Blue Works
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
Product form : Mixture
Product name. : Blue Works
1.2. Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture : Deodorizer
1.3. Details of the supplier of the safety data sheet
PolyPortables, Inc.
163 Breakstone Drive
Dahlonega, Georgia 30533
T: 706-864-3776 (US)
1.4. Emergency telephone number
Emergency number : (001) 1-800- 535-5053 - 24 hours
SECTION 2: Hazards identification
2.1. Classification of the substance or mixture
GHS-US classification
Acute Tox. 4 (Oral) H302
Skin Irrit. 2 H315
Eye Irrit. 2B H320
2.2. Label elements
GHS-US labelling
Hazard pictograms (GHS-US) :
Date of issue: 12/12/2013 Version: 1.0
GHS07
Signal word (GHS-US) : Warning
Hazard statements (GHS-US) : H302 - Harmful if swallowed
H315 - Causes skin irritation
H320 - Causes eye irritation
Precautionary statements (GHS-US) : P264 - Wash thoroughly after handling
P270 - Do not eat, drink or smoke when using this product
P280 - Wear protective gloves/protective clothing/eye protection/face protection
P301+P312 - If swallowed, call a doctor if you feel unwell
P302+P352 - IF ON SKIN: Wash with plenty of soap and water
P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing
P330 - If swallowed, rinse mouth
P332+P337+P313 - If skin/eye irritation occurs: Get medical advice/attention
P362 - Take off contaminated clothing
P501 - Dispose of contents/container in accordance with local and national regulations
2.3. Other hazards
No additional information available
2.4. Unknown acute toxicity (GHS-US)
25 percent of the mixture consists of ingredient(s) of unknown acute toxicity (Oral)/(Dermal)/(Inhalation (Dust/Mist)).
SECTION 3: Composition/information on ingredients
3.1. Substances
Not applicable
Full text of H-phrases: see section 16
12/12/2013 EN (English) SDS ID: PolyPortables_1300001 Page 1
Blue Works
Name
Product identifier
%
GHS-US classification
Do not enter fire area without proper protective equipment, including respiratory protection. Wear
Avoid contact with skin and eyes. Chemical goggles or safety glasses. Wear suitable gloves.
Avoid contact with skin and eyes. Equip cleanup crew with proper protection. Chemical goggles
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
3.2. Mixture
Only components contributing to the product classification above the applicable thresholds are displayed.
Surfactant Blend
Cationic Surfactant
Ethanol
SECTION 4: First aid measures
4.1. Description of first aid measures
(CAS No)
(CAS No)
(CAS No)
68551-12-2
68424-85-1
64-17-5
11 - 29 Eye Dam. 1, H318
5 - 19 Flam. Liq. 3, H226
Acute Tox. 4 (Oral), H302
Skin Corr. 1B, H314
<= 10 Flam. Liq. 2, H225
First-aid measures general : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice
(show the label where possible).
First-aid measures after inhalation : Remove to fresh air and keep at rest in a position comfortable for breathing. Call a POISON
CENTER/doctor/physician if you feel unwell.
First-aid measures after skin contact : Rinse skin with water/shower. Remove/Take off immediately all contaminated clothing. If skin
irritation or rash occurs: Immediately call a POISON CENTER or doctor/physician.
First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing. If eye irritation persists: Get medical advice/attention.
First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting unless directed to do so by medical personnel. Call a
4.2. Most important symptoms and effects, both acute and delayed
POISON CENTER/doctor/physician if you feel unwell.
Symptoms/injuries after inhalation : Inhalation may cause: irritation, coughing, shortness of breath.
Symptoms/injuries after skin contact : Causes skin irritation.
Symptoms/injuries after eye contact : Causes serious eye irritation.
Symptoms/injuries after ingestion : Swallowing a small quantity of this material will result in serious health hazard.
4.3. Indication of any immediate medical attention and special treatment needed
All treatments should be based on observed signs and symptoms of distress in the patient.
SECTION 5: Firefighting measures
5.1. Extinguishing media
Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand.
Unsuitable extinguishing media : Do not use a heavy water stream.
5.2. Special hazards arising from the substance or mixture
Fire hazard : Sustained combustion was not observed during testing at 60.5 °C and 75 °C.
Explosion hazard : Product is not explosive.
5.3. Advice for firefighters
Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any
chemical fire. Avoid (reject) fire-fighting water to enter environment.
Protection during firefighting :
a self contained breathing apparatus. Wear fire/flame resistant/retardant clothing.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
Protective equipment :
Nitrile gloves. Butyl rubber gloves.
Emergency procedures : Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment :
or face shield with safety glasses. Wear suitable gloves: nitrile rubber. butyl rubber.
Emergency procedures : Ventilate area. Small quantities of liquid spill: take up in non-combustible absorbent material and
shovel into container for disposal. Impound and recover large spill by mixing it with inert granular
6.2. Environmental precautions
solids.
Prevent entry to sewers and public waters.
12/12/2013 EN (English) SDS ID: PolyPortables_1300001 2/7
Blue Works
Avoid contact with skin and eyes. Use in a well ventilated area.
Ethanol (64
-17-5)
Avoid all unnecessary exposure.
with adequate ventilation. If needed, use an air
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
6.3. Methods and material for containment and cleaning up
Methods for cleaning up : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect
6.4. Reference to other sections
spillage.
Section 7: safe handling.
Section 8: personal protective equipment.
Section 13: disposal information.
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Precautions for safe handling :
Hygiene measures : Wash hands and other exposed areas with mild soap and water before eating, drinking or
7.2. Conditions for safe storage, including any incompatibilities
smoking and when leaving work. Wash contaminated clothing before reuse.
Storage conditions : Do not freeze. Keep container tightly closed. Keep only in the original container in a cool well
ventilated place. Protect from moisture. To maintain shelf life, avoid prolinged exposure to high
or low temparatures. Store at temperatures not exceeding 110 F.
Incompatible products : Strong bases. Strong oxidizing agents..
7.3. Specific end use(s)
Deoderizer.
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
USA ACGIH ACGIH TWA (mg/m³) 1884 mg/m³
USA ACGIH ACGIH TWA (ppm) 1000 ppm
USA OSHA OSHA PEL (TWA) (mg/m3) 1900 mg/m³
USA OSHA OSHA PEL (TWA) (ppm) 1000 ppm
8.2. Exposure controls
Appropriate engineering controls : Either local exhaust or general room ventilation is usually required.
Personal protective equipment :
Hand protection : Wear protective gloves. butyl rubber. nitrile rubber gloves.
Eye protection : Chemical goggles or face shield.
Skin and body protection : Wear suitable protective clothing.
Respiratory protection : No special respiratory protection equipment is recommended under normal conditions of use
-purifying respirator with organic vapor cartridges
and a dust/mist prefilter.
Other information : When using, do not eat, drink or smoke.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Physical state : Liquid
Appearance : Slightly viscous blue liquid.
Colour : Deep blue. Colourless.
Odour : perfumed. characteristic.
Odour threshold : No data available
pH : 6 - 8
Relative evaporation rate (butylacetate=1) : No data available
Melting point : No data available
Freezing point : < 0 °C
Boiling point : 95 °C
Flash point : 39.7 °C
Self ignition temperature : No data available
12/12/2013 EN (English) SDS ID: PolyPortables_1300001 3/7
Blue Works
Blue Works
Cationic Surfactant (68424
-85-1)
Surfactant Blend (68551
-12-2)
Ethanol (64
-17-5)
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Decomposition temperature : No data available
Flammability (solid, gas) : No data available
Vapour pressure : No data available
Relative vapour density at 20 °C : No data available
Relative density : No data available
Relative gas density : 1
Solubility : No data available
Log Pow : No data available
Log Kow : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosive properties : Product is not explosive.
Oxidising properties : No oxidizing properties.
Explosive limits : No data available
9.2. Other information
VOC content : < 10 %
SECTION 10: Stability and reactivity
10.1. Reactivity
No additional information available
10.2. Chemical stability
The product is stable at normal handling and storage conditions.
10.3. Possibility of hazardous reactions
Hazardous polymerization will not occur.
10.4. Conditions to avoid
Extremely high or low temperatures.
10.5. Incompatible materials
Strong bases. Strong oxidizing agents.
10.6. Hazardous decomposition products
Carbon monoxide. Carbon dioxide. Thermal decomposition generates corrosive vapours.
SECTION 11: Toxicological information
11.1. Information on toxicological effects
Acute toxicity : Harmful if swallowed.
ATE (oral) 500.000 mg/kg bodyweight
LD50 oral rat 304.5 mg/kg
ATE (oral) 304.500 mg/kg bodyweight
LD50 oral rat > 2000 mg/kg
LD50 dermal rat > 2000 mg/kg
LD50 oral rat 10470 mg/kg
LD50 dermal rabbit > 20000 mg/kg
LC50 inhalation rat (mg/l) 133.8 mg/l/4h
ATE (oral) 10470.000 mg/kg
ATE (dust,mist) 133.800 mg/l/4h
Skin corrosion/irritation : Causes skin irritation.
Serious eye damage/irritation : Causes eye irritation.
12/12/2013 EN (English) SDS ID: PolyPortables_1300001 4/7
Blue Works
All components
Cationic Surfactant (68424
-85-1)
Blue Wor
ks
Cationic Surfactant (68424
-85-1)
Blue Works
Avoid release to the environment.
Avoid release to the environment.
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Respiratory or skin sensitisation : Not classified. Based on available data, the classification criteria are not met
Germ cell mutagenicity : Not classified. Based on available data, the classification criteria are not met
Carcinogenicity : Not classified
IARC group Not listed in carcinogenicity class
National Toxicology Program (NTP) Status Not listed in carcinogenicity class
Reproductive toxicity : Not classified. Based on available data, the classification criteria are not met
Specific target organ toxicity (single exposure) : Not classified. Based on available data, the classification criteria are not met
Specific target organ toxicity (repeated
exposure)
Aspiration hazard : Not classified. Based on available data, the classification criteria are not met
Potential Adverse human health effects and
: Not classified. Based on available data, the classification criteria are not met
: Harmful if swallowed.
symptoms
Symptoms/injuries after eye contact : Causes serious eye damage.
Symptoms/injuries after ingestion : Swallowing a small quantity of this material will result in serious health hazard.
SECTION 12: Ecological information
12.1. Toxicity
LC50 fishes 1 0.93 mg/l predicted by PNN
EC50 Daphnia 1 1.6 predicted by Ecosar
12.2. Persistence and degradability
Persistence and degradability Not established.
Persistence and degradability Not expected to persist. Readily biodegradable.
12.3. Bioaccumulative potential
Bioaccumulative potential Not established.
12.4. Mobility in soil
No additional information available
12.5. Other adverse effects
Other information :
SECTION 13: Disposal considerations
13.1. Waste treatment methods
Waste disposal recommendations : Dispose in a safe manner in accordance with local/national regulations.
Ecology - waste materials :
SECTION 14: Transport information
In accordance with DOT
Not a dangerous good in regard to transport regulations
Additional information
Other information : No supplementary information available.
ADR
Transport document description :
Transport by sea
No additional information available
12/12/2013 EN (English) SDS ID: PolyPortables_1300001 5/7
Blue Works
Cationic Surfactant (68424
-85-1)
S
urfactant Blend (68551
-12-2)
E
thanol (64
-17-5)
Blue Works
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Air transport
Not regulated per IATA
SECTION 15: Regulatory information
15.1. US Federal regulations
Listed on the United States TSCA (Toxic Substances Control Act) inventory
EPA TSCA Regulatory Flag T - T - indicates a substance that is the subject of a Section 4 test rule under TSCA.
EPA TSCA Regulatory Flag XU - XU - indicates a substance exempt from reporting under the Inventory Update Reporting
Rule, i.e., Partial Updating of the TSCA Inventory Data Base Production and Site Reports (40
Listed on the United States TSCA (Toxic Substances Control Act) inventory
15.2. International regulations
CANADA
WHMIS Classification Class D Division 2 Subdivision B - Toxic material causing other toxic effects
CFR 710(C)).
EU-Regulations
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Acute Tox. 4 (Oral) H302
Skin Irrit. 2 H315
Eye Irrit. 2 H319
Full text of H-phrases: see section 16
Classification according to Directive 67/548/EEC or 1999/45/EC
C; R34
Full text of R-phrases: see section 16
15.2.2. National regulations
No additional information available
15.3. US State regulations
No additional information available
SECTION 16: Other information
Indication of changes : Revision : GHS classification information.
Data sources : ESIS (European chemincal Substances Information System; accessed at:
http://esis.jrc.ec.europa.eu/index.php?PGM=cla
European Chemicals Agency (ECHA) Registered Substances list. Accessed at
http://echa.europa.eu/
Krister Forsberg and S.Z. Mansdorf, "Quick Selection Guide to Chemical Protective Clothing",
Fifth Edition.
National Fire Protection Association. Fire Protection Guide to Hazardous Materials; 10th edition.
US National Library of Medicine National Institutes of Health Haz-Map. Accessed at
http://hazmap.nlm.nih.gov
US National Library of Medicine TOXNET Toxicology Data Network. Reregistration Eligibility
Decision for Alkyl Dimethyl Benzyl Ammonium Chloride (ADBAC); accessed at
http://www.epa.gov/oppsrrd1/REDs/adbac_red.pdf
12/12/2013 EN (English) SDS ID: PolyPortables_1300001 6/7
Blue Works
ACGIH (Ameri
ATE: Acute Toxicity Estimate.
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Abbreviations and acronyms :
can Conference of Government Industrial Hygienists).
CAS (Chemical Abstracts Service) number.
EC50: Environmental Concentration associated with a response by 50% of the test population.
GHS: Globally Harmonized System (of Classification and Labeling of Chemicals
LD50: Lethal Dose for 50% of the test population.
OSHA: Occupational Safety & Health Administration.
STEL: Short Term Exposure Limits.
TSCA: Toxic Substances Control Act.
TWA: Time Weighted Average.
Other information : None.
Full text of H-phrases: see section 16:
------ Acute Tox. 4 (Oral) Acute toxicity (oral) Category 4
------ Eye Dam. 1 Serious eye damage/eye irritation Category 1
------ Eye Irrit. 2B Serious eye damage/eye irritation Category 2B
------ Flam. Liq. 2 Flammable liquids Category 2
------ Flam. Liq. 3 Flammable liquids Category 3
------ Skin Corr. 1B skin corrosion/irritation Category 1B
------ Skin Irrit. 2 skin corrosion/irritation Category 2
------ H225 Highly flammable liquid and vapour
------ H226 Flammable liquid and vapour
------ H302 Harmful if swallowed
------ H314 Causes severe skin burns and eye damage
------ H315 Causes skin irritation
------ H318 Causes serious eye damage
------ H320 Causes eye irritation
NFPA health hazard : 1 - Exposure could cause irritation but only minor residual
injury even if no treatment is given.
NFPA fire hazard : 0 - Materials that will not burn.
NFPA reactivity : 0 - Normally stable, even under fire exposure conditions,
and not reactive with water.
SDS US (GHS HazCom 2012)
SDS Prepared by: The Redstone Group, LLC
6397 Emerald Pkwy.
Suite 200
Dublin, OH 43016
T 614-923-7472
www.redstonegrp.com
This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as
guaranteeing any specific property of the product.
12/12/2013 EN (English) SDS ID: PolyPortables_1300001 7/7
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