PerfPower 24012 User Manual

Material Safety Data Sheet
Issuing Date 17-Sep-2012 Revision Date 12-Jun-2013
1. PRODUCT AND COMPANY IDENTIFICATION
Product Name Perfpower Go Green Batteries
Recommended Use
Supplier Address
Power By Go Green dba Perfpower Go Green 4675 Route 9 N Howell New Jersey 07731 US Phone:7329945901 Fax:7329945905 Contact:Michael Westermeier Email:mwestermeier@powerbygogreen. com Contact Phone011-732-994-5901
Alkaline battery.
2. HAZARDS IDENTIFICATION
Emergency Overview
Revision Number 2
This product is an article. No exposure to hazardous chemicals is expected to occur during intended product use.
Misuse of the product may result in exposure to hazardous chemicals.
Potential Health Effects Principle Routes of Exposure
Acute Toxicity
Eyes Skin Inhalation Ingestion
Chronic Effects
Aggravated Medical Conditions
Environmental Hazard
In case of rupture: Corrosive to the eyes and may cause severe damage including blindness. In case of rupture: Causes burns. In case of rupture: Harmful by inhalation. Causes burns. In case of rupture: Harmful if swallowed. Ingestion causes burns of the upper digestive and respiratory tract.
Upon rupture of sealed battery: Possible risks of irreversible effects. Chronic exposure to corrosive fumes/gases may cause erosion of the teeth followed by jaw necrosis. Bronchial irritation with chronic cough and frequent attacks of pneumonia are common. Gastrointestinal disturbances may also be seen. Avoid repeated exposure. May cause adverse effects on the bone marrow and blood-forming system. May cause adverse liver effects.
Central nervous system. Pre-existing eye disorders. Blood disorders. Kidney disorders. Liver disorders. Skin disorders. Respiratory disorders. Central Vascular System (CVS).
See Section 12 for additional Ecological Information. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Odor NoneAppearance Green Physical State Solid.
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3. COMPOSITION/INFORMATION ON INGREDIENTS
.
Chemical Name CAS-No Weight %
Manganese dioxide 1313-13-9 40-70
Zinc 7440-66-6 15-40
Fe(III) 2-[N,N-bis(carboxylatomethyl)amino] benzoate,
5H2O Water 7732-18-5 10-30
Potassium hydroxide 1310-58-3 5-10
Carbon 7440-44-0 1 - 5
brass 12597-71-6 1 - 5
94731-06-3 15-40
4. FIRST AID MEASURES
General Advice
Eye Contact
Skin Contact
Inhalation
Ingestion
Notes to Physician
Protection of First-aiders
Flammable Properties
Flash Point
Suitable Extinguishing Media
Hazardous Combustion Products
Explosion Data Sensitivity to Mechanical Impact
This is a battery. In case of rupture:
Immediate medical attention is required. Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Keep eye wide open while rinsing. Do not rub affected area.
Immediate medical attention is required. Wash off immediately with soap and plenty of water removing all contaminated clothes and shoes.
Move to fresh air. Call a physician or Poison Control Center immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Call a physician or Poison Control Center immediately. Do NOT induce vomiting.
Treat symptomatically.
Use personal protective equipment. Avoid contact with skin, eyes and clothing.
5. FIRE-FIGHTING MEASURES
Not flammable.
Not determined.
Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.
Hazardous metal fumes and oxides.
No.
Specific Hazards Arising from the Chemical
Sensitivity to Static Discharge
Protective Equipment and Precautions for Firefighters
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Move containers from fire area if you can do it without risk.
NFPA
Health Hazard 1
Flammability 0
The product causes burns of eyes, skin and mucous membranes. Thermal decomposition can lead to release of irritating gases and vapors. In the event of fire and/or explosion do not breathe fumes. Sealed containers may rupture when heated
No.
Stability 0 Physical and Chemical
Hazards -
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6. ACCIDENTAL RELEASE MEASURES
Personal Precautions
Environmental Precautions
Methods for Containment
Methods for Cleaning Up
Use personal protective equipment. Avoid contact with skin, eyes and clothing.
Refer to protective measures listed in Sections 7 and 8.
Prevent further leakage or spillage if safe to do so.
Use personal protective equipment. Pick up and transfer to properly labeled containers. Clean contaminated surface thoroughly.
7. HANDLING AND STORAGE
Handling
Storage
In case of rupture: Handle product only in closed system or provide appropriate exhaust ventilation at machinery. Avoid contact with skin, eyes and clothing.
Keep containers tightly closed in a dry, cool and well-ventilated place. Keep away from heat. Protect from moisture.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Exposure Guidelines
Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH
Manganese dioxide
1313-13-9
Potassium hydroxide
1310-58-3
brass
12597-71-6
TWA: 0.2 mg/m
Ceiling: 2 mg/m
TWA: 1 mg/m3 Cu dust and mist IDLH: 100 mg/m3 Cu dust and mist
3
Mn (vacated) Ceiling: 5 mg/m
3
Ceiling: 5 mg/m3 Mn
(vacated) Ceiling: 2 mg/m
3
3
IDLH: 500 mg/m
TWA: 1 mg/m
STEL: 3 mg/m
Ceiling: 2 mg/m
TWA: 1 mg/m
3
Mn
3
Mn
3
Mn
3
3
Cu dust and mist
ACGIH TLV: American Conference of Governmental Industrial Hygienists - Threshold Limit Value. OSHA PEL: Occupational Safety and Health Administration - Permissible Exposure Limits. NIOSH IDLH: Immediately Dangerous to Life or Health.
Other Exposure Guidelines
Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962 (11th Cir., 1992).
Engineering Measures
Showers Eyewash stations Ventilation systems
Personal Protective Equipment
Eye/Face Protection Skin and Body Protection Respiratory Protection
Tightly fitting safety goggles. No special protective equipment required. No protective equipment is needed under normal use conditions. If exposure limits are exceeded or irritation is experienced, ventilation and evacuation may be required.
Hygiene Measures
Handle in accordance with good industrial hygiene and safety practice. When using, do not eat, drink or smoke. Remove and wash contaminated clothing before re-use. Keep away from food, drink and animal feeding stuffs.
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9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance Odor Threshold pH
Flash Point Decomposition Temperature Melting Point/Range
Flammability Limits in Air
Water Solubility Evaporation Rate Vapor Density
Stability
Incompatible Products
Conditions to Avoid
Hazardous Decomposition Products
Hazardous Polymerization
Green. No information available No information available
No information available. No information available No information available
No information available
Immiscible in water No information available No data available
Odor Physical State
Autoignition Temperature Boiling Point/Range
Explosion Limits
Solubility Vapor Pressure Partition Coefficient: n-
octanol/water
None. Solid
No information available No information available
No information available
No information available No data available
10. STABILITY AND REACTIVITY
Stable under recommended storage conditions.
Incompatible with strong acids and bases. Incompatible with oxidizing agents.
Exposure to air or moisture over prolonged periods.
Thermal decomposition can lead to release of irritating gases and vapors.
Hazardous polymerization does not occur.
Acute Toxicity
Product Information
Chemical Name LD50 Oral LD50 Dermal LC50 Inhalation
Manganese dioxide = 9000 mg/kg ( Rat ) - -
Potassium hydroxide = 214 mg/kg ( Rat ) - -
Carbon > 10000 mg/kg ( Rat ) - -
Chronic Toxicity
Chronic Toxicity
Target Organ Effects
11. TOXICOLOGICAL INFORMATION
Upon rupture of sealed battery: Possible risks of irreversible effects. Chronic exposure to corrosive fumes/gases may cause erosion of the teeth followed by jaw necrosis. Bronchial irritation with chronic cough and frequent attacks of pneumonia are common. Gastrointestinal disturbances may also be seen. Avoid repeated exposure. May cause adverse effects on the bone marrow and blood-forming system. May cause adverse liver effects.
Blood. Central nervous system (CNS). Central Vascular System (CVS). Eyes. Kidney. Liver. Respiratory system. Skin.
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12. ECOLOGICAL INFORMATION
Ecotoxicity
Harmful to aquatic organisms.
Chemical Name Toxicity to Algae Toxicity to Fish Toxicity to Microorganisms Daphnia Magna (Water Flea)
Zinc EC50: 0.09 - 0.125 mg/L (72
h static) Pseudokirchneriella
subcapitata EC50: 0.11 - 0.271 mg/L (96 h static) Pseudokirchneriella
subcapitata
Potassium hydroxide LC50: 80 mg/L (96 h static)
LC50: 2.16-3.05 mg/L (96 h
flow-through) Pimephales
promelas
LC50: 7.8 mg/L (96 h static)
Cyprinus carpio
LC50: 0.45 mg/L (96 h semi-
static) Cyprinus carpio
LC50: 30 mg/L (96 h )
Cyprinus carpio LC50: 0.59 mg/L (96 h semiĀ­static) Oncorhynchus mykiss
LC50: 0.41 mg/L (96 h static)
Oncorhynchus mykiss
LC50: 3.5 mg/L (96 h static)
Lepomis macrochirus
LC50: 0.211-0.269 mg/L (96 h
semi-static) Pimephales
promelas
LC50: 0.24 mg/L (96 h flow-
through) Oncorhynchus
mykiss
LC50: 2.66 mg/L (96 h static)
Pimephales promelas
Gambusia affinis
EC50: 0.139 - 0.908 mg/L (48
h Static) Daphnia magna
Chemical Name Log Pow
Manganese dioxide 0
Potassium hydroxide 0.83
13. DISPOSAL CONSIDERATIONS
Waste Disposal Methods
Contaminated Packaging
California Hazardous Waste Codes
This product contains one or more substances that are listed with the State of California as a hazardous waste.
Chemical Name California EHW California Carc California Hazardous Waste California Waste - Part 2
Zinc Ignitable powder STLC (for PBTs): 250 mg/L
Potassium hydroxide Toxic
brass Toxic STLC (for PBTs): 25 mg/L
This material, as supplied, is not a hazardous waste according to Federal regulations (40 CFR
261). This material could become a hazardous waste if it is mixed with or otherwise comes in contact with a hazardous waste, if chemical additions are made to this material, or if the material is processed or otherwise altered. Consult 40 CFR 261 to determine whether the altered material is a hazardous waste. Consult the appropriate state, regional, or local regulations for additional requirements. Dispose of in accordance with local regulations
Do not re-use empty containers.
181
TTLC (for PBTs): 5000 mg/kg
Corrosive
TTLC (for PBTs): 2500 mg/kg
14. TRANSPORT INFORMATION
DOT
NOT REGULATED
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14. TRANSPORT INFORMATION
TDG
MEX
ICAO
IATA
IMDG/IMO
Not regulated
Not regulated
Not regulated
Not regulated
Not regulated
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15. REGULATORY INFORMATION
International Inventories
TSCA DSL
Complies Not determined
U.S. Federal Regulations
SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372:
Chemical Name CAS-No Weight % SARA 313 - Threshold
Manganese dioxide 1313-13-9 40-70 1.0
Zinc 7440-66-6 15-40 1.0
brass 12597-71-6 1 - 5 1.0
SARA 311/312 Hazard Categories
Acute Health Hazard Chronic Health Hazard Fire Hazard Sudden Release of Pressure Hazard Reactive Hazard
Yes Yes No No No
Clean Water Act
This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42):
Chemical Name CWA - Reportable
Quantities
Zinc X X
Potassium hydroxide 1000 lb X
brass X
CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous
Values %
Substances
Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) (see 40 CFR 61)
This product contains the following substances which are listed hazardous air pollutants (HAPS) under Section 112 of the Clean Air Act:
Chemical Name CAS-No Weight % HAPS data VOC Chemicals Class 1 Ozone
Depletors
Manganese dioxide 1313-13-9 40-70
Class 2 Ozone
Depletors
CERCLA
This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302):
Chemical Name Hazardous Substances RQs Extremely Hazardous Substances RQs
Zinc 1000 lb
Potassium hydroxide 1000 lb
U.S. State Regulations
California Proposition 65
This product does not contain any Proposition 65 chemicals.
U.S. State Right-to-Know Regulations
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Chemical Name Massachusetts New Jersey Pennsylvania Illinois Rhode Island
Potassium hydroxide X X X X
Manganese dioxide X X X
International Regulations
Mexico - Grade
Chemical Name Carcinogen Status Exposure Limits
Manganese dioxide Mexico: TWA= 0.2 mg/m
Minimum risk, Grade 0
3
Canada
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR.
WHMIS Hazard Class
Non-controlled
Chemical Name NPRI
Manganese dioxide X
Legend
NPRI - National Pollutant Release Inventory
16. OTHER INFORMATION
Prepared By
Product Stewardship 23 British American Blvd. Latham, NY 12110 1-800-572-6501
Issuing Date
Revision Date
Revision Note
General Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text
17-Sep-2012
12-Jun-2013
No information available
End of Safety Data Sheet
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