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644973
User Manual
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Pledge 644973 User Manual

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Page 1
Safety Data Sheet
according to Hazard Communication Standard; 29 CFR 1910.1200
Version 0.0
Print Date 09/06/2016
Revision Date 00/00/0000
SDS Number 350000021022 GEN_SOF Number 45845
Product name
:
PLEDGE® EVERYDAY CLEANER MULTI SURFACE ­CLEAN CITRUS SCENT
Recommended use
:
Speciality Cleaner
Manufacturer, importer, supplier
:
S.C. Johnson & Son, Inc. 1525 Howe Street Racine WI 53403-2236
Telephone
:
+18005585252
Emergency telephone number
:
24 Hour Medical Emergency Phone: (866)231-5406
24 Hour International Emergency Phone: (703)527-3887 24 Hour Transport Emergency Phone: (800)424-9300
Hazard classification
Hazard category
Hazards identification
Flammable liquids
Category 4
Combustible liquid.
Other hazards
:
None identified
1. PRODUCT AND COMPANY IDENTIFICATION
Product information
2. HAZARDS IDENTIFICATION
Classification of the substance or mixture
Globally Harmonized System (GHS) Classification
Labelling
Hazard statements
Combustible liquid.
Precautionary statements
In case of fire: Use dry sand, dry chemical or alcohol-resistant foam for extinction. Store in a well-ventilated place. Keep cool. Dispose of contents/ container to an approved incineration plant. Keep away from heat/sparks/open flames/hot surfaces. No smoking. Wear protective gloves.
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Page 2
Safety Data Sheet
according to Hazard Communication Standard; 29 CFR 1910.1200
Version 0.0
Print Date 09/06/2016
Revision Date 00/00/0000
SDS Number 350000021022 GEN_SOF Number 45845
Chemical Name
CAS-No.
Weight percent
Ethyl alcohol
64-17-5
0.10 - 1.00
Eye contact
:
No special requirements
Skin contact
:
No special requirements
Inhalation
:
No special requirements.
Ingestion
:
No special requirements
Suitable extinguishing media
:
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Specific hazards during firefighting
:
Flammable liquid. Vapors are heavier than air and may travel to a source of ignition and flash back. Liquid run-off to sewers may create fire/explosion hazard. Container may melt and leak in heat of fire.
Further information
:
Although this product has a flash point below 200 Deg F, it is an aqueous solution containing an alcohol and does not sustain combustion. Cool and use caution when approaching or handling fire-exposed containers. Fight fire with normal precautions from a reasonable distance. For large quantities of
3. COMPOSITION/INFORMATION ON INGREDIENTS
The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret.
For additional information on product ingredients, see www.whatsinsidescjohnson.com.
4. FIRST AID MEASURES
5. FIREFIGHTING MEASURES
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Page 3
Safety Data Sheet
according to Hazard Communication Standard; 29 CFR 1910.1200
Version 0.0
Print Date 09/06/2016
Revision Date 00/00/0000
SDS Number 350000021022 GEN_SOF Number 45845
flammable liquids, consider containment to prevent the spread of fire. Standard procedure for chemical fires. Wear full protective clothing and positive pressure self-contained breathing apparatus. In case of fire and/or explosion do not breathe fumes.
Personal precautions
:
Remove all sources of ignition. Beware of vapours accumulating to form explosive concentrations. Vapours can accumulate in low areas. Wear personal protective equipment. Wash thoroughly after handling.
Environmental precautions
:
Outside of normal use, avoid release to the environment.
Methods and materials for containment and cleaning up
:
Use only non-sparking equipment. Dike large spills. Clean residue from spill site.
Precautions for safe handling
:
Avoid contact with skin, eyes and clothing. For personal protection see section 8. Use only as directed. KEEP OUT OF REACH OF CHILDREN AND PETS.
Advice on protection against fire and explosion
:
Keep away from sources of ignition - No smoking.
Requirements for storage areas and containers
:
Keep container closed when not in use. Store in a well-ventilated place. Keep cool.
6. ACCIDENTAL RELEASE MEASURES
7. HANDLING AND STORAGE
Handling
Storage
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Page 4
Safety Data Sheet
according to Hazard Communication Standard; 29 CFR 1910.1200
Version 0.0
Print Date 09/06/2016
Revision Date 00/00/0000
SDS Number 350000021022 GEN_SOF Number 45845
Components
CAS-No.
mg/m3
ppm
Non-
standard
units
Basis
Ethyl alcohol
64-17-5
1,900 mg/m3
1,000 ppm
-
OSHA TWA
Ethyl alcohol
64-17-5
-
1,000 ppm
- ACGIH
STEL
Respiratory protection
:
No special requirements.
Hand protection
:
No special requirements.
Eye protection
:
Safety glasses with side-shields
Skin and body protection
:
No special requirements.
Hygiene measures
:
Handle in accordance with good industrial hygiene and safety practice. Wash thoroughly after handling.
Form
:
liquid
Color
:
clear
Odor
:
pleasant
Odour Threshold
:
No data available
pH
:
6.0
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Occupational Exposure Limits
Personal protective equipment
9. PHYSICAL AND CHEMICAL PROPERTIES
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Page 5
Safety Data Sheet
according to Hazard Communication Standard; 29 CFR 1910.1200
Version 0.0
Print Date 09/06/2016
Revision Date 00/00/0000
SDS Number 350000021022 GEN_SOF Number 45845
at (20 °C)
Melting point/freezing point
:
No data available
Initial boiling point and boiling range
:
No data available
Flash point
:
64 °C
147.2 °F Method: Tag Closed Cup (TCC)
Evaporation rate
:
No data available
Flammability (solid, gas)
:
Does not sustain combustion.
Upper/lower flammability or explosive limits
:
No data available
Vapour pressure
:
No data available
Vapour density
:
No data available
Relative density
:
0.99 g/cm3 at 20 °C
Solubility(ies)
:
completely soluble
Partition coefficient: n­octanol/water
:
No data available
Auto-ignition temperature
:
No data available
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Page 6
Safety Data Sheet
according to Hazard Communication Standard; 29 CFR 1910.1200
Version 0.0
Print Date 09/06/2016
Revision Date 00/00/0000
SDS Number 350000021022 GEN_SOF Number 45845
Decomposition temperature
:
No data available
Viscosity, dynamic
:
No data available
Viscosity, kinematic
:
No data available
Oxidizing properties
:
No data available
Volatile Organic Compounds Total VOC (wt. %)*
:
0.5 % - additional exemptions may apply *as defined by US Federal and State Consumer Product Regulations
Other information
:
None identified
:
No data available
Possibility of hazardous reactions
:
If accidental mixing occurs and toxic gas is formed, exit area immediately. Do not return until well ventilated.
Conditions to avoid
:
Heat, flames and sparks.
Incompatible materials
:
Strong oxidizing agents Do not mix with bleach or any other household cleaners. Strong bases
Hazardous decomposition products
:
Thermal decomposition can lead to release of irritating gases and vapours.
10. STABILITY AND REACTIVITY
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Page 7
Safety Data Sheet
according to Hazard Communication Standard; 29 CFR 1910.1200
Version 0.0
Print Date 09/06/2016
Revision Date 00/00/0000
SDS Number 350000021022 GEN_SOF Number 45845
Emergency Overview
:
Warning
Acute oral toxicity
:
LD50 estimated > 5,000 mg/kg
Acute inhalation toxicity
:
LC50 Measured > 2.58 mg/l
Acute dermal toxicity
:
LD50 Measured > 5,050 mg/kg
GHS Properties
Classification
Routes of entry
Acute toxicity
No classification proposed
-
Skin corrosion/irritation
No classification proposed
-
Serious eye damage/eye irritation
No classification proposed
-
Skin sensitisation
No classification proposed
-
Respiratory sensitisation
No classification proposed
-
Germ cell mutagenicity
No classification proposed
-
Carcinogenicity
No classification proposed
-
Reproductive toxicity
No classification proposed
-
Specific target organ toxicity - single exposure
No classification proposed
- Specific target organ
No classification proposed
-
11. TOXICOLOGICAL INFORMATION
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Page 8
Safety Data Sheet
according to Hazard Communication Standard; 29 CFR 1910.1200
Version 0.0
Print Date 09/06/2016
Revision Date 00/00/0000
SDS Number 350000021022 GEN_SOF Number 45845
toxicity - repeated exposure
Aspiration hazard
No classification proposed
-
Aggravated Medical Condition
:
None known.
Ethyl alcohol
flow­through test LC50
Pimephales promelas (fathead minnow)
14,200 mg/l
96 h
Ethyl alcohol
static test EC50
Daphnia magna (Water flea)
2 mg/l
48 h
NOEC
Daphnia magna
9.6 mg/l
9 d
Components
End point
Species
Value
Exposure time
Components
End point
Species
Value
Exposure time
12. ECOLOGICAL INFORMATION
Product : The product itself has not been tested. Toxicity
The ingredients in this formula have been reviewed and no adverse impact to the environment is expected when used according to label directions.
Toxicity to fish
Toxicity to aquatic invertebrates
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Page 9
Safety Data Sheet
according to Hazard Communication Standard; 29 CFR 1910.1200
Version 0.0
Print Date 09/06/2016
Revision Date 00/00/0000
SDS Number 350000021022 GEN_SOF Number 45845
Ethyl alcohol
Static EC50
Chlorella vulgaris (Fresh water algae)
275 mg/l
72 h
Component
Biodegradation
Exposure time
Summary
Ethyl alcohol
97 %
28 d
Readily biodegradable
Component
Bioconcentration factor (BCF)
Partition Coefficient n­Octanol/water (log)
Ethyl alcohol
3.2 estimated
-0.35 Measured
Component
End point
Value
Ethyl alcohol
No data available
Component
Results
Ethyl alcohol
Not fulfilling PBT and vPvB criteria
Other adverse effects
:
None known. Consumer may discard empty container in trash, or recycle
Components
End point
Species
Value
Exposure time
Toxicity to aquatic plants
Persistence and degradability
Bioaccumulative potential
Mobility
PBT and vPvB assessment
13. DISPOSAL CONSIDERATIONS
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Page 10
Safety Data Sheet
according to Hazard Communication Standard; 29 CFR 1910.1200
Version 0.0
Print Date 09/06/2016
Revision Date 00/00/0000
SDS Number 350000021022 GEN_SOF Number 45845
where facilities exist.
Notification status
:
All ingredients of this product are listed or are excluded from listing on the U.S. Toxic Substances Control Act (TSCA) Chemical Substance Inventory.
Notification status
:
All ingredients of this product comply with the New Substances Notification requirements under the Canadian Environmental Protection Act (CEPA).
California Prop. 65
:
This product is not subject to the reporting requirements under California's Proposition 65.
14. TRANSPORT INFORMATION
Please refer to the Bill of Lading/receiving documents for up-to-date shipping information.
Land transport
Not classified as dangerous in the meaning of transport regulations.
Sea transport
Not classified as dangerous in the meaning of transport regulations.
Air transport
Not classified as dangerous in the meaning of transport regulations.
15. REGULATORY INFORMATION
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Page 11
Safety Data Sheet
according to Hazard Communication Standard; 29 CFR 1910.1200
Version 0.0
Print Date 09/06/2016
Revision Date 00/00/0000
SDS Number 350000021022 GEN_SOF Number 45845
Health
0
Flammability
2
Reactivity
0
Health
0
Fire
2
Reactivity
0
Special
-
Prepared by
SC Johnson Global Safety Assessment & Regulatory Affairs (GSARA)
16. OTHER INFORMATION
HMIS Ratings
NFPA Ratings
This information is being provided in accordance with the Occupational Safety and Health Administration (OSHA) regulation (29 CFR 1910.1200). The information supplied is designed for workplaces where product use and frequency of exposure exceeds that established for the labeled consumer use.
Further information
This document has been prepared using data from sources considered to be technically reliable. It does not constitute a warranty, expressed or implied, as to the accuracy of the information contained herein. Actual conditions of use are beyond the seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws and regulations.
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