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SAFETY DATA SHEET
PHOTOCENTRIC 3D RESIN (FIRM)
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SAFETY DATA SHEET
PHOTOCENTRIC 3D RESIN (FIRM)
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Section 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
1.2. Relevant identified uses of the substance or mixture and uses advised against
Product name:
PHOTOCENTRIC 3D DAYLIGHT FIRM RESIN
Use of substance / mixture:
1.3. Details of the supplier of the safety data sheet
PC30: Photo-chemicals for 3D printing.
Company name: Photocentric Ltd
Cambridge house
Oxney Road
Peterborough
Cambridgeshire
PE1 5YW
England
Compilation date: 22/02/2017
Revision No: 2
1.4. Emergency telephone number
Emergency tel: +44 (0) 1733 349937
Section 2: Hazards identification
Tel: +44 (0) 1733 349937
Email:
(office hours only)
2.1. Classification of the substance or mixture
Classification under CLP: Aquatic Chronic 3: H412; Eye Irrit. 2: H319; Skin Irrit. 2: H315; Skin Sens. 1A: H317; STOT
SE 3: H335
Most important adverse effects: Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation.
May cause respiratory irritation. Harmful to aquatic life with long lasting effects.
2.2. Label elements
Label elements:
Hazard statements: H315: Causes skin irritation.
H317: May cause an allergic skin reaction.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
H412: Harmful to aquatic life with long lasting effects.
Hazard pictograms: GHS07: Exclamation mark
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Precautionary statements: P280: Wear protective gloves/protective clothing/eye protection/face protection.
Signal words: Warning
P302+352: IF ON SKIN: Wash with plenty of water/soap and water.
P304+340: IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305+351+338: IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
2.3. Other hazards
P312: Call a POISON CENTER/doctor if you feel unwell.
P321: Specific treatment (see instructions on this label).
PBT:
Section 3:
Composition/information
This product is not identified as a PBT/vPvB substance.
3.2. Mixtures
Hazardous ingredients:
BISPHENOL A ETHOXYLATE DIMETHACRYLATE
EINECS CAS PBT / WEL CLP Classification Percent
- Proprietary -
DIACRYLATE
- Proprietary -
ACRYLATE
- Proprietary - Skin Irrit. 2: H315; Eye Irrit. 2: H319 1-10%
ACRYLATE
- Proprietary - Eye Irrit. 2: H319; Skin Irrit. 2: H315;
ACRYLATE
- Proprietary -
PHOTOINITIATOR
- Proprietary - Flam. Sol. 1: H228; Repr. 2: H361f;
Section 4: First aid measures
4.1. Description of first aid measures
Skin contact: Remove all contaminated clothes and footwear immediately unless stuck to skin. W ash
on ingredients
Skin Irrit. 2: H315; Skin Sens. 1A:
H317; Eye Irrit. 2: H319; STOT SE 3:
H335
Eye Irrit. 2: H319; Skin Irrit. 2: H315;
Skin Sens. 1: H317
Skin Sens. 1: H317
Acute Tox. 4: H302; Skin Sens. 1A:
H317; Aquatic Chronic 1: H410
STOT RE 2: H373; Aquatic Chronic 2:
H411
50-70%
10-30%
1-10%
1-10%
1-2.5%
immediately with plenty of soap and water.
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4.2. Most important symptoms and effects, both acute and delayed
Eye contact: Bathe the eye with running water for 15 minutes. Consult a doctor.
Ingestion: Wash out mouth with water. Consult a doctor.
Inhalation: Remove casualty from exposure ensuring one's own safety whilst doing so. Consult a
doctor.
Delayed / immediate effects:
4.3. Indication of any immediate medical attention and special treatment needed
Skin contact: There may be irritation and redness at the site of contact.
Eye contact: There may be irritation and redness. The eyes may water profusely.
Ingestion: There may be soreness and redness of the mouth and throat.
Inhalation: There may be irritation of the throat with a feeling of tightness in the chest. Exposure may
cause coughing or wheezing.
Immediate effects can be expected after short-term exposure.
Immediate / special treatment:
Section 5: Fire-fighting measures
Eye bathing equipment should be available on the premises.
5.1. Extinguishing media
Extinguishing media: Suitable extinguishing media for the surrounding fire should be used. Use water spray
5.2. Special hazards arising from the substance or mixture
to cool containers.
5.3. Advice for fire-fighters
Exposure hazards:
Advice for fire-fighters: Wear self-contained breathing apparatus. Wear protective clothing to prevent contact
In combustion emits toxic fumes.
with skin and eyes.
Section 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Personal precautions: Refer to section 8 of SDS for personal protection details. If outside do not approach from
downwind. If outside keep bystanders upwind and away from danger point. Mark out the
contaminated area with signs and prevent access to unauthorised personnel. Turn
6.2. Environmental precautions
leaking containers leak-side up to prevent the escape of liquid.
Environmental precautions:
6.3. Methods and material for containment and cleaning up
Do not discharge into drains or rivers. Contain the spillage using bunding.
Clean-up procedures: Absorb into dry earth or sand. Transfer to a closable, labelled salvage container for
disposal by an appropriate method.
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6.4. Reference to other sections
Reference to other sections:
Section 7: Handling and storage
7.1. Precautions for safe handling
Handling requirements: Avoid direct contact with the substance. Ensure there is sufficient ventilation of the area.
7.2. Conditions for safe storage, including any incompatibilities
7.3. Specific end use(s)
Storage conditions:
Section 8: Exposure controls/personal protection
Specific end use(s):
8.1. Control parameters
Workplace exposure limits:
DNEL/PNEC Values
8.2. Exposure controls
DNEL / PNEC
Section 9: Physical and chemical properties
Engineering measures: Ensure there is sufficient ventilation of the area.
Respiratory protection: Self-contained breathing apparatus must be available in case of emergency.
Hand protection: Protective gloves.
Eye protection: Safety glasses. Ensure eye bath is to hand.
Skin protection:
9.1. Information on basic physical and chemical properties
Evaporation rate:
Solubility in water:
Also soluble in:
Flammability limits %: lower:
Kinematic viscosity:
Viscosity test method:
Boiling point/range°C:
Colour:
Odour:
Oxidising:
Viscosity:
Flash point°C:
State:
Refer to section 8 of SDS.
Do not handle in a confined space. Avoid the formation or spread of mists in the air.
Store in a cool, well ventilated area. Keep container tightly closed.
No data available.
No data available.
No data available.
Protective clothing.
Liquid
Various colours
Characteristic odour
Negligible
No data available.
No data available.
Most organic solvents.
Viscous
200-300cPs
Brookfield Spindle L2 @ 25 C
No data available.
No data available.
>93
Melting point/range°C: No data available.
upper: No data available.
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Autoflammability°C: No data available. Relative density: No data available.
9.2. Other information
pH: No data available. VOC g/l: No data available.
Other information:
Section 10: Stability and reactivity
No data available.
10.1. Reactivity
10.2. Chemical stability
Reactivity:
Stable under recommended transport or storage conditions.
10.3. Possibility of hazardous reactions
Chemical stability:
Stable under normal conditions.
10.4. Conditions to avoid
Hazardous reactions: Hazardous reactions will not occur under normal transport or storage conditions.
Decomposition may occur on exposure to conditions or materials listed below.
10.5. Incompatible materials
Conditions to avoid:
Heat.
10.6. Hazardous decomposition products
Materials to avoid:
Strong oxidising agents. Strong acids.
Haz. decomp. products:
Section 11: Toxicological information
In combustion emits toxic fumes.
11.1. Information on toxicological effects
Part.coeff. n-octanol/water: No data available.
Hazardous ingredients:
DIACRYLATE
IPR RAT LD50 760 mg/kg
ORL RAT LD50 5 gm/kg
ACRYLATE
IPR RAT LD50 55 mg/kg
ORL RAT LD50 5190 µl/kg
Relevant hazards for product:
Hazard Route Basis
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Skin corrosion/irritation DRM Hazardous: calculated
Serious eye damage/irritation OPT Hazardous: calculated
Respiratory/skin sensitisation - Hazardous: calculated
STOT-single exposure INH Hazardous: calculated
Symptoms / routes of exposure
Skin contact: There may be irritation and redness at the site of contact.
Eye contact: There may be irritation and redness. The eyes may water profusely.
Ingestion: There may be soreness and redness of the mouth and throat.
Inhalation: There may be irritation of the throat with a feeling of tightness in the chest. Exposure may
cause coughing or wheezing.
Delayed / immediate effects:
Immediate effects can be expected after short-term exposure.
Section 12: Ecological information
12.1. Toxicity
12.2. Persistence and degradability
Ecotoxicity values:
No data available.
Persistence and degradability:
12.3. Bioaccumulative potential
Biodegradable.
Bioaccumulative potential:
12.4. Mobility in soil
12.5. Results of PBT and vPvB assessment
Mobility:
No bioaccumulation potential.
Readily absorbed into soil.
12.6. Other adverse effects
PBT identification:
This product is not identified as a PBT/vPvB substance.
Other adverse effects:
Section 13: Disposal considerations
Negligible ecotoxicity.
13.1. Waste treatment methods
Disposal operations: Transfer to a suitable container and arrange for collection by specialised disposal
Section 14: Transport information
Transport class:
company.
NB: The user's attention is drawn to the possible existence of regional or national
regulations regarding disposal.
This product does not require a classification for transport.
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[final page]
Section 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
15.2. Chemical Safety Assessment
Chemical safety assessment: A chemical safety assessment has not been carried out for the substance or the mixture
Specific regulations:
Not applicable.
Section 16: Other information
by the supplier.
Other information
Phrases used in s.2 and s.3: H228: Flammable solid.
Other information: This safety data sheet is prepared in accordance with Commission Regulation (EU) No
2015/830.
* indicates text in the SDS which has changed since the last revision.
H302: Harmful if swallowed.
H315: Causes skin irritation.
H317: May cause an allergic skin reaction.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
H361f: Suspected of damaging fertility.
H373: May cause damage to organs <or state all organs affected, if known> through
prolonged or repeated exposure <state route of exposure if it is conclusively proven that
no other routes of exposure cause the hazard>.
H410: Very toxic to aquatic life with long lasting effects.
H411: Toxic to aquatic life with long lasting effects.
H412: Harmful to aquatic life with long lasting effects.
Legal disclaimer: The above information is believed to be correct but does not purport to be all inclusive
and shall be used only as a guide. This company shall not be held liable for any
damage resulting from handling or from contact with the above product.
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