Page 1
SAFETY DATA SHEET
Revision Date 08-Feb-2019 Version 6
1. IDENTIFICATION
Product identifier
Product Name
Other means of identification
Product Code
Recommended use of the chemical and restrictions on use
Recommended Use
Uses advised against
Details of the supplier of the safety data sheet
Manufacturer Address
ITW Permatex
6875 Parkland Blvd.
Solon, Ohio 44139 USA
Telephone: 1-87-Permatex
(866) 732-9502
24-hour emergency phone number
Chem-Tel: 800-255-3924
International Emergency:
00+1+ 813-248-0585
Contract Number: MIS0003453
6BR SENSOR SAFE BLUE SILICONE RTV 3 OZ
80022
Sealant
No information available
May Also Be Distributed by:
ITW Permatex Canada
101-2360 Bristol Circle
Oakville, ON Canada L6H 6M5
Telephone: (800) 924-6994
E-mail address: [email protected]
2. HAZARDS IDENTIFICATION
Classification
OSHA Regulatory Status
This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)
Serious eye damage/eye irritation Category 2A
Skin sensitization Category 1
Carcinogenicity Category 2
Label elements
Emergency Overview
Signal word
Warning
Causes serious eye irritation
May cause an allergic skin reaction
Suspected of causing cancer
_____________________________________________________________________________________________
Page 1 / 8
Page 2
80022 - 6BR SENSOR SAFE BLUE SILICONE RTV 3
Revision Date 08-Feb-2019
OZ
_____________________________________________________________________________________________
Appearance Blue Physical state Paste Odor Mild
Precautionary Statements - Prevention
Obtain special instructions before use
Do not handle until all safety precautions have been read and understood
Use personal protective equipment as required
Wash face, hands and any exposed skin thoroughly after handling
Avoid breathing dust/fume/gas/mist/vapors/spray
Contaminated work clothing should not be allowed out of the workplace
Precautionary Statements - Response
IF exposed: Call a POISON CENTER or doctor/physician
Specific treatment (see supplemental first aid instructions on this label)
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
If eye irritation persists: Get medical advice/attention
IF ON SKIN: Wash with plenty of soap and water
If skin irritation or rash occurs: Get medical advice/attention
Wash contaminated clothing before reuse
Precautionary Statements - Storage
Store in a well-ventilated place. Keep container tightly closed
Precautionary Statements - Disposal
Dispose of contents/container to an approved waste disposal plant
Hazards not otherwise classified (HNOC)
Not applicable
Other Information
Not applicable
Unknown acute toxicity 30.554 % of the mixture consists of ingredient(s) of unknown toxicity
3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name CAS No Weight-%
LIMESTONE 1317-65-3 10 - 30
CALCIUM CARBONATE 471-34-1 10 - 30
DISTILLATES (PETROLEUM),
HYDROTREATED LIGHT
2-BUTANONE OXIME 96-29-7 1 - 5
64742-47-8 3 - 7
4. FIRST AID MEASURES
Description of first aid measures
General advice
Get medical advice/attention if you feel unwell.
_____________________________________________________________________________________________
Page 2 / 8
Page 3
80022 - 6BR SENSOR SAFE BLUE SILICONE RTV 3
Revision Date 08-Feb-2019
OZ
_____________________________________________________________________________________________
Eye contact
Skin contact
Inhalation
Ingestion
Self-protection of the first aider
Most important symptoms and effects, both acute and delayed
Symptoms
Indication of any immediate medical attention and special treatment needed
Note to physicians
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. If eye irritation persists: Get medical
advice/attention.
IF ON SKIN:. Wash with soap and water. If skin irritation or rash occurs: Get medical
advice/attention. Wash contaminated clothing before reuse.
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for
breathing. If symptoms persist, call a physician.
IF SWALLOWED:. Do NOT induce vomiting. Never give anything by mouth to an
unconscious person. Call a physician.
Use personal protective equipment as required.
May cause allergic skin reaction.
Treat symptomatically.
5. FIRE-FIGHTING MEASURES
Suitable extinguishing media
Carbon dioxide (CO2), Dry chemical, Foam
Unsuitable extinguishing media
None
Specific hazards arising from the chemical
None in particular.
Explosion data
Sensitivity to Mechanical Impact
Sensitivity to Static Discharge
Protective equipment and precautions for firefighters
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full
protective gear.
None.
None.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Personal precautions
Environmental precautions
Environmental precautions
Methods and material for containment and cleaning up
Methods for containment
Ensure adequate ventilation, especially in confined areas. Avoid contact with eyes and skin.
Use personal protective equipment as required.
See Section 12 for additional Ecological Information.
Prevent further leakage or spillage if safe to do so.
Methods for cleaning up
Ensure adequate ventilation. Flood with water to complete polymerization and scrape off
floor. Sweep up and shovel into suitable containers for disposal. Clean up spill thoroughly
as residue is slippery.
_____________________________________________________________________________________________
Page 3 / 8
Page 4
80022 - 6BR SENSOR SAFE BLUE SILICONE RTV 3
Revision Date 08-Feb-2019
OZ
_____________________________________________________________________________________________
Prevention of secondary hazards
Clean contaminated objects and areas thoroughly observing environmental regulations.
7. HANDLING AND STORAGE
Precautions for safe handling
Advice on safe handling
Handle in accordance with good industrial hygiene and safety practice. Avoid breathing
vapors or mists. Avoid contact with skin, eyes or clothing. Wash thoroughly after handling.
Wash contaminated clothing before reuse. Use personal protective equipment as required.
Conditions for safe storage, including any incompatibilities
Storage Conditions
Incompatible materials
Keep container tightly closed in a dry and well-ventilated place. Protect from moisture.
Strong oxidizing agents, Acids, Water
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters
Exposure Guidelines
Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH
LIMESTONE
1317-65-3
CALCIUM CARBONATE
471-34-1
NIOSH IDLH Immediately Dangerous to Life or Health
.
- TWA: 15 mg/m3 total dust
- - TWA: 10 mg/m3 total dust
TWA: 5 mg/m3 respirable fraction
(vacated) TWA: 15 mg/m3 total
dust
(vacated) TWA: 5 mg/m3 respirable
fraction
TWA: 10 mg/m3 total dust
TWA: 5 mg/m3 respirable dust
TWA: 5 mg/m3 respirable dust
Other Information
Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962
(11th Cir., 1992).
Appropriate engineering controls
Engineering Controls
Showers
Eyewash stations
Ventilation systems
Individual protection measures, such as personal protective equipment
Eye/face protection
Skin and body protection
Respiratory protection
Tight sealing safety goggles.
Wear protective natural rubber, nitrile rubber, Neoprene™ or PVC gloves.
Use NIOSH-approved air-purifying respirator with organic vapor cartridge or canister, as
appropriate.
General Hygiene Considerations
Handle in accordance with good industrial hygiene and safety practice. Regular cleaning of
equipment, work area and clothing is recommended.
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1. Information on basic physical and chemical properties
Physical state
Appearance
Odor
Odor threshold
Paste
Blue
Mild
No information available
_____________________________________________________________________________________________
Page 4 / 8
Page 5
80022 - 6BR SENSOR SAFE BLUE SILICONE RTV 3
Revision Date 08-Feb-2019
OZ
_____________________________________________________________________________________________
Property Values Remarks • Method
pH
Melting point / freezing point
Boiling point / boiling range
Flash point
Evaporation rate
Flammability (solid, gas)
Flammability Limit in Air
Upper flammability limit:
Lower flammability limit:
Vapor pressure
Vapor density
Relative density
Water solubility
Solubility(ies)
Partition coefficient
Autoignition temperature
Decomposition temperature
Kinematic viscosity
Dynamic viscosity
Explosive properties
Oxidizing properties
No information available
No information available
No information available Not
Applicable
> 100 °C / > 212 °F Tag Closed Cup
No information available
No information available
No information available
No information available
<5 mm Hg
>1 Air = 1
1.43
Not applicable Polymerization
No information available
No information available
No information available
No information available
No information available
No information available
No information available
No information available
Polymerization
Other Information
Softening point
Molecular weight
VOC Content (%)
Density
Bulk density
SADT (self-accelerating
decomposition temperature)
No information available
No information available
<3%, <43 g/l
No information available
No information available
No information available
10. STABILITY AND REACTIVITY
Reactivity
No information available
Chemical stability
Stable under normal conditions
Possibility of Hazardous Reactions
None under normal processing.
Conditions to avoid
Excessive heat.
Incompatible materials
Strong oxidizing agents, Acids, Water
Hazardous Decomposition Products
Carbon oxides
Nitrogen oxides (NOx)
Formaldehyde
May release 2-butanone oxime (ethyl methyl ketoxime) at elevated temperature
11. TOXICOLOGICAL INFORMATION
Information on likely routes of exposure
_____________________________________________________________________________________________
Page 5 / 8
Page 6
80022 - 6BR SENSOR SAFE BLUE SILICONE RTV 3
Revision Date 08-Feb-2019
OZ
_____________________________________________________________________________________________
Inhalation
Eye contact
Skin contact
Ingestion
Chemical Name Oral LD50 Dermal LD50 Inhalation LC50
CALCIUM CARBONATE
471-34-1
DISTILLATES (PETROLEUM),
HYDROTREATED LIGHT
64742-47-8
2-BUTANONE OXIME
96-29-7
May cause irritation of respiratory tract.
Contact with eyes may cause irritation. May cause redness and tearing of the eyes.
May cause skin irritation and/or dermatitis. May cause sensitization by skin contact.
Ingestion may cause irritation to mucous membranes.
= 6450 mg/kg ( Rat ) - > 5000 mg/kg ( Rat ) > 2000 mg/kg ( Rabbit ) > 5.2 mg/L ( Rat ) 4 h
= 930 mg/kg ( Rat ) 1000 - 1800 mg/kg ( Rabbit ) > 4.83 mg/L ( Rat ) 4 h
Information on toxicological effects
Symptoms
No information available.
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Sensitization
Germ cell mutagenicity
Carcinogenicity
Target Organ Effects
No information available.
No information available.
No information available.
Eyes, Respiratory system, Skin.
The following values are calculated based on chapter 3.1 of the GHS document .
ATEmix (oral)
ATEmix (dermal)
13876 mg/kg
10606 mg/kg
12. ECOLOGICAL INFORMATION
Ecotoxicity
95.074 % of the mixture consists of component(s) of unknown hazards to the aquatic environment
Persistence and degradability
No information available.
Bioaccumulation
No information available.
Mobility
No information available.
Chemical Name Partition coefficient
2-BUTANONE OXIME
96-29-7
0.65
Other adverse effects
No information available
13. DISPOSAL CONSIDERATIONS
Waste treatment methods
Disposal of wastes
Disposal should be in accordance with applicable regional, national and local laws and
regulations.
_____________________________________________________________________________________________
Page 6 / 8
Page 7
80022 - 6BR SENSOR SAFE BLUE SILICONE RTV 3
Revision Date 08-Feb-2019
OZ
_____________________________________________________________________________________________
Contaminated packaging
US EPA Waste Number
DOT
Proper shipping name:
IATA
Proper shipping name:
IMDG
Proper shipping name:
Do not reuse container.
Not applicable
Not regulated
Not regulated
Not regulated
15. REGULATORY INFORMATION
International Inventories
TSCA
DSL/NDSL
EINECS/ELINCS
ENCS
IECSC
KECL
PICCS
AICS
Complies
Complies
Complies
Not determined
Complies
Complies
Complies
Complies
14. TRANSPORT INFORMATION
Legend:
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List
EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances
ENCS - Japan Existing and New Chemical Substances
IECSC - China Inventory of Existing Chemical Substances
KECL - Korean Existing and Evaluated Chemical Substances
PICCS - Philippines Inventory of Chemicals and Chemical Substances
AICS - Australian Inventory of Chemical Substances
US Federal Regulations
SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any
chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372
SARA 311/312 Hazard Categories
Acute health hazard
Chronic Health Hazard
Fire hazard
Sudden release of pressure hazard
Reactive Hazard
CWA (Clean Water Act)
This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21
and 40 CFR 122.42)
CERCLA
This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and
Yes
No
No
No
No
_____________________________________________________________________________________________
Page 7 / 8
Page 8
80022 - 6BR SENSOR SAFE BLUE SILICONE RTV 3
Revision Date 08-Feb-2019
OZ
_____________________________________________________________________________________________
Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level
pertaining to releases of this material
US State Regulations
California Proposition 65
This product is not known to contain any chemicals listed as carcinogens or reproductive toxins.
U.S. State Right-to-Know Regulations
Chemical Name New Jersey Massachusetts Pennsylvania
LIMESTONE
1317-65-3
CI PIGMENT BLUE 15, CI #74160
147-14-8
U.S. EPA Label Information
EPA Pesticide Registration Number
WHMIS Hazard Class
D2B - Toxic materials
Not applicable
X X X
X - X
16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION OF THE LAST REVISION
NFPA Health hazards 2 Flammability 1 Instability 0
HMIS Health hazards 2 Flammability 1 Physical hazards 0 Personal protection B
NFPA (National Fire Protection Association)
HMIS (Hazardous Material Information System)
Revision Date
Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the
date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage,
transportation, disposal and release and is not to be considered a warranty or quality specification. The information
relates only to the specific material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text.
08-Feb-2019
End of Safety Data Sheet
-
_____________________________________________________________________________________________
Page 8 / 8
Loading...