Used primarily for extrusion-based 3D printing processes
3. Manufacturer information
Manufacturer:
JF Polymers (Suzhou) Co. Ltd.
Address:
Haicheng Industrial Park
Building 7
Changshu Economic and Technological Zone (CEDZ) Changshu, Suzhou, Jiangsu Province, 215513
China
Tel/Fax:
+86-512-52096516 / +86-512-52096512
4. Emergency contact number
Emergency telephone number:
+86-512-52096516; or call LOCAL POISON CONTROL CENTER
Version 4.0
1. Classification of the substance of mixture
1.1. Classification according to Directive 67/548/EEC or 1999/45/EC as amended
This substance does not meet the criteria for classification according to Directive 67/548/EEC as amended.
1.2. Classification according to Regulation (EC) No 1272/2008 as amended
This substance does not meet the criteria for classification according to Regulation (EC) 1272/2008 as amended.
2. Label elements
Not applicable.
3. Other hazards
Not likely to be an irritant in the solid form. Danger of burns when heated/molten material is handled.
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Chemical Name
CAS No.
Weight (%)
Exposure Limits
Poly(lactic acid) resin
9051-89-2
70-100%
None
Acrylic polymer (s)
-
0-30%
None
Section 3: Composition/information on ingredients
Section 4: First aid measures
Section 5: Fire-fighting measures
Nov. 2018
Safety Data Sheet
Version 4.0
1. Substances
1. Description of first aid measures
1.1. Inhalation
Move to fresh air and keep at rest in a position comfortable for breathing. Call a physician immediately if irritation persists.
1.2. Skin contact
Rinse immediately with plenty of water. If skin irritation persists, call a physician. Cool skin rapidly with cold water after
contact with hot polymer.
1.3. Eye contact
Rinse immediately with plenty of water. Call a physician immediately.
1.4. Ingestion
Drink water as a precaution. Never give anything by mouth to an unconscious person. Do not induce omitting without
medical advice. Call a physician immediately.
2. Most important symptoms and effects, both acute and delayed
Burns resulted from contacting or handling heated/molten materials
3. Indication of any immediate medical attention and special treatment needed
Provide general supportive measures and treat symptomatically.
1. Suitable extinguishing media
Foam. Water. Carbon dioxide (CO2). Dry chemical. Alcohol resistant foams are preferred if available. General-purpose
synthetic foams (including AFFF) or protein foams may function, but much less effectively.
2. Special hazards arising from the substance or mixture
No specific hazard.
3. Advice for fire fighters
Follow the general fire precautions indicated in the workplace. Self-contained breathing apparatus and full protective
clothing must be worn in case of fire. Use standard firefighting procedures and consider the hazards of other involved
materials. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with
a full face-piece operated in positive pressure mode.
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Section 6: Accidental release measures
Section 8: Exposure controls/personal protection
Section 7: Handling and storage
Nov. 2018
Safety Data Sheet
Version 4.0
1. Personal precautions, protective equipment and emergency procedures
Lab coat. Impervious gloves. Safety glasses with side shields.
2. Environmental precautions
Do not flush into surface water or sanitary sewer system. Do not allow material to contaminate ground water system.
3. Methods and materials for containment and cleaning up
Shovel into suitable container for disposal.
1. Precautions for safe handling
Avoid prolonged contact with skin and eyes. Avoid dust formation. Workers should be protected from the possibility of
contact with molten material. Low hazard for usual industrial or commercial handling.
2. Conditions for safe storage
Store in a cool, dry, well-ventilated area. Keep away from heat, sparks and flames. Keep containers closed. Avoid moisture
contamination. Transferring dry pellets or granules between containers or charging into solvents can cause a build-up of
static electricity which can be sufficient to cause fires and/or explosions in the presence of flammable materials.
Equipment should provide a means of dissipating any charges that may develop.
1. Control parameters
Consult local authorities for acceptable exposure limits.
Biological limit values:
No biological exposure limits noted for the ingredient(s)
Recommended monitoring procedures:
Not available
Derived no-effect level (DNEL):
Not available
Predicted no effect concentrations (PNECs):
Not available
2. Engineering controls
Use local exhaust ventilation to maintain airborne concentrations below the TLV. Suitable respiratory equipment should be
used in cases of insufficient ventilation or where operational procedures demand it. For guidance on engineering control
measures refer to publications such as the ACGIH current edition of 'Industrial Ventilation, a manual of Recommended
Practice.
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Section 9: Physical and chemical properties
Nov. 2018
Safety Data Sheet
Version 4.0
3. Personal protective equipment
Eyes:
safety glasses with side-shields
Skin:
lab coat
Respiratory:
Wear appropriate respirator when ventilation is inadequate.
Hands:
Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling
chemical products if a risk assessment indicates this is necessary.
Personal protective:
equipment
1. Information on basic physical and chemical properties
Appearance: Solid
Color: Various
Odor: Almost Odorless
Odor threshold: Not available
pH: Not applicable
Melting point/freezing point: 149˚C
Softening temperature: 61˚C
Boiling point: Not applicable
Flash point: Not applicable
Evaporation rate: Not applicable
Flammability: Not available
Upper/lower flammability or explosive limits: Not available
Vapor pressure: Not applicable
Vapor density: Not applicable
Relative density: 1.21 g/cm3
Solubility: No available
Partition coefficient (n-octanol/water): No available
Auto-ignition temperature: > 350˚C
Decomposition temperature: No available
Viscosity: Not applicable
Unlikely under normal industrial use. If the product is heated to temperatures excessively higher than those recommended
on the technical data sheet, thermal decomposition is possible. Combustion products may include: carbon oxides (CO,
CO2), nitrogen oxides (NO, NO2 etc.), hydrocarbons, HCN
1. Likely routes of exposure
Inhalation:
Non-irritating to the respiratory system.
Skin contact:
No data available
Eye contact:
May cause physical abrasion in contact with eyes. Molten polymer will cause serious burns to the eyes.
Ingestion:
No data available
2. Symptoms
Dust may irritate throat and respiratory system and cause coughing. Direct contact with eyes may cause temporary
irritation.
3. Information on toxicological effects
Acute toxicity: Dusts may irritate the respiratory tract, skin and eyes.
Skin corrosion/irritation: Dust may irritate skin.
Serious eye damage/eye irritation: Dust may irritate the eyes. Exposed may experience eye tearing, redness, and
discomfort.
Respiratory sensitization: Not classified.
Skin sensitization: Not a skin sensitizer.
Germ cell mutagenicity: Not expected to be mutagenic.
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Section 12: Ecological information
Section 13: Disposal considerations
Section 14: Transport information
Nov. 2018
Carcinogenicity: The ingredients of this product are not classified as carcinogenic by ACGIH or IARC, not regulated as
carcinogens by OSHA, and not listed as carcinogens by NTP.
Reproductive toxicity: Not classified.
Specific target organ toxicity - single exposure: No data available
Specific target organ toxicity - repeated exposure: No data available
Aspiration hazard: Due to the physical form of the product it is not an aspiration hazard.
Mixture versus substance information: Not applicable.
Other information: Pre-existing skin and respiratory conditions including dermatitis, asthma and chronic lung disease might
be aggravated by exposure.
Safety Data Sheet
Version 4.0
1. Toxicity
The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or
frequent spills can have a harmful or damaging effect on the environment.
2. Persistence and degradability
No data available.
3. Bioaccumulative potential
Does not bioaccumulate. Inherently biodegradable.
4. Mobility in soil
Not available.
5. Other adverse effects
The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or
frequent spills can have a harmful or damaging effect on the environment.
1. Waste treatment methods
In accordance with local and national regulations. Do not contaminate ponds, waterways or ditches with chemical or used
container. Contact manufacturer if needed.
ADR: Not regulated as dangerous goods.
RID: Not regulated as dangerous goods.
AND: Not regulated as dangerous goods.
IATA: Not regulated as dangerous goods.
IMDG: Not regulated as dangerous goods.
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code:
This substance/mixture is not intended to be transported in bulk.
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Section 15: Regulatory information
Nov. 2018
Safety Data Sheet
Version 4.0
1. Safety, health and environmental regulations/legislation specific for the
substance or mixture EU regulations
Regulation (EC) No. 1005/2009 on substances that deplete the ozone layer, Annex I
Not listed.
Regulation (EC) No. 1005/2009 on substances that deplete the ozone layer, Annex II
Not listed.
Regulation (EC) No. 850/2004 On persistent organic pollutants, Annex I as amended
Not listed.
Regulation (EC) No. 689/2008 concerning the export and import of dangerous chemicals, Annex I, part 1 as amended
Not listed.
Regulation (EC) No. 689/2008 concerning the export and import of dangerous chemicals, Annex I, part 2 as amended
Not listed.
Regulation (EC) No. 689/2008 concerning the export and import of dangerous chemicals, Annex I, part 3 as amended
Not listed.
Regulation (EC) No. 689/2008 concerning the export and import of dangerous chemicals, Annex V as amended
Not listed.
Regulation (EC) No. 166/2006 Annex II Pollutant Release and Transfer Registry
Not listed.
Regulation (EC) No. 1907/2006, REACH Article 59(10) Candidate List as currently published by ECHA
Not listed.
Authorizations
Regulation (EC) No. 1907/2006, REACH Annex XIV Substances subject to authorization, as amended
Not listed.
Restrictions on use
Regulation (EC) No. 1907/2006, REACH Annex XVII Substances subject to restriction on marketing and use as amended
Not listed.
Directive 2004/37/EC:
on the protection of workers from the risks related to exposure to carcinogens and mutagens at work
Not listed.
Directive 92/85/EEC:
on the safety and health of pregnant workers and workers who have recently given birth or are breastfeeding
Not listed.
Other EU regulations
Directive 96/82/EC (Seveso II):
on the control of major-accident hazards involving dangerous substances
Not listed.
Directive 98/24/EC:
on the protection of the health and safety of workers from the risks related to chemical agents at work
Not listed.
Directive 94/33/EC:
on the protection of young people at work
Not listed.
Other regulations
This Safety Data Sheet complies with the requirements of Regulation (EC) No 1907/2006.
National regulations:
Not available.
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Section 16: Other information
Nov. 2018
Safety Data Sheet
Version 4.0
2. Chemical safety assessment
No Chemical Safety Assessment has been carried out.
Revision information
Date of this revision: Apr 26, 2017
Declare to reader
During handling and use, product can cause static discharge. In the presence of flammable materials, a fire and/or
explosion may occur. Molten material may cause thermal eye burns. Molten material may cause thermal skin burns.
Processing vapors may cause respiratory tract irritation.
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