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307951
User Manual
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Pledge 307951 User Manual

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Page 1
Safety Data Sheet
according to Hazard Communication Standard; 29 CFR 1910.1200
Version 1.1
Print Date 03/04/2015
Revision Date 02/25/2015
SDS Number 350000021920
Product name
:
PLEDGE® MULTISURFACE II ANTIBACTERIAL (FRESH CITRUS)
Recommended use
:
Disinfectant
Manufacturer, importer, supplier
:
S.C. Johnson & Son, Inc. 1525 Howe Street Racine WI 53403-2236
Telephone
:
+18005585252
Emergency telephone number
:
24 Hour Medical Emergency Phone: (866)231-5406
24 Hour International Emergency Phone: (703)527-3887 24 Hour Transport Emergency Phone: (800)424-9300
Hazard classification
Hazard category
Hazards identification
Gases under pressure
Compressed gas
Contains gas under pressure; may explode if heated.
Other hazards
:
None identified
1. PRODUCT AND COMPANY IDENTIFICATION
Product information
2. HAZARDS IDENTIFICATION
Classification of the substance or mixture
Globally Harmonized System (GHS) Classification
Labelling Hazard symbols
Gas cylinder
Signal word Warning
Hazard statements
Contains gas under pressure; may explode if heated.
Precautionary statements
Protect from sunlight. Store in a well-ventilated place.
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Page 2
Safety Data Sheet
according to Hazard Communication Standard; 29 CFR 1910.1200
Version 1.1
Print Date 03/04/2015
Revision Date 02/25/2015
SDS Number 350000021920
Chemical Name
CAS-No.
Weight percent
Isopropanol
67-63-0
1.00 - 5.00
Alkyl ethylbenzalkonium
85409-23-0
0.0001 - 0.10
n-Alkyl Dimethyl Benzyl Ammonium Chloride
53516-76-0
0.0001 - 0.10
Eye contact
:
No special requirements
Skin contact
:
No special requirements
Inhalation
:
No special requirements.
Ingestion
:
No special requirements
Suitable extinguishing media
:
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Specific hazards during firefighting
:
Aerosol Product - Containers may rocket or explode in heat of fire.
Further information
:
Fight fire from maximum distance or protected area. Cool and use caution when approaching or handling fire-exposed containers. Wear full protective clothing and positive pressure self-contained breathing apparatus. In case of fire and/or explosion do not breathe fumes.
3. COMPOSITION/INFORMATION ON INGREDIENTS
The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret.
For additional information on product ingredients, see www.whatsinsidescjohnson.com.
4. FIRST AID MEASURES
5. FIREFIGHTING MEASURES
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Page 3
Safety Data Sheet
according to Hazard Communication Standard; 29 CFR 1910.1200
Version 1.1
Print Date 03/04/2015
Revision Date 02/25/2015
SDS Number 350000021920
Personal precautions
:
Remove all sources of ignition. Wash thoroughly after handling.
Environmental precautions
:
Outside of normal use, avoid release to the environment.
Methods and materials for containment and cleaning up
:
Sweep up and shovel into suitable containers for disposal. Clean residue from spill site.
Precautions for safe handling
:
Avoid contact with skin, eyes and clothing. For personal protection see section 8. KEEP OUT OF REACH OF CHILDREN AND PETS.
Advice on protection against fire and explosion
:
Normal measures for preventive fire protection.
Components
CAS-No.
mg/m3
ppm
Non-
standard
units
Basis
Isopropanol
67-63-0
980 mg/m3
400 ppm
-
OSHA TWA
Isopropanol
67-63-0
-
400 ppm
- ACGIH
STEL
Isopropanol
67-63-0
-
200 ppm
- ACGIH
TWA
Respiratory protection
:
No special requirements.
6. ACCIDENTAL RELEASE MEASURES
7. HANDLING AND STORAGE
Handling
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Occupational Exposure Limits
Personal protective equipment
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Page 4
Safety Data Sheet
according to Hazard Communication Standard; 29 CFR 1910.1200
Version 1.1
Print Date 03/04/2015
Revision Date 02/25/2015
SDS Number 350000021920
Hand protection
:
No special requirements.
Eye protection
:
No special requirements.
Skin and body protection
:
No special requirements.
Hygiene measures
:
Handle in accordance with good industrial hygiene and safety practice. Wash thoroughly after handling.
Form
:
aerosol Compressed gas
Color
:
clear
Odor
:
pleasant
Odour Threshold
:
No data available
pH
:
8.0 - 9.0 (undiluted)
Melting point/freezing point
:
No data available
Initial boiling point and boiling range
:
No data available
Flash point
:
does not flash
Evaporation rate
:
No data available
Flammability (solid, gas)
:
No data available
Upper/lower flammability or explosive limits
:
No data available
9. PHYSICAL AND CHEMICAL PROPERTIES
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Page 5
Safety Data Sheet
according to Hazard Communication Standard; 29 CFR 1910.1200
Version 1.1
Print Date 03/04/2015
Revision Date 02/25/2015
SDS Number 350000021920
Vapour pressure
:
No data available
Vapour density
:
No data available
Relative density
:
0.99 g/cm3 at 20 °C
Solubility(ies)
:
completely soluble
Partition coefficient: n­octanol/water
:
No data available
Auto-ignition temperature
:
No data available
Decomposition temperature
:
No data available
Viscosity, dynamic
:
No data available
Viscosity, kinematic
:
No data available
Oxidizing properties
:
No data available
Volatile Organic Compounds Total VOC (wt. %)*
:
1.7 % - additional exemptions may apply *as defined by US Federal and State Consumer Product Regulations
Other information
:
None identified
:
No data available
Possibility of hazardous
:
If accidental mixing occurs and toxic gas is formed, exit area
10. STABILITY AND REACTIVITY
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Page 6
Safety Data Sheet
according to Hazard Communication Standard; 29 CFR 1910.1200
Version 1.1
Print Date 03/04/2015
Revision Date 02/25/2015
SDS Number 350000021920
reactions
immediately. Do not return until well ventilated.
Conditions to avoid
:
Direct sources of heat.
Incompatible materials
:
Do not mix with bleach or any other household cleaners. Strong bases
Hazardous decomposition products
:
Thermal decomposition can lead to release of irritating gases and vapours.
Emergency Overview
:
Warning
Acute oral toxicity
:
LD50 Measured > 5,000 mg/kg
Acute inhalation toxicity
:
LC50 Measured > 5.11 mg/l
Acute dermal toxicity
:
LD50 Measured > 5,000 mg/kg GHS Properties
Classification
Routes of entry
Acute toxicity
No classification proposed
-
Skin corrosion/irritation
No classification proposed
-
Serious eye damage/eye irritation
No classification proposed
-
Skin sensitisation
No classification proposed
-
Respiratory sensitisation
No classification proposed
-
11. TOXICOLOGICAL INFORMATION
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Page 7
Safety Data Sheet
according to Hazard Communication Standard; 29 CFR 1910.1200
Version 1.1
Print Date 03/04/2015
Revision Date 02/25/2015
SDS Number 350000021920
Germ cell mutagenicity
No classification proposed
-
Carcinogenicity
No classification proposed
-
Reproductive toxicity
No classification proposed
-
Specific target organ toxicity - single exposure
No classification proposed
-
Specific target organ toxicity - repeated exposure
No classification proposed
-
Aspiration hazard
No classification proposed
-
Aggravated Medical Condition
:
None known.
Isopropanol
LC50
Pimephales promelas (fathead minnow)
9,640 mg/l
96 h Alkyl ethylbenzalkonium
No data available
n-Alkyl Dimethyl Benzyl Ammonium Chloride
No data available
Components
End point
Species
Value
Exposure time
12. ECOLOGICAL INFORMATION
Product : The product itself has not been tested. Toxicity
The ingredients in this formula have been reviewed and no adverse impact to the environment is expected when used according to label directions.
Toxicity to fish
Toxicity to aquatic invertebrates
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Page 8
Safety Data Sheet
according to Hazard Communication Standard; 29 CFR 1910.1200
Version 1.1
Print Date 03/04/2015
Revision Date 02/25/2015
SDS Number 350000021920
Isopropanol
EC50
Daphnia magna (Water flea)
13,299 mg/l
48 h Alkyl ethylbenzalkonium
EC50 No data available
Daphnia (water flea)
0.016 mg/l
n-Alkyl Dimethyl Benzyl Ammonium Chloride
No data available
Isopropanol
EC50
Desmodesmus subspicatus (green algae)
> 1,000 mg/l
72 h Alkyl ethylbenzalkonium
No data available
n-Alkyl Dimethyl Benzyl Ammonium Chloride
No data available
Component
Biodegradation
Exposure time
Summary
Isopropanol
53 %
5 d
Readily biodegradable
Alkyl ethylbenzalkonium
60 %
13 d
Readily biodegradable
n-Alkyl Dimethyl Benzyl Ammonium Chloride
No data available
Component
Bioconcentration factor (BCF)
Partition Coefficient n­Octanol/water (log)
Components
End point
Species
Value
Exposure time
Components
End point
Species
Value
Exposure time
Toxicity to aquatic plants
Persistence and degradability
Bioaccumulative potential
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Page 9
Safety Data Sheet
according to Hazard Communication Standard; 29 CFR 1910.1200
Version 1.1
Print Date 03/04/2015
Revision Date 02/25/2015
SDS Number 350000021920
Isopropanol
0.96 estimated
0.05
Alkyl ethylbenzalkonium
No data available
No data available
n-Alkyl Dimethyl Benzyl Ammonium Chloride
No data available
No data available
Component
End point
Value
Isopropanol
No data available
Alkyl ethylbenzalkonium
No data available
n-Alkyl Dimethyl Benzyl Ammonium Chloride
No data available
Component
Results
Isopropanol
Not fulfilling PBT and vPvB criteria
Alkyl ethylbenzalkonium
Not fulfilling PBT and vPvB criteria
n-Alkyl Dimethyl Benzyl Ammonium Chloride
Not fulfilling PBT and vPvB criteria
Other adverse effects
:
None known.
Consumer may discard empty container in trash, or recycle where facilities exist.
Mobility
PBT and vPvB assessment
13. DISPOSAL CONSIDERATIONS
14. TRANSPORT INFORMATION
Please refer to the Bill of Lading/receiving documents for up-to-date shipping information.
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Page 10
Safety Data Sheet
according to Hazard Communication Standard; 29 CFR 1910.1200
Version 1.1
Print Date 03/04/2015
Revision Date 02/25/2015
SDS Number 350000021920
Land transport
Sea transport
Air transport
UN number
1950
1950
1950
UN proper shipping name
UN 1950 AEROSOLS, Non-Flammable, 2.2, LTD QTY
UN 1950 AEROSOLS, Non­Flammable, 2.2, LTD QTY
UN 1950 AEROSOLS, Non-Flammable, 2.2, LTD QTY
Transport hazard class(es)
2.2 2 2.2
Packing group
- - -
Environmental hazards
-
- -
Special precautions for user
Limited quantities derogation may be applicable to this product, please check transport documents.
Limited quantities derogation may be applicable to this product, please check transport documents.
Limited quantities derogation may be applicable to this product, please check transport documents.
Notification status
:
All ingredients of this product are listed or are excluded from listing on the U.S. Toxic Substances Control Act (TSCA) Chemical Substance Inventory.
Notification status
:
All ingredients of this product comply with the New Substances Notification requirements under the Canadian Environmental
15. REGULATORY INFORMATION
FIFRA Labeling
This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets, and for workplace labels of non-pesticide chemicals. Following is the hazard information as required on the pesticide label:
Contents under pressure. Exposure to temperatures above 130° F may cause bursting.
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Page 11
Safety Data Sheet
according to Hazard Communication Standard; 29 CFR 1910.1200
Version 1.1
Print Date 03/04/2015
Revision Date 02/25/2015
SDS Number 350000021920
Protection Act (CEPA).
California Prop. 65
:
This product is not subject to the reporting requirements under California's Proposition 65.
Registration # / Agency
4822-576/US/EPA
Health
1
Flammability
0
Reactivity
0
Health
1
Fire
0
Reactivity
0
Special
-
16. OTHER INFORMATION
HMIS Ratings
NFPA Ratings
This information is being provided in accordance with the Occupational Safety and Health Administration (OSHA) regulation (29 CFR 1910.1200). The information supplied is designed for workplaces where product use and frequency of exposure exceeds that established for the labeled consumer use.
Further information
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Page 12
Safety Data Sheet
according to Hazard Communication Standard; 29 CFR 1910.1200
Version 1.1
Print Date 03/04/2015
Revision Date 02/25/2015
SDS Number 350000021920
Prepared by
SC Johnson Global Safety Assessment & Regulatory Affairs (GSARA)
This document has been prepared using data from sources considered to be technically reliable. It does not constitute a warranty, expressed or implied, as to the accuracy of the information contained herein. Actual conditions of use are beyond the seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws and regulations.
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