SECTION 1 - PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME:
CHEMICAL FAMILY NAME: Detergent
PRODUCT USE: Bath Cleaner.
U.N. NUMBER: Not Applicable
U.N. DANGEROUS GOODS CLASS: Non-Regulated Material
SUPPLIER/MANUFACTURER'S NAME: Phoenix Products Company
ADDRESS: 55 Container Drive, Terryville, CT 06786, USA
EMERGENCY PHONE: TOLL-FREE in USA
U.S. PERS Emergency Telephone 800-633-8253
BUSINESS PHONE: 860-589-7502
DATE OF PREPARATION: September 2011
DATE OF LAST REVISION: September 2011
Poly Science Bath Cleaner
SECTION 2 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW: This product is a pale yellow liquid with little or no odor. Exposure can be irritating to eyes,
respiratory system and skin. It is a non-flammable liquid. The Environmental effects of this product have not been investigated.
US DOT SYMBOLS CANADA (WHMIS) SYMBOLS EUROPEAN and (GHS) Hazard Symbols
Non-Regulated
EU LABELING AND CLASSIFICATION:
Classification of the substance or mixture according to Regulation (EC) No1272/2008 Annex 1
EC# 231-791-2 This substance is not classified in the Annex I of Directive 67/548/EEC
EC# 201-069-1 This substance is not classified in the Annex I of Directive 67/548/EEC
EC# 201-180-5 This substance is not classified in the Annex I of Directive 67/548/EEC
EC# 271-531-5 This substance is not classified in the Annex I of Directive 67/548/EEC
CAS# 84133-50-6 is not listed in inventory
EC# 203-049-8 This substance is not classified in the Annex I of Directive 67/548/EEC
GHS Hazard Classification(s):
Eye Irritant Category 2A
Signal Word: Warning!
Hazard Statement(s): Precautionary Statement(s):
H319: Causes serious eye irritation
Hazard Symbol(s):
[Xi] Irritant
P260: Do not breath dust/fume/gas/mist/vapors/spray
P264: Wash hands thoroughly after handling
P271: Use only in well ventilated area.
P280: Wear protective glov es/protective clothing/eye
protection/face protection/
Risk Phrases:
R36: Irritating to eyes
HEALTH HAZARDS OR RISKS FROM EXPOSURE:
ACUTE: Exposure to this product may cause irritation of the ey es, respiratory system and skin. Ingestion may cause gastrointestinal
irritation including pain, vomiting or diarrhea.
CHRONIC: This product contains an ingredient which may be corrosive.
Safety Phrases:
S2: Keep out of the reach of children
S26: In case of contact w ith eyes, rinse immediately with
plenty of water and seek medical advice.
S36: Wear suitable protective clothing.
TARGET ORGANS:
ACUTE: Eye, respiratory System, Skin CHRONIC: None Known
SECTION 3 - COMPOSITION and INFORMATION ON INGREDIENTS
HAZARDOUS INGREDIENTS: CAS # EINECS # ICSC # WT %
Water 7732-18-5 231-791-2 Not Listed 50 – 70%
Citric Acid 77-92-9 201-069-1 0855 5 - 15%
Glycolic Acid 79-14-1 201-180-5 1537 5 – 15%
Isopropylamine Sulfonate 68584-24-7 271-531-5 Not Listed 1 – 10%
Alcohol Ethoxylate 84133-50-6 Not Listed Not Listed 1 – 5%
Triethanol Amine 102-71-6 203-049-8 1034 1 – 5%
Balance of other ingredients are non-hazardous or less than 1% in concentration (or 0.1% for
carcinogens, reproductive toxins, or respiratory sensitizers).
NOTE:
ALL WHMIS required information is included in appropriate sections based on the ANSI Z400.1-2004 format. This product has been classified in
accordance with the hazard criteria of the CPR and the MSDS contai ns all the information required by the CPR, EU Directives and the
Japanese Industrial Standard JIS Z 7250: 2000.
HAZARD CLASSIFICATION;
RISK PHRASES
HAZARD CLASSIFICATION: None
RISK PHRASES: None
HAZARD CLASSIFICATION: None
RISK PHRASES: None
HAZARD CLASSIFICATION: None
RISK PHRASES: None
HAZARD CLASSIFICATION: None
RISK PHRASES: None
HAZARD CLASSIFICATION: None
RISK PHRASES: None
HAZARD CLASSIFICATION: None
RISK PHRASES: None
SECTION 4 - FIRST-AID MEASURES
Contaminated individuals of chemic al exposure must be taken for medical attention if any adverse effect occurs. Rescuers shoul d be
taken for medical attention, if necessary. Take copy of label and MSDS to health professional with contaminated individual.
EYE CONTACT: If product enters the eyes, open eyes while under gentle running water for at least 15 minutes. Seek
medical attention.
SKIN CONTACT:
contaminated clothing. Launder before re-use.
INHALATION: If breathing becomes difficult, remove victim to fresh air. If necessary, use artificial respiration to support
vital functions. Seek medical attention if breathing dificulty continues.
INGESTION:
If product is swallowed, call physician or poison control center for most current information. If professional
advice is not available, do not induce vo miting. Never induce vomiting or give diluents (milk or water) to someone who
is unconscious, having convulsions, or who cannot swallow. Seek medical advice. Take a copy of the label and/or
MSDS with the victim to the health professional.
MEDICAL CONDITIONS A GGRAVATED BY EXPOSURE:
prolonged contact.
RECOMMENDATIONS TO PHYSICIANS: Treat symptoms and reduce over-exposure.
Wash skin thoroughly after handling. Seek medical att ention if irritation develops and persists. Remove
Pre-existing skin, or eye problems may be aggravated by
SECTION 5 - FIRE-FIGHTING MEASURES
September 2011 Page 2 of 6 Rev 1
AUTOIGNITION TEMPERATURE:
FLAMMABLE LIMITS (in air by volume, %):
FIRE EXTINGUISHING MATERIALS:
UNUSUAL FIRE AND EXPLOSION HAZARDS:
Explosion Sensitivity to Mechanical Impact:
Explosion Sensitivity to Static Discharge:
SPECIAL FIRE-FIGHTING PROCEDURES:
NFPA RATING SYSTEM HMIS RATING SYSTEM
Flammability
Health
1
0
0
Reactivity
-
Other
Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe * = Chronic hazard
Not Applicable
Lower (LEL):
NA Upper (UEL): NA
As appropriate for surrounding fire. Carbon dioxide, foam, dry
chemical, halon, or water spray.
This product is non-flammable and has no known explosion hazards.
Not Sensitive.
Not Sensitive
Incipient fire responders should wear eye protection. Structural
firefighters must wear Self-C ontained Breathing Apparatus and full
protective equipment. Isolate materials not yet involved in the fire and
protect personnel. Move containers fr om fire area if this can be done
without risk; otherwise, cool with carefully applied water spray. If
possible, prevent runoff water from entering storm drains, bodies of
water, or other environmentally sensitive areas.
HAZARDOUS MATERIAL IDENTIFICATION SYSTEM
HEALTH HAZARD (BLUE)
FLAMMABILITY HAZARD (RED)
PHYSICAL HAZARD (YELLOW) 0
PROTECTIVE EQUIPMENT
EYES RESPIRATORY HANDS BODY
See Sect 8
For Routine Industrial Use and Handling Applications
1
0
See
Sect 8
SECTION 6 - ACCIDENTAL RELEASE MEASURES
SPILL AND LEAK RESPONSE: Personnel should be trained for spill response operations.
SPILLS: Contain spill if safe to do so. Prevent entry into drains, sewers, and other waterways. Soak up w ith an absorbent material an d
place in an appropriate container for disposal. Dispose of in accordance with applicable Federal, State, and local procedures (see
Section 13, Disposal Considerations).
SECTION 7 - HANDLING and STORAGE
WORK PRACTICES AND HYGIENE PRA CTICES: As w ith all chemicals, avoid getting this product ON YOU or IN YOU. Wash
thoroughly after handling this product. Do not eat, drink, smoke, or apply cosmetics while handling this product. Avoid breat hing
vapors.mists/sprays generated by this product. Use in a well-ventilated location. Remove contaminated clothing immediately.
STORAGE AND HANDLING PRACTICES: Containers of this product must be properly labeled. Store containers in a cool, dry location.
Keep container tightly closed when not in use. Store away from strong acids or oxidizers.
SECTION 8 - EXPOSURE CONTROLS - PERSONAL PROTECTION
EXPOSURE LIMITS/GUIDELINES:
Chemical Name CAS# ACGIH TWA OSHA TWA SWA
Water 7732-18-5
Not Listed Not Listed Not Listed
Citric Acid 77-92-9
Glycolic Acid 79-14-1
Isopropylamine Sulfonate 68584-24-7
Alcohol Ethoxylate 84133-50-6
Triethanol Amine 102-71-6
Not Listed Not Listed Not Listed
Not Listed Not Listed Not Listed
Not Listed Not Listed Not Listed
Not Listed Not Listed Not Listed
Not Listed Not Listed Not Listed
Currently, International exposure limits are not established for the components of this product. Please check with competent authority
in each country for the most recent limits in place.
VENTILATION AND ENGINEERING CONTROLS: Use with adequate ventilation to ensure ex posure levels are maintained below the
limits provided below. Use local exhaust vent ilation to control airborne dust. Ensure eyewash/safety shower stations are avai lable near
areas where this product is used.
The following information on appropriate Personal Protective Equipment is provided to assist employers in complying with OSHA
regulations found in 29 CFR Subpart I (beginning at 1910.132) or equivalent standard of Canada, or standards of EU member states
(including EN 149 for respiratory PPE, and EN 166 for face/eye protection), and those of Japan. Please reference applicable
regulations and standards for relevant details.
RESPIRATORY PROTECTION: Maintain airborne contaminant concentrations below guidelines listed above. Please check with
competent authority in each country for the most recent limits in place. If necessary, use only respiratory protection authorized in the
U.S. Federal OSHA Respiratory Protection Standard (29 CF R 1910.134), equivalent U.S. State standards, Canadian CSA Standard
Z94.4-93, the European Standard EN149, or EU member states.
EYE PROTECTION: Safety glasses. If necessary, refer to U.S. OSHA 29 CFR 1910.133 or appropriate Canadian Standards.
HAND PROTECTION: Use chemical resistant gloves to prevent skin contact.. If necessary, refer to U.S. OSHA 29 CFR 1910.138 or
appropriate Standards of Canada.
BODY PROTECTION: Use body protection appropriate to prevent contact (e .g. lab coat, overalls). If necessary , refer to appropriate
Standards of Canada, or appropriate Standards of the EU, Australian Standards, or relevant Japanese Standards.
SECTION 9 - PHYSICAL and CHEMICAL PROPERTIES
PHYSICAL STATE:
APPEARANCE & ODOR:
ODOR THRESHOLD (PPM):
VAPOR PRESSURE (mmHg):
VAPOR DENSITY (AIR=1):
BY WEIGHT:
EVAPORATION RATE (nBuAc = 1):
BOILING POINT (C°):
FREEZING POINT (C°):
pH:
SPECIFIC GRAVITY 20°C: (WATER =1)
SOLUBILITY IN WATER (%)
COEFFICIENT OF WATER/OIL DIST.:
VOC:
CHEMICAL FAMILY:
Liquid
Pale yellow liquid with little or no odor.
Not Available
17 @ 20°C (68°F)
>1
Not Available
<1
103°C (217°F)
Not Applicable.
2.5
1.12
Complete
Not Available
None
Detergent
SECTION 10 - STABILITY and REACTIVITY
STABILITY: Product is stable
DECOMPOSITION PRODUCTS: When heated to decomposition this product produces Oxides of carbon
(COx),Hydrocarbons,Oxygen, Hydrogen (H).
MATERIALS WITH WHICH SUBSTANCE IS INCOMPATIBLE: Strong acids and strong oxidizing agents.
HAZARDOUS POLYMERIZATION: Will not occur.
CONDITIONS TO AVOID: Contact with incompatible materials.
September 2011 Page 4 of 6 Rev 1
SECTION 11 - TOXICOLOGICAL INFORMATION
TOXICITY DATA: Toxicity data is available for mixture:
CAS# 77-92-9 LD50 Oral (Rat) 3000 mg/kg
SUSPECTED CANCER AGENT: None of the ingredients are found on the following lists: F EDERAL OSHA Z LIST, NTP,
CAL/OSHA, IARC and therefore is not considered to be, nor suspected to be a cancer-causing agent by these agencies.
IRRITANCY OF PRODUCT: Contact with this product can be irritating to exposed skin, eyes and respiratory system.
SENSITIZATION OF PRODUCT: This product is not considered a sensitizer.
REPRODUCTIVE TOXICITY INFORMATION:
No information concerning the effect s of this product and its components on
the human reproductive system.
SECTION 12 - ECOLOGICAL INFORMATION
ALL WORK PRACTICES MUST BE AIMED AT ELIMINATING ENVIRONMENTAL CONTAMINATION.
ENVIRONMENTAL STABILITY: No Data available at this time.
EFFECT OF MATERIAL ON PLANTS or ANIMALS: No evidence is currently available on this product’s effects on plants or animals.
EFFECT OF CHEMICAL ON AQUATIC LIFE: No evidence is currently available on this product’s effects on aquatic life.
SECTION 13 - DISPOSAL CONSIDERATIONS
PREPARING WASTES FOR DISPOSA L: Waste disposal must be in accordance with appropriate Federal, State, and local
regulations, those of Canada, Australia, EU Member States and Japan.
SECTION 14 - TRANSPORTATION INFORMATION
US DOT; IATA; IMO; ADR:
THIS PRODUCT IS NOT HAZARDOUS AS DEFINED BY 49 CFR 172.101 BY THE U.S. DEPARTMENT OF TRANSPORTATION.
PROPER SHIPPING NAME: Non-Regulated Material
HAZARD CLASS NUMBER and DESCRIPTION: Not Applicable
UN IDENTIFICATION NUMBER: Not Applicable
PACKING GROUP: Not Applicable.
DOT LABEL(S) REQUIRED: Not Applicable
NORTH AMERICAN EMERGENCY RESPONSE GUIDEBOOK NUMBER (2004): Not Applicable
MARINE POLLUTANT: None of the ingredients are classified by the DOT as a Marine Pollutant (as defined by 49 CFR
172.101, Appendix B)
U.S. DEPARTMENT OF TRANSPORTATION (DOT) SHIPPING REGULATIONS:
This product is not classified as dangerous goods, per U.S. DOT regulations, under 49 CFR 172.101.
TRANSPORT CANADA, TRANSPORTATION OF DANGEROUS GOODS REGULATIONS:
This product is not classified as Dangerous Goods, per regulations of Transport Canada.
INTERNATIONAL AIR TRANSPORT ASSOCIATION (IATA):
This product is not classified as Dangerous Goods, by rules of IATA:
INTERNATIONAL MARITIME ORGANIZATION (IMO) DESIGNATION:
This product is not classified as Dangerous Goods by the International Maritime Organization.
EUROPEAN AGREEMENT CONCERNING THE INTERNATIONAL CARRIAGE OF DANGEROUS GOODS BY ROAD (ADR):
This product is not classified by the United Nations Economic Commission for Europe to be dangerous goods.
SECTION 15 - REGULATORY INFORMATION
UNITED STATES REGULATIONS
SARA REPORTING REQUIREMENTS: This product is not subject to the reporting requirements of Sections 302, 304 and 313 of
Title III of the Superfund Amendments and Reauthorization Act., as follows: None
TSCA: All components in this product are listed on the US Toxic Substances Control Act (TSCA) inventory of chemicals.
SARA 311/312:
Acute Health: Yes Chronic Health: No Fire: No Reactivity: No
U.S. SARA THRESHOLD PLANNING QUANTITY: There are no specific T hreshold Planning Quantities for this product. The
default Federal MSDS submission and invent ory requirement filing threshold of 10, 000 lb (4,540 kg) may apply, per 40 CFR
370.20.
U.S. CERCLA REPORTABLE QUANTITY (RQ): None
CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT (PROPOSITION 65): None of the ingredients are on
the California Proposition 65 lists.
CANADIAN REGULATIONS:
CANADIAN DSL/NDSL INVENTORY STATUS: All of the components of this product are on the DSL Inventory
CANADIAN ENVIRONMENTAL PROTECTION ACT (CEPA) PRIORITIES SUBSTANCES LISTS: No component of this product is
on the CEPA First Priorities Substance Lists.
CANADIAN WHMIS CLASSIFICATION and SYMBOLS: This product is categorized as a Controlled Product, Hazard Class D2B as
per the Controlled Product Regulations
EUROPEAN ECONOMIC COMMUNITY INFORMATION:
EU LABELING AND CLASSIFICATION:
Classification of the mixture according to Regulation (EC) No1272/2008. See section 2 for details.
AUSTRALIAN INFORMATION FOR PRODUCT:
AUSTRALIAN INVENTORY OF CHEMICAL SUBSTANCES (AICS) STATUS: All components of this product are listed on the AICS.
STANDARD FOR THE UNIFORM SCHEDULING OF DRUGS AND POISONS: Not applicable.
JAPANESE INFORMATION FOR PRODUCT:
JAPANESE MINISTER OF INTERNATIONAL TRADE AND INDUSTRY (MITI) STATUS: The components of this product are not
listed as Class I Specified Chemical Substa nces, Class II Specified Chemical Substances , or Designated Chemical Substances by
the Japanese MITI.
INTERNATIONAL CHEMICAL INVENTORIES:
Listing of the components on individual country Chemical Inventories is as follows:
Asia-Pac: Listed
Australian Inventory of Chemical Substances (AICS): Listed
Korean Existing Chemicals List (ECL): Listed
Japanese Existing National Inventory of Chemical Substances (ENCS): Listed
Philippines Inventory if Chemicals and Chemical Substances (PICCS): Listed
Swiss Giftliste List of Toxic Substances: Listed
U.S. TSCA: Listed
polyclean BATH CLEANER should be used for cleaning and removing rust and mineral deposits from stainless
steel and polycarbonate tanks. Concentrated.
DIRECTIONS FOR USE:For each gallon of water, add 1.25 fluid oz (about 7 capfuls) of bath cleaner.
Always add bath cleaner to water when diluting.
EXPOSURE CONTROLS/ PERSONALPROTECTION: For instructions regarding appropriate eye, skin, and respiratory
protection, read MSDS.
STORAGE: Store away from incompatible materials. Keep containers closed when not in use.
FIRST AID IF IN EYES: Check for and remove contact lenses. Flush eyes with clear, running water for 15 minutes
while holding eyelids open: if irritation persists, consult a physician.
IF SWALLOWED: Do not induce vomiting, seek medical attention. Dilute with two glasses of water.
Never given anything by mouth to an unconscious person.
IF INHALED: Remove victim to fresh air. If irritation persists, seek medical attention.
IF ON SKIN OR CLOTHING: Remove contaminated clothing. Wash thoroughly with soap and water.
Seek medical attention of irritation persists.
September 2011 Page 6 of 6 Rev 1
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