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SAFETY DATA SHEET
Revision Date 15-May-2020 Version 7
1. IDENTIFICATION
Product identifier
Product Name
Other means of identification
Product Code
Recommended use of the chemical and restrictions on use
Recommended Use
Uses advised against
Details of the supplier of the safety data sheet
Manufacturer Address
ITW Permatex
6875 Parkland Blvd.
Solon, Ohio 44139 USA
Telephone: 1-87-Permatex
(866) 732-9502
24-hour emergency phone number
Chem-Tel: 800-255-3924
International Emergency:
00+1+ 813-248-0585
Contract Number: MIS0003453
ULTRA BLACK GASKET MAKER 3.35OZ
82180
Sealant
No information available
May Also Be Distributed by:
ITW Permatex Canada
101-2360 Bristol Circle
Oakville, ON Canada L6H 6M5
Telephone: (800) 924-6994
E-mail address: [email protected]
2. HAZARDS IDENTIFICATION
Classification
OSHA Regulatory Status
This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)
Serious eye damage/eye irritation Category 2A
Skin sensitization Category 1
Carcinogenicity Category 2
Label elements
Emergency Overview
Signal word
Warning
Causes serious eye irritation
May cause an allergic skin reaction
Suspected of causing cancer
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Appearance Black Physical state Paste Liquid Odor Mild
Precautionary Statements - Prevention
Obtain special instructions before use
Do not handle until all safety precautions have been read and understood
Use personal protective equipment as required
Wash face, hands and any exposed skin thoroughly after handling
Avoid breathing dust/fume/gas/mist/vapors/spray
Contaminated work clothing should not be allowed out of the workplace
Wear protective gloves/protective clothing/eye protection/face protection
Precautionary Statements - Response
IF exposed or concerned: Get medical advice/attention
Specific treatment (see .? on this label)
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
If eye irritation persists: Get medical advice/attention
IF ON SKIN: Wash with plenty of soap and water
If skin irritation or rash occurs: Get medical advice/attention
Wash contaminated clothing before reuse
Precautionary Statements - Storage
Store locked up
Precautionary Statements - Disposal
Dispose of contents/container to an approved waste disposal plant
Hazards not otherwise classified (HNOC)
Not applicable
Other Information
Harmful to aquatic life with long lasting effects.
Unknown acute toxicity 0% of the mixture consists of ingredient(s) of unknown toxicity
3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name CAS No Weight-%
CALCIUM CARBONATE 471-34-1 15 - 40
LIMESTONE 1317-65-3 10 - 30
2-BUTANONE OXIME 96-29-7 1 - 5
CARBON BLACK 1333-86-4 0.1 - 1
4. FIRST AID MEASURES
Description of first aid measures
General advice
Eye contact
If symptoms persist, call a physician.
Immediately flush with plenty of water. After initial flushing, remove any contact lenses and
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continue flushing for at least 15 minutes. Keep eye wide open while rinsing. If symptoms
persist, call a physician.
Skin contact
Inhalation
Ingestion
Self-protection of the first aider
Most important symptoms and effects, both acute and delayed
Symptoms
Indication of any immediate medical attention and special treatment needed
Note to physicians
IF ON SKIN:. Wash with soap and water. If skin irritation or rash occurs: Get medical
advice/attention. Wash contaminated clothing before reuse. Immediate medical attention is
not required. Wash off immediately with soap and plenty of water while removing all
contaminated clothes and shoes. If skin irritation persists, call a physician.
Immediate medical attention is not required. If symptoms persist, call a physician. Move to
fresh air in case of accidental inhalation of vapors or decomposition products.
Clean mouth with water and drink afterwards plenty of water. Never give anything by mouth
to an unconscious person. Call a physician. Do NOT induce vomiting.
Use personal protective equipment as required.
May cause allergic skin reaction.
Treat symptomatically.
5. FIRE-FIGHTING MEASURES
Suitable extinguishing media
Use, Use dry chemical, Carbon dioxide (CO2), Water spray (fog), Alcohol resistant foam
Unsuitable extinguishing media
None
Specific hazards arising from the chemical
Keep product and empty container away from heat and sources of ignition. Risk of ignition.
Explosion data
Sensitivity to Mechanical Impact
Sensitivity to Static Discharge
Protective equipment and precautions for firefighters
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full
protective gear.
None.
None.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Personal precautions
Environmental precautions
Environmental precautions
Methods and material for containment and cleaning up
Methods for containment
Evacuate personnel to safe areas. Keep people away from and upwind of spill/leak.
Remove all sources of ignition. Pay attention to flashback. Take precautionary measures
against static discharges. Use personal protective equipment as required.
See section 12 for additional ecological information. Prevent further leakage or spillage if
safe to do so. Prevent product from entering drains.
Prevent further leakage or spillage if safe to do so.
Methods for cleaning up
Use personal protective equipment as required. Dam up. Cover liquid spill with sand, earth
or other non-combustible absorbent material. Take up mechanically, placing in appropriate
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containers for disposal. Clean contaminated surface thoroughly. Soak up with inert
absorbent material. Pick up and transfer to properly labeled containers. Take precautionary
measures against static discharges.
Prevention of secondary hazards
Clean contaminated objects and areas thoroughly observing environmental regulations.
7. HANDLING AND STORAGE
Precautions for safe handling
Advice on safe handling
Use with local exhaust ventilation. All equipment used when handling the product must be
grounded. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use
personal protective equipment as required. Do not breathe
dust/fume/gas/mist/vapors/spray. Take necessary action to avoid static electricity discharge
(which might cause ignition of organic vapors).
Conditions for safe storage, including any incompatibilities
Storage Conditions
Keep container tightly closed in a dry and well-ventilated place. Protect from moisture. Keep
containers tightly closed in a cool, well-ventilated place. Keep away from heat. Keep in
properly labeled containers.
Incompatible materials
Strong oxidizing agents, Acids, Water
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters
Exposure Guidelines
Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH
CALCIUM CARBONATE
471-34-1
LIMESTONE
1317-65-3
CARBON BLACK
1333-86-4
NIOSH IDLH Immediately Dangerous to Life or Health
.
- - TWA: 10 mg/m3 total dust
- TWA: 15 mg/m3 total dust
TWA: 3 mg/m3 inhalable particulate
matter
TWA: 5 mg/m3 respirable fraction
(vacated) TWA: 15 mg/m3 total
dust
(vacated) TWA: 5 mg/m3 respirable
fraction
TWA: 3.5 mg/m3
(vacated) TWA: 3.5 mg/m3
TWA: 5 mg/m3 respirable dust
TWA: 10 mg/m3 total dust
TWA: 5 mg/m3 respirable dust
IDLH: 1750 mg/m3
TWA: 3.5 mg/m3
TWA: 0.1 mg/m3 Carbon black in
presence of Polycyclic aromatic
hydrocarbons PAH
Other Information
Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962
(11th Cir., 1992).
Appropriate engineering controls
Engineering Controls
Showers
Eyewash stations
Ventilation systems
Individual protection measures, such as personal protective equipment
Eye/face protection
Skin and body protection
Respiratory protection
Tight sealing safety goggles.
Wear protective natural rubber, nitrile rubber, Neoprene™ or PVC gloves.
Use NIOSH-approved air-purifying respirator with organic vapor cartridge or canister, as
appropriate.
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General Hygiene Considerations
When using do not eat, drink or smoke. Regular cleaning of equipment, work area and
clothing is recommended.
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1. Information on basic physical and chemical properties
Physical state
Appearance
Odor
Odor threshold
Property Values Remarks • Method
pH
Melting point / freezing point
Boiling point / boiling range
Flash point
Evaporation rate
Flammability (solid, gas)
Flammability Limit in Air
Upper flammability limit:
Lower flammability limit:
Vapor pressure
Vapor density
Relative density
Water solubility
Solubility(ies)
Partition coefficient
Autoignition temperature
Decomposition temperature
Kinematic viscosity
Dynamic viscosity
Explosive properties
Oxidizing properties
Paste Liquid
Black
Mild
No information available
No information available
No information available
No information available Polymerization
> 95 °C / > 203 °F Tag Closed Cup
No information available
No information available
No information available
No information available
<5 mm Hg @ 80°F
>1 Air = 1
1.44
Not applicable Polymerization
No information available
No information available
No information available
No information available
No information available
No information available
No information available
No information available
Other Information
Softening point
Molecular weight
VOC Content (%)
Density
Bulk density
SADT (self-accelerating
decomposition temperature)
Reactivity
No information available
Chemical stability
Stable under normal conditions
Possibility of Hazardous Reactions
None under normal processing.
Conditions to avoid
Excessive heat. Heat, flames and sparks.
Incompatible materials
Strong oxidizing agents, Acids, Water
Hazardous Decomposition Products
No information available
No information available
3%
No information available
No information available
No information available
10. STABILITY AND REACTIVITY
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Carbon oxides
Nitrogen oxides (NOx)
Formaldehyde
May release 2-butanone oxime (ethyl methyl ketoxime) at elevated temperature
11. TOXICOLOGICAL INFORMATION
Information on likely routes of exposure
Inhalation
Eye contact
Skin contact
Ingestion
Chemical Name Oral LD50 Dermal LD50 Inhalation LC50
CALCIUM CARBONATE
471-34-1
2-BUTANONE OXIME
96-29-7
CARBON BLACK
1333-86-4
May cause irritation of respiratory tract.
Contact with eyes may cause irritation. May cause redness and tearing of the eyes.
May cause skin irritation and/or dermatitis. May cause sensitization by skin contact.
Ingestion may cause irritation to mucous membranes.
= 6450 mg/kg ( Rat ) - -
= 930 mg/kg ( Rat ) 1000 - 1800 mg/kg ( Rabbit ) > 4.83 mg/L ( Rat ) 4 h
> 15400 mg/kg ( Rat ) > 3 g/kg ( Rabbit ) -
Information on toxicological effects
Symptoms
No information available.
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Sensitization
Germ cell mutagenicity
Carcinogenicity
Chemical Name ACGIH IARC NTP OSHA
CARBON BLACK
1333-86-4
ACGIH (American Conference of Governmental Industrial Hygienists)
A3 - Animal Carcinogen
IARC (International Agency for Research on Cancer)
Group 2B - Possibly Carcinogenic to Humans
OSHA (Occupational Safety and Health Administration of the US Department of Labor)
X - Present
Target Organ Effects
No information available.
No information available.
The table below indicates whether each agency has listed any ingredient as a carcinogen.
A3 Group 2B - X
Eyes, Respiratory system, Skin.
The following values are calculated based on chapter 3.1 of the GHS document .
ATEmix (oral)
ATEmix (dermal)
14639 mg/kg
27922 mg/kg
12. ECOLOGICAL INFORMATION
Ecotoxicity
0.001 % of the mixture consists of component(s) of unknown hazards to the aquatic environment
Persistence and degradability
No information available.
Bioaccumulation
No information available.
Mobility
No information available.
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Chemical Name Partition coefficient
2-BUTANONE OXIME
96-29-7
Other adverse effects
No information available
0.65
13. DISPOSAL CONSIDERATIONS
Waste treatment methods
Disposal of wastes
Contaminated packaging
US EPA Waste Number
This product contains one or more substances that are listed with the State of California as a hazardous waste.
Disposal should be in accordance with applicable regional, national and local laws and
regulations.
Do not reuse container.
Not applicable
14. TRANSPORT INFORMATION
DOT
Ethanol
IATA
Ethanol
IMDG
Ethanol
Not regulated
Not regulated
Not regulated
15. REGULATORY INFORMATION
International Inventories
TSCA
DSL/NDSL
EINECS/ELINCS
ENCS
IECSC
KECL
PICCS
AICS
Complies
Complies
Does not comply
Does not comply
Complies
Complies
Complies
Complies
Legend:
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List
EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances
ENCS - Japan Existing and New Chemical Substances
IECSC - China Inventory of Existing Chemical Substances
KECL - Korean Existing and Evaluated Chemical Substances
PICCS - Philippines Inventory of Chemicals and Chemical Substances
AICS - Australian Inventory of Chemical Substances
US Federal Regulations
SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any
chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372
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SARA 311/312 Hazard Categories
Acute health hazard
Chronic Health Hazard
Fire hazard
Sudden release of pressure hazard
Reactive Hazard
Yes
No
No
No
No
CWA (Clean Water Act)
This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40
CFR 122.42)
CERCLA
This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and
Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level
pertaining to releases of this material
US State Regulations
California Proposition 65
This product contains the following Proposition 65 chemicals
Chemical Name
CARBON BLACK
1333-86-4
California Proposition 65
*Carcinogen (airborne, unbound particles of respirable
size)
SILICA, QUARTZ
14808-60-7
*Carcinogen (airborne particles of respirable size only)
• *The asterisked chemical(s) listed are not subject to Proposition 65 because they are not airborne in the finished product
U.S. State Right-to-Know Regulations
Chemical Name New Jersey Massachusetts Pennsylvania
LIMESTONE
1317-65-3
ALUMINIUM POWDER
7429-90-5
CARBON BLACK
1333-86-4
SILICA, QUARTZ
14808-60-7
X X X
X X X
X X X
X X X
U.S. EPA Label Information
EPA Pesticide Registration Number
Not applicable
WHMIS Hazard Class
D2B - Toxic materials
16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION OF THE LAST REVISION
NFPA Health hazards 2 Flammability 1 Instability 0
HMIS Health hazards 2 Flammability 1 Physical hazards 0
NFPA (National Fire Protection Association)
HMIS (Hazardous Material Information System)
Revision Date
15-May-2020
-
Personal protection B
Disclaimer
Illinois Tool Works Inc. believes the information contained in this data sheet is accurate as of the date compiled.
However, Illinois Tool Works Inc. makes no warranty, express or implied, as to the accuracy, reliability or completeness
of the information. User is responsible for evaluating whether such information or this product is fit for a particular
purpose and suitable for a particular use or application. The information in this data sheet may not be valid if this
product is used in combination with other products or in processes for which it was not designed. Illinois Tool Works Inc.
disclaims any liability for consequential or incidental damages of any kind, including lost profits, arising from the sale or
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use of this product. Ensure you have the most current version of this data sheet by contacting us or reviewing our web
site.
End of Safety Data Sheet
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