Persil 09421 User Manual

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F-161

Safety Data Sheet

Revision Number: 003.0

Issue Date: 10/20/2015

The Dial Corporation, a Henkel Company; 7201 E. Henkel Way; Scottsdale, AZ 85255-9672

Persil Proclean Power-Liquid

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HAZARD CLASS

HAZARD CATEGORY

SKIN IRRITATION

EYE IRRITATION

The hazards described in this OSHA Globally Harmonized System Safety Data Sheet (SDS) are not intended for consumers, and does not address consumer use of the product. For information regarding consumer applications of this product, refer to the product label.

1. IDENTIFICATION OF THE SUBSTANCE OR MIXTURE AND OF THE SUPPLIER

Product identifier used on the label: Persil Proclean Power-Liquid – Original Scent, Intense Fresh, Sensitive Skin, Coldwater, Extra Fresh Linen Persil Proclean Power-Liquid 2in1 – Original Scent

Other means of identification: 1936304, 1932506 (Original); 1932509 (Intense Fresh); 1932511 (Sensitive Skin); 2047699 (Coldwater);

Recommended use of the chemical and restrictions on use: Universal, No restrictions on use. Name, address and telephone number of the chemical manufacturer:

Emergency telephone number: Medical Emergencies: 1-888-689-9082

The Dial Corporation, a Henkel Company 7201 E. Henkel Way Scottsdale, AZ 85255-9672 USA

CHEMTREC: 1-800-424-9300 (24 hours daily) Internet: www.henkelna.com

2061233 (Extra Fresh Linen); 1936322 (2in1)

2. HAZARD IDENTIFICATION

Classification of the substance or mixture in accordance with paragraph (d) of §1910.1200

Signal word, hazard statement(s), symbol(s) and precautionary statement(s) in accordance with paragraph (f) of §1910.1200

Signal word: WARNING Hazard Statement(s): Causes skin irritation.

Causes serious eye irritation.

Symbol(s): Precautionary Statements: Prevention: Wash thoroughly after handling.

Wear eye and face protection. Wear protective gloves.

Response: IF ON SKIN: Wash with plenty of soap and water.

IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to remove. Continue rinsing. If skin irritation occurs: Get medical attention. If eye irritation persists: Get medical attention. Take off contaminated clothing.

Storage: Not prescribed Disposal: Dispose of contents and/or container according to Federal, State/Provincial and local governmental regulations.

Hazards not otherwise classified: Not available.

Classification complies with OSHA Hazard Communication Standard (29 CFR 1910.1200) and is consistent with the provisions of the United Nations Globally Harmonized System of Classification and Labeling of Chemicals (GHS).

See Section 11 for additional toxicological information.

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The Dial Corporation, a Henkel Company; 7201 E. Henkel Way; Scottsdale, AZ 85255-9672

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3. COMPOSITION / INFORMATION ON INGREDIENTS

Chemical Name*

CAS Number (Unique Identifier)

Concentration

Alcohols, C10-16, ethoxylated, sulfates, sodium salts, 2EO

68585-34-2

10 – 30 %

Alcohols, C12-18, 7EO

68213-23-0

5 – 10 %

Benzenesulfonic acid, C10-13-alkyl derivs., sodium salts

68411-30-3

1 – 5 %

trisodium citrate

68-04-2

1 – 5 %

Alcohols, C12-18, 7-EO, sulfates, sodium salts

68081-91-4

1 – 5 %

Propane-1,2-diol

57-55-6

1 – 5 %

Sodium EDTA

64-02-8

1 – 5 %

Ethanol denatured

64-17-5

0 - 5 %

Boric acid / Sodium metaborate

10043-35-3 / 7775-19-1

0.1 – 1 %

The following chemicals are classified as health hazards in accordance with paragraph (d) of § 1910.1200.

*The specific chemical identity and/or exact percentage (concentration) of composition has been withheld because a trade secret is claimed in accordance with paragraph (i) of §1910.1200.

4. FIRST AID MEASURES

Description of necessary measures

Most important symptoms and effects, both acute and delayed

Indication of any immediate medical attention and special treatment needed

Inhalation: Remove from exposure area to fresh air. Contact physician or local poison control center. Skin contact: Rinse affected area with large amounts of water until no evidence of product remains. Get medical attention if irritation persists. Eye contact: Rinse eyes immediately with plenty of water, occasionally lifting upper and lower lids, until no evidence of product remains. Get

medical attention if pain or irritation persist. Ingestion: Dilution by rinsing the mouth and giving water or milk to drink is generally recommended. Contact physician or local poison control center.

After eye contact: Moderate to strong irritation of the eyes (redness, swelling, burning, watering eyes). After skin contact: Temporary irritation of the skin (redness, swelling, burning). After inhalation: Breathing high vapor concentrations may produce anesthetic effects, nausea, dizziness, headache. After ingestion: Ingestion may cause irritation of mouth, throat, digestive tract, diarrhea and vomiting.

After eye contact: Hold eye open and rinse slowly and gently with water for 15 - 20 minutes. After skin contact: Rinse affected area with large amounts water until no evidence of product remains. After inhalation: Remove from exposure area to fresh air. After ingestion: Dilution by rinsing the mouth and giving water or milk to drink is generally recommended.

5. FIRE FIGHTING MEASURES

Suitable (and unsuitable) extinguishing media

Specific hazards arising from the chemical

Oxides of carbon and oxides of nitrogen.

Special protective equipment and precautions for fire-fighters

In case of fire, wear a full-face positive-pressure self-contained breathing apparatus and protective suit. Shut off all ignition sources Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Avoid breathing vapors, keep upwind. Keep unnecessary personnel away.

Suitable extinguishing media: Dry chemical, carbon dioxide, water spray or regular foam. Unsuitable extinguishing media: None

6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures Wear skin, eye and respiratory protection as recommended in Section 8. Stop or reduce any leaks if it is safe to do so. Spills present a slipping hazard. Keep unnecessary personnel away. Ensure clean-up is conducted by trained personnel only. Make sure area is slip-free before re-opening to traffic.

Environmental Precautions

Small or household quantities may be disposed in sewer or other liquid waste system. For larger quantities check with your local water treatment plant. Methods and materials for containment and cleaning up

SMALL SPILLS: Contain and absorb with sand or other non-combustible absorbent material and place into containers for later disposal. Wash site of spillage thoroughly with water. LARGE SPILLS: Dike far ahead of spill to prevent further movement. Recover by pumping or by using a suitable absorbent material and place into containers for later disposal. Dispose in suitable waste container.

7. HANDLING AND STORAGE

Precautions for safe handling

Do not get in eyes or skin. Do not ingest. Use with adequate ventilation. Avoid generating aerosols and mists. Keep the containers closed when not in use.

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The Dial Corporation, a Henkel Company; 7201 E. Henkel Way; Scottsdale, AZ 85255-9672

Persil Proclean Power-Liquid

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Hazardous Component(s)

ACGIH

OSHA PEL

AIHA WEEL

OTHER

Alcohols, C10-16, ethoxylated, sulfates, sodium salts, 2EO

None

Propane-1,2-diol

None

None 10 mg/m3 TWA Aerosol

None

Sodium EDTA

None

Ethanol denatured

1,000 ppm STEL

1,000 ppm (1,900 mg/m3) PEL

None

Conditions for safe storage, including any incompatibilities

Store away from incompatible substances, excessive heat, flames, sparks or other ignition sources. Storage areas for large quantities (warehouse) should be well ventilated. Keep the containers tightly closed when not in use.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

OSHA permissible exposure limit (PEL), American Conference of Governmental Industrial Hygienists (ACGIH) Threshold Limit Value (TLV), and any other exposure limit used or recommended by the chemical manufacturer, importer, or employer preparing the safety data sheet, where available.

Appropriate engineering controls

Provide local exhaust or general dilution ventilation to keep potential exposure to airborne contaminants below the permissible exposure limits where mists or vapors may be generated.

Individual protection measures

Respiratory: If respiratory protection is required, it must be based on the contamination levels found in the workplace, must not exceed the

working limits of the respirator and be jointly approved by the National Institute for Occupational Safety and Health and the Mine Safety and Health Administration (NIOSH-MSHA).

Eye: Splash-proof safety glasses are required to prevent eye contact where splashing of product may occur. Hand/Body: Chemical-resistant gloves are required where repeated or prolonged skin contact may occur. Protective clothing is required

where repeated or prolonged skin contact may occur.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance: liquid, colored or clear Odor: fresh, floral Odor threshold: Not available. pH: 8.2 – 8.6 (25 °C) Melting point/ range: Not available. Boiling point/range: Not available. Flash point: Not available. Evaporation rate: Not available. Flammable/Explosive limits - lower: Not available. Flammable/Explosive limits - upper: Not available. Vapor pressure: Not available. Vapor density: Not available. Solubility in water: Not available. Partition coefficient (n-octanol/water): Not available. Autoignition temperature: Not available. Decomposition temperature: Not available. Viscosity: 275 - 700 mPa.s VOC content: Not available. Specific gravity: 1.075 - 1.095 at 20 °C (68°F)

10. STABILITY AND REACTIVITY

Reactivity: This product reacts with acids. Chemical stability: Stable under normal ambient temperature (70°F, 21°C) and pressure (1 atm). Possibility of hazardous reactions: Hazardous polymerization does not occur under normal temperatures and pressures. Conditions to avoid: Avoid storing in direct sunlight and avoid extremes of temperature. Incompatible materials: Strong oxidizers, acids. Hazardous decomposition products: Thermal decomposition products may include oxides of carbon.

11. TOXICOLOGICAL INFORMATION

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The Dial Corporation, a Henkel Company; 7201 E. Henkel Way; Scottsdale, AZ 85255-9672

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Likely routes of exposure including symptoms related to characteristics

Hazardous Component(s)

LD50s and LC50s

Immediate and Delayed Health Effects

Alcohols, C10-16, ethoxylated, sulfates, sodium salts, 2EO

None

Irritant Alcohols, C12-18, 7EO

Oral LD50 (RAT) = 1,700 mg/kg

Central nervous system, Irritant

Benzenesulfonic acid, C10-13-alkyl derivs., sodium salts

Oral LD50 (RAT) = 1,080 mg/kg

Irritant trisodium citrate

None

Irritant, Metabolic

Alcohols, C12-18, 7-EO, sulfates, sodium salts

None

No Data

Propane-1,2-diol

Oral LD50 (RABBIT) = 18 g/kg Oral LD50 (RAT) = 30 g/kg

Irritant Sodium EDTA

Oral LD50 (RAT) = > 2.000 mg/kg

Irritant

Ethanol denatured

Oral LD50 (RAT) = 9,9 g/kg Oral LD50 (RAT) = 6,2 g/kg Oral LD50 (RAT) = 17,8 g/kg Oral LD50 (RAT) = 11,5 g/kg Oral LD50 (RAT) = 10,6 g/kg Oral LD50 (RAT) = 7.060 mg/kg Inhalation LC50 (RAT, 10 h) = 20000 ppm

Central nervous system, Irritant

Boric acid

Oral LD50 (RAT) = 2.660 mg/kg Dermal LD50 (RABBIT) = > 2.000 mg/kg Inhalation LC50 (RAT, 4 h) = > 0,002 mg/l

Behavioral, Central nervous system, Developmental, Gastrointestinal, Irritant, Kidney, Liver, Skin, Less weight gain and food intake.

Sodium metaborate, anhydrous

Oral LD50 (RAT) = 2.330 mg/kg

Cardiac, Central nervous system, Developmental, Gastrointestinal tract, Irritant, Kidney, Metabolic

Hazardous Component(s)

NTP Carcinogen

IARC Carcinogen

OSHA Carcinogen

Alcohols, C10-16, ethoxylated, sulfates, sodium salts, 2EO

Alcohols, C12-18, 7EO

Benzenesulfonic acid, C10-13-alkyl derivs., sodium salts

trisodium citrate

Alcohols, C12-18, 7-EO, sulfates, sodium salts

Propane-1,2-diol

Sodium EDTA

Ethanol denatured

Boric acid

Sodium metaborate, anhydrous

Other relevant toxicity information:

This product is a laundry care product. The use of this product by consumers is safe under normal and reasonable foreseen use.

Numerical measures of toxicity, including delayed and immediate effect

Inhalation: Unlikely to occur due to the physical properties of the product. Inhalation of product mist may cause irritation of the nose,

throat, and respiratory tract.

Skin contact: Repeated or prolonged excessive exposure may cause irritation or dermatitis. Eye contact: This product may cause irritation with stinging, tearing, and redness. Ingestion: Ingestion of large quantities may cause gastrointestinal irritation with nausea, vomiting and diarrhea. Physical/Chemical: No physical/chemical hazards are anticipated for this product.

Carcinogenicity information

Carcinogenicity None of the ingredients in this product are listed as carcinogens by the International Agency for Research on Cancer Mutagenicity None of the ingredients in this product are known to cause mutagenicity.

Toxicity to reproduction Not a Reproductive Toxicant.

(IARC), the National Toxicology Program (NTP) or the Occupational Safety and Health Administration (OSHA)..

12. ECOLOGICAL INFORMATION

Aquatic Toxicity:

The following toxicity information is available for the hazardous ingredient(s) when used as technical grade and is provided as reference for the occupational settings. This product is anticipated to be safe for the environment at concentrations predicted in household settings under normal use conditions.

Toxicity to fish:

The aquatic toxicity profile of this product has not been determined.

Toxicity to aquatic invertebrates:

The aquatic toxicity profile of this product has not been determined.

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The Dial Corporation, a Henkel Company; 7201 E. Henkel Way; Scottsdale, AZ 85255-9672

Persil Proclean Power-Liquid

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Hazardous substances

Result value

Route of application

Species

Method

Alcohols, C10-16, ethoxylated, sulfates, sodium salts, 2EO

readily biodegradable

aerobic

80 - 83 %

OECD 301 B Alcohols, C12-18, ethoxylated

readily biodegradable

aerobic

79 %

OECD 301 D

Benzenesulfonic acid, C10-13-alkyl derivs., sodium salts

readily biodegradable

aerobic

85 %

OECD 301 B trisodium citrate

readily biodegradable

aerobic

79 %

EU Method C.4-E

Propane-1,2-diol

readily biodegradable

aerobic

> 70 %

OECD 301 A

Ethanol denatured

readily biodegradable

aerobic

> 70 %

OECD Guideline 301 D (Ready Biodegradability: Closed Bottle Test)

Toxicity to algae:

The aquatic toxicity profile of this product has not been determined.

Persistence and degradability:

Bioaccumulation Potential: The bioaccumulation potential of this product has not been determined. Mobility: The mobility of this product (in soil and water) has not been determined.

13. DISPOSAL CONSIDERATIONS

Waste Number and Description: Not applicable Disposal Considerations: Not regulated

Disposal of products: This product is not a RCRA hazardous waste and can be disposed of in accordance with federal, state and local

regulations.

Disposal of packages: Do not reuse this container. Place in trash.

14. TRANSPORT INFORMATION

The information in this section is for reference only and should not take the place of a shipping paper (bill of lading) specific to an order. Please note that the proper shipping classification may vary by packaging, properties, and mode of transportation.

U.S. Department of Transportation Ground (49 CFR)

Proper shipping name: Not regulated Hazard class or division: None Identification number: None Packing group: None

International Air Transportation (ICAO/IATA)

Proper shipping name: Not regulated Hazard class or division: None Identification number: None Packing group: None

Water Transportation (IMO/IMDG)

Proper shipping name: Not regulated Hazard class or division: None Identification number: None Packing group: None

15. REGULATORY INFORMATION

Occupational safety and health act: Hazard Communication Standard, 29 CFR 1910.1200(g) Appendix D: The Occupational Safety and Health Administration (OSHA) require that the Safety Data Sheets (SDSs) are readily accessible to employees for all hazardous chemicals in the workplace. Since the use pattern and exposure in the workplace are generally not consistent with those experienced by consumers, this SDS may contain health hazard information not relevant to consumer use.

United States Regulatory Information

TSCA 8 (b) Inventory Status All components of this product are either listed on or exempt from the U.S. Toxic Substances Control Act

(TSCA) chemical substance inventory.

TSCA 12 (b) Export Notification: None above reporting de minimis CERCLA/SARA Section 302: None above reporting de minimis CERCLA/SARA Section 311/312: Not available. CERCLA/SARA Section 313: None above reporting de minimis

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The Dial Corporation, a Henkel Company; 7201 E. Henkel Way; Scottsdale, AZ 85255-9672

Persil Proclean Power-Liquid

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California Proposition 65: This product does not contain substances listed under California Proposition 65.

Canada Regulatory Information:

Canadian Environmental Protection Act:

Inventory Status: All components of this product are listed on either the Canadian Domestic Substances List (DSL) or the Non-Domestic Substances List (NDSL).

16. OTHER INFORMATION

DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel Corporation and its

affiliates (“Henkel”) does not assume responsibility for any results obtained by persons over whose methods Henkel has no control. It is the user’s

responsibility to determine the suitability of Henkel’s products or any production methods mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and persons against any hazards that may be involved in the handling and use of any Henkel’s products. In light of the foregoing, Henkel specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular purpose, arising from sale or use of Henkel’s products. Henkel further disclaims any liability for consequential or incidental damages of any kind, including lost profits.

This safety data sheet contains changes from the previous version in sections: 1, 3, 9, 11, 12 Prepared by: R&D Support Services Issue date: 10/20/2015 Supercedes: Rev. 2, 05/27/2015