MATERIAL SAFETY DATA SHEET
According EC 91/155
1. Identification of the substance/preparation
MSDS : 22464
Product code 12nc : 4222 018 55311
Supplier : PHILIPS DOMESTIC APPLIANCES AND PERSONALCARE
Tradename : CLEANING FLUID HQ200
General description : CLEANING FLUID
Use : Various
Publicationdate : 2005-04-12
Emergency phonenumber +31 (0)497-598315
2. Composition/information on ingredients
Component CAS-number EC-number Percentage EC-label
WATER 7732-18-5 231-791-2 ≥95.0 %
ALCOHOLS, C10-12, ETHOXYLATED, PROPOXYLATED 68154-97-2 <1.0 % Xi,N;R: 41-51/53
PHENOXYETHANOL, 2- 122-99-6 204-589-7 <2.0 % Xn;R: 22-36
BRONOPOL (INN) 52-51-7 200-143-0 <0.5 % Xn,N;R: 21/22-37/38-41-50
3. Hazard identification
4. First-aid measures
Skin : Remove residue substance as soon as possible from the skin (f.i. rinse with much water).
Ingestion : Let drink 1 or 2 glasses of water. In case of general disorders call for a doctor.
Inhalation : Bring the victim into the fresh air as soon as possible, let rest and if necessary call for a doctor.
Eyes : Rinse for a long time with much water. In case of eye-sight disturbances consult a doctor.
Remarks first aid : none
5. Fire fighting measures
Fire-extinguisher : determined by surrounding
Hazardous decomposition products in fire : carbon monoxide
6. Accidental_release measures
Spillage procedure : Absorb the liquid in appropriate absorbent (e.g. Powersorb, dry sand, diatomite, vermiculite etc.), shovel the
Emergency procedure : not applicable
mixture into plastic bags and remove to the central depot for hazardous waste.
7. Handling and storage
Local exhausting : Under normal circumstances not applicable.
Storage conditions : Product must be stored frost free.
Storage code (on behalf of PGS
15)
: none
8. Exposure controls/personal protection
Exposure limits :
Remarks exposure limits :
Odour threshold (20ºC; 1013 mbar) :
Advised personal protection :
applicable to: Netherlands (20 ºC; 1013 mbar)
No MAC(STEL) has been laid down. WATER
No MAC(STEL) has been laid down. ALCOHOLS, C10-12, ETHOXYLATED, PROPOXYLATED
TLV: 110 mg/m3 PHENOXYETHANOL, 2No MAC(STEL) has been laid down. BRONOPOL (INN)
applicable to: Germany (20 ºC; 1013 mbar)
TLV: 110 mg/m3 PHENOXYETHANOL, 2C=Ceiling; S=Skin
none
not traceable
skin : none (when used normally)
eyes : none (when used normally)
inhalation : none (when sufficient exhausting)
MSDS 22464 created on 2005-11-16 - page 1
9. Physical and chemical properties
Physical state : liquid
Colour : type dependent
Odour : like lemon
Vapor rate/range : not traceable
Boiling point/range : ≥100 ºC (1013 mbar)
Melting point/range : ≤0 ºC
Flash point/range : not applicable
Explosive limits : not applicable
Dust explosions possible in air : not applicable
Relative density : ≥1.000 -≤1.025 (water=1) (20 ºC)
Vapour pressure : ≤2.3 kPa (20 ºC)
Solubility in water : complete
Solubility in fat : not traceable
pH : ≥5 -≤9
Viscosity : 1.0 mPa.s (20 ºC)
Autoignition temperature : not applicable
Decomposition temperature : not traceable
Electrostatic chargement : no
10. Stability and reactivity
Conditions to avoid : none
Reactions with water : no
Hazardous reactions with : none
Hazardous decomposition products at heating : none
11. Toxicological information
Symptoms
Skin * local : The substance is prickling: redness.
Ingestion * local : The substance is prickling: sore throat.
Inhalation * local : The substance is with atomising prickling: sore throat.
Eyes * local : The substance is prickling: redness.
Remarks symptoms : None
* general : Probably no absorbtion worth mentioning.
* general : Probably no absorbtion worth mentioning.
* general : Probably no absorbtion worth mentioning.
Toxicity :
LD-50: 2.06 g/kg (ORL-RAT), ALCOHOLS, C10-12, ETHOXYLATED, PROPOXYLATED Source : Supplier
LD-50: 1.26 g/kg (ORL-RAT), PHENOXYETHANOL, 2- Source : IUCLID
LD-50: 14.422 g/kg (SKN-RAT), PHENOXYETHANOL, 2- Source : IUCLID
LD-50: 554 mg/kg (IPR-RAT), PHENOXYETHANOL, 2- Source : Sigma-Aldrich
LD-50: 180 mg/kg (ORL-RAT), BRONOPOL (INN) Source : Easi View
LD-50: 1.6 g/kg (SKN-RAT), BRONOPOL (INN) Source : Easi View
Ames test : negative PHENOXYETHANOL, 2- Source : IUCLID
12. Ecotoxicological information
Biological oxygen demand (5) : 0.002 g/g PHENOXYETHANOL, 2- Source : IUCLID
Chemical oxygen demand : 2.127 g/g PHENOXYETHANOL, 2- Source : IUCLID
Biological(5)/chemical oxygen
demand ratio
Degradability : easy degradable PHENOXYETHANOL, 2- Source : IUCLID
Biochemical factor : not traceable
Log Po/w : 1.13 PHENOXYETHANOL, 2- Source : IUCLID
Henry Constant : 2.02E-7 atm m3/mol PHENOXYETHANOL, 2- Source : Easi View
Ecotoxicity :
LC-50: 344 mg/l/96H (Fish), PHENOXYETHANOL, 2- Source : IUCLID
EC-50: >500 mg/l/48H (Daphnia), PHENOXYETHANOL, 2- Source : IUCLID
IC-50: >500 mg/l/72H (Algae), PHENOXYETHANOL, 2- Source : IUCLID
LC-50: 0.167 mg/l/96H (Fish), BRONOPOL (INN) Source : Easi View
EC-50: 0.01 mg/l/48H (Daphnia), BRONOPOL (INN) Source : Easi View
Remarks on ecotoxicity : none
: 0.0009 PHENOXYETHANOL, 2-
2.7 BRONOPOL (INN) Source : Easi View
13. Disposal considerations
Remainder material or uncleaned empty packagings have to be incinerated in a proper installation or dumped on an approved landfill, in accordance
with local and national legislation. Consider also return delivery to supplier.
14. Transport information
MSDS 22464 created on 2005-11-16 - page 2