Page 1
Safety Data Sheet
according to Hazard Communication Standard; 29 CFR 1910.1200
PLEDGE® MULTISURFACE WIPES - FRESH CITRUS
Version 1.1
Print Date 04/16/2019
Revision Date 02/25/2015
SDS Number 350000021055
350000021116
1/11
1. PRODUCT AND COMPANY IDENTIFICATION
Product information
Product name
:
PLEDGE® MULTISURFACE WIPES - FRESH CITRUS
Recommended use
:
Hard Surface Cleaner
Manufacturer, importer,
supplier
:
S.C. Johnson & Son, Inc.
1525 Howe Street
Racine WI 53403-2236
Telephone
:
+18005585252
Emergency telephone
number
:
24 Hour Medical Emergency Phone: (866)231-5406
24 Hour International Emergency Phone: (703)527-3887
24 Hour Transport Emergency Phone: (800)424-9300
2. HAZARDS IDENTIFICATION
Classification of the substance or mixture
Globally Harmonized System (GHS) Classification
This product does not meet the criteria for classification in any hazard class according to regulation
OSHA 29 CFR 1910.1200.
Labelling
Precautionary statements
Other hazards
:
None identified
3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name
CAS-No.
Weight percent
Cellulose
9004-34-6
10.00 - 30.00
Ethyl alcohol
64-17-5
0.10 - 1.00
The specific chemical identity and/or exact percentage (concentration) of this composition has been
withheld as a trade secret.
Page 2
Safety Data Sheet
according to Hazard Communication Standard; 29 CFR 1910.1200
PLEDGE® MULTISURFACE WIPES - FRESH CITRUS
Version 1.1
Print Date 04/16/2019
Revision Date 02/25/2015
SDS Number 350000021055
350000021116
2/11
For additional information on product ingredients, see www.whatsinsidescjohnson.com.
4. FIRST AID MEASURES
Eye contact
:
No special requirements
Skin contact
:
No special requirements
Inhalation
:
No special requirements.
Ingestion
:
No special requirements
5. FIREFIGHTING MEASURES
Suitable extinguishing
media
:
Use water spray, alcohol-resistant foam, dry chemical or
carbon dioxide.
Further information
:
Although this product has a flash point below 200 Deg F, it is
an aqueous solution containing an alcohol and does not
sustain combustion. Fight fire with normal precautions from a
reasonable distance. Standard procedure for chemical fires.
Wear full protective clothing and positive pressure selfcontained breathing apparatus. In case of fire and/or explosion
do not breathe fumes.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions
:
Wash thoroughly after handling.
Environmental
precautions
:
Outside of normal use, avoid release to the environment.
Methods and materials
for containment and
cleaning up
:
Sweep up and shovel into suitable containers for disposal.
Clean residue from spill site.
Page 3
Safety Data Sheet
according to Hazard Communication Standard; 29 CFR 1910.1200
PLEDGE® MULTISURFACE WIPES - FRESH CITRUS
Version 1.1
Print Date 04/16/2019
Revision Date 02/25/2015
SDS Number 350000021055
350000021116
3/11
7. HANDLING AND STORAGE
Handling
Precautions for safe
handling
:
Avoid contact with skin, eyes and clothing.
For personal protection see section 8.
KEEP OUT OF REACH OF CHILDREN AND PETS.
Advice on protection
against fire and explosion
:
Normal measures for preventive fire protection.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Occupational Exposure Limits
Components
CAS-No.
mg/m3
ppm
Non-
standard
units
Basis
Cellulose
9004-34-6
5 mg/m3
-
-
OSHA TWA
Cellulose
9004-34-6
15 mg/m3
-
-
OSHA TWA
Cellulose
9004-34-6
10 mg/m3
-
- ACGIH
TWA
Ethyl alcohol
64-17-5
1,900 mg/m3
1,000 ppm
-
OSHA TWA
Ethyl alcohol
64-17-5
-
1,000 ppm
- ACGIH
STEL
Personal protective equipment
Respiratory protection
:
No special requirements.
Hand protection
:
No special requirements.
Eye protection
:
No special requirements.
Skin and body protection
:
No special requirements.
Hygiene measures
:
Handle in accordance with good industrial hygiene and safety
Page 4
Safety Data Sheet
according to Hazard Communication Standard; 29 CFR 1910.1200
PLEDGE® MULTISURFACE WIPES - FRESH CITRUS
Version 1.1
Print Date 04/16/2019
Revision Date 02/25/2015
SDS Number 350000021055
350000021116
4/11
practice. Wash thoroughly after handling.
9. PHYSICAL AND CHEMICAL PROPERTIES
Form
:
solid
Color
:
white
Odor
:
pleasant
Odour Threshold
:
No data available
pH : 6.0
at (20 °C)
Melting point/freezing point
:
No data available
Initial boiling point and
boiling range
:
No data available
Flash point
:
64 °C
147.2 °F
Evaporation rate
:
No data available
Flammability (solid, gas)
:
Does not sustain combustion.
Upper/lower flammability or
explosive limits
:
No data available
Vapour pressure
:
Not applicable
Vapour density
:
No data available
Page 5
Safety Data Sheet
according to Hazard Communication Standard; 29 CFR 1910.1200
PLEDGE® MULTISURFACE WIPES - FRESH CITRUS
Version 1.1
Print Date 04/16/2019
Revision Date 02/25/2015
SDS Number 350000021055
350000021116
5/11
Relative density
:
No data available
Solubility(ies)
:
negligible
Partition coefficient: noctanol/water
:
No data available
Auto-ignition temperature
:
No data available
Decomposition temperature
:
No data available
Viscosity, dynamic
:
Not applicable
Viscosity, kinematic
:
Not applicable
Oxidizing properties
:
No data available
Volatile Organic
Compounds
Total VOC (wt. %)*
:
0.3 % - additional exemptions may apply
*as defined by US Federal and State Consumer Product
Regulations
Other information
:
None identified
:
10. STABILITY AND REACTIVITY
Possibility of hazardous
reactions
:
If accidental mixing occurs and toxic gas is formed, exit area
immediately. Do not return until well ventilated.
Conditions to avoid
:
Direct sources of heat.
Page 6
Safety Data Sheet
according to Hazard Communication Standard; 29 CFR 1910.1200
PLEDGE® MULTISURFACE WIPES - FRESH CITRUS
Version 1.1
Print Date 04/16/2019
Revision Date 02/25/2015
SDS Number 350000021055
350000021116
6/11
Incompatible materials
:
Do not mix with bleach or any other household cleaners.
Strong bases
Hazardous decomposition
products
:
Thermal decomposition can lead to release of irritating gases
and vapours.
11. TOXICOLOGICAL INFORMATION
Emergency Overview
:
This product does not meet the criteria for classification in any
hazard class according to regulation OSHA 29 CFR
1910.1200.
Acute oral toxicity
:
LD50
estimated
> 5,000 mg/kg
Acute inhalation toxicity
:
LC50
Measured
> 2.58 mg/l
Acute dermal toxicity
:
LD50
Measured
> 5,050 mg/kg
GHS Properties
Classification
Routes of entry
Acute toxicity
No classification proposed
-
Skin corrosion/irritation
No classification proposed
-
Serious eye
damage/eye irritation
No classification proposed
-
Skin sensitisation
No classification proposed
-
Respiratory
sensitisation
No classification proposed
-
Germ cell mutagenicity
No classification proposed
-
Page 7
Safety Data Sheet
according to Hazard Communication Standard; 29 CFR 1910.1200
PLEDGE® MULTISURFACE WIPES - FRESH CITRUS
Version 1.1
Print Date 04/16/2019
Revision Date 02/25/2015
SDS Number 350000021055
350000021116
7/11
Carcinogenicity
No classification proposed
-
Reproductive toxicity
No classification proposed
-
Specific target organ
toxicity - single
exposure
No classification proposed
-
Specific target organ
toxicity - repeated
exposure
No classification proposed
-
Aspiration hazard
No classification proposed
-
Aggravated Medical
Condition
:
None known.
12. ECOLOGICAL INFORMATION
Product : The product itself has not been tested.
Toxicity
The ingredients in this formula have been reviewed and no adverse impact to the environment is
expected when used according to label directions.
Toxicity to fish
Cellulose
No data
available
Ethyl alcohol
flowthrough
test LC50
Pimephales promelas
(fathead minnow)
14,200
mg/l
96 h
Toxicity to aquatic invertebrates
Components
End point
Species
Value
Exposure
time
Components
End point
Species
Value
Exposure
time
Page 8
Safety Data Sheet
according to Hazard Communication Standard; 29 CFR 1910.1200
PLEDGE® MULTISURFACE WIPES - FRESH CITRUS
Version 1.1
Print Date 04/16/2019
Revision Date 02/25/2015
SDS Number 350000021055
350000021116
8/11
Cellulose
No data
available
Ethyl alcohol
static test
EC50
Daphnia magna (Water
flea)
2 mg/l
48 h
NOEC
Daphnia magna
9.6 mg/l
9 d
Toxicity to aquatic plants
Cellulose
No data
available
Ethyl alcohol
Static
EC50
Chlorella vulgaris (Fresh
water algae)
275 mg/l
72 h
Persistence and degradability
Component
Biodegradation
Exposure
time
Summary
Cellulose
No data available
Ethyl alcohol
97 %
28 d
Readily biodegradable
Bioaccumulative potential
Component
Bioconcentration
factor (BCF)
Partition Coefficient nOctanol/water (log)
Cellulose
No data available
No data available
Ethyl alcohol
3.2 estimated
-0.35 Measured
Components
End point
Species
Value
Exposure
time
Page 9
Safety Data Sheet
according to Hazard Communication Standard; 29 CFR 1910.1200
PLEDGE® MULTISURFACE WIPES - FRESH CITRUS
Version 1.1
Print Date 04/16/2019
Revision Date 02/25/2015
SDS Number 350000021055
350000021116
9/11
Mobility
Component
End point
Value
Cellulose
No data available
Ethyl alcohol
No data available
PBT and vPvB assessment
Component
Results
Cellulose
Not fulfilling PBT and vPvB criteria
Ethyl alcohol
Not fulfilling PBT and vPvB criteria
Other adverse effects
:
None known.
13. DISPOSAL CONSIDERATIONS
Consumer may discard empty container in trash, or recycle
where facilities exist.
14. TRANSPORT INFORMATION
Please refer to the Bill of Lading/receiving documents for up-to-date shipping information.
Land transport
Not classified as dangerous in the meaning of transport regulations.
Sea transport
Not classified as dangerous in the meaning of transport regulations.
Air transport
Not classified as dangerous in the meaning of transport regulations.
15. REGULATORY INFORMATION
Page 10
Safety Data Sheet
according to Hazard Communication Standard; 29 CFR 1910.1200
PLEDGE® MULTISURFACE WIPES - FRESH CITRUS
Version 1.1
Print Date 04/16/2019
Revision Date 02/25/2015
SDS Number 350000021055
350000021116
10/11
Notification status
:
All ingredients of this product are listed or are excluded from
listing on the U.S. Toxic Substances Control Act (TSCA)
Chemical Substance Inventory.
Notification status
:
All ingredients of this product comply with the New Substances
Notification requirements under the Canadian Environmental
Protection Act (CEPA).
California Prop. 65
:
This product is not subject to the reporting requirements under
California's Proposition 65.
16. OTHER INFORMATION
HMIS Ratings
Health
0
Flammability
2
Reactivity
0
NFPA Ratings
Health
0
Fire
2
Reactivity
0
Special
-
This information is being provided in accordance with the Occupational Safety and Health Administration
(OSHA) regulation (29 CFR 1910.1200). The information supplied is designed for workplaces where
product use and frequency of exposure exceeds that established for the labeled consumer use.
Further information
Page 11
Safety Data Sheet
according to Hazard Communication Standard; 29 CFR 1910.1200
PLEDGE® MULTISURFACE WIPES - FRESH CITRUS
Version 1.1
Print Date 04/16/2019
Revision Date 02/25/2015
SDS Number 350000021055
350000021116
11/11
This document has been prepared using data from sources considered to be technically reliable. It does
not constitute a warranty, expressed or implied, as to the accuracy of the information contained herein.
Actual conditions of use are beyond the seller's control. User is responsible to evaluate all available
information when using product for any particular use and to comply with all Federal, State, Provincial
and Local laws and regulations.
Prepared by
SC Johnson Global Safety Assessment &
Regulatory Affairs (GSARA)
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