listed

nonylphenol

Listed

SARA 311/312

United States

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LN-901 HEAVY DUTY AHE90112TN0

Product name

Product code

Date of issue

Version

00407693

3 April 2019

Section 15. Regulatory information

SARA 313

SARA 313 notifications must not be detached from the SDS and any copying and redistribution of the SDS shall include copying and redistribution of the notice attached to copies of the SDS subsequently redistributed.

Supplier notification

Chemical name

cyclohexane

110-82-7

7 - 13

CAS number

Concentration

Classification

Distillates (petroleum), light distillate hydrotreating process, low-boiling

≥10 - ≤20

GERM CELL MUTAGENICITY - Category 1B CARCINOGENICITY - Category 1B ASPIRATION HAZARD - Category 1 HNOC - Defatting irritant

cyclohexane

≥10 - <20

FLAMMABLE LIQUIDS - Category 2 SKIN IRRITATION - Category 2 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2 ASPIRATION HAZARD - Category 1

n-hexane

<1.0

FLAMMABLE LIQUIDS - Category 2 SKIN IRRITATION - Category 2 TOXIC TO REPRODUCTION (Fertility) - Category 2 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2 ASPIRATION HAZARD - Category 1 HNOC - Defatting irritant

titanium dioxide

≤1.0

CARCINOGENICITY - Category 2

cristobalite (<10 microns)

<1.0

CARCINOGENICITY - Category 1A SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 1 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (inhalation) - Category 1

crystalline silica, respirable powder (<10 microns)

<1.0

CARCINOGENICITY - Category 1A SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 1 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (inhalation) - Category 1

crystalline silica, respirable powder (>10 microns)

≤1.0

CARCINOGENICITY - Category 1A

Name

Classification

Composition/information on ingredients

United States

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LN-901 HEAVY DUTY AHE90112TN0

Product name

Product code

Date of issue

Version

00407693

3 April 2019

Section 15. Regulatory information

Additional environmental information is contained on the Environmental Data Sheet for this product, which can be obtained from your PPG representative.

California Prop. 65

WARNING

: Cancer and Reproductive Harm - www.P65Warnings.ca.gov.

Section 16. Other information

Key to abbreviations

ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) UN = United Nations

Hazardous Material Information System (U.S.A.)

303

National Fire Protection Association (U.S.A.)

Health

Instability

Flammability

Health

Flammability

Physical hazards

Disclaimer

The information contained in this data sheet is based on present scientific and technical knowledge. The purpose of this information is to draw attention to the health and safety aspects concerning the products supplied by PPG, and to recommend precautionary measures for the storage and handling of the products. No warranty or guarantee is given in respect of the properties of the products. No liability can be accepted for any failure to observe the precautionary measures described in this data sheet or for any misuse of the products.

Date of previous issue

2/19/2019

Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks. Although HMIS® ratings and the associated label are not required on MSDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered trademark and service mark of the American Coatings Association, Inc.

The customer is responsible for determining the PPE code for this material. For more information on HMIS® Personal Protective Equipment (PPE) codes, consult the HMIS® Implementation Manual.

Indicates information that has changed from previously issued version.

Organization that prepared the MSDS

EHS

::::::2*2

( * ) - Chronic effects

United States

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PPG Industries LN-901 DATA SHEET

Specifications and Main Features

Frequently Asked Questions

User Manual