
WDR1-C, PENTEL CO., LTD., 1, 2012/11/30, 1/5
Preparation Date 2012/11/30
Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product Name
Product Code
Company Name
Address
Company Contact
Phone Number
Recommended Use
and Restriction on
Use
Section 2 - HAZARDS IDENTIFICATION
GHS Classification
Health Hazards
GHS Label Elements
Symbols
Signal Word
Hazard Statements
Prevention
Precautionary
Statements
7-2,KOAMICHO,NIHONBASHI,CHUO-KU,TOKYO
QUALITY ASSURANCE DEPARTMENT I
048-928-6668
048-928-9190
Specific target organ toxicity(single exposure)
Category 2(respiratory
apparatus,heart,kidney,central nervous system)
Specific target organ toxicity(repeated exposure)
Category 2(central nervous system,respiratory
apparatus,heart)
Acute hazards to the aquatic environment
Category 3
Chronic hazards to the aquatic environment
Category 3
Other hazards than mentioned above are Not
applicable or No data available.
H371 May cause damage to respiratory
apparatus,heart,kidney,central nervous system.
H373 May cause damage to respiratory
apparatus,heart,central nervous system through
prolonged or repeated exposure.
H402 Harmful to aquatic life
H412 Harmful to aquatic life with long lasting
effects
Do not breathe mist, vapours and spray.(P260)
Wash hands thoroughly after handling.(P264)
Do not eat, drink or smoke when using this
product.(P270)
Pentel Rolling Writer Roller Ball Capped Pen
R100-A Black, R100-B Red, R100-C Blue, R100-D Green, R100-V Violet Pens

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Response
Precautionary
Statements
Storage
Precautionary
Statements
Disposal
Precautionary
Statements
Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS
Distinction of Substance
or Mixture
(2)-230 Existing 107-21-1
o-Phenylenediamine 0.4% C6H8N2 (3)-185 Existing 95-54-5
Impurities and/or Stabilizing Additives which Contribute to the Classification
No information available
Section 4 - FIRST AID MEASURES
Inhalation
Skin Contact
Eye Contact
Ingestion
Section 5 - FIRE FIGHTING MEASURES
Extinguishing Media
Section 6 - ACCIDENTAL RELEASE MEASURES
Personal Precautions,
Protective Equipment and
Emergency Procedures
Environmental
Precautions
Decontamination/Absorpti
on/Sweeping/Vacuming/
Neutralization
Avoid release to the environment.(P273)
IF exposed or if you feel unwell: Call a
doctor.(P309+P311)
Get medical advice and attention if you feel
unwell.(P314)
Dispose of contents and container in accordance
with local, regional and national regulations (to be
specified).(P501)
If breathing is difficult, move affected person to
the open air. Keep him or her at rest to allow
easier breathing.
Get medical advice and attention if you feel unwell.
Wash with soap and plenty of water.
Chemical Name or
Generic Name
Concentration or Its
Ranges
Formula
ENCS No./ISHL No.
If skin irritation or rash occurs: Get medical
advice and attention.
Wash eyes carefully for several minutes with
water. Take off contact lenses if easily removed,
and continue to wash eyes afterwards.
When the ocular stimulation lasts, Seek medical
treatment and advice.
Rinse a mouth. Don't make vomit by force.
Get medical advice and attention if you feel unwell.
Carbon dioxide, dry chemicals, water sprinkling,
and general foam extinguishing agents
No information available
Pay attention not to cause the influence on the
environment by discharging into rivers.
This product is water pollutant. Prevent soil
contamination, or the product from flowing into the
drain systems.
Collect the material into a disposal container by
sucking up or sweeping up.

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Methods and Equipment
for Containment and
Cleaning up
Prevention Measures for
Secondary Accidents
Section 7 - HANDLING AND STORAGE
Handling Technical Measures
Local and General
Ventilation
Precautions for Safe
Handling
Prevents Handling of
Imcompatible
Substances or
Mixtures
Storage Precautionary
Statements
Imcompatible
Substances or
Mixtures
Material Used in
Packaging/Container
s
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
Engineering Controls
Personal Protective
Equipment
Hand Protection
Eye Protection
Specific Hygine Measures
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
Appearance Physical State
Colour
Odour
pH
Initial Boiling Point and
Boiling Ranges
Absorb spills with inert materials (such as dry sand
or soil) and collect them into chemical-waste
disposal container.
Cleansing the contaminated area thoroughly with
water after removal.
Prevent flowing into drain, sewage, basement, and
closed area.
Remove thoroughly since the smooth and slippery
surface will be formed on the floor.
Provide ventilation system and Use necessary
personal protective equipment as described in "8.
EXPOSURE CONTROLS AND PERSONAL
Provide local ventilations and a full ventilation
system as described in "8. EXPOSURE
CONTROLS AND PERSONAL PROTECTION."
Avoid the contact with eyes.
Wash hands thoroughly after handling.
Avoid high temperature and direct sunlight.
Refer to "10. STABILITY AND REACTIVITY"
The storage facility should be privided with
necessary lighting, lighting equipment, and
ventilator to store and handle dangerous goods.
Refer to "10. STABILITY AND REACTIVITY"
Have containers keep away from direct sunlight
and heat.
Packaging materials and containers are not
legislated, but use sturdy and closed-type
containers.
A general proper ventilation is enough to control
concentration in air.
Use a personal protective apparatus for
respiratory organs whenever necessary.
Use necessary personal protective gloves.
Use an adequate personal eye protector.
Use the personal protective clothing and full face
mask whenever necessary.
Wash hands thoroughly after handling.

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Section 10 - STABILITY AND REACTIVITY
Stability
Possibility of Hazardous
Reaction
Hazardous Decomposition
Products
Section 11 - TOXICOLOGICAL INFORMATION
Acute Toxicity
Section 12 - ECOLOGICAL INFORMATION
Ecotoxicity
Section 13 - DISPOSAL CONSIDERATIONS
Residual Waste
Contaminated Container
and Packaging
Section 14 - TRANSPORT INFORMATION
International Regulations
Regulatory
Information by Sea
Regulatory
Information by Air
UN No.
Regulations in Japan
Regulatory
Information by Road
or Rail
Regulatory
Information by Sea
Regulatory
Information by Air
UN No.
Section 15 - REGULATORY INFORMATION
Section 16 - OTHER INFORMATION
Information Contact
The material is stable under storage and handling
conditions comprised with the regulations.
No data available
No data available
No data available
No information available
No information available
No information available
For disposal, conform with the standards provided
by related laws and local public bodies.
Commission the authorized waste disposal
company, or a local public body who conducts the
disposal, to dispose of the material.
Recycle containers after cleansing, or carry out
the disposal under the related laws and regulations
and the standards of the local governments.
In case of disposal of empty containers, remove
the content thoroughly.
Not applicable
Not applicable
Not applicable
Not applicable
Not applicable
Not applicable
Not applicable
Regulatory information with regard to this product in your country or in your region should be
examined by your own responsibility.
Not applicable
Not applicable

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This information is furnished without warranty
express or implied.
This information is believed to be accurate to the
best knowledge of PENTEL Co., Ltd. but not
assumes leagal responsibility for use of or reliance
upon this information.