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PHN-50
data sheet
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Pentel PHN-50 data sheet

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Page 1
EC safety data sheet
Trade name: Oil Pastels
Product no.: PHN-50 pale orange
Replaced version: 1.0.0, issued: 12.06.2012
Region: GB
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1
Product identifier
Trade name
Oil Pastels
1.2
Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses of the substance or mixture
art supplies
pastel colour
Uses advised against
No data available.
1.3
Details of the supplier of the safety data sheet
Address
Pentel Bürobedarf-Handelsgesellschaft mbH
Lademannbogen 143
22339
Hamburg
GERMANY
Telephone no.
+49 (0) 40 / 53 80 91 - 0
Fax no.
+49 (0) 40 / 53 85 58 - 7
Information provided by / telephone
+49 (0) 40 / 53 80 91 - 0
Advice on Safety Data Sheet
sdb_info@umco.de
1.4
Emergency telephone number
For medical advice (in German and English): +49 (0)551 192 40 (Giftinformationszentrum Nord)
SECTION 2: Hazards identification
2.1
Classification of the substance or mixture
Classification information
This product does not meet the classification and labelling criteria given in the Regulation (EC) No 1272/2008 (CLP).
This product does not meet the classification and labelling criteria given in the Dangerous Preparations Directive (1999/45/EC; DPD)
2.2
Label elements
Not relevant
Labelling information
The data subject of this Material Safety Data sheet refer to the paint contained in this product.
2.3
Other hazards
No data available.
Page 1(9)
Page 2
EC safety data sheet
Trade name: Oil Pastels
Product no.: PHN-50 pale orange
Replaced version: 1.0.0, issued: 12.06.2012
Region: GB
SECTION 3: Composition/information on ingredients
3.1
Substances
Not applicable. The product is not a substance.
3.2
Mixtures
Hazardous ingredients
No
Substance name
Additional information
CAS / EC / Index / REACH no
Classification 67/548/EEC
Classification (EC) 1272/2008 (CLP)
Concentration
%
1
titanium-dioxide
13463-67-7 236-675-5
-
-
- - >
1.00
- < 5.00
%-b.w.
Full Text for all R-phrases , H-phrases and EUH-phrases: pls. see section 16
SECTION 4: First aid measures
4.1
Description of first aid measures
General information
In case of persisting adverse effects, consult a physician.
After inhalation
Ensure supply of fresh air.
After skin contact
When in contact with the skin, clean with soap and water. Do NOT use solvents or thinners.
After eye contact
Separate eyelids, wash the eyes thoroughly with water (15 min.).
After ingestion
Call a doctor. Never give anything by mouth to an unconscious person. Do not induce vomiting.
4.2
Most important symptoms and effects, both acute and delayed
No data available.
4.3
Indication of any immediate medical attention and special treatment needed
No data available.
SECTION 5: Firefighting measures
5.1
Extinguishing media
Suitable extinguishing media
Product itself is non-combustible; adapt fire extinguishing measures to surrounding areas.
Unsuitable extinguishing media
No data available.
5.2
Special hazards arising from the substance or mixture
In the event of fire, the following can be released: Carbon dioxide (CO2); Carbon monoxide (CO)
5.3
Advice for firefighters
Use self-contained breathing apparatus. Wear protective clothing.
SECTION 6: Accidental release measures
6.1
Personal precautions, protective equipment and emergency procedures
For non-emergency personnel
Refer to protective measures listed in sections 7 and 8. Ensure adequate ventilation.
Page 2(9)
Page 3
EC safety data sheet
Trade name: Oil Pastels
Product no.: PHN-50 pale orange
Replaced version: 1.0.0, issued: 12.06.2012
Region: GB
For emergency responders
No data available. Personal protective equipment (PPE) - see Section 8.
6.2
Environmental precautions
Do not discharge into the drains/surface waters/groundwater.
6.3
Methods and material for containment and cleaning up
Take up mechanically. Send in suitable containers for recovery or disposal.
6.4
Reference to other sections
No data available.
SECTION 7: Handling and storage
7.1
Precautions for safe handling
Advice on safe handling
Observe the usual precautions for handling chemicals. Provide good ventilation of working area (local exhaust ventilation, if necessary).
General protective and hygiene measures
Observe the usual precautions when handling chemicals. Keep away from foodstuffs and beverages. Do not eat, drink or smoke during work time. Clean skin thoroughly after work; apply skin cream.
7.2
Conditions for safe storage, including any incompatibilities
Technical measures and storage conditions
Keep container tightly closed and dry in a cool, well-ventilated place.
Requirements for storage rooms and vessels
Containers which are opened must be carefully closed and kept upright to prevent leakage. Always keep in containers of same material as the original one.
Advice on storage assembly
None known
7.3
Specific end use(s)
No data available.
SECTION 8: Exposure controls/personal protection
8.1
Control parameters
Occupational exposure limit values
No
Substance name
CAS no.
EC no.
1
titanium-dioxide
13463-67-7
236-675-5
List of approved workplace exposure limits (WELs) / EH40
Titanium dioxide
total inhalable dust
TWA
10
mg/m³
List of approved workplace exposure limits (WELs) / EH40
Titanium dioxide
respirable dust
TWA
4
mg/m³
true
8.2
Exposure controls
Appropriate engineering controls
No data available.
Personal protective equipment
Respiratory protection
If workplace exposure limits are exceeded, a respiration protection approved for this particular job must be worn. In case of dust, aerosol and mist formation, take appropriate measures for breathing protection in the event workplace threshold values are not specified.
Page 3(9)
Page 4
EC safety data sheet
Trade name: Oil Pastels
Product no.: PHN-50 pale orange
Replaced version: 1.0.0, issued: 12.06.2012
Region: GB
Eye / face protection
Safety glasses (EN 166)
Hand protection
Sufficient protection is given wearing suitable protective gloves checked according to i.e. EN 374, in the event of risk of skin contact with the product . Before use, the protective gloves should be tested in any case for its specific work­station suitability (i.e. mechanical resistance, product compatibility and antistatic properties). Adhere to the manufacturer’s instructions and information relating to the use, storage, care and replacement of protective gloves. Protective gloves shall be replaced immediately when physically damaged or worn. Design operations thus to avoid permanent use of protective gloves.
Other
Normal chemical work clothing.
Environmental exposure controls
No data available.
SECTION 9: Physical and chemical properties
9.1
Information on basic physical and chemical properties
Form/Colour
liquid
according product name
270
U_9005
Odour
alkohol-like
180
Odour threshold
No data available
pH value
No data available
Boiling point / boiling range
No data available
Melting point / melting range
Value
69.82
°C
Method
ASTM D 3418
69.82
Page 4(9)
Page 5
EC safety data sheet
Trade name: Oil Pastels
Product no.: PHN-50 pale orange
Replaced version: 1.0.0, issued: 12.06.2012
Region: GB
Decomposition point / decomposition range
No data available
Flash point
No data available
Auto-ignition temperature
No data available
Oxidising properties
No data available
Explosive properties
No data available
Flammability (solid, gas)
No data available
Lower flammability or explosive limits
No data available
Upper flammability or explosive limits
No data available
Vapour pressure
No data available
Vapour density
No data available
Evaporation rate
No data available
Relative density
No data available
Density
No data available
Solubility in water
No data available
Solubility(ies)
No data available
Partition coefficient: n-octanol/water
No data available
Viscosity
No data available
9.2
Other information
Other information
No data available.
SECTION 10: Stability and reactivity
10.1
Reactivity
No data available.
10.2
Chemical stability
No data available.
10.3
Possibility of hazardous reactions
No data available.
10.4
Conditions to avoid
Stable under recommended storage and handling conditions(See section 7).
Page 5(9)
Page 6
EC safety data sheet
Trade name: Oil Pastels
Product no.: PHN-50 pale orange
Replaced version: 1.0.0, issued: 12.06.2012
Region: GB
10.5
Incompatible materials
None known.
10.6
Hazardous decomposition products
No hazardous decomposition products known.
SECTION 11: Toxicological information
11.1
Information on toxicological effects
Acute oral toxicity
No
Product Name
1
Oil Pastels
Remarks
No data available.
Acute dermal toxicity
No
Product Name
1
Oil Pastels
Remarks
No data available.
Acute inhalational toxicity
No
Product Name
1
Oil Pastels
Remarks
No data available.
Lk.7000882
Skin corrosion/irritation
No
Product Name
1
Oil Pastels
Remarks
No data available.
Serious eye damage/irritation
No
Product Name
1
Oil Pastels
Remarks
No data available.
Respiratory tract irritation
Remarks
No data available.
Respiratory or skin sensitisation
No data available
Germ cell mutagenicity
No data available
Reproduction toxicity
No data available
Carcinogenicity
No data available
STOT-single exposure
No data available
STOT-repeated exposure
No data available
Aspiration hazard
No data available
Page 6(9)
Page 7
EC safety data sheet
Trade name: Oil Pastels
Product no.: PHN-50 pale orange
Replaced version: 1.0.0, issued: 12.06.2012
Region: GB
SECTION 12: Ecological information
12.1
Toxicity
Toxicity to fish (acute)
No
Product Name
1
Oil Pastels
Remarks
No data available.
Lk.2098
Toxicity to fish (chronic)
No data available
Toxicity to Daphnia (acute)
No
Product Name
1
Oil Pastels
Remarks
No data available.
Lk.2098
Toxicity to Daphnia (chronic)
No data available
Toxicity to algae (acute)
No
Product Name
1
Oil Pastels
Remarks
No data available.
Lk.2098
Toxicity to algae (chronic)
No data available
Bacteria toxicity
No
Product Name
1
Oil Pastels
Remarks
No data available.
Lk.2099
12.2
Persistence and degradability
Biodegradability
No
Product Name
1
Oil Pastels
Remarks
No data available.
Lk.2100
12.3
Bioaccumulative potential
No data available.
12.4
Mobility in soil
No data available.
12.5
Results of PBT and vPvB assessment
No data available.
12.6
Other adverse effects
No data available.
12.7
Other information
Other information
Do not discharge product unmonitored into the environment.
710
SECTION 13: Disposal considerations
13.1
Waste treatment methods
Product
Allocation of a waste code number, according to the European Waste Catalogue, should be carried out in agreement with the regional waste disposal company.
Page 7(9)
Page 8
EC safety data sheet
Trade name: Oil Pastels
Product no.: PHN-50 pale orange
Replaced version: 1.0.0, issued: 12.06.2012
Region: GB
Packaging
Residuals must be removed from packaging and when emptied completely disposed of in accordance with the regulations for waste removal. Incompletely emptied packaging must be disposed of in the form of disposal specified by the regional disposer.
SECTION 14: Transport information
14.1
Transport ADR/RID/ADN
The product is not subject to ADR/RID/ADN regulations.
14.2
Transport IMDG
The product is not subject to IMDG regulations.
14.3
Transport ICAO-TI / IATA
The product is not subject to ICAO-TI / IATA regulations.
14.4
Other information
No data available.
14.5
Environmental hazards
Information on environmental hazards, if relevant, please see 14.1 - 14.3.
14.6
Special precautions for user
No data available.
14.7
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not relevant
SECTION 15: Regulatory information
15.1
Safety, health and environmental regulations/legislation specific for the substance or mixture
EU regulations
Regulation (EC) No 1907/2006 (REACH) Annex XIV (List of substances subject to authorisation)
According to the data available and/or specifications supplied by upstream suppliers, this product does not contain any substances considered as substances requiring authorisation as listed on Annex XIV of the REACH regulation (EC) 1907/2006.
REACH candidate list of substances of very high concern (SVHC) for authorisation
According to available data and the information provided by preliminary suppliers, the product does not contain substances that are considered substances meeting the criteria for inclusion in annex XIV (List of Substances Subject to Authorisation) as laid down in Article 57 and article 59 of REACH (EC) 1907/2006.
Regulation (EC) No 1907/2006 (REACH) Annex XVII: RESTRICTIONS ON THE MANUFACTURE, PLACING ON THE MARKET AND USE OF CERTAIN DANGEROUS SUBSTANCES, PREPARATIONS AND ARTICLES
According to the data available and/or specifications supplied by upstream suppliers, this product does not contain any substances requiring authorisation as listed on Annex XIV of the REACH regulation (EC) 1907/2006.
Council Directive 96/82/EC on the control of major-accident hazards involving dangerous substances
Remarks
Annex I, part 1 + 2: not mentioned. With regard to possibly appropriate decomposition products see Chapter 10.
15.2
Chemical safety assessment
No data available.
SECTION 16: Other information
Department issuing safety data sheet
UMCO Umwelt Consult GmbH
Georg-Wilhelm-Str. 183 , 21107 Hamburg, Germany
Tel.: +49 40 / 79 02 36 300 Fax: +49 40 / 79 02 36 357 e-mail: umco@umco.de
Page 8(9)
Page 9
EC safety data sheet
Trade name: Oil Pastels
Product no.: PHN-50 pale orange
Replaced version: 1.0.0, issued: 12.06.2012
Region: GB
This information is based on our present state of knowledge and experience. The security data sheet describes products with a view to the security requirements. However, it should not constitute a guarantee for any specific product properties and shall not establish a legally valid relationship.
Alterations/supplements: Alterations to the previous edition are marked in the left-hand margin.
.
Page 9(9)
Page 10
EC safety data sheet
Trade name: Oil Pastels
Product no.: PHN-50 brown
Replaced version: 1.0.0, issued: 12.06.2012
Region: GB
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1
Product identifier
Trade name
Oil Pastels
1.2
Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses of the substance or mixture
art supplies
pastel colour
Uses advised against
No data available.
1.3
Details of the supplier of the safety data sheet
Address
Pentel Bürobedarf-Handelsgesellschaft mbH
Lademannbogen 143
22339
Hamburg
GERMANY
Telephone no.
+49 (0) 40 / 53 80 91 - 0
Fax no.
+49 (0) 40 / 53 85 58 - 7
Information provided by / telephone
+49 (0) 40 / 53 80 91 - 0
Advice on Safety Data Sheet
sdb_info@umco.de
1.4
Emergency telephone number
For medical advice (in German and English): +49 (0)551 192 40 (Giftinformationszentrum Nord)
SECTION 2: Hazards identification
2.1
Classification of the substance or mixture
Classification information
This product does not meet the classification and labelling criteria given in the Regulation (EC) No 1272/2008 (CLP).
This product does not meet the classification and labelling criteria given in the Dangerous Preparations Directive (1999/45/EC; DPD)
2.2
Label elements
Not relevant
Labelling information
The data subject of this Material Safety Data sheet refer to the paint contained in this product.
2.3
Other hazards
No data available.
Page 1(10)
Page 11
EC safety data sheet
Trade name: Oil Pastels
Product no.: PHN-50 brown
Replaced version: 1.0.0, issued: 12.06.2012
Region: GB
SECTION 3: Composition/information on ingredients
3.1
Substances
Not applicable. The product is not a substance.
3.2
Mixtures
Hazardous ingredients
No
Substance name
Additional information
CAS / EC / Index / REACH no
Classification 67/548/EEC
Classification (EC) 1272/2008 (CLP)
Concentration
%
1
titanium-dioxide
13463-67-7 236-675-5
-
-
- - >
10.00
- < 30.00
%-b.w.
2
diiron trioxide
1309-37-1 215-168-2
-
-
- - >
1.00
- < 5.00
%-b.w.
Full Text for all R-phrases , H-phrases and EUH-phrases: pls. see section 16
SECTION 4: First aid measures
4.1
Description of first aid measures
General information
In case of persisting adverse effects, consult a physician.
After inhalation
Ensure supply of fresh air.
After skin contact
When in contact with the skin, clean with soap and water. Do NOT use solvents or thinners.
After eye contact
Separate eyelids, wash the eyes thoroughly with water (15 min.).
After ingestion
Call a doctor. Never give anything by mouth to an unconscious person. Do not induce vomiting.
4.2
Most important symptoms and effects, both acute and delayed
No data available.
4.3
Indication of any immediate medical attention and special treatment needed
No data available.
SECTION 5: Firefighting measures
5.1
Extinguishing media
Suitable extinguishing media
Product itself is non-combustible; adapt fire extinguishing measures to surrounding areas.
Unsuitable extinguishing media
No data available.
5.2
Special hazards arising from the substance or mixture
In the event of fire, the following can be released: Carbon dioxide (CO2); Carbon monoxide (CO)
5.3
Advice for firefighters
Use self-contained breathing apparatus. Wear protective clothing.
Page 2(10)
Page 12
EC safety data sheet
Trade name: Oil Pastels
Product no.: PHN-50 brown
Replaced version: 1.0.0, issued: 12.06.2012
Region: GB
SECTION 6: Accidental release measures
6.1
Personal precautions, protective equipment and emergency procedures
For non-emergency personnel
Refer to protective measures listed in sections 7 and 8. Ensure adequate ventilation.
For emergency responders
No data available. Personal protective equipment (PPE) - see Section 8.
6.2
Environmental precautions
Do not discharge into the drains/surface waters/groundwater.
6.3
Methods and material for containment and cleaning up
Take up mechanically. Send in suitable containers for recovery or disposal.
6.4
Reference to other sections
No data available.
SECTION 7: Handling and storage
7.1
Precautions for safe handling
Advice on safe handling
Observe the usual precautions for handling chemicals. Provide good ventilation of working area (local exhaust ventilation, if necessary).
General protective and hygiene measures
Observe the usual precautions when handling chemicals. Keep away from foodstuffs and beverages. Do not eat, drink or smoke during work time. Clean skin thoroughly after work; apply skin cream.
7.2
Conditions for safe storage, including any incompatibilities
Technical measures and storage conditions
Keep container tightly closed and dry in a cool, well-ventilated place.
Requirements for storage rooms and vessels
Containers which are opened must be carefully closed and kept upright to prevent leakage. Always keep in containers of same material as the original one.
Advice on storage assembly
None known
7.3
Specific end use(s)
No data available.
Page 3(10)
Page 13
EC safety data sheet
Trade name: Oil Pastels
Product no.: PHN-50 brown
Replaced version: 1.0.0, issued: 12.06.2012
Region: GB
SECTION 8: Exposure controls/personal protection
8.1
Control parameters
Occupational exposure limit values
No
Substance name
CAS no.
EC no.
1
titanium-dioxide
13463-67-7
236-675-5
List of approved workplace exposure limits (WELs) / EH40
Titanium dioxide
total inhalable dust
TWA
10
mg/m³
List of approved workplace exposure limits (WELs) / EH40
Titanium dioxide
respirable dust
TWA
4
mg/m³
2
diiron trioxide
1309-37-1
215-168-2
List of approved workplace exposure limits (WELs) / EH40
Iron oxide
fume
Fe
STEL
10
mg/m³
TWA
5
mg/m³
List of approved workplace exposure limits (WELs) / EH40
Rouge
total inhalable dust
TWA
10
mg/m³
List of approved workplace exposure limits (WELs) / EH40
Rouge
respirable dust
TWA
4
mg/m³
true
8.2
Exposure controls
Appropriate engineering controls
No data available.
Personal protective equipment
Respiratory protection
If workplace exposure limits are exceeded, a respiration protection approved for this particular job must be worn. In case of dust, aerosol and mist formation, take appropriate measures for breathing protection in the event workplace threshold values are not specified.
Eye / face protection
Safety glasses (EN 166)
Hand protection
Sufficient protection is given wearing suitable protective gloves checked according to i.e. EN 374, in the event of risk of skin contact with the product . Before use, the protective gloves should be tested in any case for its specific work­station suitability (i.e. mechanical resistance, product compatibility and antistatic properties). Adhere to the manufacturer’s instructions and information relating to the use, storage, care and replacement of protective gloves. Protective gloves shall be replaced immediately when physically damaged or worn. Design operations thus to avoid permanent use of protective gloves.
Other
Normal chemical work clothing.
Environmental exposure controls
No data available.
Page 4(10)
Page 14
EC safety data sheet
Trade name: Oil Pastels
Product no.: PHN-50 brown
Replaced version: 1.0.0, issued: 12.06.2012
Region: GB
SECTION 9: Physical and chemical properties
9.1
Information on basic physical and chemical properties
Form/Colour
liquid
according product name
270
U_9005
Odour
alkohol-like
180
Odour threshold
No data available
pH value
No data available
Boiling point / boiling range
No data available
Melting point / melting range
Value
69.82
°C
Method
ASTM D 3418
69.82
Page 5(10)
Page 15
EC safety data sheet
Trade name: Oil Pastels
Product no.: PHN-50 brown
Replaced version: 1.0.0, issued: 12.06.2012
Region: GB
Decomposition point / decomposition range
No data available
Flash point
No data available
Auto-ignition temperature
No data available
Oxidising properties
No data available
Explosive properties
No data available
Flammability (solid, gas)
No data available
Lower flammability or explosive limits
No data available
Upper flammability or explosive limits
No data available
Vapour pressure
No data available
Vapour density
No data available
Evaporation rate
No data available
Relative density
No data available
Density
No data available
Solubility in water
No data available
Solubility(ies)
No data available
Partition coefficient: n-octanol/water
No data available
Viscosity
No data available
9.2
Other information
Other information
No data available.
SECTION 10: Stability and reactivity
10.1
Reactivity
No data available.
10.2
Chemical stability
No data available.
10.3
Possibility of hazardous reactions
No data available.
10.4
Conditions to avoid
Stable under recommended storage and handling conditions(See section 7).
Page 6(10)
Page 16
EC safety data sheet
Trade name: Oil Pastels
Product no.: PHN-50 brown
Replaced version: 1.0.0, issued: 12.06.2012
Region: GB
10.5
Incompatible materials
None known.
10.6
Hazardous decomposition products
No hazardous decomposition products known.
SECTION 11: Toxicological information
11.1
Information on toxicological effects
Acute oral toxicity
No
Product Name
1
Oil Pastels
Remarks
No data available.
Acute dermal toxicity
No
Product Name
1
Oil Pastels
Remarks
No data available.
Acute inhalational toxicity
No
Product Name
1
Oil Pastels
Remarks
No data available.
Lk.7000882
Skin corrosion/irritation
No
Product Name
1
Oil Pastels
Remarks
No data available.
Serious eye damage/irritation
No
Product Name
1
Oil Pastels
Remarks
No data available.
Respiratory tract irritation
Remarks
No data available.
Respiratory or skin sensitisation
No data available
Germ cell mutagenicity
No data available
Reproduction toxicity
No data available
Carcinogenicity
No data available
STOT-single exposure
No data available
STOT-repeated exposure
No data available
Aspiration hazard
No data available
Page 7(10)
Page 17
EC safety data sheet
Trade name: Oil Pastels
Product no.: PHN-50 brown
Replaced version: 1.0.0, issued: 12.06.2012
Region: GB
SECTION 12: Ecological information
12.1
Toxicity
Toxicity to fish (acute)
No
Product Name
1
Oil Pastels
Remarks
No data available.
Lk.2098
Toxicity to fish (chronic)
No data available
Toxicity to Daphnia (acute)
No
Product Name
1
Oil Pastels
Remarks
No data available.
Lk.2098
Toxicity to Daphnia (chronic)
No data available
Toxicity to algae (acute)
No
Product Name
1
Oil Pastels
Remarks
No data available.
Lk.2098
Toxicity to algae (chronic)
No data available
Bacteria toxicity
No
Product Name
1
Oil Pastels
Remarks
No data available.
Lk.2099
12.2
Persistence and degradability
Biodegradability
No
Product Name
1
Oil Pastels
Remarks
No data available.
Lk.2100
12.3
Bioaccumulative potential
No data available.
12.4
Mobility in soil
No data available.
12.5
Results of PBT and vPvB assessment
No data available.
12.6
Other adverse effects
No data available.
12.7
Other information
Other information
Do not discharge product unmonitored into the environment.
710
SECTION 13: Disposal considerations
13.1
Waste treatment methods
Product
Allocation of a waste code number, according to the European Waste Catalogue, should be carried out in agreement with the regional waste disposal company.
Page 8(10)
Page 18
EC safety data sheet
Trade name: Oil Pastels
Product no.: PHN-50 brown
Replaced version: 1.0.0, issued: 12.06.2012
Region: GB
Packaging
Residuals must be removed from packaging and when emptied completely disposed of in accordance with the regulations for waste removal. Incompletely emptied packaging must be disposed of in the form of disposal specified by the regional disposer.
SECTION 14: Transport information
14.1
Transport ADR/RID/ADN
The product is not subject to ADR/RID/ADN regulations.
14.2
Transport IMDG
The product is not subject to IMDG regulations.
14.3
Transport ICAO-TI / IATA
The product is not subject to ICAO-TI / IATA regulations.
14.4
Other information
No data available.
14.5
Environmental hazards
Information on environmental hazards, if relevant, please see 14.1 - 14.3.
14.6
Special precautions for user
No data available.
14.7
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not relevant
SECTION 15: Regulatory information
15.1
Safety, health and environmental regulations/legislation specific for the substance or mixture
EU regulations
Regulation (EC) No 1907/2006 (REACH) Annex XIV (List of substances subject to authorisation)
According to the data available and/or specifications supplied by upstream suppliers, this product does not contain any substances considered as substances requiring authorisation as listed on Annex XIV of the REACH regulation (EC) 1907/2006.
REACH candidate list of substances of very high concern (SVHC) for authorisation
According to available data and the information provided by preliminary suppliers, the product does not contain substances that are considered substances meeting the criteria for inclusion in annex XIV (List of Substances Subject to Authorisation) as laid down in Article 57 and article 59 of REACH (EC) 1907/2006.
Regulation (EC) No 1907/2006 (REACH) Annex XVII: RESTRICTIONS ON THE MANUFACTURE, PLACING ON THE MARKET AND USE OF CERTAIN DANGEROUS SUBSTANCES, PREPARATIONS AND ARTICLES
According to the data available and/or specifications supplied by upstream suppliers, this product does not contain any substances requiring authorisation as listed on Annex XIV of the REACH regulation (EC) 1907/2006.
Council Directive 96/82/EC on the control of major-accident hazards involving dangerous substances
Remarks
Annex I, part 1 + 2: not mentioned. With regard to possibly appropriate decomposition products see Chapter 10.
15.2
Chemical safety assessment
No data available.
SECTION 16: Other information
Department issuing safety data sheet
UMCO Umwelt Consult GmbH
Georg-Wilhelm-Str. 183 , 21107 Hamburg, Germany
Tel.: +49 40 / 79 02 36 300 Fax: +49 40 / 79 02 36 357 e-mail: umco@umco.de
Page 9(10)
Page 19
EC safety data sheet
Trade name: Oil Pastels
Product no.: PHN-50 brown
Replaced version: 1.0.0, issued: 12.06.2012
Region: GB
This information is based on our present state of knowledge and experience. The security data sheet describes products with a view to the security requirements. However, it should not constitute a guarantee for any specific product properties and shall not establish a legally valid relationship.
Alterations/supplements: Alterations to the previous edition are marked in the left-hand margin.
.
Page 10(10)
Page 20
EC safety data sheet
Trade name: Oil Pastels
Product no.: PHN-50 red
Replaced version: 1.0.0, issued: 12.06.2012
Region: GB
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1
Product identifier
Trade name
Oil Pastels
1.2
Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses of the substance or mixture
art supplies
pastel colour
Uses advised against
No data available.
1.3
Details of the supplier of the safety data sheet
Address
Pentel Bürobedarf-Handelsgesellschaft mbH
Lademannbogen 143
22339
Hamburg
GERMANY
Telephone no.
+49 (0) 40 / 53 80 91 - 0
Fax no.
+49 (0) 40 / 53 85 58 - 7
Information provided by / telephone
+49 (0) 40 / 53 80 91 - 0
Advice on Safety Data Sheet
sdb_info@umco.de
1.4
Emergency telephone number
For medical advice (in German and English): +49 (0)551 192 40 (Giftinformationszentrum Nord)
SECTION 2: Hazards identification
2.1
Classification of the substance or mixture
Classification information
This product does not meet the classification and labelling criteria given in the Regulation (EC) No 1272/2008 (CLP).
This product does not meet the classification and labelling criteria given in the Dangerous Preparations Directive (1999/45/EC; DPD)
2.2
Label elements
Not relevant
Labelling information
The data subject of this Material Safety Data sheet refer to the paint contained in this product.
2.3
Other hazards
No data available.
Page 1(9)
Page 21
EC safety data sheet
Trade name: Oil Pastels
Product no.: PHN-50 red
Replaced version: 1.0.0, issued: 12.06.2012
Region: GB
SECTION 3: Composition/information on ingredients
3.1
Substances
Not applicable. The product is not a substance.
3.2
Mixtures
Hazardous ingredients
No
Substance name
Additional information
CAS / EC / Index / REACH no
Classification 67/548/EEC
Classification (EC) 1272/2008 (CLP)
Concentration
%
1
manganese, 4-[(5-chloro-4-methyl-2-sulfophenyl)azo]-3-hydroxy-2­naphthalenecarboxylic acid complex, C.I. Pigment Red 48:4 (15865:4)
5280-66-0 226-102-7
-
-
- - >
1.00
- < 5.00
%-b.w.
Full Text for all R-phrases , H-phrases and EUH-phrases: pls. see section 16
SECTION 4: First aid measures
4.1
Description of first aid measures
General information
In case of persisting adverse effects, consult a physician.
After inhalation
Ensure supply of fresh air.
After skin contact
When in contact with the skin, clean with soap and water. Do NOT use solvents or thinners.
After eye contact
Separate eyelids, wash the eyes thoroughly with water (15 min.).
After ingestion
Call a doctor. Never give anything by mouth to an unconscious person. Do not induce vomiting.
4.2
Most important symptoms and effects, both acute and delayed
No data available.
4.3
Indication of any immediate medical attention and special treatment needed
No data available.
SECTION 5: Firefighting measures
5.1
Extinguishing media
Suitable extinguishing media
Product itself is non-combustible; adapt fire extinguishing measures to surrounding areas.
Unsuitable extinguishing media
No data available.
5.2
Special hazards arising from the substance or mixture
In the event of fire, the following can be released: Carbon dioxide (CO2); Carbon monoxide (CO)
5.3
Advice for firefighters
Use self-contained breathing apparatus. Wear protective clothing.
SECTION 6: Accidental release measures
6.1
Personal precautions, protective equipment and emergency procedures
For non-emergency personnel
Refer to protective measures listed in sections 7 and 8. Ensure adequate ventilation.
Page 2(9)
Page 22
EC safety data sheet
Trade name: Oil Pastels
Product no.: PHN-50 red
Replaced version: 1.0.0, issued: 12.06.2012
Region: GB
For emergency responders
No data available. Personal protective equipment (PPE) - see Section 8.
6.2
Environmental precautions
Do not discharge into the drains/surface waters/groundwater.
6.3
Methods and material for containment and cleaning up
Take up mechanically. Send in suitable containers for recovery or disposal.
6.4
Reference to other sections
No data available.
SECTION 7: Handling and storage
7.1
Precautions for safe handling
Advice on safe handling
Observe the usual precautions for handling chemicals. Provide good ventilation of working area (local exhaust ventilation, if necessary).
General protective and hygiene measures
Observe the usual precautions when handling chemicals. Keep away from foodstuffs and beverages. Do not eat, drink or smoke during work time. Clean skin thoroughly after work; apply skin cream.
7.2
Conditions for safe storage, including any incompatibilities
Technical measures and storage conditions
Keep container tightly closed and dry in a cool, well-ventilated place.
Requirements for storage rooms and vessels
Containers which are opened must be carefully closed and kept upright to prevent leakage. Always keep in containers of same material as the original one.
Advice on storage assembly
None known
7.3
Specific end use(s)
No data available.
SECTION 8: Exposure controls/personal protection
8.1
Control parameters
Occupational exposure limit values
No
Substance name
CAS no.
EC no.
1
manganese, 4-[(5-chloro-4-methyl-2­sulfophenyl)azo]-3-hydroxy-2-naphthalenecarboxylic acid complex, C.I. Pigment Red 48:4 (15865:4)
5280-66-0
226-102-7 List of approved workplace exposure limits (WELs) / EH40
Manganese compounds
Mn
TWA
5
mg/m³
2
DUST
List of approved workplace exposure limits (WELs) / EH40
total inhalable dust
TWA
10
mg/m³
List of approved workplace exposure limits (WELs) / EH40
respirable dust
TWA
4
mg/m³
true
Page 3(9)
Page 23
EC safety data sheet
Trade name: Oil Pastels
Product no.: PHN-50 red
Replaced version: 1.0.0, issued: 12.06.2012
Region: GB
8.2
Exposure controls
Appropriate engineering controls
No data available.
Personal protective equipment
Respiratory protection
If workplace exposure limits are exceeded, a respiration protection approved for this particular job must be worn. In case of dust, aerosol and mist formation, take appropriate measures for breathing protection in the event workplace threshold values are not specified.
Eye / face protection
Safety glasses (EN 166)
Hand protection
Sufficient protection is given wearing suitable protective gloves checked according to i.e. EN 374, in the event of risk of skin contact with the product . Before use, the protective gloves should be tested in any case for its specific work­station suitability (i.e. mechanical resistance, product compatibility and antistatic properties). Adhere to the manufacturer’s instructions and information relating to the use, storage, care and replacement of protective gloves. Protective gloves shall be replaced immediately when physically damaged or worn. Design operations thus to avoid permanent use of protective gloves.
Other
Normal chemical work clothing.
Environmental exposure controls
No data available.
SECTION 9: Physical and chemical properties
9.1
Information on basic physical and chemical properties
Form/Colour
liquid
according product name
270
U_9005
Odour
alkohol-like
180
Odour threshold
No data available
pH value
No data available
Boiling point / boiling range
No data available
Melting point / melting range
Value
69.82
°C
Method
ASTM D 3418
69.82
Page 4(9)
Page 24
EC safety data sheet
Trade name: Oil Pastels
Product no.: PHN-50 red
Replaced version: 1.0.0, issued: 12.06.2012
Region: GB
Decomposition point / decomposition range
No data available
Flash point
No data available
Auto-ignition temperature
No data available
Oxidising properties
No data available
Explosive properties
No data available
Flammability (solid, gas)
No data available
Lower flammability or explosive limits
No data available
Upper flammability or explosive limits
No data available
Vapour pressure
No data available
Vapour density
No data available
Evaporation rate
No data available
Relative density
No data available
Density
No data available
Solubility in water
No data available
Solubility(ies)
No data available
Partition coefficient: n-octanol/water
No data available
Viscosity
No data available
9.2
Other information
Other information
No data available.
SECTION 10: Stability and reactivity
10.1
Reactivity
No data available.
10.2
Chemical stability
No data available.
10.3
Possibility of hazardous reactions
No data available.
10.4
Conditions to avoid
Stable under recommended storage and handling conditions(See section 7).
Page 5(9)
Page 25
EC safety data sheet
Trade name: Oil Pastels
Product no.: PHN-50 red
Replaced version: 1.0.0, issued: 12.06.2012
Region: GB
10.5
Incompatible materials
None known.
10.6
Hazardous decomposition products
No hazardous decomposition products known.
SECTION 11: Toxicological information
11.1
Information on toxicological effects
Acute oral toxicity
No
Product Name
1
Oil Pastels
Remarks
No data available.
Acute dermal toxicity
No
Product Name
1
Oil Pastels
Remarks
No data available.
Acute inhalational toxicity
No
Product Name
1
Oil Pastels
Remarks
No data available.
Lk.7000882
Skin corrosion/irritation
No
Product Name
1
Oil Pastels
Remarks
No data available.
Serious eye damage/irritation
No
Product Name
1
Oil Pastels
Remarks
No data available.
Respiratory tract irritation
Remarks
No data available.
Respiratory or skin sensitisation
No data available
Germ cell mutagenicity
No data available
Reproduction toxicity
No data available
Carcinogenicity
No data available
STOT-single exposure
No data available
STOT-repeated exposure
No data available
Aspiration hazard
No data available
Page 6(9)
Page 26
EC safety data sheet
Trade name: Oil Pastels
Product no.: PHN-50 red
Replaced version: 1.0.0, issued: 12.06.2012
Region: GB
SECTION 12: Ecological information
12.1
Toxicity
Toxicity to fish (acute)
No
Product Name
1
Oil Pastels
Remarks
No data available.
Lk.2098
Toxicity to fish (chronic)
No data available
Toxicity to Daphnia (acute)
No
Product Name
1
Oil Pastels
Remarks
No data available.
Lk.2098
Toxicity to Daphnia (chronic)
No data available
Toxicity to algae (acute)
No
Product Name
1
Oil Pastels
Remarks
No data available.
Lk.2098
Toxicity to algae (chronic)
No data available
Bacteria toxicity
No
Product Name
1
Oil Pastels
Remarks
No data available.
Lk.2099
12.2
Persistence and degradability
Biodegradability
No
Product Name
1
Oil Pastels
Remarks
No data available.
Lk.2100
12.3
Bioaccumulative potential
No data available.
12.4
Mobility in soil
No data available.
12.5
Results of PBT and vPvB assessment
No data available.
12.6
Other adverse effects
No data available.
12.7
Other information
Other information
Do not discharge product unmonitored into the environment.
710
SECTION 13: Disposal considerations
13.1
Waste treatment methods
Product
Allocation of a waste code number, according to the European Waste Catalogue, should be carried out in agreement with the regional waste disposal company.
Page 7(9)
Page 27
EC safety data sheet
Trade name: Oil Pastels
Product no.: PHN-50 red
Replaced version: 1.0.0, issued: 12.06.2012
Region: GB
Packaging
Residuals must be removed from packaging and when emptied completely disposed of in accordance with the regulations for waste removal. Incompletely emptied packaging must be disposed of in the form of disposal specified by the regional disposer.
SECTION 14: Transport information
14.1
Transport ADR/RID/ADN
The product is not subject to ADR/RID/ADN regulations.
14.2
Transport IMDG
The product is not subject to IMDG regulations.
14.3
Transport ICAO-TI / IATA
The product is not subject to ICAO-TI / IATA regulations.
14.4
Other information
No data available.
14.5
Environmental hazards
Information on environmental hazards, if relevant, please see 14.1 - 14.3.
14.6
Special precautions for user
No data available.
14.7
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not relevant
SECTION 15: Regulatory information
15.1
Safety, health and environmental regulations/legislation specific for the substance or mixture
EU regulations
Regulation (EC) No 1907/2006 (REACH) Annex XIV (List of substances subject to authorisation)
According to the data available and/or specifications supplied by upstream suppliers, this product does not contain any substances considered as substances requiring authorisation as listed on Annex XIV of the REACH regulation (EC) 1907/2006.
REACH candidate list of substances of very high concern (SVHC) for authorisation
According to available data and the information provided by preliminary suppliers, the product does not contain substances that are considered substances meeting the criteria for inclusion in annex XIV (List of Substances Subject to Authorisation) as laid down in Article 57 and article 59 of REACH (EC) 1907/2006.
Regulation (EC) No 1907/2006 (REACH) Annex XVII: RESTRICTIONS ON THE MANUFACTURE, PLACING ON THE MARKET AND USE OF CERTAIN DANGEROUS SUBSTANCES, PREPARATIONS AND ARTICLES
According to the data available and/or specifications supplied by upstream suppliers, this product does not contain any substances requiring authorisation as listed on Annex XIV of the REACH regulation (EC) 1907/2006.
Council Directive 96/82/EC on the control of major-accident hazards involving dangerous substances
Remarks
Annex I, part 1 + 2: not mentioned. With regard to possibly appropriate decomposition products see Chapter 10.
15.2
Chemical safety assessment
No data available.
SECTION 16: Other information
Department issuing safety data sheet
UMCO Umwelt Consult GmbH
Georg-Wilhelm-Str. 183 , 21107 Hamburg, Germany
Tel.: +49 40 / 79 02 36 300 Fax: +49 40 / 79 02 36 357 e-mail: umco@umco.de
Page 8(9)
Page 28
EC safety data sheet
Trade name: Oil Pastels
Product no.: PHN-50 red
Replaced version: 1.0.0, issued: 12.06.2012
Region: GB
This information is based on our present state of knowledge and experience. The security data sheet describes products with a view to the security requirements. However, it should not constitute a guarantee for any specific product properties and shall not establish a legally valid relationship.
Alterations/supplements: Alterations to the previous edition are marked in the left-hand margin.
.
Page 9(9)
Page 29
EC safety data sheet
Trade name: Oil Pastels
Product no.: PHN-50 yellow
Replaced version: 1.0.0, issued: 12.06.2012
Region: GB
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1
Product identifier
Trade name
Oil Pastels
1.2
Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses of the substance or mixture
art supplies
pastel colour
Uses advised against
No data available.
1.3
Details of the supplier of the safety data sheet
Address
Pentel Bürobedarf-Handelsgesellschaft mbH
Lademannbogen 143
22339
Hamburg
GERMANY
Telephone no.
+49 (0) 40 / 53 80 91 - 0
Fax no.
+49 (0) 40 / 53 85 58 - 7
Information provided by / telephone
+49 (0) 40 / 53 80 91 - 0
Advice on Safety Data Sheet
sdb_info@umco.de
1.4
Emergency telephone number
For medical advice (in German and English): +49 (0)551 192 40 (Giftinformationszentrum Nord)
SECTION 2: Hazards identification
2.1
Classification of the substance or mixture
Classification information
This product does not meet the classification and labelling criteria given in the Regulation (EC) No 1272/2008 (CLP).
This product does not meet the classification and labelling criteria given in the Dangerous Preparations Directive (1999/45/EC; DPD)
2.2
Label elements
Not relevant
Labelling information
The data subject of this Material Safety Data sheet refer to the paint contained in this product.
2.3
Other hazards
No data available.
Page 1(9)
Page 30
EC safety data sheet
Trade name: Oil Pastels
Product no.: PHN-50 yellow
Replaced version: 1.0.0, issued: 12.06.2012
Region: GB
SECTION 3: Composition/information on ingredients
3.1
Substances
Not applicable. The product is not a substance.
3.2
Mixtures
Hazardous ingredients
No
Substance name
Additional information
CAS / EC / Index / REACH no
Classification 67/548/EEC
Classification (EC) 1272/2008 (CLP)
Concentration
%
1
titanium-dioxide
13463-67-7 236-675-5
-
-
- - >
5.00
- < 10.00
%-b.w.
Full Text for all R-phrases , H-phrases and EUH-phrases: pls. see section 16
SECTION 4: First aid measures
4.1
Description of first aid measures
General information
In case of persisting adverse effects, consult a physician.
After inhalation
Ensure supply of fresh air.
After skin contact
When in contact with the skin, clean with soap and water. Do NOT use solvents or thinners.
After eye contact
Separate eyelids, wash the eyes thoroughly with water (15 min.).
After ingestion
Call a doctor. Never give anything by mouth to an unconscious person. Do not induce vomiting.
4.2
Most important symptoms and effects, both acute and delayed
No data available.
4.3
Indication of any immediate medical attention and special treatment needed
No data available.
SECTION 5: Firefighting measures
5.1
Extinguishing media
Suitable extinguishing media
Product itself is non-combustible; adapt fire extinguishing measures to surrounding areas.
Unsuitable extinguishing media
No data available.
5.2
Special hazards arising from the substance or mixture
In the event of fire, the following can be released: Carbon dioxide (CO2); Carbon monoxide (CO)
5.3
Advice for firefighters
Use self-contained breathing apparatus. Wear protective clothing.
SECTION 6: Accidental release measures
6.1
Personal precautions, protective equipment and emergency procedures
For non-emergency personnel
Refer to protective measures listed in sections 7 and 8. Ensure adequate ventilation.
Page 2(9)
Page 31
EC safety data sheet
Trade name: Oil Pastels
Product no.: PHN-50 yellow
Replaced version: 1.0.0, issued: 12.06.2012
Region: GB
For emergency responders
No data available. Personal protective equipment (PPE) - see Section 8.
6.2
Environmental precautions
Do not discharge into the drains/surface waters/groundwater.
6.3
Methods and material for containment and cleaning up
Take up mechanically. Send in suitable containers for recovery or disposal.
6.4
Reference to other sections
No data available.
SECTION 7: Handling and storage
7.1
Precautions for safe handling
Advice on safe handling
Observe the usual precautions for handling chemicals. Provide good ventilation of working area (local exhaust ventilation, if necessary).
General protective and hygiene measures
Observe the usual precautions when handling chemicals. Keep away from foodstuffs and beverages. Do not eat, drink or smoke during work time. Clean skin thoroughly after work; apply skin cream.
7.2
Conditions for safe storage, including any incompatibilities
Technical measures and storage conditions
Keep container tightly closed and dry in a cool, well-ventilated place.
Requirements for storage rooms and vessels
Containers which are opened must be carefully closed and kept upright to prevent leakage. Always keep in containers of same material as the original one.
Advice on storage assembly
None known
7.3
Specific end use(s)
No data available.
SECTION 8: Exposure controls/personal protection
8.1
Control parameters
Occupational exposure limit values
No
Substance name
CAS no.
EC no.
1
titanium-dioxide
13463-67-7
236-675-5
List of approved workplace exposure limits (WELs) / EH40
Titanium dioxide
total inhalable dust
TWA
10
mg/m³
List of approved workplace exposure limits (WELs) / EH40
Titanium dioxide
respirable dust
TWA
4
mg/m³
true
8.2
Exposure controls
Appropriate engineering controls
No data available.
Personal protective equipment
Respiratory protection
If workplace exposure limits are exceeded, a respiration protection approved for this particular job must be worn. In case of dust, aerosol and mist formation, take appropriate measures for breathing protection in the event workplace threshold values are not specified.
Page 3(9)
Page 32
EC safety data sheet
Trade name: Oil Pastels
Product no.: PHN-50 yellow
Replaced version: 1.0.0, issued: 12.06.2012
Region: GB
Eye / face protection
Safety glasses (EN 166)
Hand protection
Sufficient protection is given wearing suitable protective gloves checked according to i.e. EN 374, in the event of risk of skin contact with the product . Before use, the protective gloves should be tested in any case for its specific work­station suitability (i.e. mechanical resistance, product compatibility and antistatic properties). Adhere to the manufacturer’s instructions and information relating to the use, storage, care and replacement of protective gloves. Protective gloves shall be replaced immediately when physically damaged or worn. Design operations thus to avoid permanent use of protective gloves.
Other
Normal chemical work clothing.
Environmental exposure controls
No data available.
SECTION 9: Physical and chemical properties
9.1
Information on basic physical and chemical properties
Form/Colour
liquid
according product name
270
U_9005
Odour
alkohol-like
180
Odour threshold
No data available
pH value
No data available
Boiling point / boiling range
No data available
Melting point / melting range
Value
69.82
°C
Method
ASTM D 3418
69.82
Page 4(9)
Page 33
EC safety data sheet
Trade name: Oil Pastels
Product no.: PHN-50 yellow
Replaced version: 1.0.0, issued: 12.06.2012
Region: GB
Decomposition point / decomposition range
No data available
Flash point
No data available
Auto-ignition temperature
No data available
Oxidising properties
No data available
Explosive properties
No data available
Flammability (solid, gas)
No data available
Lower flammability or explosive limits
No data available
Upper flammability or explosive limits
No data available
Vapour pressure
No data available
Vapour density
No data available
Evaporation rate
No data available
Relative density
No data available
Density
No data available
Solubility in water
No data available
Solubility(ies)
No data available
Partition coefficient: n-octanol/water
No data available
Viscosity
No data available
9.2
Other information
Other information
No data available.
SECTION 10: Stability and reactivity
10.1
Reactivity
No data available.
10.2
Chemical stability
No data available.
10.3
Possibility of hazardous reactions
No data available.
10.4
Conditions to avoid
Stable under recommended storage and handling conditions(See section 7).
Page 5(9)
Page 34
EC safety data sheet
Trade name: Oil Pastels
Product no.: PHN-50 yellow
Replaced version: 1.0.0, issued: 12.06.2012
Region: GB
10.5
Incompatible materials
None known.
10.6
Hazardous decomposition products
No hazardous decomposition products known.
SECTION 11: Toxicological information
11.1
Information on toxicological effects
Acute oral toxicity
No
Product Name
1
Oil Pastels
Remarks
No data available.
Acute dermal toxicity
No
Product Name
1
Oil Pastels
Remarks
No data available.
Acute inhalational toxicity
No
Product Name
1
Oil Pastels
Remarks
No data available.
Lk.7000882
Skin corrosion/irritation
No
Product Name
1
Oil Pastels
Remarks
No data available.
Serious eye damage/irritation
No
Product Name
1
Oil Pastels
Remarks
No data available.
Respiratory tract irritation
Remarks
No data available.
Respiratory or skin sensitisation
No data available
Germ cell mutagenicity
No data available
Reproduction toxicity
No data available
Carcinogenicity
No data available
STOT-single exposure
No data available
STOT-repeated exposure
No data available
Aspiration hazard
No data available
Page 6(9)
Page 35
EC safety data sheet
Trade name: Oil Pastels
Product no.: PHN-50 yellow
Replaced version: 1.0.0, issued: 12.06.2012
Region: GB
SECTION 12: Ecological information
12.1
Toxicity
Toxicity to fish (acute)
No
Product Name
1
Oil Pastels
Remarks
No data available.
Lk.2098
Toxicity to fish (chronic)
No data available
Toxicity to Daphnia (acute)
No
Product Name
1
Oil Pastels
Remarks
No data available.
Lk.2098
Toxicity to Daphnia (chronic)
No data available
Toxicity to algae (acute)
No
Product Name
1
Oil Pastels
Remarks
No data available.
Lk.2098
Toxicity to algae (chronic)
No data available
Bacteria toxicity
No
Product Name
1
Oil Pastels
Remarks
No data available.
Lk.2099
12.2
Persistence and degradability
Biodegradability
No
Product Name
1
Oil Pastels
Remarks
No data available.
Lk.2100
12.3
Bioaccumulative potential
No data available.
12.4
Mobility in soil
No data available.
12.5
Results of PBT and vPvB assessment
No data available.
12.6
Other adverse effects
No data available.
12.7
Other information
Other information
Do not discharge product unmonitored into the environment.
710
SECTION 13: Disposal considerations
13.1
Waste treatment methods
Product
Allocation of a waste code number, according to the European Waste Catalogue, should be carried out in agreement with the regional waste disposal company.
Page 7(9)
Page 36
EC safety data sheet
Trade name: Oil Pastels
Product no.: PHN-50 yellow
Replaced version: 1.0.0, issued: 12.06.2012
Region: GB
Packaging
Residuals must be removed from packaging and when emptied completely disposed of in accordance with the regulations for waste removal. Incompletely emptied packaging must be disposed of in the form of disposal specified by the regional disposer.
SECTION 14: Transport information
14.1
Transport ADR/RID/ADN
The product is not subject to ADR/RID/ADN regulations.
14.2
Transport IMDG
The product is not subject to IMDG regulations.
14.3
Transport ICAO-TI / IATA
The product is not subject to ICAO-TI / IATA regulations.
14.4
Other information
No data available.
14.5
Environmental hazards
Information on environmental hazards, if relevant, please see 14.1 - 14.3.
14.6
Special precautions for user
No data available.
14.7
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not relevant
SECTION 15: Regulatory information
15.1
Safety, health and environmental regulations/legislation specific for the substance or mixture
EU regulations
Regulation (EC) No 1907/2006 (REACH) Annex XIV (List of substances subject to authorisation)
According to the data available and/or specifications supplied by upstream suppliers, this product does not contain any substances considered as substances requiring authorisation as listed on Annex XIV of the REACH regulation (EC) 1907/2006.
REACH candidate list of substances of very high concern (SVHC) for authorisation
According to available data and the information provided by preliminary suppliers, the product does not contain substances that are considered substances meeting the criteria for inclusion in annex XIV (List of Substances Subject to Authorisation) as laid down in Article 57 and article 59 of REACH (EC) 1907/2006.
Regulation (EC) No 1907/2006 (REACH) Annex XVII: RESTRICTIONS ON THE MANUFACTURE, PLACING ON THE MARKET AND USE OF CERTAIN DANGEROUS SUBSTANCES, PREPARATIONS AND ARTICLES
According to the data available and/or specifications supplied by upstream suppliers, this product does not contain any substances requiring authorisation as listed on Annex XIV of the REACH regulation (EC) 1907/2006.
Council Directive 96/82/EC on the control of major-accident hazards involving dangerous substances
Remarks
Annex I, part 1 + 2: not mentioned. With regard to possibly appropriate decomposition products see Chapter 10.
15.2
Chemical safety assessment
No data available.
SECTION 16: Other information
Department issuing safety data sheet
UMCO Umwelt Consult GmbH
Georg-Wilhelm-Str. 183 , 21107 Hamburg, Germany
Tel.: +49 40 / 79 02 36 300 Fax: +49 40 / 79 02 36 357 e-mail: umco@umco.de
Page 8(9)
Page 37
EC safety data sheet
Trade name: Oil Pastels
Product no.: PHN-50 yellow
Replaced version: 1.0.0, issued: 12.06.2012
Region: GB
This information is based on our present state of knowledge and experience. The security data sheet describes products with a view to the security requirements. However, it should not constitute a guarantee for any specific product properties and shall not establish a legally valid relationship.
Alterations/supplements: Alterations to the previous edition are marked in the left-hand margin.
.
Page 9(9)
Page 38
EC safety data sheet
Trade name: Oil Pastels
Product no.: PHN-50 pale blue
Replaced version: 1.0.0, issued: 12.06.2012
Region: GB
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1
Product identifier
Trade name
Oil Pastels
1.2
Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses of the substance or mixture
art supplies
pastel colour
Uses advised against
No data available.
1.3
Details of the supplier of the safety data sheet
Address
Pentel Bürobedarf-Handelsgesellschaft mbH
Lademannbogen 143
22339
Hamburg
GERMANY
Telephone no.
+49 (0) 40 / 53 80 91 - 0
Fax no.
+49 (0) 40 / 53 85 58 - 7
Information provided by / telephone
+49 (0) 40 / 53 80 91 - 0
Advice on Safety Data Sheet
sdb_info@umco.de
1.4
Emergency telephone number
For medical advice (in German and English): +49 (0)551 192 40 (Giftinformationszentrum Nord)
SECTION 2: Hazards identification
2.1
Classification of the substance or mixture
Classification information
This product does not meet the classification and labelling criteria given in the Regulation (EC) No 1272/2008 (CLP).
This product does not meet the classification and labelling criteria given in the Dangerous Preparations Directive (1999/45/EC; DPD)
2.2
Label elements
Not relevant
Labelling information
The data subject of this Material Safety Data sheet refer to the paint contained in this product.
2.3
Other hazards
No data available.
Page 1(9)
Page 39
EC safety data sheet
Trade name: Oil Pastels
Product no.: PHN-50 pale blue
Replaced version: 1.0.0, issued: 12.06.2012
Region: GB
SECTION 3: Composition/information on ingredients
3.1
Substances
Not applicable. The product is not a substance.
3.2
Mixtures
Hazardous ingredients
No
Substance name
Additional information
CAS / EC / Index / REACH no
Classification 67/548/EEC
Classification (EC) 1272/2008 (CLP)
Concentration
%
1
titanium-dioxide
13463-67-7 236-675-5
-
-
- - >
1.00
- < 5.00
%-b.w.
Full Text for all R-phrases , H-phrases and EUH-phrases: pls. see section 16
SECTION 4: First aid measures
4.1
Description of first aid measures
General information
In case of persisting adverse effects, consult a physician.
After inhalation
Ensure supply of fresh air.
After skin contact
When in contact with the skin, clean with soap and water. Do NOT use solvents or thinners.
After eye contact
Separate eyelids, wash the eyes thoroughly with water (15 min.).
After ingestion
Call a doctor. Never give anything by mouth to an unconscious person. Do not induce vomiting.
4.2
Most important symptoms and effects, both acute and delayed
No data available.
4.3
Indication of any immediate medical attention and special treatment needed
No data available.
SECTION 5: Firefighting measures
5.1
Extinguishing media
Suitable extinguishing media
Product itself is non-combustible; adapt fire extinguishing measures to surrounding areas.
Unsuitable extinguishing media
No data available.
5.2
Special hazards arising from the substance or mixture
In the event of fire, the following can be released: Carbon dioxide (CO2); Carbon monoxide (CO)
5.3
Advice for firefighters
Use self-contained breathing apparatus. Wear protective clothing.
SECTION 6: Accidental release measures
6.1
Personal precautions, protective equipment and emergency procedures
For non-emergency personnel
Refer to protective measures listed in sections 7 and 8. Ensure adequate ventilation.
Page 2(9)
Page 40
EC safety data sheet
Trade name: Oil Pastels
Product no.: PHN-50 pale blue
Replaced version: 1.0.0, issued: 12.06.2012
Region: GB
For emergency responders
No data available. Personal protective equipment (PPE) - see Section 8.
6.2
Environmental precautions
Do not discharge into the drains/surface waters/groundwater.
6.3
Methods and material for containment and cleaning up
Take up mechanically. Send in suitable containers for recovery or disposal.
6.4
Reference to other sections
No data available.
SECTION 7: Handling and storage
7.1
Precautions for safe handling
Advice on safe handling
Observe the usual precautions for handling chemicals. Provide good ventilation of working area (local exhaust ventilation, if necessary).
General protective and hygiene measures
Observe the usual precautions when handling chemicals. Keep away from foodstuffs and beverages. Do not eat, drink or smoke during work time. Clean skin thoroughly after work; apply skin cream.
7.2
Conditions for safe storage, including any incompatibilities
Technical measures and storage conditions
Keep container tightly closed and dry in a cool, well-ventilated place.
Requirements for storage rooms and vessels
Containers which are opened must be carefully closed and kept upright to prevent leakage. Always keep in containers of same material as the original one.
Advice on storage assembly
None known
7.3
Specific end use(s)
No data available.
SECTION 8: Exposure controls/personal protection
8.1
Control parameters
Occupational exposure limit values
No
Substance name
CAS no.
EC no.
1
titanium-dioxide
13463-67-7
236-675-5
List of approved workplace exposure limits (WELs) / EH40
Titanium dioxide
total inhalable dust
TWA
10
mg/m³
List of approved workplace exposure limits (WELs) / EH40
Titanium dioxide
respirable dust
TWA
4
mg/m³
true
8.2
Exposure controls
Appropriate engineering controls
No data available.
Personal protective equipment
Respiratory protection
If workplace exposure limits are exceeded, a respiration protection approved for this particular job must be worn. In case of dust, aerosol and mist formation, take appropriate measures for breathing protection in the event workplace threshold values are not specified.
Page 3(9)
Page 41
EC safety data sheet
Trade name: Oil Pastels
Product no.: PHN-50 pale blue
Replaced version: 1.0.0, issued: 12.06.2012
Region: GB
Eye / face protection
Safety glasses (EN 166)
Hand protection
Sufficient protection is given wearing suitable protective gloves checked according to i.e. EN 374, in the event of risk of skin contact with the product . Before use, the protective gloves should be tested in any case for its specific work­station suitability (i.e. mechanical resistance, product compatibility and antistatic properties). Adhere to the manufacturer’s instructions and information relating to the use, storage, care and replacement of protective gloves. Protective gloves shall be replaced immediately when physically damaged or worn. Design operations thus to avoid permanent use of protective gloves.
Other
Normal chemical work clothing.
Environmental exposure controls
No data available.
SECTION 9: Physical and chemical properties
9.1
Information on basic physical and chemical properties
Form/Colour
liquid
according product name
270
U_9005
Odour
alkohol-like
180
Odour threshold
No data available
pH value
No data available
Boiling point / boiling range
No data available
Melting point / melting range
Value
69.82
°C
Method
ASTM D 3418
69.82
Page 4(9)
Page 42
EC safety data sheet
Trade name: Oil Pastels
Product no.: PHN-50 pale blue
Replaced version: 1.0.0, issued: 12.06.2012
Region: GB
Decomposition point / decomposition range
No data available
Flash point
No data available
Auto-ignition temperature
No data available
Oxidising properties
No data available
Explosive properties
No data available
Flammability (solid, gas)
No data available
Lower flammability or explosive limits
No data available
Upper flammability or explosive limits
No data available
Vapour pressure
No data available
Vapour density
No data available
Evaporation rate
No data available
Relative density
No data available
Density
No data available
Solubility in water
No data available
Solubility(ies)
No data available
Partition coefficient: n-octanol/water
No data available
Viscosity
No data available
9.2
Other information
Other information
No data available.
SECTION 10: Stability and reactivity
10.1
Reactivity
No data available.
10.2
Chemical stability
No data available.
10.3
Possibility of hazardous reactions
No data available.
10.4
Conditions to avoid
Stable under recommended storage and handling conditions(See section 7).
Page 5(9)
Page 43
EC safety data sheet
Trade name: Oil Pastels
Product no.: PHN-50 pale blue
Replaced version: 1.0.0, issued: 12.06.2012
Region: GB
10.5
Incompatible materials
None known.
10.6
Hazardous decomposition products
No hazardous decomposition products known.
SECTION 11: Toxicological information
11.1
Information on toxicological effects
Acute oral toxicity
No
Product Name
1
Oil Pastels
Remarks
No data available.
Acute dermal toxicity
No
Product Name
1
Oil Pastels
Remarks
No data available.
Acute inhalational toxicity
No
Product Name
1
Oil Pastels
Remarks
No data available.
Lk.7000882
Skin corrosion/irritation
No
Product Name
1
Oil Pastels
Remarks
No data available.
Serious eye damage/irritation
No
Product Name
1
Oil Pastels
Remarks
No data available.
Respiratory tract irritation
Remarks
No data available.
Respiratory or skin sensitisation
No data available
Germ cell mutagenicity
No data available
Reproduction toxicity
No data available
Carcinogenicity
No data available
STOT-single exposure
No data available
STOT-repeated exposure
No data available
Aspiration hazard
No data available
Page 6(9)
Page 44
EC safety data sheet
Trade name: Oil Pastels
Product no.: PHN-50 pale blue
Replaced version: 1.0.0, issued: 12.06.2012
Region: GB
SECTION 12: Ecological information
12.1
Toxicity
Toxicity to fish (acute)
No
Product Name
1
Oil Pastels
Remarks
No data available.
Lk.2098
Toxicity to fish (chronic)
No data available
Toxicity to Daphnia (acute)
No
Product Name
1
Oil Pastels
Remarks
No data available.
Lk.2098
Toxicity to Daphnia (chronic)
No data available
Toxicity to algae (acute)
No
Product Name
1
Oil Pastels
Remarks
No data available.
Lk.2098
Toxicity to algae (chronic)
No data available
Bacteria toxicity
No
Product Name
1
Oil Pastels
Remarks
No data available.
Lk.2099
12.2
Persistence and degradability
Biodegradability
No
Product Name
1
Oil Pastels
Remarks
No data available.
Lk.2100
12.3
Bioaccumulative potential
No data available.
12.4
Mobility in soil
No data available.
12.5
Results of PBT and vPvB assessment
No data available.
12.6
Other adverse effects
No data available.
12.7
Other information
Other information
Do not discharge product unmonitored into the environment.
710
SECTION 13: Disposal considerations
13.1
Waste treatment methods
Product
Allocation of a waste code number, according to the European Waste Catalogue, should be carried out in agreement with the regional waste disposal company.
Page 7(9)
Page 45
EC safety data sheet
Trade name: Oil Pastels
Product no.: PHN-50 pale blue
Replaced version: 1.0.0, issued: 12.06.2012
Region: GB
Packaging
Residuals must be removed from packaging and when emptied completely disposed of in accordance with the regulations for waste removal. Incompletely emptied packaging must be disposed of in the form of disposal specified by the regional disposer.
SECTION 14: Transport information
14.1
Transport ADR/RID/ADN
The product is not subject to ADR/RID/ADN regulations.
14.2
Transport IMDG
The product is not subject to IMDG regulations.
14.3
Transport ICAO-TI / IATA
The product is not subject to ICAO-TI / IATA regulations.
14.4
Other information
No data available.
14.5
Environmental hazards
Information on environmental hazards, if relevant, please see 14.1 - 14.3.
14.6
Special precautions for user
No data available.
14.7
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not relevant
SECTION 15: Regulatory information
15.1
Safety, health and environmental regulations/legislation specific for the substance or mixture
EU regulations
Regulation (EC) No 1907/2006 (REACH) Annex XIV (List of substances subject to authorisation)
According to the data available and/or specifications supplied by upstream suppliers, this product does not contain any substances considered as substances requiring authorisation as listed on Annex XIV of the REACH regulation (EC) 1907/2006.
REACH candidate list of substances of very high concern (SVHC) for authorisation
According to available data and the information provided by preliminary suppliers, the product does not contain substances that are considered substances meeting the criteria for inclusion in annex XIV (List of Substances Subject to Authorisation) as laid down in Article 57 and article 59 of REACH (EC) 1907/2006.
Regulation (EC) No 1907/2006 (REACH) Annex XVII: RESTRICTIONS ON THE MANUFACTURE, PLACING ON THE MARKET AND USE OF CERTAIN DANGEROUS SUBSTANCES, PREPARATIONS AND ARTICLES
According to the data available and/or specifications supplied by upstream suppliers, this product does not contain any substances requiring authorisation as listed on Annex XIV of the REACH regulation (EC) 1907/2006.
Council Directive 96/82/EC on the control of major-accident hazards involving dangerous substances
Remarks
Annex I, part 1 + 2: not mentioned. With regard to possibly appropriate decomposition products see Chapter 10.
15.2
Chemical safety assessment
No data available.
SECTION 16: Other information
Department issuing safety data sheet
UMCO Umwelt Consult GmbH
Georg-Wilhelm-Str. 183 , 21107 Hamburg, Germany
Tel.: +49 40 / 79 02 36 300 Fax: +49 40 / 79 02 36 357 e-mail: umco@umco.de
Page 8(9)
Page 46
EC safety data sheet
Trade name: Oil Pastels
Product no.: PHN-50 pale blue
Replaced version: 1.0.0, issued: 12.06.2012
Region: GB
This information is based on our present state of knowledge and experience. The security data sheet describes products with a view to the security requirements. However, it should not constitute a guarantee for any specific product properties and shall not establish a legally valid relationship.
Alterations/supplements: Alterations to the previous edition are marked in the left-hand margin.
.
Page 9(9)
Page 47
EC safety data sheet
Trade name: Oil Pastels
Product no.: PHN-50 yellow green
Replaced version: 1.0.0, issued: 12.06.2012
Region: GB
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1
Product identifier
Trade name
Oil Pastels
1.2
Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses of the substance or mixture
art supplies
pastel colour
Uses advised against
No data available.
1.3
Details of the supplier of the safety data sheet
Address
Pentel Bürobedarf-Handelsgesellschaft mbH
Lademannbogen 143
22339
Hamburg
GERMANY
Telephone no.
+49 (0) 40 / 53 80 91 - 0
Fax no.
+49 (0) 40 / 53 85 58 - 7
Information provided by / telephone
+49 (0) 40 / 53 80 91 - 0
Advice on Safety Data Sheet
sdb_info@umco.de
1.4
Emergency telephone number
For medical advice (in German and English): +49 (0)551 192 40 (Giftinformationszentrum Nord)
SECTION 2: Hazards identification
2.1
Classification of the substance or mixture
Classification information
This product does not meet the classification and labelling criteria given in the Regulation (EC) No 1272/2008 (CLP).
This product does not meet the classification and labelling criteria given in the Dangerous Preparations Directive (1999/45/EC; DPD)
2.2
Label elements
Not relevant
Labelling information
The data subject of this Material Safety Data sheet refer to the paint contained in this product.
2.3
Other hazards
No data available.
Page 1(9)
Page 48
EC safety data sheet
Trade name: Oil Pastels
Product no.: PHN-50 yellow green
Replaced version: 1.0.0, issued: 12.06.2012
Region: GB
SECTION 3: Composition/information on ingredients
3.1
Substances
Not applicable. The product is not a substance.
3.2
Mixtures
Hazardous ingredients
No
Substance name
Additional information
CAS / EC / Index / REACH no
Classification 67/548/EEC
Classification (EC) 1272/2008 (CLP)
Concentration
%
1
titanium-dioxide
13463-67-7 236-675-5
-
-
- - >
1.00
- < 5.00
%-b.w.
Full Text for all R-phrases , H-phrases and EUH-phrases: pls. see section 16
SECTION 4: First aid measures
4.1
Description of first aid measures
General information
In case of persisting adverse effects, consult a physician.
After inhalation
Ensure supply of fresh air.
After skin contact
When in contact with the skin, clean with soap and water. Do NOT use solvents or thinners.
After eye contact
Separate eyelids, wash the eyes thoroughly with water (15 min.).
After ingestion
Call a doctor. Never give anything by mouth to an unconscious person. Do not induce vomiting.
4.2
Most important symptoms and effects, both acute and delayed
No data available.
4.3
Indication of any immediate medical attention and special treatment needed
No data available.
SECTION 5: Firefighting measures
5.1
Extinguishing media
Suitable extinguishing media
Product itself is non-combustible; adapt fire extinguishing measures to surrounding areas.
Unsuitable extinguishing media
No data available.
5.2
Special hazards arising from the substance or mixture
In the event of fire, the following can be released: Carbon dioxide (CO2); Carbon monoxide (CO)
5.3
Advice for firefighters
Use self-contained breathing apparatus. Wear protective clothing.
SECTION 6: Accidental release measures
6.1
Personal precautions, protective equipment and emergency procedures
For non-emergency personnel
Refer to protective measures listed in sections 7 and 8. Ensure adequate ventilation.
Page 2(9)
Page 49
EC safety data sheet
Trade name: Oil Pastels
Product no.: PHN-50 yellow green
Replaced version: 1.0.0, issued: 12.06.2012
Region: GB
For emergency responders
No data available. Personal protective equipment (PPE) - see Section 8.
6.2
Environmental precautions
Do not discharge into the drains/surface waters/groundwater.
6.3
Methods and material for containment and cleaning up
Take up mechanically. Send in suitable containers for recovery or disposal.
6.4
Reference to other sections
No data available.
SECTION 7: Handling and storage
7.1
Precautions for safe handling
Advice on safe handling
Observe the usual precautions for handling chemicals. Provide good ventilation of working area (local exhaust ventilation, if necessary).
General protective and hygiene measures
Observe the usual precautions when handling chemicals. Keep away from foodstuffs and beverages. Do not eat, drink or smoke during work time. Clean skin thoroughly after work; apply skin cream.
7.2
Conditions for safe storage, including any incompatibilities
Technical measures and storage conditions
Keep container tightly closed and dry in a cool, well-ventilated place.
Requirements for storage rooms and vessels
Containers which are opened must be carefully closed and kept upright to prevent leakage. Always keep in containers of same material as the original one.
Advice on storage assembly
None known
7.3
Specific end use(s)
No data available.
SECTION 8: Exposure controls/personal protection
8.1
Control parameters
Occupational exposure limit values
No
Substance name
CAS no.
EC no.
1
titanium-dioxide
13463-67-7
236-675-5
List of approved workplace exposure limits (WELs) / EH40
Titanium dioxide
total inhalable dust
TWA
10
mg/m³
List of approved workplace exposure limits (WELs) / EH40
Titanium dioxide
respirable dust
TWA
4
mg/m³
true
8.2
Exposure controls
Appropriate engineering controls
No data available.
Personal protective equipment
Respiratory protection
If workplace exposure limits are exceeded, a respiration protection approved for this particular job must be worn. In case of dust, aerosol and mist formation, take appropriate measures for breathing protection in the event workplace threshold values are not specified.
Page 3(9)
Page 50
EC safety data sheet
Trade name: Oil Pastels
Product no.: PHN-50 yellow green
Replaced version: 1.0.0, issued: 12.06.2012
Region: GB
Eye / face protection
Safety glasses (EN 166)
Hand protection
Sufficient protection is given wearing suitable protective gloves checked according to i.e. EN 374, in the event of risk of skin contact with the product . Before use, the protective gloves should be tested in any case for its specific work­station suitability (i.e. mechanical resistance, product compatibility and antistatic properties). Adhere to the manufacturer’s instructions and information relating to the use, storage, care and replacement of protective gloves. Protective gloves shall be replaced immediately when physically damaged or worn. Design operations thus to avoid permanent use of protective gloves.
Other
Normal chemical work clothing.
Environmental exposure controls
No data available.
SECTION 9: Physical and chemical properties
9.1
Information on basic physical and chemical properties
Form/Colour
liquid
according product name
270
U_9005
Odour
alkohol-like
180
Odour threshold
No data available
pH value
No data available
Boiling point / boiling range
No data available
Melting point / melting range
Value
69.82
°C
Method
ASTM D 3418
69.82
Page 4(9)
Page 51
EC safety data sheet
Trade name: Oil Pastels
Product no.: PHN-50 yellow green
Replaced version: 1.0.0, issued: 12.06.2012
Region: GB
Decomposition point / decomposition range
No data available
Flash point
No data available
Auto-ignition temperature
No data available
Oxidising properties
No data available
Explosive properties
No data available
Flammability (solid, gas)
No data available
Lower flammability or explosive limits
No data available
Upper flammability or explosive limits
No data available
Vapour pressure
No data available
Vapour density
No data available
Evaporation rate
No data available
Relative density
No data available
Density
No data available
Solubility in water
No data available
Solubility(ies)
No data available
Partition coefficient: n-octanol/water
No data available
Viscosity
No data available
9.2
Other information
Other information
No data available.
SECTION 10: Stability and reactivity
10.1
Reactivity
No data available.
10.2
Chemical stability
No data available.
10.3
Possibility of hazardous reactions
No data available.
10.4
Conditions to avoid
Stable under recommended storage and handling conditions(See section 7).
Page 5(9)
Page 52
EC safety data sheet
Trade name: Oil Pastels
Product no.: PHN-50 yellow green
Replaced version: 1.0.0, issued: 12.06.2012
Region: GB
10.5
Incompatible materials
None known.
10.6
Hazardous decomposition products
No hazardous decomposition products known.
SECTION 11: Toxicological information
11.1
Information on toxicological effects
Acute oral toxicity
No
Product Name
1
Oil Pastels
Remarks
No data available.
Acute dermal toxicity
No
Product Name
1
Oil Pastels
Remarks
No data available.
Acute inhalational toxicity
No
Product Name
1
Oil Pastels
Remarks
No data available.
Lk.7000882
Skin corrosion/irritation
No
Product Name
1
Oil Pastels
Remarks
No data available.
Serious eye damage/irritation
No
Product Name
1
Oil Pastels
Remarks
No data available.
Respiratory tract irritation
Remarks
No data available.
Respiratory or skin sensitisation
No data available
Germ cell mutagenicity
No data available
Reproduction toxicity
No data available
Carcinogenicity
No data available
STOT-single exposure
No data available
STOT-repeated exposure
No data available
Aspiration hazard
No data available
Page 6(9)
Page 53
EC safety data sheet
Trade name: Oil Pastels
Product no.: PHN-50 yellow green
Replaced version: 1.0.0, issued: 12.06.2012
Region: GB
SECTION 12: Ecological information
12.1
Toxicity
Toxicity to fish (acute)
No
Product Name
1
Oil Pastels
Remarks
No data available.
Lk.2098
Toxicity to fish (chronic)
No data available
Toxicity to Daphnia (acute)
No
Product Name
1
Oil Pastels
Remarks
No data available.
Lk.2098
Toxicity to Daphnia (chronic)
No data available
Toxicity to algae (acute)
No
Product Name
1
Oil Pastels
Remarks
No data available.
Lk.2098
Toxicity to algae (chronic)
No data available
Bacteria toxicity
No
Product Name
1
Oil Pastels
Remarks
No data available.
Lk.2099
12.2
Persistence and degradability
Biodegradability
No
Product Name
1
Oil Pastels
Remarks
No data available.
Lk.2100
12.3
Bioaccumulative potential
No data available.
12.4
Mobility in soil
No data available.
12.5
Results of PBT and vPvB assessment
No data available.
12.6
Other adverse effects
No data available.
12.7
Other information
Other information
Do not discharge product unmonitored into the environment.
710
SECTION 13: Disposal considerations
13.1
Waste treatment methods
Product
Allocation of a waste code number, according to the European Waste Catalogue, should be carried out in agreement with the regional waste disposal company.
Page 7(9)
Page 54
EC safety data sheet
Trade name: Oil Pastels
Product no.: PHN-50 yellow green
Replaced version: 1.0.0, issued: 12.06.2012
Region: GB
Packaging
Residuals must be removed from packaging and when emptied completely disposed of in accordance with the regulations for waste removal. Incompletely emptied packaging must be disposed of in the form of disposal specified by the regional disposer.
SECTION 14: Transport information
14.1
Transport ADR/RID/ADN
The product is not subject to ADR/RID/ADN regulations.
14.2
Transport IMDG
The product is not subject to IMDG regulations.
14.3
Transport ICAO-TI / IATA
The product is not subject to ICAO-TI / IATA regulations.
14.4
Other information
No data available.
14.5
Environmental hazards
Information on environmental hazards, if relevant, please see 14.1 - 14.3.
14.6
Special precautions for user
No data available.
14.7
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not relevant
SECTION 15: Regulatory information
15.1
Safety, health and environmental regulations/legislation specific for the substance or mixture
EU regulations
Regulation (EC) No 1907/2006 (REACH) Annex XIV (List of substances subject to authorisation)
According to the data available and/or specifications supplied by upstream suppliers, this product does not contain any substances considered as substances requiring authorisation as listed on Annex XIV of the REACH regulation (EC) 1907/2006.
REACH candidate list of substances of very high concern (SVHC) for authorisation
According to available data and the information provided by preliminary suppliers, the product does not contain substances that are considered substances meeting the criteria for inclusion in annex XIV (List of Substances Subject to Authorisation) as laid down in Article 57 and article 59 of REACH (EC) 1907/2006.
Regulation (EC) No 1907/2006 (REACH) Annex XVII: RESTRICTIONS ON THE MANUFACTURE, PLACING ON THE MARKET AND USE OF CERTAIN DANGEROUS SUBSTANCES, PREPARATIONS AND ARTICLES
According to the data available and/or specifications supplied by upstream suppliers, this product does not contain any substances requiring authorisation as listed on Annex XIV of the REACH regulation (EC) 1907/2006.
Council Directive 96/82/EC on the control of major-accident hazards involving dangerous substances
Remarks
Annex I, part 1 + 2: not mentioned. With regard to possibly appropriate decomposition products see Chapter 10.
15.2
Chemical safety assessment
No data available.
SECTION 16: Other information
Department issuing safety data sheet
UMCO Umwelt Consult GmbH
Georg-Wilhelm-Str. 183 , 21107 Hamburg, Germany
Tel.: +49 40 / 79 02 36 300 Fax: +49 40 / 79 02 36 357 e-mail: umco@umco.de
Page 8(9)
Page 55
EC safety data sheet
Trade name: Oil Pastels
Product no.: PHN-50 yellow green
Replaced version: 1.0.0, issued: 12.06.2012
Region: GB
This information is based on our present state of knowledge and experience. The security data sheet describes products with a view to the security requirements. However, it should not constitute a guarantee for any specific product properties and shall not establish a legally valid relationship.
Alterations/supplements: Alterations to the previous edition are marked in the left-hand margin.
.
Page 9(9)
Page 56
EC safety data sheet
Trade name: Oil Pastels
Product no.: PHN-50 green
Replaced version: 1.0.0, issued: 12.06.2012
Region: GB
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1
Product identifier
Trade name
Oil Pastels
1.2
Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses of the substance or mixture
art supplies
pastel colour
Uses advised against
No data available.
1.3
Details of the supplier of the safety data sheet
Address
Pentel Bürobedarf-Handelsgesellschaft mbH
Lademannbogen 143
22339
Hamburg
GERMANY
Telephone no.
+49 (0) 40 / 53 80 91 - 0
Fax no.
+49 (0) 40 / 53 85 58 - 7
Information provided by / telephone
+49 (0) 40 / 53 80 91 - 0
Advice on Safety Data Sheet
sdb_info@umco.de
1.4
Emergency telephone number
For medical advice (in German and English): +49 (0)551 192 40 (Giftinformationszentrum Nord)
SECTION 2: Hazards identification
2.1
Classification of the substance or mixture
Classification information
This product does not meet the classification and labelling criteria given in the Regulation (EC) No 1272/2008 (CLP).
This product does not meet the classification and labelling criteria given in the Dangerous Preparations Directive (1999/45/EC; DPD)
2.2
Label elements
Not relevant
Labelling information
The data subject of this Material Safety Data sheet refer to the paint contained in this product.
2.3
Other hazards
No data available.
Page 1(9)
Page 57
EC safety data sheet
Trade name: Oil Pastels
Product no.: PHN-50 green
Replaced version: 1.0.0, issued: 12.06.2012
Region: GB
SECTION 3: Composition/information on ingredients
3.1
Substances
Not applicable. The product is not a substance.
3.2
Mixtures
Hazardous ingredients
No
Substance name
Additional information
CAS / EC / Index / REACH no
Classification 67/548/EEC
Classification (EC) 1272/2008 (CLP)
Concentration
%
1
titanium-dioxide
13463-67-7 236-675-5
-
-
- - >
10.00
- < 30.00
%-b.w.
Full Text for all R-phrases , H-phrases and EUH-phrases: pls. see section 16
SECTION 4: First aid measures
4.1
Description of first aid measures
General information
In case of persisting adverse effects, consult a physician.
After inhalation
Ensure supply of fresh air.
After skin contact
When in contact with the skin, clean with soap and water. Do NOT use solvents or thinners.
After eye contact
Separate eyelids, wash the eyes thoroughly with water (15 min.).
After ingestion
Call a doctor. Never give anything by mouth to an unconscious person. Do not induce vomiting.
4.2
Most important symptoms and effects, both acute and delayed
No data available.
4.3
Indication of any immediate medical attention and special treatment needed
No data available.
SECTION 5: Firefighting measures
5.1
Extinguishing media
Suitable extinguishing media
Product itself is non-combustible; adapt fire extinguishing measures to surrounding areas.
Unsuitable extinguishing media
No data available.
5.2
Special hazards arising from the substance or mixture
In the event of fire, the following can be released: Carbon dioxide (CO2); Carbon monoxide (CO)
5.3
Advice for firefighters
Use self-contained breathing apparatus. Wear protective clothing.
SECTION 6: Accidental release measures
6.1
Personal precautions, protective equipment and emergency procedures
For non-emergency personnel
Refer to protective measures listed in sections 7 and 8. Ensure adequate ventilation.
Page 2(9)
Page 58
EC safety data sheet
Trade name: Oil Pastels
Product no.: PHN-50 green
Replaced version: 1.0.0, issued: 12.06.2012
Region: GB
For emergency responders
No data available. Personal protective equipment (PPE) - see Section 8.
6.2
Environmental precautions
Do not discharge into the drains/surface waters/groundwater.
6.3
Methods and material for containment and cleaning up
Take up mechanically. Send in suitable containers for recovery or disposal.
6.4
Reference to other sections
No data available.
SECTION 7: Handling and storage
7.1
Precautions for safe handling
Advice on safe handling
Observe the usual precautions for handling chemicals. Provide good ventilation of working area (local exhaust ventilation, if necessary).
General protective and hygiene measures
Observe the usual precautions when handling chemicals. Keep away from foodstuffs and beverages. Do not eat, drink or smoke during work time. Clean skin thoroughly after work; apply skin cream.
7.2
Conditions for safe storage, including any incompatibilities
Technical measures and storage conditions
Keep container tightly closed and dry in a cool, well-ventilated place.
Requirements for storage rooms and vessels
Containers which are opened must be carefully closed and kept upright to prevent leakage. Always keep in containers of same material as the original one.
Advice on storage assembly
None known
7.3
Specific end use(s)
No data available.
SECTION 8: Exposure controls/personal protection
8.1
Control parameters
Occupational exposure limit values
No
Substance name
CAS no.
EC no.
1
titanium-dioxide
13463-67-7
236-675-5
List of approved workplace exposure limits (WELs) / EH40
Titanium dioxide
total inhalable dust
TWA
10
mg/m³
List of approved workplace exposure limits (WELs) / EH40
Titanium dioxide
respirable dust
TWA
4
mg/m³
true
8.2
Exposure controls
Appropriate engineering controls
No data available.
Personal protective equipment
Respiratory protection
If workplace exposure limits are exceeded, a respiration protection approved for this particular job must be worn. In case of dust, aerosol and mist formation, take appropriate measures for breathing protection in the event workplace threshold values are not specified.
Page 3(9)
Page 59
EC safety data sheet
Trade name: Oil Pastels
Product no.: PHN-50 green
Replaced version: 1.0.0, issued: 12.06.2012
Region: GB
Eye / face protection
Safety glasses (EN 166)
Hand protection
Sufficient protection is given wearing suitable protective gloves checked according to i.e. EN 374, in the event of risk of skin contact with the product . Before use, the protective gloves should be tested in any case for its specific work­station suitability (i.e. mechanical resistance, product compatibility and antistatic properties). Adhere to the manufacturer’s instructions and information relating to the use, storage, care and replacement of protective gloves. Protective gloves shall be replaced immediately when physically damaged or worn. Design operations thus to avoid permanent use of protective gloves.
Other
Normal chemical work clothing.
Environmental exposure controls
No data available.
SECTION 9: Physical and chemical properties
9.1
Information on basic physical and chemical properties
Form/Colour
liquid
according product name
270
U_9005
Odour
alkohol-like
180
Odour threshold
No data available
pH value
No data available
Boiling point / boiling range
No data available
Melting point / melting range
Value
69.82
°C
Method
ASTM D 3418
69.82
Page 4(9)
Page 60
EC safety data sheet
Trade name: Oil Pastels
Product no.: PHN-50 green
Replaced version: 1.0.0, issued: 12.06.2012
Region: GB
Decomposition point / decomposition range
No data available
Flash point
No data available
Auto-ignition temperature
No data available
Oxidising properties
No data available
Explosive properties
No data available
Flammability (solid, gas)
No data available
Lower flammability or explosive limits
No data available
Upper flammability or explosive limits
No data available
Vapour pressure
No data available
Vapour density
No data available
Evaporation rate
No data available
Relative density
No data available
Density
No data available
Solubility in water
No data available
Solubility(ies)
No data available
Partition coefficient: n-octanol/water
No data available
Viscosity
No data available
9.2
Other information
Other information
No data available.
SECTION 10: Stability and reactivity
10.1
Reactivity
No data available.
10.2
Chemical stability
No data available.
10.3
Possibility of hazardous reactions
No data available.
10.4
Conditions to avoid
Stable under recommended storage and handling conditions(See section 7).
Page 5(9)
Page 61
EC safety data sheet
Trade name: Oil Pastels
Product no.: PHN-50 green
Replaced version: 1.0.0, issued: 12.06.2012
Region: GB
10.5
Incompatible materials
None known.
10.6
Hazardous decomposition products
No hazardous decomposition products known.
SECTION 11: Toxicological information
11.1
Information on toxicological effects
Acute oral toxicity
No
Product Name
1
Oil Pastels
Remarks
No data available.
Acute dermal toxicity
No
Product Name
1
Oil Pastels
Remarks
No data available.
Acute inhalational toxicity
No
Product Name
1
Oil Pastels
Remarks
No data available.
Lk.7000882
Skin corrosion/irritation
No
Product Name
1
Oil Pastels
Remarks
No data available.
Serious eye damage/irritation
No
Product Name
1
Oil Pastels
Remarks
No data available.
Respiratory tract irritation
Remarks
No data available.
Respiratory or skin sensitisation
No data available
Germ cell mutagenicity
No data available
Reproduction toxicity
No data available
Carcinogenicity
No data available
STOT-single exposure
No data available
STOT-repeated exposure
No data available
Aspiration hazard
No data available
Page 6(9)
Page 62
EC safety data sheet
Trade name: Oil Pastels
Product no.: PHN-50 green
Replaced version: 1.0.0, issued: 12.06.2012
Region: GB
SECTION 12: Ecological information
12.1
Toxicity
Toxicity to fish (acute)
No
Product Name
1
Oil Pastels
Remarks
No data available.
Lk.2098
Toxicity to fish (chronic)
No data available
Toxicity to Daphnia (acute)
No
Product Name
1
Oil Pastels
Remarks
No data available.
Lk.2098
Toxicity to Daphnia (chronic)
No data available
Toxicity to algae (acute)
No
Product Name
1
Oil Pastels
Remarks
No data available.
Lk.2098
Toxicity to algae (chronic)
No data available
Bacteria toxicity
No
Product Name
1
Oil Pastels
Remarks
No data available.
Lk.2099
12.2
Persistence and degradability
Biodegradability
No
Product Name
1
Oil Pastels
Remarks
No data available.
Lk.2100
12.3
Bioaccumulative potential
No data available.
12.4
Mobility in soil
No data available.
12.5
Results of PBT and vPvB assessment
No data available.
12.6
Other adverse effects
No data available.
12.7
Other information
Other information
Do not discharge product unmonitored into the environment.
710
SECTION 13: Disposal considerations
13.1
Waste treatment methods
Product
Allocation of a waste code number, according to the European Waste Catalogue, should be carried out in agreement with the regional waste disposal company.
Page 7(9)
Page 63
EC safety data sheet
Trade name: Oil Pastels
Product no.: PHN-50 green
Replaced version: 1.0.0, issued: 12.06.2012
Region: GB
Packaging
Residuals must be removed from packaging and when emptied completely disposed of in accordance with the regulations for waste removal. Incompletely emptied packaging must be disposed of in the form of disposal specified by the regional disposer.
SECTION 14: Transport information
14.1
Transport ADR/RID/ADN
The product is not subject to ADR/RID/ADN regulations.
14.2
Transport IMDG
The product is not subject to IMDG regulations.
14.3
Transport ICAO-TI / IATA
The product is not subject to ICAO-TI / IATA regulations.
14.4
Other information
No data available.
14.5
Environmental hazards
Information on environmental hazards, if relevant, please see 14.1 - 14.3.
14.6
Special precautions for user
No data available.
14.7
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not relevant
SECTION 15: Regulatory information
15.1
Safety, health and environmental regulations/legislation specific for the substance or mixture
EU regulations
Regulation (EC) No 1907/2006 (REACH) Annex XIV (List of substances subject to authorisation)
According to the data available and/or specifications supplied by upstream suppliers, this product does not contain any substances considered as substances requiring authorisation as listed on Annex XIV of the REACH regulation (EC) 1907/2006.
REACH candidate list of substances of very high concern (SVHC) for authorisation
According to available data and the information provided by preliminary suppliers, the product does not contain substances that are considered substances meeting the criteria for inclusion in annex XIV (List of Substances Subject to Authorisation) as laid down in Article 57 and article 59 of REACH (EC) 1907/2006.
Regulation (EC) No 1907/2006 (REACH) Annex XVII: RESTRICTIONS ON THE MANUFACTURE, PLACING ON THE MARKET AND USE OF CERTAIN DANGEROUS SUBSTANCES, PREPARATIONS AND ARTICLES
According to the data available and/or specifications supplied by upstream suppliers, this product does not contain any substances requiring authorisation as listed on Annex XIV of the REACH regulation (EC) 1907/2006.
Council Directive 96/82/EC on the control of major-accident hazards involving dangerous substances
Remarks
Annex I, part 1 + 2: not mentioned. With regard to possibly appropriate decomposition products see Chapter 10.
15.2
Chemical safety assessment
No data available.
SECTION 16: Other information
Department issuing safety data sheet
UMCO Umwelt Consult GmbH
Georg-Wilhelm-Str. 183 , 21107 Hamburg, Germany
Tel.: +49 40 / 79 02 36 300 Fax: +49 40 / 79 02 36 357 e-mail: umco@umco.de
Page 8(9)
Page 64
EC safety data sheet
Trade name: Oil Pastels
Product no.: PHN-50 green
Replaced version: 1.0.0, issued: 12.06.2012
Region: GB
This information is based on our present state of knowledge and experience. The security data sheet describes products with a view to the security requirements. However, it should not constitute a guarantee for any specific product properties and shall not establish a legally valid relationship.
Alterations/supplements: Alterations to the previous edition are marked in the left-hand margin.
.
Page 9(9)
Page 65
EC safety data sheet
Trade name: Oil Pastels
Product no.: PHN-50 cobalt blue
Replaced version: 1.0.0, issued: 12.06.2012
Region: GB
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1
Product identifier
Trade name
Oil Pastels
1.2
Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses of the substance or mixture
art supplies
pastel colour
Uses advised against
No data available.
1.3
Details of the supplier of the safety data sheet
Address
Pentel Bürobedarf-Handelsgesellschaft mbH
Lademannbogen 143
22339
Hamburg
GERMANY
Telephone no.
+49 (0) 40 / 53 80 91 - 0
Fax no.
+49 (0) 40 / 53 85 58 - 7
Information provided by / telephone
+49 (0) 40 / 53 80 91 - 0
Advice on Safety Data Sheet
sdb_info@umco.de
1.4
Emergency telephone number
For medical advice (in German and English): +49 (0)551 192 40 (Giftinformationszentrum Nord)
SECTION 2: Hazards identification
2.1
Classification of the substance or mixture
Classification information
This product does not meet the classification and labelling criteria given in the Regulation (EC) No 1272/2008 (CLP).
This product does not meet the classification and labelling criteria given in the Dangerous Preparations Directive (1999/45/EC; DPD)
2.2
Label elements
Not relevant
Labelling information
The data subject of this Material Safety Data sheet refer to the paint contained in this product.
2.3
Other hazards
No data available.
Page 1(9)
Page 66
EC safety data sheet
Trade name: Oil Pastels
Product no.: PHN-50 cobalt blue
Replaced version: 1.0.0, issued: 12.06.2012
Region: GB
SECTION 3: Composition/information on ingredients
3.1
Substances
Not applicable. The product is not a substance.
3.2
Mixtures
Hazardous ingredients
No
Substance name
Additional information
CAS / EC / Index / REACH no
Classification 67/548/EEC
Classification (EC) 1272/2008 (CLP)
Concentration
%
1
titanium-dioxide
13463-67-7 236-675-5
-
-
- - >
5.00
- < 10.00
%-b.w.
Full Text for all R-phrases , H-phrases and EUH-phrases: pls. see section 16
SECTION 4: First aid measures
4.1
Description of first aid measures
General information
In case of persisting adverse effects, consult a physician.
After inhalation
Ensure supply of fresh air.
After skin contact
When in contact with the skin, clean with soap and water. Do NOT use solvents or thinners.
After eye contact
Separate eyelids, wash the eyes thoroughly with water (15 min.).
After ingestion
Call a doctor. Never give anything by mouth to an unconscious person. Do not induce vomiting.
4.2
Most important symptoms and effects, both acute and delayed
No data available.
4.3
Indication of any immediate medical attention and special treatment needed
No data available.
SECTION 5: Firefighting measures
5.1
Extinguishing media
Suitable extinguishing media
Product itself is non-combustible; adapt fire extinguishing measures to surrounding areas.
Unsuitable extinguishing media
No data available.
5.2
Special hazards arising from the substance or mixture
In the event of fire, the following can be released: Carbon dioxide (CO2); Carbon monoxide (CO)
5.3
Advice for firefighters
Use self-contained breathing apparatus. Wear protective clothing.
SECTION 6: Accidental release measures
6.1
Personal precautions, protective equipment and emergency procedures
For non-emergency personnel
Refer to protective measures listed in sections 7 and 8. Ensure adequate ventilation.
Page 2(9)
Page 67
EC safety data sheet
Trade name: Oil Pastels
Product no.: PHN-50 cobalt blue
Replaced version: 1.0.0, issued: 12.06.2012
Region: GB
For emergency responders
No data available. Personal protective equipment (PPE) - see Section 8.
6.2
Environmental precautions
Do not discharge into the drains/surface waters/groundwater.
6.3
Methods and material for containment and cleaning up
Take up mechanically. Send in suitable containers for recovery or disposal.
6.4
Reference to other sections
No data available.
SECTION 7: Handling and storage
7.1
Precautions for safe handling
Advice on safe handling
Observe the usual precautions for handling chemicals. Provide good ventilation of working area (local exhaust ventilation, if necessary).
General protective and hygiene measures
Observe the usual precautions when handling chemicals. Keep away from foodstuffs and beverages. Do not eat, drink or smoke during work time. Clean skin thoroughly after work; apply skin cream.
7.2
Conditions for safe storage, including any incompatibilities
Technical measures and storage conditions
Keep container tightly closed and dry in a cool, well-ventilated place.
Requirements for storage rooms and vessels
Containers which are opened must be carefully closed and kept upright to prevent leakage. Always keep in containers of same material as the original one.
Advice on storage assembly
None known
7.3
Specific end use(s)
No data available.
SECTION 8: Exposure controls/personal protection
8.1
Control parameters
Occupational exposure limit values
No
Substance name
CAS no.
EC no.
1
titanium-dioxide
13463-67-7
236-675-5
List of approved workplace exposure limits (WELs) / EH40
Titanium dioxide
total inhalable dust
TWA
10
mg/m³
List of approved workplace exposure limits (WELs) / EH40
Titanium dioxide
respirable dust
TWA
4
mg/m³
true
8.2
Exposure controls
Appropriate engineering controls
No data available.
Personal protective equipment
Respiratory protection
If workplace exposure limits are exceeded, a respiration protection approved for this particular job must be worn. In case of dust, aerosol and mist formation, take appropriate measures for breathing protection in the event workplace threshold values are not specified.
Page 3(9)
Page 68
EC safety data sheet
Trade name: Oil Pastels
Product no.: PHN-50 cobalt blue
Replaced version: 1.0.0, issued: 12.06.2012
Region: GB
Eye / face protection
Safety glasses (EN 166)
Hand protection
Sufficient protection is given wearing suitable protective gloves checked according to i.e. EN 374, in the event of risk of skin contact with the product . Before use, the protective gloves should be tested in any case for its specific work­station suitability (i.e. mechanical resistance, product compatibility and antistatic properties). Adhere to the manufacturer’s instructions and information relating to the use, storage, care and replacement of protective gloves. Protective gloves shall be replaced immediately when physically damaged or worn. Design operations thus to avoid permanent use of protective gloves.
Other
Normal chemical work clothing.
Environmental exposure controls
No data available.
SECTION 9: Physical and chemical properties
9.1
Information on basic physical and chemical properties
Form/Colour
liquid
according product name
270
U_9005
Odour
alkohol-like
180
Odour threshold
No data available
pH value
No data available
Boiling point / boiling range
No data available
Melting point / melting range
Value
69.82
°C
Method
ASTM D 3418
69.82
Page 4(9)
Page 69
EC safety data sheet
Trade name: Oil Pastels
Product no.: PHN-50 cobalt blue
Replaced version: 1.0.0, issued: 12.06.2012
Region: GB
Decomposition point / decomposition range
No data available
Flash point
No data available
Auto-ignition temperature
No data available
Oxidising properties
No data available
Explosive properties
No data available
Flammability (solid, gas)
No data available
Lower flammability or explosive limits
No data available
Upper flammability or explosive limits
No data available
Vapour pressure
No data available
Vapour density
No data available
Evaporation rate
No data available
Relative density
No data available
Density
No data available
Solubility in water
No data available
Solubility(ies)
No data available
Partition coefficient: n-octanol/water
No data available
Viscosity
No data available
9.2
Other information
Other information
No data available.
SECTION 10: Stability and reactivity
10.1
Reactivity
No data available.
10.2
Chemical stability
No data available.
10.3
Possibility of hazardous reactions
No data available.
10.4
Conditions to avoid
Stable under recommended storage and handling conditions(See section 7).
Page 5(9)
Page 70
EC safety data sheet
Trade name: Oil Pastels
Product no.: PHN-50 cobalt blue
Replaced version: 1.0.0, issued: 12.06.2012
Region: GB
10.5
Incompatible materials
None known.
10.6
Hazardous decomposition products
No hazardous decomposition products known.
SECTION 11: Toxicological information
11.1
Information on toxicological effects
Acute oral toxicity
No
Product Name
1
Oil Pastels
Remarks
No data available.
Acute dermal toxicity
No
Product Name
1
Oil Pastels
Remarks
No data available.
Acute inhalational toxicity
No
Product Name
1
Oil Pastels
Remarks
No data available.
Lk.7000882
Skin corrosion/irritation
No
Product Name
1
Oil Pastels
Remarks
No data available.
Serious eye damage/irritation
No
Product Name
1
Oil Pastels
Remarks
No data available.
Respiratory tract irritation
Remarks
No data available.
Respiratory or skin sensitisation
No data available
Germ cell mutagenicity
No data available
Reproduction toxicity
No data available
Carcinogenicity
No data available
STOT-single exposure
No data available
STOT-repeated exposure
No data available
Aspiration hazard
No data available
Page 6(9)
Page 71
EC safety data sheet
Trade name: Oil Pastels
Product no.: PHN-50 cobalt blue
Replaced version: 1.0.0, issued: 12.06.2012
Region: GB
SECTION 12: Ecological information
12.1
Toxicity
Toxicity to fish (acute)
No
Product Name
1
Oil Pastels
Remarks
No data available.
Lk.2098
Toxicity to fish (chronic)
No data available
Toxicity to Daphnia (acute)
No
Product Name
1
Oil Pastels
Remarks
No data available.
Lk.2098
Toxicity to Daphnia (chronic)
No data available
Toxicity to algae (acute)
No
Product Name
1
Oil Pastels
Remarks
No data available.
Lk.2098
Toxicity to algae (chronic)
No data available
Bacteria toxicity
No
Product Name
1
Oil Pastels
Remarks
No data available.
Lk.2099
12.2
Persistence and degradability
Biodegradability
No
Product Name
1
Oil Pastels
Remarks
No data available.
Lk.2100
12.3
Bioaccumulative potential
No data available.
12.4
Mobility in soil
No data available.
12.5
Results of PBT and vPvB assessment
No data available.
12.6
Other adverse effects
No data available.
12.7
Other information
Other information
Do not discharge product unmonitored into the environment.
710
SECTION 13: Disposal considerations
13.1
Waste treatment methods
Product
Allocation of a waste code number, according to the European Waste Catalogue, should be carried out in agreement with the regional waste disposal company.
Page 7(9)
Page 72
EC safety data sheet
Trade name: Oil Pastels
Product no.: PHN-50 cobalt blue
Replaced version: 1.0.0, issued: 12.06.2012
Region: GB
Packaging
Residuals must be removed from packaging and when emptied completely disposed of in accordance with the regulations for waste removal. Incompletely emptied packaging must be disposed of in the form of disposal specified by the regional disposer.
SECTION 14: Transport information
14.1
Transport ADR/RID/ADN
The product is not subject to ADR/RID/ADN regulations.
14.2
Transport IMDG
The product is not subject to IMDG regulations.
14.3
Transport ICAO-TI / IATA
The product is not subject to ICAO-TI / IATA regulations.
14.4
Other information
No data available.
14.5
Environmental hazards
Information on environmental hazards, if relevant, please see 14.1 - 14.3.
14.6
Special precautions for user
No data available.
14.7
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not relevant
SECTION 15: Regulatory information
15.1
Safety, health and environmental regulations/legislation specific for the substance or mixture
EU regulations
Regulation (EC) No 1907/2006 (REACH) Annex XIV (List of substances subject to authorisation)
According to the data available and/or specifications supplied by upstream suppliers, this product does not contain any substances considered as substances requiring authorisation as listed on Annex XIV of the REACH regulation (EC) 1907/2006.
REACH candidate list of substances of very high concern (SVHC) for authorisation
According to available data and the information provided by preliminary suppliers, the product does not contain substances that are considered substances meeting the criteria for inclusion in annex XIV (List of Substances Subject to Authorisation) as laid down in Article 57 and article 59 of REACH (EC) 1907/2006.
Regulation (EC) No 1907/2006 (REACH) Annex XVII: RESTRICTIONS ON THE MANUFACTURE, PLACING ON THE MARKET AND USE OF CERTAIN DANGEROUS SUBSTANCES, PREPARATIONS AND ARTICLES
According to the data available and/or specifications supplied by upstream suppliers, this product does not contain any substances requiring authorisation as listed on Annex XIV of the REACH regulation (EC) 1907/2006.
Council Directive 96/82/EC on the control of major-accident hazards involving dangerous substances
Remarks
Annex I, part 1 + 2: not mentioned. With regard to possibly appropriate decomposition products see Chapter 10.
15.2
Chemical safety assessment
No data available.
SECTION 16: Other information
Department issuing safety data sheet
UMCO Umwelt Consult GmbH
Georg-Wilhelm-Str. 183 , 21107 Hamburg, Germany
Tel.: +49 40 / 79 02 36 300 Fax: +49 40 / 79 02 36 357 e-mail: umco@umco.de
Page 8(9)
Page 73
EC safety data sheet
Trade name: Oil Pastels
Product no.: PHN-50 cobalt blue
Replaced version: 1.0.0, issued: 12.06.2012
Region: GB
This information is based on our present state of knowledge and experience. The security data sheet describes products with a view to the security requirements. However, it should not constitute a guarantee for any specific product properties and shall not establish a legally valid relationship.
Alterations/supplements: Alterations to the previous edition are marked in the left-hand margin.
.
Page 9(9)
Page 74
EC safety data sheet
Trade name: Oil Pastels
Product no.: PHN-50 gray
Replaced version: 1.0.0, issued: 12.06.2012
Region: GB
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1
Product identifier
Trade name
Oil Pastels
1.2
Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses of the substance or mixture
art supplies
pastel colour
Uses advised against
No data available.
1.3
Details of the supplier of the safety data sheet
Address
Pentel Bürobedarf-Handelsgesellschaft mbH
Lademannbogen 143
22339
Hamburg
GERMANY
Telephone no.
+49 (0) 40 / 53 80 91 - 0
Fax no.
+49 (0) 40 / 53 85 58 - 7
Information provided by / telephone
+49 (0) 40 / 53 80 91 - 0
Advice on Safety Data Sheet
sdb_info@umco.de
1.4
Emergency telephone number
For medical advice (in German and English): +49 (0)551 192 40 (Giftinformationszentrum Nord)
SECTION 2: Hazards identification
2.1
Classification of the substance or mixture
Classification information
This product does not meet the classification and labelling criteria given in the Regulation (EC) No 1272/2008 (CLP).
This product does not meet the classification and labelling criteria given in the Dangerous Preparations Directive (1999/45/EC; DPD)
2.2
Label elements
Not relevant
Labelling information
The data subject of this Material Safety Data sheet refer to the paint contained in this product.
2.3
Other hazards
No data available.
Page 1(9)
Page 75
EC safety data sheet
Trade name: Oil Pastels
Product no.: PHN-50 gray
Replaced version: 1.0.0, issued: 12.06.2012
Region: GB
SECTION 3: Composition/information on ingredients
3.1
Substances
Not applicable. The product is not a substance.
3.2
Mixtures
Hazardous ingredients
No
Substance name
Additional information
CAS / EC / Index / REACH no
Classification 67/548/EEC
Classification (EC) 1272/2008 (CLP)
Concentration
%
1
titanium-dioxide
13463-67-7 236-675-5
-
-
- - >
1.00
- < 5.00
%-b.w.
Full Text for all R-phrases , H-phrases and EUH-phrases: pls. see section 16
SECTION 4: First aid measures
4.1
Description of first aid measures
General information
In case of persisting adverse effects, consult a physician.
After inhalation
Ensure supply of fresh air.
After skin contact
When in contact with the skin, clean with soap and water. Do NOT use solvents or thinners.
After eye contact
Separate eyelids, wash the eyes thoroughly with water (15 min.).
After ingestion
Call a doctor. Never give anything by mouth to an unconscious person. Do not induce vomiting.
4.2
Most important symptoms and effects, both acute and delayed
No data available.
4.3
Indication of any immediate medical attention and special treatment needed
No data available.
SECTION 5: Firefighting measures
5.1
Extinguishing media
Suitable extinguishing media
Product itself is non-combustible; adapt fire extinguishing measures to surrounding areas.
Unsuitable extinguishing media
No data available.
5.2
Special hazards arising from the substance or mixture
In the event of fire, the following can be released: Carbon dioxide (CO2); Carbon monoxide (CO)
5.3
Advice for firefighters
Use self-contained breathing apparatus. Wear protective clothing.
SECTION 6: Accidental release measures
6.1
Personal precautions, protective equipment and emergency procedures
For non-emergency personnel
Refer to protective measures listed in sections 7 and 8. Ensure adequate ventilation.
Page 2(9)
Page 76
EC safety data sheet
Trade name: Oil Pastels
Product no.: PHN-50 gray
Replaced version: 1.0.0, issued: 12.06.2012
Region: GB
For emergency responders
No data available. Personal protective equipment (PPE) - see Section 8.
6.2
Environmental precautions
Do not discharge into the drains/surface waters/groundwater.
6.3
Methods and material for containment and cleaning up
Take up mechanically. Send in suitable containers for recovery or disposal.
6.4
Reference to other sections
No data available.
SECTION 7: Handling and storage
7.1
Precautions for safe handling
Advice on safe handling
Observe the usual precautions for handling chemicals. Provide good ventilation of working area (local exhaust ventilation, if necessary).
General protective and hygiene measures
Observe the usual precautions when handling chemicals. Keep away from foodstuffs and beverages. Do not eat, drink or smoke during work time. Clean skin thoroughly after work; apply skin cream.
7.2
Conditions for safe storage, including any incompatibilities
Technical measures and storage conditions
Keep container tightly closed and dry in a cool, well-ventilated place.
Requirements for storage rooms and vessels
Containers which are opened must be carefully closed and kept upright to prevent leakage. Always keep in containers of same material as the original one.
Advice on storage assembly
None known
7.3
Specific end use(s)
No data available.
SECTION 8: Exposure controls/personal protection
8.1
Control parameters
Occupational exposure limit values
No
Substance name
CAS no.
EC no.
1
titanium-dioxide
13463-67-7
236-675-5
List of approved workplace exposure limits (WELs) / EH40
Titanium dioxide
total inhalable dust
TWA
10
mg/m³
List of approved workplace exposure limits (WELs) / EH40
Titanium dioxide
respirable dust
TWA
4
mg/m³
true
8.2
Exposure controls
Appropriate engineering controls
No data available.
Personal protective equipment
Respiratory protection
If workplace exposure limits are exceeded, a respiration protection approved for this particular job must be worn. In case of dust, aerosol and mist formation, take appropriate measures for breathing protection in the event workplace threshold values are not specified.
Page 3(9)
Page 77
EC safety data sheet
Trade name: Oil Pastels
Product no.: PHN-50 gray
Replaced version: 1.0.0, issued: 12.06.2012
Region: GB
Eye / face protection
Safety glasses (EN 166)
Hand protection
Sufficient protection is given wearing suitable protective gloves checked according to i.e. EN 374, in the event of risk of skin contact with the product . Before use, the protective gloves should be tested in any case for its specific work­station suitability (i.e. mechanical resistance, product compatibility and antistatic properties). Adhere to the manufacturer’s instructions and information relating to the use, storage, care and replacement of protective gloves. Protective gloves shall be replaced immediately when physically damaged or worn. Design operations thus to avoid permanent use of protective gloves.
Other
Normal chemical work clothing.
Environmental exposure controls
No data available.
SECTION 9: Physical and chemical properties
9.1
Information on basic physical and chemical properties
Form/Colour
liquid
according product name
270
U_9005
Odour
alkohol-like
180
Odour threshold
No data available
pH value
No data available
Boiling point / boiling range
No data available
Melting point / melting range
Value
69.82
°C
Method
ASTM D 3418
69.82
Page 4(9)
Page 78
EC safety data sheet
Trade name: Oil Pastels
Product no.: PHN-50 gray
Replaced version: 1.0.0, issued: 12.06.2012
Region: GB
Decomposition point / decomposition range
No data available
Flash point
No data available
Auto-ignition temperature
No data available
Oxidising properties
No data available
Explosive properties
No data available
Flammability (solid, gas)
No data available
Lower flammability or explosive limits
No data available
Upper flammability or explosive limits
No data available
Vapour pressure
No data available
Vapour density
No data available
Evaporation rate
No data available
Relative density
No data available
Density
No data available
Solubility in water
No data available
Solubility(ies)
No data available
Partition coefficient: n-octanol/water
No data available
Viscosity
No data available
9.2
Other information
Other information
No data available.
SECTION 10: Stability and reactivity
10.1
Reactivity
No data available.
10.2
Chemical stability
No data available.
10.3
Possibility of hazardous reactions
No data available.
10.4
Conditions to avoid
Stable under recommended storage and handling conditions(See section 7).
Page 5(9)
Page 79
EC safety data sheet
Trade name: Oil Pastels
Product no.: PHN-50 gray
Replaced version: 1.0.0, issued: 12.06.2012
Region: GB
10.5
Incompatible materials
None known.
10.6
Hazardous decomposition products
No hazardous decomposition products known.
SECTION 11: Toxicological information
11.1
Information on toxicological effects
Acute oral toxicity
No
Product Name
1
Oil Pastels
Remarks
No data available.
Acute dermal toxicity
No
Product Name
1
Oil Pastels
Remarks
No data available.
Acute inhalational toxicity
No
Product Name
1
Oil Pastels
Remarks
No data available.
Lk.7000882
Skin corrosion/irritation
No
Product Name
1
Oil Pastels
Remarks
No data available.
Serious eye damage/irritation
No
Product Name
1
Oil Pastels
Remarks
No data available.
Respiratory tract irritation
Remarks
No data available.
Respiratory or skin sensitisation
No data available
Germ cell mutagenicity
No data available
Reproduction toxicity
No data available
Carcinogenicity
No data available
STOT-single exposure
No data available
STOT-repeated exposure
No data available
Aspiration hazard
No data available
Page 6(9)
Page 80
EC safety data sheet
Trade name: Oil Pastels
Product no.: PHN-50 gray
Replaced version: 1.0.0, issued: 12.06.2012
Region: GB
SECTION 12: Ecological information
12.1
Toxicity
Toxicity to fish (acute)
No
Product Name
1
Oil Pastels
Remarks
No data available.
Lk.2098
Toxicity to fish (chronic)
No data available
Toxicity to Daphnia (acute)
No
Product Name
1
Oil Pastels
Remarks
No data available.
Lk.2098
Toxicity to Daphnia (chronic)
No data available
Toxicity to algae (acute)
No
Product Name
1
Oil Pastels
Remarks
No data available.
Lk.2098
Toxicity to algae (chronic)
No data available
Bacteria toxicity
No
Product Name
1
Oil Pastels
Remarks
No data available.
Lk.2099
12.2
Persistence and degradability
Biodegradability
No
Product Name
1
Oil Pastels
Remarks
No data available.
Lk.2100
12.3
Bioaccumulative potential
No data available.
12.4
Mobility in soil
No data available.
12.5
Results of PBT and vPvB assessment
No data available.
12.6
Other adverse effects
No data available.
12.7
Other information
Other information
Do not discharge product unmonitored into the environment.
710
SECTION 13: Disposal considerations
13.1
Waste treatment methods
Product
Allocation of a waste code number, according to the European Waste Catalogue, should be carried out in agreement with the regional waste disposal company.
Page 7(9)
Page 81
EC safety data sheet
Trade name: Oil Pastels
Product no.: PHN-50 gray
Replaced version: 1.0.0, issued: 12.06.2012
Region: GB
Packaging
Residuals must be removed from packaging and when emptied completely disposed of in accordance with the regulations for waste removal. Incompletely emptied packaging must be disposed of in the form of disposal specified by the regional disposer.
SECTION 14: Transport information
14.1
Transport ADR/RID/ADN
The product is not subject to ADR/RID/ADN regulations.
14.2
Transport IMDG
The product is not subject to IMDG regulations.
14.3
Transport ICAO-TI / IATA
The product is not subject to ICAO-TI / IATA regulations.
14.4
Other information
No data available.
14.5
Environmental hazards
Information on environmental hazards, if relevant, please see 14.1 - 14.3.
14.6
Special precautions for user
No data available.
14.7
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not relevant
SECTION 15: Regulatory information
15.1
Safety, health and environmental regulations/legislation specific for the substance or mixture
EU regulations
Regulation (EC) No 1907/2006 (REACH) Annex XIV (List of substances subject to authorisation)
According to the data available and/or specifications supplied by upstream suppliers, this product does not contain any substances considered as substances requiring authorisation as listed on Annex XIV of the REACH regulation (EC) 1907/2006.
REACH candidate list of substances of very high concern (SVHC) for authorisation
According to available data and the information provided by preliminary suppliers, the product does not contain substances that are considered substances meeting the criteria for inclusion in annex XIV (List of Substances Subject to Authorisation) as laid down in Article 57 and article 59 of REACH (EC) 1907/2006.
Regulation (EC) No 1907/2006 (REACH) Annex XVII: RESTRICTIONS ON THE MANUFACTURE, PLACING ON THE MARKET AND USE OF CERTAIN DANGEROUS SUBSTANCES, PREPARATIONS AND ARTICLES
According to the data available and/or specifications supplied by upstream suppliers, this product does not contain any substances requiring authorisation as listed on Annex XIV of the REACH regulation (EC) 1907/2006.
Council Directive 96/82/EC on the control of major-accident hazards involving dangerous substances
Remarks
Annex I, part 1 + 2: not mentioned. With regard to possibly appropriate decomposition products see Chapter 10.
15.2
Chemical safety assessment
No data available.
SECTION 16: Other information
Department issuing safety data sheet
UMCO Umwelt Consult GmbH
Georg-Wilhelm-Str. 183 , 21107 Hamburg, Germany
Tel.: +49 40 / 79 02 36 300 Fax: +49 40 / 79 02 36 357 e-mail: umco@umco.de
Page 8(9)
Page 82
EC safety data sheet
Trade name: Oil Pastels
Product no.: PHN-50 gray
Replaced version: 1.0.0, issued: 12.06.2012
Region: GB
This information is based on our present state of knowledge and experience. The security data sheet describes products with a view to the security requirements. However, it should not constitute a guarantee for any specific product properties and shall not establish a legally valid relationship.
Alterations/supplements: Alterations to the previous edition are marked in the left-hand margin.
.
Page 9(9)
Page 83
EC safety data sheet
Trade name: Oil Pastels
Product no.: PHN-50 black
Replaced version: 1.0.0, issued: 12.06.2012
Region: GB
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1
Product identifier
Trade name
Oil Pastels
1.2
Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses of the substance or mixture
art supplies
pastel colour
Uses advised against
No data available.
1.3
Details of the supplier of the safety data sheet
Address
Pentel Bürobedarf-Handelsgesellschaft mbH
Lademannbogen 143
22339
Hamburg
GERMANY
Telephone no.
+49 (0) 40 / 53 80 91 - 0
Fax no.
+49 (0) 40 / 53 85 58 - 7
Information provided by / telephone
+49 (0) 40 / 53 80 91 - 0
Advice on Safety Data Sheet
sdb_info@umco.de
1.4
Emergency telephone number
For medical advice (in German and English): +49 (0)551 192 40 (Giftinformationszentrum Nord)
SECTION 2: Hazards identification
2.1
Classification of the substance or mixture
Classification information
This product does not meet the classification and labelling criteria given in the Regulation (EC) No 1272/2008 (CLP).
This product does not meet the classification and labelling criteria given in the Dangerous Preparations Directive (1999/45/EC; DPD)
2.2
Label elements
Not relevant
Labelling information
The data subject of this Material Safety Data sheet refer to the paint contained in this product.
2.3
Other hazards
No data available.
Page 1(9)
Page 84
EC safety data sheet
Trade name: Oil Pastels
Product no.: PHN-50 black
Replaced version: 1.0.0, issued: 12.06.2012
Region: GB
SECTION 3: Composition/information on ingredients
3.1
Substances
Not applicable. The product is not a substance.
3.2
Mixtures
Hazardous ingredients
No
Substance name
Additional information
CAS / EC / Index / REACH no
Classification 67/548/EEC
Classification (EC) 1272/2008 (CLP)
Concentration
%
1
CARBON BLACK
1333-86-4 215-609-9
-
-
- - >
1.00
- < 5.00
%-b.w.
2
titanium-dioxide
13463-67-7 236-675-5
-
-
- - >
1.00
- < 5.00
%-b.w.
Full Text for all R-phrases , H-phrases and EUH-phrases: pls. see section 16
SECTION 4: First aid measures
4.1
Description of first aid measures
General information
In case of persisting adverse effects, consult a physician.
After inhalation
Ensure supply of fresh air.
After skin contact
When in contact with the skin, clean with soap and water. Do NOT use solvents or thinners.
After eye contact
Separate eyelids, wash the eyes thoroughly with water (15 min.).
After ingestion
Call a doctor. Never give anything by mouth to an unconscious person. Do not induce vomiting.
4.2
Most important symptoms and effects, both acute and delayed
No data available.
4.3
Indication of any immediate medical attention and special treatment needed
No data available.
SECTION 5: Firefighting measures
5.1
Extinguishing media
Suitable extinguishing media
Product itself is non-combustible; adapt fire extinguishing measures to surrounding areas.
Unsuitable extinguishing media
No data available.
5.2
Special hazards arising from the substance or mixture
In the event of fire, the following can be released: Carbon dioxide (CO2); Carbon monoxide (CO)
5.3
Advice for firefighters
Use self-contained breathing apparatus. Wear protective clothing.
Page 2(9)
Page 85
EC safety data sheet
Trade name: Oil Pastels
Product no.: PHN-50 black
Replaced version: 1.0.0, issued: 12.06.2012
Region: GB
SECTION 6: Accidental release measures
6.1
Personal precautions, protective equipment and emergency procedures
For non-emergency personnel
Refer to protective measures listed in sections 7 and 8. Ensure adequate ventilation.
For emergency responders
No data available. Personal protective equipment (PPE) - see Section 8.
6.2
Environmental precautions
Do not discharge into the drains/surface waters/groundwater.
6.3
Methods and material for containment and cleaning up
Take up mechanically. Send in suitable containers for recovery or disposal.
6.4
Reference to other sections
No data available.
SECTION 7: Handling and storage
7.1
Precautions for safe handling
Advice on safe handling
Observe the usual precautions for handling chemicals. Provide good ventilation of working area (local exhaust ventilation, if necessary).
General protective and hygiene measures
Observe the usual precautions when handling chemicals. Keep away from foodstuffs and beverages. Do not eat, drink or smoke during work time. Clean skin thoroughly after work; apply skin cream.
7.2
Conditions for safe storage, including any incompatibilities
Technical measures and storage conditions
Keep container tightly closed and dry in a cool, well-ventilated place.
Requirements for storage rooms and vessels
Containers which are opened must be carefully closed and kept upright to prevent leakage. Always keep in containers of same material as the original one.
Advice on storage assembly
None known
7.3
Specific end use(s)
No data available.
SECTION 8: Exposure controls/personal protection
8.1
Control parameters
Occupational exposure limit values
No
Substance name
CAS no.
EC no.
1
CARBON BLACK
1333-86-4
215-609-9
List of approved workplace exposure limits (WELs) / EH40
Carbon black
STEL
7
mg/m³
TWA
3.5
mg/m³
2
titanium-dioxide
13463-67-7
236-675-5
List of approved workplace exposure limits (WELs) / EH40
Titanium dioxide
total inhalable dust
TWA
10
mg/m³
List of approved workplace exposure limits (WELs) / EH40
Titanium dioxide
respirable dust
TWA
4
mg/m³
true
Page 3(9)
Page 86
EC safety data sheet
Trade name: Oil Pastels
Product no.: PHN-50 black
Replaced version: 1.0.0, issued: 12.06.2012
Region: GB
8.2
Exposure controls
Appropriate engineering controls
No data available.
Personal protective equipment
Respiratory protection
If workplace exposure limits are exceeded, a respiration protection approved for this particular job must be worn. In case of dust, aerosol and mist formation, take appropriate measures for breathing protection in the event workplace threshold values are not specified.
Eye / face protection
Safety glasses (EN 166)
Hand protection
Sufficient protection is given wearing suitable protective gloves checked according to i.e. EN 374, in the event of risk of skin contact with the product . Before use, the protective gloves should be tested in any case for its specific work­station suitability (i.e. mechanical resistance, product compatibility and antistatic properties). Adhere to the manufacturer’s instructions and information relating to the use, storage, care and replacement of protective gloves. Protective gloves shall be replaced immediately when physically damaged or worn. Design operations thus to avoid permanent use of protective gloves.
Other
Normal chemical work clothing.
Environmental exposure controls
No data available.
SECTION 9: Physical and chemical properties
9.1
Information on basic physical and chemical properties
Form/Colour
liquid
according product name
270
U_9005
Odour
alkohol-like
180
Odour threshold
No data available
pH value
No data available
Boiling point / boiling range
No data available
Melting point / melting range
Value
69.82
°C
Method
ASTM D 3418
69.82
Page 4(9)
Page 87
EC safety data sheet
Trade name: Oil Pastels
Product no.: PHN-50 black
Replaced version: 1.0.0, issued: 12.06.2012
Region: GB
Decomposition point / decomposition range
No data available
Flash point
No data available
Auto-ignition temperature
No data available
Oxidising properties
No data available
Explosive properties
No data available
Flammability (solid, gas)
No data available
Lower flammability or explosive limits
No data available
Upper flammability or explosive limits
No data available
Vapour pressure
No data available
Vapour density
No data available
Evaporation rate
No data available
Relative density
No data available
Density
No data available
Solubility in water
No data available
Solubility(ies)
No data available
Partition coefficient: n-octanol/water
No data available
Viscosity
No data available
9.2
Other information
Other information
No data available.
SECTION 10: Stability and reactivity
10.1
Reactivity
No data available.
10.2
Chemical stability
No data available.
10.3
Possibility of hazardous reactions
No data available.
10.4
Conditions to avoid
Stable under recommended storage and handling conditions(See section 7).
Page 5(9)
Page 88
EC safety data sheet
Trade name: Oil Pastels
Product no.: PHN-50 black
Replaced version: 1.0.0, issued: 12.06.2012
Region: GB
10.5
Incompatible materials
None known.
10.6
Hazardous decomposition products
No hazardous decomposition products known.
SECTION 11: Toxicological information
11.1
Information on toxicological effects
Acute oral toxicity
No
Product Name
1
Oil Pastels
Remarks
No data available.
Acute dermal toxicity
No
Product Name
1
Oil Pastels
Remarks
No data available.
Acute inhalational toxicity
No
Product Name
1
Oil Pastels
Remarks
No data available.
Lk.7000882
Skin corrosion/irritation
No
Product Name
1
Oil Pastels
Remarks
No data available.
Serious eye damage/irritation
No
Product Name
1
Oil Pastels
Remarks
No data available.
Respiratory tract irritation
Remarks
No data available.
Respiratory or skin sensitisation
No data available
Germ cell mutagenicity
No data available
Reproduction toxicity
No data available
Carcinogenicity
No data available
STOT-single exposure
No data available
STOT-repeated exposure
No data available
Aspiration hazard
No data available
Page 6(9)
Page 89
EC safety data sheet
Trade name: Oil Pastels
Product no.: PHN-50 black
Replaced version: 1.0.0, issued: 12.06.2012
Region: GB
SECTION 12: Ecological information
12.1
Toxicity
Toxicity to fish (acute)
No
Product Name
1
Oil Pastels
Remarks
No data available.
Lk.2098
Toxicity to fish (chronic)
No data available
Toxicity to Daphnia (acute)
No
Product Name
1
Oil Pastels
Remarks
No data available.
Lk.2098
Toxicity to Daphnia (chronic)
No data available
Toxicity to algae (acute)
No
Product Name
1
Oil Pastels
Remarks
No data available.
Lk.2098
Toxicity to algae (chronic)
No data available
Bacteria toxicity
No
Product Name
1
Oil Pastels
Remarks
No data available.
Lk.2099
12.2
Persistence and degradability
Biodegradability
No
Product Name
1
Oil Pastels
Remarks
No data available.
Lk.2100
12.3
Bioaccumulative potential
No data available.
12.4
Mobility in soil
No data available.
12.5
Results of PBT and vPvB assessment
No data available.
12.6
Other adverse effects
No data available.
12.7
Other information
Other information
Do not discharge product unmonitored into the environment.
710
SECTION 13: Disposal considerations
13.1
Waste treatment methods
Product
Allocation of a waste code number, according to the European Waste Catalogue, should be carried out in agreement with the regional waste disposal company.
Page 7(9)
Page 90
EC safety data sheet
Trade name: Oil Pastels
Product no.: PHN-50 black
Replaced version: 1.0.0, issued: 12.06.2012
Region: GB
Packaging
Residuals must be removed from packaging and when emptied completely disposed of in accordance with the regulations for waste removal. Incompletely emptied packaging must be disposed of in the form of disposal specified by the regional disposer.
SECTION 14: Transport information
14.1
Transport ADR/RID/ADN
The product is not subject to ADR/RID/ADN regulations.
14.2
Transport IMDG
The product is not subject to IMDG regulations.
14.3
Transport ICAO-TI / IATA
The product is not subject to ICAO-TI / IATA regulations.
14.4
Other information
No data available.
14.5
Environmental hazards
Information on environmental hazards, if relevant, please see 14.1 - 14.3.
14.6
Special precautions for user
No data available.
14.7
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not relevant
SECTION 15: Regulatory information
15.1
Safety, health and environmental regulations/legislation specific for the substance or mixture
EU regulations
Regulation (EC) No 1907/2006 (REACH) Annex XIV (List of substances subject to authorisation)
According to the data available and/or specifications supplied by upstream suppliers, this product does not contain any substances considered as substances requiring authorisation as listed on Annex XIV of the REACH regulation (EC) 1907/2006.
REACH candidate list of substances of very high concern (SVHC) for authorisation
According to available data and the information provided by preliminary suppliers, the product does not contain substances that are considered substances meeting the criteria for inclusion in annex XIV (List of Substances Subject to Authorisation) as laid down in Article 57 and article 59 of REACH (EC) 1907/2006.
Regulation (EC) No 1907/2006 (REACH) Annex XVII: RESTRICTIONS ON THE MANUFACTURE, PLACING ON THE MARKET AND USE OF CERTAIN DANGEROUS SUBSTANCES, PREPARATIONS AND ARTICLES
According to the data available and/or specifications supplied by upstream suppliers, this product does not contain any substances requiring authorisation as listed on Annex XIV of the REACH regulation (EC) 1907/2006.
Council Directive 96/82/EC on the control of major-accident hazards involving dangerous substances
Remarks
Annex I, part 1 + 2: not mentioned. With regard to possibly appropriate decomposition products see Chapter 10.
15.2
Chemical safety assessment
No data available.
SECTION 16: Other information
Department issuing safety data sheet
UMCO Umwelt Consult GmbH
Georg-Wilhelm-Str. 183 , 21107 Hamburg, Germany
Tel.: +49 40 / 79 02 36 300 Fax: +49 40 / 79 02 36 357 e-mail: umco@umco.de
Page 8(9)
Page 91
EC safety data sheet
Trade name: Oil Pastels
Product no.: PHN-50 black
Replaced version: 1.0.0, issued: 12.06.2012
Region: GB
This information is based on our present state of knowledge and experience. The security data sheet describes products with a view to the security requirements. However, it should not constitute a guarantee for any specific product properties and shall not establish a legally valid relationship.
Alterations/supplements: Alterations to the previous edition are marked in the left-hand margin.
.
Page 9(9)
Page 92
EC safety data sheet
Trade name: Oil Pastels
Product no.: PHN-50 white
Replaced version: 1.0.0, issued: 12.06.2012
Region: GB
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1
Product identifier
Trade name
Oil Pastels
1.2
Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses of the substance or mixture
art supplies
pastel colour
Uses advised against
No data available.
1.3
Details of the supplier of the safety data sheet
Address
Pentel Bürobedarf-Handelsgesellschaft mbH
Lademannbogen 143
22339
Hamburg
GERMANY
Telephone no.
+49 (0) 40 / 53 80 91 - 0
Fax no.
+49 (0) 40 / 53 85 58 - 7
Information provided by / telephone
+49 (0) 40 / 53 80 91 - 0
Advice on Safety Data Sheet
sdb_info@umco.de
1.4
Emergency telephone number
For medical advice (in German and English): +49 (0)551 192 40 (Giftinformationszentrum Nord)
SECTION 2: Hazards identification
2.1
Classification of the substance or mixture
Classification information
This product does not meet the classification and labelling criteria given in the Regulation (EC) No 1272/2008 (CLP).
This product does not meet the classification and labelling criteria given in the Dangerous Preparations Directive (1999/45/EC; DPD)
2.2
Label elements
Not relevant
Labelling information
The data subject of this Material Safety Data sheet refer to the paint contained in this product.
2.3
Other hazards
No data available.
Page 1(9)
Page 93
EC safety data sheet
Trade name: Oil Pastels
Product no.: PHN-50 white
Replaced version: 1.0.0, issued: 12.06.2012
Region: GB
SECTION 3: Composition/information on ingredients
3.1
Substances
Not applicable. The product is not a substance.
3.2
Mixtures
Hazardous ingredients
No
Substance name
Additional information
CAS / EC / Index / REACH no
Classification 67/548/EEC
Classification (EC) 1272/2008 (CLP)
Concentration
%
1
titanium-dioxide
13463-67-7 236-675-5
-
-
- - >
1.00
- < 5.00
%-b.w.
Full Text for all R-phrases , H-phrases and EUH-phrases: pls. see section 16
SECTION 4: First aid measures
4.1
Description of first aid measures
General information
In case of persisting adverse effects, consult a physician.
After inhalation
Ensure supply of fresh air.
After skin contact
When in contact with the skin, clean with soap and water. Do NOT use solvents or thinners.
After eye contact
Separate eyelids, wash the eyes thoroughly with water (15 min.).
After ingestion
Call a doctor. Never give anything by mouth to an unconscious person. Do not induce vomiting.
4.2
Most important symptoms and effects, both acute and delayed
No data available.
4.3
Indication of any immediate medical attention and special treatment needed
No data available.
SECTION 5: Firefighting measures
5.1
Extinguishing media
Suitable extinguishing media
Product itself is non-combustible; adapt fire extinguishing measures to surrounding areas.
Unsuitable extinguishing media
No data available.
5.2
Special hazards arising from the substance or mixture
In the event of fire, the following can be released: Carbon dioxide (CO2); Carbon monoxide (CO)
5.3
Advice for firefighters
Use self-contained breathing apparatus. Wear protective clothing.
SECTION 6: Accidental release measures
6.1
Personal precautions, protective equipment and emergency procedures
For non-emergency personnel
Refer to protective measures listed in sections 7 and 8. Ensure adequate ventilation.
Page 2(9)
Page 94
EC safety data sheet
Trade name: Oil Pastels
Product no.: PHN-50 white
Replaced version: 1.0.0, issued: 12.06.2012
Region: GB
For emergency responders
No data available. Personal protective equipment (PPE) - see Section 8.
6.2
Environmental precautions
Do not discharge into the drains/surface waters/groundwater.
6.3
Methods and material for containment and cleaning up
Take up mechanically. Send in suitable containers for recovery or disposal.
6.4
Reference to other sections
No data available.
SECTION 7: Handling and storage
7.1
Precautions for safe handling
Advice on safe handling
Observe the usual precautions for handling chemicals. Provide good ventilation of working area (local exhaust ventilation, if necessary).
General protective and hygiene measures
Observe the usual precautions when handling chemicals. Keep away from foodstuffs and beverages. Do not eat, drink or smoke during work time. Clean skin thoroughly after work; apply skin cream.
7.2
Conditions for safe storage, including any incompatibilities
Technical measures and storage conditions
Keep container tightly closed and dry in a cool, well-ventilated place.
Requirements for storage rooms and vessels
Containers which are opened must be carefully closed and kept upright to prevent leakage. Always keep in containers of same material as the original one.
Advice on storage assembly
None known
7.3
Specific end use(s)
No data available.
SECTION 8: Exposure controls/personal protection
8.1
Control parameters
Occupational exposure limit values
No
Substance name
CAS no.
EC no.
1
titanium-dioxide
13463-67-7
236-675-5
List of approved workplace exposure limits (WELs) / EH40
Titanium dioxide
total inhalable dust
TWA
10
mg/m³
List of approved workplace exposure limits (WELs) / EH40
Titanium dioxide
respirable dust
TWA
4
mg/m³
true
8.2
Exposure controls
Appropriate engineering controls
No data available.
Personal protective equipment
Respiratory protection
If workplace exposure limits are exceeded, a respiration protection approved for this particular job must be worn. In case of dust, aerosol and mist formation, take appropriate measures for breathing protection in the event workplace threshold values are not specified.
Page 3(9)
Page 95
EC safety data sheet
Trade name: Oil Pastels
Product no.: PHN-50 white
Replaced version: 1.0.0, issued: 12.06.2012
Region: GB
Eye / face protection
Safety glasses (EN 166)
Hand protection
Sufficient protection is given wearing suitable protective gloves checked according to i.e. EN 374, in the event of risk of skin contact with the product . Before use, the protective gloves should be tested in any case for its specific work­station suitability (i.e. mechanical resistance, product compatibility and antistatic properties). Adhere to the manufacturer’s instructions and information relating to the use, storage, care and replacement of protective gloves. Protective gloves shall be replaced immediately when physically damaged or worn. Design operations thus to avoid permanent use of protective gloves.
Other
Normal chemical work clothing.
Environmental exposure controls
No data available.
SECTION 9: Physical and chemical properties
9.1
Information on basic physical and chemical properties
Form/Colour
liquid
according product name
270
U_9005
Odour
alkohol-like
180
Odour threshold
No data available
pH value
No data available
Boiling point / boiling range
No data available
Melting point / melting range
Value
69.82
°C
Method
ASTM D 3418
69.82
Page 4(9)
Page 96
EC safety data sheet
Trade name: Oil Pastels
Product no.: PHN-50 white
Replaced version: 1.0.0, issued: 12.06.2012
Region: GB
Decomposition point / decomposition range
No data available
Flash point
No data available
Auto-ignition temperature
No data available
Oxidising properties
No data available
Explosive properties
No data available
Flammability (solid, gas)
No data available
Lower flammability or explosive limits
No data available
Upper flammability or explosive limits
No data available
Vapour pressure
No data available
Vapour density
No data available
Evaporation rate
No data available
Relative density
No data available
Density
No data available
Solubility in water
No data available
Solubility(ies)
No data available
Partition coefficient: n-octanol/water
No data available
Viscosity
No data available
9.2
Other information
Other information
No data available.
SECTION 10: Stability and reactivity
10.1
Reactivity
No data available.
10.2
Chemical stability
No data available.
10.3
Possibility of hazardous reactions
No data available.
10.4
Conditions to avoid
Stable under recommended storage and handling conditions(See section 7).
Page 5(9)
Page 97
EC safety data sheet
Trade name: Oil Pastels
Product no.: PHN-50 white
Replaced version: 1.0.0, issued: 12.06.2012
Region: GB
10.5
Incompatible materials
None known.
10.6
Hazardous decomposition products
No hazardous decomposition products known.
SECTION 11: Toxicological information
11.1
Information on toxicological effects
Acute oral toxicity
No
Product Name
1
Oil Pastels
Remarks
No data available.
Acute dermal toxicity
No
Product Name
1
Oil Pastels
Remarks
No data available.
Acute inhalational toxicity
No
Product Name
1
Oil Pastels
Remarks
No data available.
Lk.7000882
Skin corrosion/irritation
No
Product Name
1
Oil Pastels
Remarks
No data available.
Serious eye damage/irritation
No
Product Name
1
Oil Pastels
Remarks
No data available.
Respiratory tract irritation
Remarks
No data available.
Respiratory or skin sensitisation
No data available
Germ cell mutagenicity
No data available
Reproduction toxicity
No data available
Carcinogenicity
No data available
STOT-single exposure
No data available
STOT-repeated exposure
No data available
Aspiration hazard
No data available
Page 6(9)
Page 98
EC safety data sheet
Trade name: Oil Pastels
Product no.: PHN-50 white
Replaced version: 1.0.0, issued: 12.06.2012
Region: GB
SECTION 12: Ecological information
12.1
Toxicity
Toxicity to fish (acute)
No
Product Name
1
Oil Pastels
Remarks
No data available.
Lk.2098
Toxicity to fish (chronic)
No data available
Toxicity to Daphnia (acute)
No
Product Name
1
Oil Pastels
Remarks
No data available.
Lk.2098
Toxicity to Daphnia (chronic)
No data available
Toxicity to algae (acute)
No
Product Name
1
Oil Pastels
Remarks
No data available.
Lk.2098
Toxicity to algae (chronic)
No data available
Bacteria toxicity
No
Product Name
1
Oil Pastels
Remarks
No data available.
Lk.2099
12.2
Persistence and degradability
Biodegradability
No
Product Name
1
Oil Pastels
Remarks
No data available.
Lk.2100
12.3
Bioaccumulative potential
No data available.
12.4
Mobility in soil
No data available.
12.5
Results of PBT and vPvB assessment
No data available.
12.6
Other adverse effects
No data available.
12.7
Other information
Other information
Do not discharge product unmonitored into the environment.
710
SECTION 13: Disposal considerations
13.1
Waste treatment methods
Product
Allocation of a waste code number, according to the European Waste Catalogue, should be carried out in agreement with the regional waste disposal company.
Page 7(9)
Page 99
EC safety data sheet
Trade name: Oil Pastels
Product no.: PHN-50 white
Replaced version: 1.0.0, issued: 12.06.2012
Region: GB
Packaging
Residuals must be removed from packaging and when emptied completely disposed of in accordance with the regulations for waste removal. Incompletely emptied packaging must be disposed of in the form of disposal specified by the regional disposer.
SECTION 14: Transport information
14.1
Transport ADR/RID/ADN
The product is not subject to ADR/RID/ADN regulations.
14.2
Transport IMDG
The product is not subject to IMDG regulations.
14.3
Transport ICAO-TI / IATA
The product is not subject to ICAO-TI / IATA regulations.
14.4
Other information
No data available.
14.5
Environmental hazards
Information on environmental hazards, if relevant, please see 14.1 - 14.3.
14.6
Special precautions for user
No data available.
14.7
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not relevant
SECTION 15: Regulatory information
15.1
Safety, health and environmental regulations/legislation specific for the substance or mixture
EU regulations
Regulation (EC) No 1907/2006 (REACH) Annex XIV (List of substances subject to authorisation)
According to the data available and/or specifications supplied by upstream suppliers, this product does not contain any substances considered as substances requiring authorisation as listed on Annex XIV of the REACH regulation (EC) 1907/2006.
REACH candidate list of substances of very high concern (SVHC) for authorisation
According to available data and the information provided by preliminary suppliers, the product does not contain substances that are considered substances meeting the criteria for inclusion in annex XIV (List of Substances Subject to Authorisation) as laid down in Article 57 and article 59 of REACH (EC) 1907/2006.
Regulation (EC) No 1907/2006 (REACH) Annex XVII: RESTRICTIONS ON THE MANUFACTURE, PLACING ON THE MARKET AND USE OF CERTAIN DANGEROUS SUBSTANCES, PREPARATIONS AND ARTICLES
According to the data available and/or specifications supplied by upstream suppliers, this product does not contain any substances requiring authorisation as listed on Annex XIV of the REACH regulation (EC) 1907/2006.
Council Directive 96/82/EC on the control of major-accident hazards involving dangerous substances
Remarks
Annex I, part 1 + 2: not mentioned. With regard to possibly appropriate decomposition products see Chapter 10.
15.2
Chemical safety assessment
No data available.
SECTION 16: Other information
Department issuing safety data sheet
UMCO Umwelt Consult GmbH
Georg-Wilhelm-Str. 183 , 21107 Hamburg, Germany
Tel.: +49 40 / 79 02 36 300 Fax: +49 40 / 79 02 36 357 e-mail: umco@umco.de
Page 8(9)
Page 100
EC safety data sheet
Trade name: Oil Pastels
Product no.: PHN-50 white
Replaced version: 1.0.0, issued: 12.06.2012
Region: GB
This information is based on our present state of knowledge and experience. The security data sheet describes products with a view to the security requirements. However, it should not constitute a guarantee for any specific product properties and shall not establish a legally valid relationship.
Alterations/supplements: Alterations to the previous edition are marked in the left-hand margin.
.
Page 9(9)
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