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SAFETY DATA SHEET
Revision Date 21-Jul-2015
1. IDENTIFICATION
Product identifier
Product Name
Other means of identification
Product Code
Synonyms
Recommended use of the chemical and restrictions on use
Recommended Use
Uses advised against
Details of the supplier of the safety data sheet
Manufacturer Address
ITW Permatex
10 Columbus Blvd.
Hartford, CT 06106 USA
Company Phone Number
24 Hour Emergency Phone Number
FUEL TANK REPAIR 1 OZ.
84334
None
Sealant
No information available
Distributor
ITW Permatex Canada
35 Brownridge Road, Unit 1
Halton Hills, ON Canada L7G 0C6
Telephone: (800) 924-6994
1-87-Permatex
(877) 376-2839
Chem-Tel: 800-255-3924
International Emergency:
00+1+ 813-248-0585
Contract Number: MIS0003453
Version 1
E-mail address
2. HAZARDS IDENTIFICATION
Classification
OSHA Regulatory Status
This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)
Skin corrosion/irritation Category 2
Serious eye damage/eye irritation Category 2
Skin sensitization Category 1
Carcinogenicity Category 1A
Label elements
Emergency Overview
Danger
Causes skin irritation
Causes serious eye irritation
May cause an allergic skin reaction
May cause cancer
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Physical state Solid Odor AmineAppearance Gray
Precautionary Statements - Prevention
Obtain special instructions before use
Do not handle until all safety precautions have been read and understood
Use personal protective equipment as required
Wash face, hands and any exposed skin thoroughly after handling
Avoid breathing dust/fume/gas/mist/vapors/spray
Contaminated work clothing should not be allowed out of the workplace
Wear protective gloves/protective clothing/eye protection/face protection
Precautionary Statements - Response
IF exposed or concerned: Get medical advice/attention
Specific treatment (see supplemental first aid instructions on this label)
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
If eye irritation persists: Get medical advice/attention
IF ON SKIN: Wash with plenty of soap and water
Take off contaminated clothing and wash before reuse
If skin irritation or rash occurs: Get medical advice/attention
Precautionary Statements - Storage
Store locked up
Precautionary Statements - Disposal
Dispose of contents/container to an approved waste disposal plant
Hazards not otherwise classified (HNOC)
Not applicable
Other Information
Very toxic to aquatic life with long lasting effects
Unknown acute toxicity 69 % of the mixture consists of ingredient(s) of unknown toxicity
3. COMPOSITION/INFORMATION ON INGREDIENTS
substance(s)
Chemical Name CAS No Weight-% Trade Secret
MAGNESIUM SILICATE 14807-96-6 30 - 60 *
GLASS OXIDE 65997-17-3 10 - 30 *
BISPHENOL A/EPICHLOROHYDRIN BASED
EPOXY RESIN
FERROSILICON 8049-17-0 5 - 10 *
CHLORINATED PARAFFIN 63449-39-8 1 - 5 *
SILICA, QUARTZ 14808-60-7 0.1 - 1 *
*The exact percentage (concentration) of composition has been withheld as a trade secret.
25068-38-6 10 - 30 *
4. FIRST AID MEASURES
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Description of first aid measures
General advice
Eye contact
Skin contact
Inhalation
Ingestion
Self-protection of the first aider
Most important symptoms and effects, both acute and delayed
Symptoms
Indication of any immediate medical attention and special treatment needed
Note to physicians
Get medical advice/attention if you feel unwell.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. If eye irritation persists: Get medical
advice/attention.
IF ON SKIN:. Wash with soap and water. If skin irritation or rash occurs: Get medical
advice/attention. Wash contaminated clothing before reuse.
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for
breathing. If symptoms persist, call a physician.
IF SWALLOWED:. Do NOT induce vomiting. Never give anything by mouth to an
unconscious person. Call a physician.
Use personal protective equipment as required. Avoid contact with skin, eyes or clothing.
See section 2 for more information.
Treat symptomatically.
5. FIRE-FIGHTING MEASURES
Suitable extinguishing media
Carbon dioxide (CO2), Dry chemical, Foam
Unsuitable extinguishing media
None.
Specific hazards arising from the chemical
None in particular.
Explosion data
Sensitivity to Mechanical Impact
Sensitivity to Static Discharge
Protective equipment and precautions for firefighters
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full
protective gear.
None.
None.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Personal precautions
Environmental precautions
Environmental precautions
Methods and material for containment and cleaning up
Methods for containment
Ensure adequate ventilation, especially in confined areas. Avoid contact with eyes and skin.
Use personal protective equipment as required.
See Section 12 for additional ecological information.
Prevent further leakage or spillage if safe to do so.
Methods for cleaning up
Ensure adequate ventilation. Sweep up and shovel into suitable containers for disposal.
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Prevention of secondary hazards
Clean contaminated objects and areas thoroughly observing environmental regulations.
7. HANDLING AND STORAGE
Precautions for safe handling
Advice on safe handling
Handle in accordance with good industrial hygiene and safety practice. Avoid breathing
vapors or mists. Avoid contact with skin, eyes or clothing. Wash thoroughly after handling.
Wash contaminated clothing before reuse. Use personal protective equipment as required.
Conditions for safe storage, including any incompatibilities
Storage Conditions
Incompatible materials
Store locked up.
Strong oxidizing agents
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters
Exposure Guidelines
Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH
MAGNESIUM SILICATE
14807-96-6
GLASS OXIDE
65997-17-3
SILICA, QUARTZ
14808-60-7
NIOSH IDLH Immediately Dangerous to Life or Health
.
TWA: 2 mg/m3 particulate matter
containing no asbestos and <1%
crystalline silica, respirable fraction
TWA: 1 fiber/cm3 respirable fibers:
length >5 µm, aspect ratio >=3:1, as
determined by the membrane filter
method at 400-450X magnification
[4-mm objective], using
phase-contrast illumination
TWA: 5 mg/m3 inhalable fraction
TWA: 0.025 mg/m3 respirable
fraction
(vacated) TWA: 2 mg/m3 respirable
dust <1% Crystalline silica,
containing no Asbestos
TWA: 20 mppcf if 1% Quartz or
more, use Quartz limit
- -
(vacated) TWA: 0.1 mg/m
respirable dust
: (30)/(%SiO2 + 2) mg/m3 TWA
total dust
: (250)/(%SiO2 + 5) mppcf TWA
respirable fraction
: (10)/(%SiO2 + 2) mg/m3 TWA
respirable fraction
3
IDLH: 1000 mg/m
TWA: 2 mg/m3 containing no
Asbestos and <1% Quartz
respirable dust
IDLH: 50 mg/m3 respirable dust
TWA: 0.05 mg/m3 respirable dust
3
Other Information
Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962
(11th Cir., 1992).
Appropriate engineering controls
Engineering Controls
Showers
Eyewash stations
Ventilation systems
Individual protection measures, such as personal protective equipment
Eye/face protection
Skin and body protection
Respiratory protection
Wear safety glasses with side shields (or goggles).
Wear protective gloves and protective clothing.
Use NIOSH-approved air-purifying respirator with organic vapor cartridge or canister, as
appropriate.
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General Hygiene Considerations
Handle in accordance with good industrial hygiene and safety practice. Regular cleaning of
equipment, work area and clothing is recommended.
9. PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
Physical state
Appearance
Odor
Odor threshold
Property
pH
Melting point / freezing point
Boiling point / boiling range
Flash point
Evaporation rate
Flammability (solid, gas)
Flammability Limit in Air
Upper flammability limit:
Lower flammability limit:
Vapor pressure
Vapor density
Relative density
Water solubility
Solubility in other solvents
Partition coefficient
Autoignition temperature
Decomposition temperature
Kinematic viscosity
Dynamic viscosity
Explosive properties
Oxidizing properties
Solid
Gray
Amine
No information available
Values
No information available
No information available
Not applicable
> 93 °C / > 200 °F
Not applicable
No information available
No information available
No information available
No information available
No information available
1.665
No information available
No information available
No information available
No information available
>200°C (>392°F)
No information available
No information available
No information available
No information available
Remarks • Method
Setaflash Closed Cup
Other Information
Softening point
Molecular weight
VOC Content (%)
Density
Bulk density
No information available
No information available
0
No information available
No information available
10. STABILITY AND REACTIVITY
Reactivity
No data available
Chemical stability
Stable under recommended storage conditions.
Possibility of Hazardous Reactions
None under normal processing.
Conditions to avoid
Excessive heat.
Incompatible materials
Strong oxidizing agents
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Hazardous Decomposition Products
Carbon oxides
Nitrogen oxides (NOx)
Halogenated compounds
Metal oxides
11. TOXICOLOGICAL INFORMATION
Information on likely routes of exposure
Inhalation
Eye contact
Skin contact
Ingestion
Chemical Name Oral LD50 Dermal LD50 Inhalation LC50
BISPHENOL
A/EPICHLOROHYDRIN BASED
EPOXY RESIN
25068-38-6
FERROSILICON
8049-17-0
CHLORINATED PARAFFIN
63449-39-8
SILICA, QUARTZ
14808-60-7
May cause irritation of respiratory tract.
Contact with eyes may cause irritation. May cause redness and tearing of the eyes.
May cause skin irritation and/or dermatitis. May cause sensitization by skin contact.
Ingestion may cause irritation to mucous membranes.
= 11400 mg/kg ( Rat ) - -
- > 20 g/kg ( Rabbit ) -
= 26100 mg/kg ( Rat ) > 10 mL/kg ( Rabbit ) -
= 500 mg/kg ( Rat ) - -
Information on toxicological effects
Symptoms
No information available.
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Sensitization
Germ cell mutagenicity
Carcinogenicity
Chemical Name ACGIH IARC NTP OSHA
MAGNESIUM SILICATE
14807-96-6
GLASS OXIDE
65997-17-3
CHLORINATED PARAFFIN
63449-39-8
SILICA, QUARTZ
14808-60-7
ACGIH (American Conference of Governmental Industrial Hygienists)
A2 - Suspected Human Carcinogen
IARC (International Agency for Research on Cancer)
Group 1 - Carcinogenic to Humans
Group 2B - Possibly Carcinogenic to Humans
Not classifiable as a human carcinogen
NTP (National Toxicology Program)
Known - Known Carcinogen
OSHA (Occupational Safety and Health Administration of the US Department of Labor)
X - Present
Target Organ Effects
No information available.
No information available.
The table below indicates whether each agency has listed any ingredient as a carcinogen.
- Group 3 - -
- Group 3 - -
- Group 2B - X
A2 Group 1 Known X
Central Vascular System (CVS), Eyes, Respiratory system.
The following values are calculated based on chapter 3.1 of the GHS document .
ATEmix (oral)
ATEmix (dermal)
12. ECOLOGICAL INFORMATION
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16755 mg/kg
54699 mg/kg
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Ecotoxicity
32 % of the mixture consists of components(s) of unknown hazards to the aquatic environment
Chemical Name Algae/aquatic plants Fish Crustacea
MAGNESIUM SILICATE
14807-96-6
CHLORINATED PARAFFIN
63449-39-8
Persistence and degradability
No information available.
Bioaccumulation
No information available.
Mobility
No information available.
- 100: 96 h Brachydanio rerio g/L
LC50 semi-static
- 300: 96 h Lepomis macrochirus
mg/L LC50 static 100: 96 h
Pimephales promelas mg/L LC50
static 94.5 - 271: 96 h
Oncorhynchus mykiss mg/L LC50
static 0.1: 96 h Lepomis
macrochirus mg/L LC50
flow-through 0.0109: 96 h
Oncorhynchus mykiss mg/L LC50
flow-through
-
102: 24 h Daphnia magna mg/L
EC50
Chemical Name Partition coefficient
CHLORINATED PARAFFIN
Other adverse effects
No information available
Waste treatment methods
Disposal of wastes
Contaminated packaging
US EPA Waste Number
DOT
Proper shipping name:
IATA
Proper shipping name:
63449-39-8
>6
13. DISPOSAL CONSIDERATIONS
Disposal should be in accordance with applicable regional, national and local laws and
regulations.
Do not reuse container.
Not applicable
14. TRANSPORT INFORMATION
Not regulated
Not regulated
IMDG
Proper shipping name:
Not regulated
15. REGULATORY INFORMATION
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International Inventories
TSCA
DSL/NDSL
EINECS/ELINCS
ENCS
IECSC
KECL
PICCS
AICS
Complies
Complies
Not determined
Not determined
Not determined
Not determined
Complies
Not determined
Legend:
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List
EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances
ENCS - Japan Existing and New Chemical Substances
IECSC - China Inventory of Existing Chemical Substances
KECL - Korean Existing and Evaluated Chemical Substances
PICCS - Philippines Inventory of Chemicals and Chemical Substances
AICS - Australian Inventory of Chemical Substances
US Federal Regulations
SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any
chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372
SARA 311/312 Hazard Categories
Acute health hazard
Chronic Health Hazard
Fire hazard
Sudden release of pressure hazard
Reactive Hazard
Yes
Yes
No
No
No
CWA (Clean Water Act)
This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40
CFR 122.42)
CERCLA
This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and
Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level
pertaining to releases of this material
US State Regulations
California Proposition 65
This product contains the following Proposition 65 chemicals
Chemical Name California Proposition 65
CHLORINATED PARAFFIN - 63449-39-8 Carcinogen
SILICA, QUARTZ - 14808-60-7 Carcinogen
U.S. State Right-to-Know Regulations
Chemical Name New Jersey Massachusetts Pennsylvania
MAGNESIUM SILICATE
14807-96-6
FERROSILICON
8049-17-0
CHLORINATED PARAFFIN
63449-39-8
3,6-DIAZAOCTANETHYLENEDIAM
IN
112-24-3
X X X
X - -
- X -
X X X
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SILICA, QUARTZ
14808-60-7
U.S. EPA Label Information
EPA Pesticide Registration Number
NFPA
HMIS
NFPA (National Fire Protection Association)
HMIS (Hazardous Material Information System)
Revision Date
Disclaimer
The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and belief
at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing,
storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The
information relates only to the specific material designated and may not be valid for such material used in combination
with any other materials or in any process, unless specified in the text.
Health hazards 2 Flammability 1
Health hazards 2 Flammability 1 Physical hazards 0 Personal protection B
Not applicable
21-Jul-2015
X X X
Instability 0
End of Safety Data Sheet
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